CN1030680C - Composition for attracting flies - Google Patents
Composition for attracting flies Download PDFInfo
- Publication number
- CN1030680C CN1030680C CN 86108161 CN86108161A CN1030680C CN 1030680 C CN1030680 C CN 1030680C CN 86108161 CN86108161 CN 86108161 CN 86108161 A CN86108161 A CN 86108161A CN 1030680 C CN1030680 C CN 1030680C
- Authority
- CN
- China
- Prior art keywords
- composition
- cis
- fly
- red
- tricosene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a compound for attracting flies, which is characterized in that a. the compound used for attracting flies comprises at least one sexual pheromone, the pheromone is selected from a base cluster, and the base cluster comprises 9-tricosene, cis-9-tricosene, 10 methyl-9-tricosene, cis-2-methyl-8-docosenoic, cis-9-docosenoic, cis-10-docosenoic and cis-10-tricosene; b. the compound contains yellow red, and the color amplitude is between 2.5R to 2.5YR; c. the compound is a graininess preparation, and average graininess specification is between 0.5 to 5 millimeters.
Description
The present invention relates to trap the composition of the attraction fly of killing fly.The invention still further relates to and attract to kill the attraction insecticides of fly and by attracting fly and making their ingested composition kill the poison bait compositions of luring of fly.
The clear 56-115706 of uncensored Japanese patent gazette is open, and fly can be attracted by yellow substance, and the color of this material is according to being 5YR to 7.5GY in the standard described in the JISZ8721.Yet the yellow substance of this color is not enough to the attraction effect of fly, and fully can not be satisfactory.
On the other hand, well-known, the 9-tricosene, cis-9-tricosene, waiting all has the effect that attracts fly as the sex pheromone of fly.Yet the attraction effect of these sex pheromones also is not enough, thus combine these as the fly controlling agent of the pheromones of attractant be still aspect the control efficiency very low.
The invention provides a kind of composition that attracts fly, said composition is higher than described prior art far away to the attraction effect of fly.
The present invention further provides a kind of attraction-insecticides, said composition can attract fly and control fly very effectively.
The present invention further provides a kind of luring-poison bait compositions, be used for attracting effectively fly and make them attracted to this poison bait very doggedly, thereby its insecticide component can be taken in the fly body in a large number, to control fly fully.
Can be clear that these purposes of the present invention and other purpose from following description.
The composition of attraction fly of the present invention is characterised in that:
A) as a kind of compound that attracts fly, contain at least a sex pheromone, this pheromones is selected from the 9-tricosene, cis-9-tricosene, 10-methyl-9-tricosene, cis-2-methyl-8-two dodecylenes, cis-9-two dodecylenes, cis-8-two dodecylenes and cis-10-tricosene
B) color is the yellowish red color of 2.5R to 2.5YR,
C) be particle mean size and be about 0.5 to about 5mm granular preparation.
The compound of the attraction fly that the present invention is used is considered to the sex pheromone of a kind of fly, it has the effect that attracts fly, but effect is lower, yet, we have been found that through research color when the preparation that contains this compound is 2.5R to a 2.5YR yellowish red color and when being the particle form of particle mean size in about particular range of 0.5 to about 5mm, said preparation has surprising high attraction effect to fly, and this is beat all.Have only when combine the as mentioned above effect of the attraction fly that just can reach high of this attraction compound, color and dosage form.If use other attraction compound, if perhaps the color of preparation exceeds 2.5R to 2.5YR particular range, if perhaps preparation is not a graininess, though perhaps be graininess, its granularity exceeds above-mentioned scope, then can not reach this significant attraction effect.
Being used for attraction compound of the present invention is a kind of sex pheromone, and it is selected from the 9-tricosene, cis-9-tricosene, 10-methyl-9-tricosene, cis-2-methyl-8-two dodecylenes, cis-9-two dodecylenes, cis-8-two dodecylenes and cis-10-tricosene.Wherein, cis-9-tricosene is particularly preferred.According to the present invention, use at least a of these compounds.Though attract the concentration of compound in said preparation in very wide scope, to change.But this concentration normally about 0.01 is to about 15% (weight), preferably about 0.02 to 4% (weight).
Essential is to be that the color of the composition of attraction fly of the present invention is the yellowish red color (according to the described standard of JISZ8721) of 2.5R to 2.5YR.If color is approximate red less than 2.5R or approximate yellow but, then can not reach the effect that desired height attracts fly less than 2.5YR.More preferably, this color is in the scope of 7.5R to 2.5YR.The brightness that also requires to have the preparation of the present invention of above-mentioned specific color is at least 4, more preferably is at least 5, and degree of saturation (according to JISZ8721) is at least 6, more preferably is at least 7.
