CN103087796A - Process and system for vibration hot-pressing dehydration quality improvement of brown coal - Google Patents
Process and system for vibration hot-pressing dehydration quality improvement of brown coal Download PDFInfo
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- CN103087796A CN103087796A CN2013100483498A CN201310048349A CN103087796A CN 103087796 A CN103087796 A CN 103087796A CN 2013100483498 A CN2013100483498 A CN 2013100483498A CN 201310048349 A CN201310048349 A CN 201310048349A CN 103087796 A CN103087796 A CN 103087796A
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- 230000018044 dehydration Effects 0.000 title claims abstract description 58
- 238000006297 dehydration reaction Methods 0.000 title claims abstract description 58
- 238000007731 hot pressing Methods 0.000 title claims abstract description 46
- 239000003077 lignite Substances 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 35
- 230000008569 process Effects 0.000 title claims abstract description 33
- 239000003245 coal Substances 0.000 claims abstract description 64
- 238000001035 drying Methods 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000746 purification Methods 0.000 claims abstract description 9
- 239000002351 wastewater Substances 0.000 claims abstract description 9
- 238000007599 discharging Methods 0.000 claims abstract description 5
- 238000009826 distribution Methods 0.000 claims description 15
- 238000000465 moulding Methods 0.000 claims description 13
- 238000009434 installation Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 6
- 239000002817 coal dust Substances 0.000 claims description 5
- 230000003068 static effect Effects 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 230000002269 spontaneous effect Effects 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000001704 evaporation Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 230000008859 change Effects 0.000 description 4
- 239000003818 cinder Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000002802 bituminous coal Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 241000272534 Struthio camelus Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004021 humic acid Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/447—Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Abstract
The invention relates to a process and system for vibration hot-pressing dehydration quality improvement of brown coal, belonging to processes and systems for processing and cleaning coal. According to the system, a discharge port of a run coal bin is connected with a feed port of a fan milled powder pre-drying device, a discharge port of the fan milled powder pre-drying device is connected with a feed port of a vibration hot-pressing dehydration quality improvement device through a powdered coal bin and a distributing device, a steam generator is connected with a steam inlet of the vibration hot-pressing dehydration quality improvement device through a steam switching valve, one end of a water outlet of the vibration hot-pressing dehydration quality improvement device is connected with the inlet of the vibration hot-pressing dehydration quality improvement device through a three-way valve, and the other end of the water outlet of the vibration hot-pressing dehydration quality improvement device is used for discharging water through a waste water purification system; and according to the process, the fan milled powdered coal is conveyed into the vibration hot-pressing dehydration quality improvement device and then preheated and hermetically sealed, steam is introduced into the device and is stopped when the coal is heated to the process temperature, and then the coal is dehydrated and formed. The brown coal can be efficiently dehydrated and formed in a shorter acting time under a comparatively mild process condition, and relapsing and spontaneous combustion are prevented, so that the brown coal is convenient to store and transport.
Description
Technical field
The present invention relates to a kind of Coal dressing and cleaning technology and system, particularly a kind of brown coal vibration hot pressing dehydration process for upgrading and system.
Technical background
Energy and environment are important guarantees of national economy and social sustainable development.The year two thousand twenty, coal will be in 60% left and right in national energy consists of.The year two thousand fifty, the ratio of coal in China's primary energy source will account for 50% left and right.In the present explored brown coal retained reserve of China, the Northeast is maximum with the Inner Mongol, accounts for 3/4 of national brown coal retained reserve; Account for 1/5 of the whole nation take Yunnan Province as the brown coal reserves of main southwest.Brown coal are the minimum coals of degree of coalification, its principal feature is that moisture content is up to 30% ~ 50%, oxygen level is up to 15% ~ 30%, high-volatile content approximately 50%, the low 14MJ/kg that is about of calorific value, the humic acids that low ash smelting point, porosity be large, contain different quantities, chemical reactivity is strong, the characteristics such as poor heat stability have limited effective utilization of brown coal.Result of study shows, brown coal are after deliming dehydration upgrading processing, and its composition and character level off to bituminous coal, will more be conducive to utilize, transportation and storing, and has important environmental economy to be worth.