The pigment that is used to make composition of the present invention have this color not only comprises common pigments (coloring material), also comprises fluorescence or luminescent substance.The example of suitable pigment is as follows:
No. 2 red (amaranth, acid is red 27,1-(4-sulfo group-1-naphthyl azo)-beta naphthal-3,6-sodium disulfonate)
No. 3 red (erythrosine, acid is red 51, the adjacent carboxyl phenyl of 9--6-hydroxyl-2,4,5, the different xanthene ketone of the 7-tetraiodo-3-disodium)
No. 102 red (new kermes, acid is red 18,1-(4-sulfone-1-naphthyl azo)-beta naphthal-6,8-disulfonic acid trisodium)
104-(1) number red (phloxin B.Acid is red 92,9-(3,4,5,6-tetrachloro-adjacent carboxyl phenyl)-6-hydroxyl-2,4,5, the different xanthene ketone of 7-tetrabromo-3-disodium)
105-(1) number red (rose agar, acid is red 94,9-(3,4,5,6-tetrachloro-adjacent carboxyl phenyl)-6-hydroxyl-2,4,5, the different xanthene ketone of the 7-tetraiodo-3-disodium)
No. 106 red (acid is red, and acid is red 52,9-(4 '-sulfo group-2 '-the sulfonium phenyl)-disodium of 6-lignocaine-3-(N, N-diethyl imino group)-different xanthene ketone of 3-)
No. 4 Huangs (tartrazines, acid is yellow 23, and 3-carboxyl-5-hydroxyl-1-is right-and sulfo group phenyl-4-is right-sulfo group phenylazo pyrazoles trisodium)
No. 5 Huangs (sunset yellow FCF, acid is yellow 3, and 1-is right-sulfo group phenylazo-beta naphthal-6-disodium sulfonate)
No. 201 red (lithol rubin B, paratonere 57-1,4-(neighbour-sulfo group-right-tolyl azo)-3-hydroxyl-2-naphthoic acid list sodium)
No. 202 red (lithol rubin B CA, paratonere 57-1,4-(neighbour-sulfo group-right-tolyl azo)-3-hydroxyl-2-naphthoic acid calcium
No. 203 red (the red C in lake, paratonere 533 (sodium) 1-(4-chloro-neighbour-sulfo group-5-tolyl azo)-beta naphthal list sodium)
No. 204 red (the red CBA in lake, paratonere 53 (barium), 1-(4-chloro-neighbour-sulfo group-5-tolyl azo)-beta naphthal barium)
No. 205 red (lithol rubin, pigment red 49 (sodium), 2-(2-hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd list sodium
No. 206 red (lithol rubin CA, pigment red 49,2-(2-hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd calcium)
No. 207 red (lithol rubin B A, pigment red 49 (barium), 2-(2-hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd barium)
No. 208 red (lithol rubin SR, pigment red 49 (strontium), 2-(2-hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd strontium)
No. 213 red (rhodamine B, alkaline purple 10, the different ton-3-ethyl chloride of 9-neighbour-carboxyl phenyl-6 lignocaines-3-ethyl imino group-3-)
No. 214 red (rhodamine B acetate, alkaline purple 10, the 9-neighbour-carboxyl phenyl-6-lignocaine-different ton-3-ethyl of 3-ethyl imino group-3-acetate)
No. 215 red (rhodamine B stearate, solvent red 49, the 9-neighbour-carboxyl phenyl-6-lignocaine-different ton-3-ethyl of 3--ethyl imino group-3-acetate)
No. 218 red (tetrachloro-tetrabromfluorescein, solvent red 92,2,4,5,7-tetrabromo-12,13,14,15-tetrachloro-3,6-fluorandiol)
No. 219 red (the red R in gorgeous lake, paratonere 64,3-hydroxy-4-phenyl azo-2-naphthoic acid calcium)
No. 220 red (dark maroon, paratonere 63 (calcium), 4-(1-sulfo group-2-naphthyl azo)-3-hydroxyl-2-naphthoic acid calcium)
No. 221 red (toluidine red, pigment red 3,1-(neighbour-nitro-right-tolyl azo)-beta naphthal)
No. 223 red (eosin, solvent red 43,2,4,5,7-tetrabromo-3,6-fluorandiol)
No. 225 red (1-is right for soudan III, solvent red 23-phenylazo-phenylazo-beta naphthal)
No. 226 red (the pink CN of helindone, red 1,5,5 '-two chloro-3,3 of urn '-the dimethyl thioindigo)
No. 227 red (acidproof magenta, acid red 33,8-amino-2-phenylazo-1-naphthols-3,6-disulfonic acid disodium)
No. 228 red (the laminated plastic colour is red, pigment red 4,1-(neighbour-chloro-right-nitrobenzophenone azo)-beta naphthal)
230-(1) number red (eosin W or W S S, acid is red 87,9-neighbour-carboxyl phenyl-6-hydroxyl-2,4,5, the different xanthene ketone-disodium of 7-tetrabromo-3-)
230-(2) number red (eosin W or W S SK, acid is red 87,9-neighbour-carboxyl phenyl-6 hydroxyl-2,4,5, the different xanthene ketone of 7-tetrabromo-3-dipotassium)
No. 231 red (Japan Red 231, acid is red 92,9-(3,4,5,6-tetrachloro-neighbour-carboxyl phenyl)-6-hydroxyl-2,4,5, the different xanthene ketone of 7-tetrabromo-3-dipotassium)
No. 232 red (rose-red K, acid is red 94,9-(3,4,5,6-tetrachloro-neighbour-carboxyl phenyl)-6-6 hydroxyl-2,4,5, the different xanthene groove of the 7-tetraiodo-3-dipotassium)
No. 201 oranges (dibromofluorescein, solvent red 72,4,5-two bromo-3,6-fluorandiol)
No. 203 oranges (permanent orange, pigment orange 5,1-(2,4-dinitrophenyl azo)-beta naphthal)
No. 204 oranges (Benzidine orange G, pigment orange 13,3,3 '-dichloro diphenyl-4,4 '-bisazo-(1-phenyl-3-methyl-5-pyrazolones ketone)
No. 205 oranges (1-is right for orange II, acid orange 7-sulfo group-phenylazo-beta naphthal list sodium)
No. 401 red (violamine R, acid violet 9,9-neighbours-carboxyl phenyl-6-4 (the different xanthene disodium of 4-sulfo group-o-tolyl imino group-3-)
No. 404 red (sun-proof is scarlet, paratonere 24,1-(4-nitro-2-tolyl azo)-2-hydroxyl-3-naphthoic acid N-anilide)
No. 405 Huangs (permanent red F5R, pigment red 48,1-(3-chloro-6-sulfo group-4-tolyl azo)-2-hydroxyl-3-naphthoic acid calcium)
No. 501 red (medicinal scarlet red, solvent red 24, neighbour-tolyl azo-neighbour-tolyl azo-beta naphthal)
No. 502 red (Ponceau 3R, edible red 6,1-(2,3, the 5-trimethylphenyl) azo-beta naphthal-3,6-disulfonic acid disodium)
No. 503 red (ponceau R, acid red 26,1-xylyl azo-beta naphthal-3,6-disulfonic acid disodium)
No. 504 red (FD C Red No. 4, edible red 1,2-(5-sulfo group-2,4-xylyl azo)-Neville acid disodium)
No. 505 red (oil red XO, solvent orange 7,1-xylyl azo-beta naphthal)
No. 506 red (the red S of sun-proof, acid red 88,4-(2-hydroxyl-1-naphthyl azo)-1-naphthalene methanesulfonic acid list sodium)
No. 401 oranges (Chinese spreads orange, pigment orange 1, α-(neighbour-nitro-right-anisyl azo)-o-acetyl-acetyl toluidine)
No. 402 oranges (4-is right for orange I, acid orange 20-sulfo group-phenylazo-1-naphthols list sodium)
Fluorescein
No. 403 oranges (orange SS, solvent orange 2,1-neighbour-tolyl azo-beta naphthal)
No. 401 Huangs (hansa yellow, pigment yellow 1, α-(neighbour-nitro-right-tolyl azo)-N-AAA)
These pigment can use separately, perhaps use at least two kinds mixture in them.Determine the amount of pigment so that the preparation of gained has the color of above-mentioned particular range.The consumption of pigment is about 0.05～4% (weight) of the present composition normally, is preferably about 0.08～2% (weight).
The composition of attraction fly of the present invention must be the particle form that particle mean size is about 0.5～5mm.If particle mean size is less than 0.5mm (being Powdered) or greater than 5mm, then said composition can not reach the desired high effect that attracts.The granularity of preparation can influence and attract this fact of effect of fly never to report so far, and our research has disclosed this fact first just.The preferred size scope of composition of the present invention is about 1-3mm.As long as said composition has above-mentioned specific granularity, then its configuration, weight etc. there is not special qualification.For example, said composition can be the form of particle, ball or sphere or dish type particle, amorphous or any required form.