Current Domestic has been developed multiple dehydration process for upgrading abroad, mainly is divided into dehydration by evaporation and non-evaporating dehydrolysis two classes.Present dehydration by evaporation technology general using stack gas or other waste heat gas are drying medium, directly contact with brown coal its heating is made the moisture in coal evaporation drying, bring thus brown coal easily to pulverize, and product lump coal is lower; Because moisture removes with gaseous form, need to absorb the latent heat of vaporization, energy consumption is high; Because carrying out under atmospheric low-temperature, structure that can not permanent change coal also can absorb water rapidly in case be in wet environment, is unfavorable for depositing, long-distance transportation, later-stage utilization and processing.The non-evaporating dehydrolysis technology removes moisture in brown coal with liquid form, change the physics and chemistry structure of brown coal by high temperature and high pressure steam (or deep fat), makes it to be transformed into the dehydration method for upgrading of similar bituminous coal, has wide development potentiality.
At present the non-evaporating dehydrolysis technology comparative maturity of exploitation is that the hot pressing dewatering process (MTE) of propositions such as the Dortmund, Germany Strauss of university is comparatively ripe non-evaporating dehydrolysis technology, but still exist need to be higher temperature and pressure; Hot pressing dehydration is longer required action time, and production efficiency is low; Pressure is uneven in the coal charge axial distribution, the shortcomings such as the easy generation in the coal cinder middle part transverse breakage of moulding.On the whole, be subjected to the impact of condition, technology, material and economic dispatch factors, the brown coal dewatering process of efficient energy-saving also need further develop.
Summary of the invention
The objective of the invention is to provide a kind of brown coal vibration hot pressing dehydration process for upgrading and system, namely in brown coal upgrading dehydration, brown coal are carried out moulding, solve the problem that easily relapses after existing hot pressing dewatering pressure skewness and brown coal upgrading dehydration.
The object of the present invention is achieved like this: this brown coal vibration hot pressing dehydration upgrading comprises technique and device;
The process for upgrading step is as follows:
A) brown coal in run coal bin are crushed to through fan mill powder process pre-drying device and deliver to Pulverized Coal Bin below 3mm, through distribution device, brown coal are sent into vibration hot pressing dehydration device for improving quality, and are airtight after preheating;
B) pass into steam in vibration hot pressing dehydration device for improving quality, the heating brown coal are to technological temperature, and temperature is 150 ~ 220 ℃, and pressure is 5~12MPa; Steam and coal charge Direct Contact Heating that steam-generating installation produces, steam come from the steam of boiler generation, brown coal are vibrated hot pressing dehydration, moulding, the moulding static pressure is 5~12MPa; Vibration exciting force size, frequency can be regulated;
C) demoulding after dehydration, moulding, after moulded coal is cooling, send into finished bin, and the coal dust that produces when cooling is sent distribution device back to;
D) after the coal charge dehydration forming as the upgraded brown coal utilization, the moisture that removes utilizes preheating aftertreatment discharging through the preheating coal charge.
Device comprises: run coal bin, fan mill powder process pre-drying device, Pulverized Coal Bin, distribution device, vibration hot pressing dehydration device for improving quality, T-valve, waste water purification system, steam cock valve and steam-generating installation; The discharge port of run coal bin is connected with the feeding mouth of fan mill powder process pre-drying device, the discharge port of fan mill powder process pre-drying device is connected with the feeding mouth of distribution device with vibration hot pressing dehydration device for improving quality by Pulverized Coal Bin, the steam-in that steam-generating installation passes through steam cock valve and vibration hot pressing dehydration device for improving quality is connected, the water outlet of vibration hot pressing dehydration device for improving quality is by T-valve, and an end is connected with the entrance of vibration hot pressing dehydration device for improving quality; One end is discharged by waste water purification system.
Beneficial effect, owing to having adopted such scheme, in vibrating machine hot pressing dewatering process, under the synergy of vibration-static pressure-heat, brown coal can be under comparatively gentle processing condition, efficiently remove moisture in shorter action time, and form the coal cinder with some strength, and can effectively prevent from relapsing and spontaneous combustion, be convenient to store and transportation, and this process system is comparatively simple, processing condition easily realize, production process safety has good industrial applications prospect.
1. employing Vibrating Compacting System, coal charge is subject to the synergy of static pressure and exciting force, can effectively improve the transmission of pressure in coal charge, the coal charge pressure be distributed vertically more even, the pressure of avoiding the coal cinder after moulding to be subject to because of the middle part is little cause intensity low, transverse breakage occurs;
2. the effect of exciting force can be accelerated dehydration, the moulding of brown coal, shortens extrusion time, enhances productivity;
3. adopt saturation steam direct heating coal charge, saturation steam undergoes phase transition, discharges latent heat strengthens the heat exchange between itself and coal charge, and heat exchange efficiency is high, shorten heat-up time, and saturated steam obtains easily in industrial production;
4. coal is heated, and the physicals of water can change in rear ature of coal surface organo-functional group character and coal, and it is more hydrophobic that coal surface becomes, and the viscosity of water, density, surface tension reduce, and helps removing of water in coal;
5. under action of mechanical pressure, by means of extruding and pore volume reduce moisture is removed, the melting of wax and bituminous matter material also is beneficial to the carrying out of extruding;
6. the change of functional group's character and pore structure makes the coal cinder after dehydration forming effectively prevent from relapsing and spontaneous combustion;
7. moisture removes with liquid form, need not to absorb the latent heat of vaporization, and thermo-efficiency is high;
8. processing condition are gentle, and dewatering efficiency is high: 150 ~ 220 ℃ of temperature, and static pressure 5~12MPa, the water content of brown coal can be reduced to 10%.Solve the problem that easily relapses after existing hot pressing dewatering pressure skewness and brown coal upgrading dehydration, reached purpose of the present invention.
Description of drawings
Fig. 1 is equipment configuration system diagram of the present invention.
In figure: 1, run coal bin; 2, fan mill powder process pre-drying device; 3, Pulverized Coal Bin; 4, distribution device; 5, vibration hot pressing dehydration device for improving quality; 6, T-valve; 7, waste water purification system; 8, steam cock valve; 9, steam-generating installation.
Embodiment
1 couple of the present invention is described in further detail below in conjunction with accompanying drawing, but not as a limitation of the invention.
Embodiment 1: the process for upgrading step is as follows:
A) brown coal in run coal bin 1 are crushed to through fan mill powder process pre-drying device 2 and deliver to Pulverized Coal Bin 3 below 3mm, through distribution device 4, brown coal are sent into vibration hot pressing dehydration device for improving quality 5, and are airtight after preheating;
B) pass into steam in vibration hot pressing dehydration device for improving quality 5, the heating brown coal are to technological temperature, and temperature is 150 ~ 220 ℃, and pressure is 5~12MPa; Steam and coal charge Direct Contact Heating that steam-generating installation 8 produces, steam come from the steam of boiler generation, brown coal are vibrated hot pressing dehydration, moulding, the moulding static pressure is 5~12MPa; Vibration exciting force size, frequency can be regulated;
C) demoulding after dehydration, moulding, after moulded coal is cooling, send into finished bin, and the coal dust that produces when cooling is sent distribution device 4 back to;
D) after the coal charge dehydration forming as the upgraded brown coal utilization, the moisture that removes utilizes preheating aftertreatment discharging through the preheating coal charge.
Device comprises: run coal bin 1, fan mill powder process pre-drying device 2, Pulverized Coal Bin 3, distribution device 4, vibration hot pressing dehydration device for improving quality 5, T-valve 6, waste water purification system 7, steam cock valve 8 and steam-generating installation 9; The discharge port of run coal bin 1 is connected with the feeding mouth of fan mill powder process pre-drying device 2, the discharge port of fan mill powder process pre-drying device 2 is connected with distribution device by Pulverized Coal Bin 3 and is connected with the dewater feeding mouth of device for improving quality 5 of vibration hot pressing, the steam-in that steam-generating installation 9 passes through steam cock valve 8 and vibration hot pressing dehydration device for improving quality 5 is connected, the water outlet of vibration hot pressing dehydration device for improving quality 5 is connected by the entrance of T-valve 6, one ends with vibration hot pressing dehydration device for improving quality 5; One end is discharged by waste water purification system 7.
brown coal in run coal bin 1 are transported in fan mill pre-drying device 2 are crushed to below 3mm, deliver in Pulverized Coal Bin 3, it is loaded into coal dust in vibration hot pressing dehydration device for improving quality 5 by distribution device 4, use the water preheat coal dust that a flow process coal charge removes, airtight material cylinder after preheating, open steam cock valve 8, with steam heating brown coal steam off switch-valve 8 to the preset temperature, vibrate subsequently hot pressing dehydration upgrading, after the coal charge dehydration forming as the upgraded brown coal utilization, the moisture that removes has higher temperature, be used for preheating next batch coal charge, enter waste water purification system 7 when in the moisture that removes, impurity is too much, discharging after purifying.
Claims (2)
1. brown coal vibrate hot pressing dehydration process for upgrading, and it is characterized in that: the process for upgrading step is as follows:
A) brown coal in run coal bin are crushed to through fan mill powder process pre-drying device and deliver to Pulverized Coal Bin below 3mm, through distribution device, brown coal are sent into vibration hot pressing dehydration device for improving quality, and are airtight after preheating;
B) pass into steam in vibration hot pressing dehydration device for improving quality, the heating brown coal are to technological temperature, and temperature is 150 ~ 220 ℃, and pressure is 5 ~ 12MPa; Steam and coal charge Direct Contact Heating that steam-generating installation produces, steam come from the steam of boiler generation, brown coal are vibrated hot pressing dehydration, moulding, the moulding static pressure is 5 ~ 12MPa; Vibration exciting force size, frequency can be regulated;
C) demoulding after dehydration, moulding, after moulded coal is cooling, send into finished bin, and the coal dust that produces when cooling is sent distribution device back to;
D) after the coal charge dehydration forming as the upgraded brown coal utilization, the moisture that removes utilizes preheating aftertreatment discharging through the preheating coal charge.
2. implement the system that brown coal vibrate hot pressing dehydration process for upgrading for one kind, it is characterized in that: device comprises: run coal bin, fan mill powder process pre-drying device, Pulverized Coal Bin, distribution device, vibration hot pressing dehydration device for improving quality, T-valve, waste water purification system, steam cock valve and steam-generating installation; The discharge port of run coal bin is connected with the feeding mouth of fan mill powder process pre-drying device, the discharge port of fan mill powder process pre-drying device is connected with the feeding mouth of distribution device with vibration hot pressing dehydration device for improving quality by Pulverized Coal Bin, the steam-in that steam-generating installation passes through steam cock valve and vibration hot pressing dehydration device for improving quality is connected, the water outlet of vibration hot pressing dehydration device for improving quality is by T-valve, and an end is connected with the entrance of vibration hot pressing dehydration device for improving quality; One end is discharged by waste water purification system.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310048349.8A CN103087796B (en) | 2013-02-07 | 2013-02-07 | Process and system for vibration hot-pressing dehydration and quality improvement of brown coal |
AU2013377629A AU2013377629B2 (en) | 2013-02-07 | 2013-04-19 | Process and system for upgrading lignite by vibration hot-pressing dehydration |
PCT/CN2013/074458 WO2014121558A1 (en) | 2013-02-07 | 2013-04-19 | Process and system for upgrading lignite by vibration hot-pressing dehydration |
Applications Claiming Priority (1)
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CN201310048349.8A CN103087796B (en) | 2013-02-07 | 2013-02-07 | Process and system for vibration hot-pressing dehydration and quality improvement of brown coal |
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CN103087796A true CN103087796A (en) | 2013-05-08 |
CN103087796B CN103087796B (en) | 2014-04-16 |
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CN201310048349.8A Expired - Fee Related CN103087796B (en) | 2013-02-07 | 2013-02-07 | Process and system for vibration hot-pressing dehydration and quality improvement of brown coal |
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CN (1) | CN103087796B (en) |
AU (1) | AU2013377629B2 (en) |
WO (1) | WO2014121558A1 (en) |
Cited By (5)
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WO2014121558A1 (en) * | 2013-02-07 | 2014-08-14 | 中国矿业大学 | Process and system for upgrading lignite by vibration hot-pressing dehydration |
CN104388143A (en) * | 2014-11-14 | 2015-03-04 | 中国矿业大学(北京) | Two-stage continuous lignite upgrading system |
CN111392811A (en) * | 2020-03-04 | 2020-07-10 | 中国矿业大学 | Multi-energy-field synergistic efficient dehydration method for coal gasification fine slag black water of entrained flow bed |
CN113234514A (en) * | 2021-05-29 | 2021-08-10 | 中国矿业大学 | Dewatering and quality improving system for high-water-content materials |
CN113877477A (en) * | 2021-10-26 | 2022-01-04 | 中国矿业大学 | Coal slime granulating and drying equipment and working method |
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CN111534351B (en) * | 2020-05-14 | 2021-09-03 | 太原理工大学 | Device for boiling coal by using waste oil and fat and use method thereof |
CN113234511B (en) * | 2021-06-25 | 2022-04-15 | 中国矿业大学 | Lignite modification method and system for treating heavy metal wastewater |
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- 2013-02-07 CN CN201310048349.8A patent/CN103087796B/en not_active Expired - Fee Related
- 2013-04-19 WO PCT/CN2013/074458 patent/WO2014121558A1/en active Application Filing
- 2013-04-19 AU AU2013377629A patent/AU2013377629B2/en not_active Ceased
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WO2014121558A1 (en) | 2014-08-14 |
CN103087796B (en) | 2014-04-16 |
AU2013377629A1 (en) | 2015-08-27 |
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