The composition of insecticide with attraction fly of the present invention can be combined so that kill the fly that is attracted effectively and effectively.Though can use various fly to be had the insecticide of insecticidal effect, wish to use pyrethroid, organic phosphor and carbamate pesticide.The example of these insecticides is as follows:
3-pi-allyl-2-methyl ring penta-2-alkene-4-ketone-1-base cis/trans-chrysanthemum monocarboxylate (common name: allethrin)
3-pi-allyl-2-methyl ring penta-2-alkene-4-ketone-1-base trans-chrysanthemate ester (common name: biological allethrin)
5-benzyl-3-furfuryl d-cis/trans-chrysanthemum monocarboxylate (common name: Chryson)
5-(2-propargyl)-3-furfuryl chrysanthemum monocarboxylate (common name: Furamethrin)
3-phenoxy benzyl cis/trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester (common name: permethrin)
3-phenoxy benzyl cis/trans-chrysanthemum monocarboxylate (common name: phenothrin)
0,0-dimethyl 0-(2,2 ,-dichloro) vinyl phosphates (DDVP)
0-o-phenyl-isopropyl methyl carbamate (common name: unden)
0,0-dimethyl 0-(3-methyl-4-nitrobenzophenone) thiophosphate (common name: Folithion)
0,0-diethyl 0-2-isopropyl-4-methyl-pyrimidine radicals (6)-thiophosphate) common name: N-(3,4,5,6-tetrahydrochysene benzene two (first) acylimino)-methyl d1-cis/trans-chrysanthemum monocarboxylate (common name (high tetramethrin) diazinon)
0,0-dimethyl S-(1,2-two carbonization ethoxyethyl)-phosphorodithioate (common name: the malathion)
Alpha-cyano-3 '-phenoxy benzyl α-isopropyl-4-chlorphenyl-acetate (common name: sumicidin)
0-(4-bromo-2,5-dichlorophenyl) 0,0-dimethyl disulfide substituted phosphate (common name: bromophos)
S-methyl N-(methylamino formyloxy) sulfo-acetimidate (common name: methomyl)
0,0-dimethyl 0-4-methyl mercapto--the toluyl sulfo-salt phosphate (trade mark: Baycid) (common name: fenthion)
Dimethyl-(2,2,2-three chloro-1-hydroxyethyls) phosphonate ester (common name: chlorophos)
0-2,4-dichlorophenyl 0-ethyl-S-propyl group-phosphorodithioate (common name: Prothiophos)
In these pesticide compounds, pyrethroid is particularly preferred.In this compounds, 5-benzyl-3-furyl methyl d-cis/trans-chrysanthemum monocarboxylate, phenothrin and permethrin most preferably.These worm agent of stopping can be used separately, and perhaps at least two kinds in them mix use.Though the ratio of used insecticide is not particularly limited, be generally present composition gross weight about 0.1 to about 15% (weight).
The composition of attraction of the present invention fly is by with a kind of suitable carriers and described compound and this mixture shaping or be granulated into a kind of suitable form with particle mean size of above-mentioned scope and prepare.The example of used carrier be the segmentation inorganic substances for example, talcum, kaolin, silicic acid, active carbon, bentonite, silica, alumina, alumina-silica, calcium carbonate, powder and diatomite pottery or pottery, with organic substance for example, paper pulp, fiber, wood powder, Icing Sugar, analysis for soybean powder, flour, starch, resin and rubber.
Preferably; the composition of attraction fly of the present invention is as foretelling preparation; for example; method be with pigment and as the attraction compound of active component and; if desired; a kind of suitable insecticide mixes mutually with a kind of solvent and/or a kind of binder solution, and this mixture is granulated into a kind of specific granularity, removes and desolvates and dry this material product.The example that is used for the solvent of this method be alcohols for example, methyl alcohol and ethanol, ketone are for example, acetone and methyl ethyl ketone, ethers for example, oxolane is with diox, and other material for example, hexane, kerosene, paraffin, benzinum, toluene, ethyl acetate and dichloroethane.The example of adhesive therefor be cellulose derivatives for example, nitrocellulose, hydroxy propyl cellulose, acetylcellulose, acetobutyryl cellulose and methylcellulose, polyvinyl alcohol, gum Arabic, sodium carboxymethylcellulose, casein, gelatin, alginic acid.This adhesive uses the most favourable with the form of about 1～20% the aqueous solution usually.
When requiring to combine with the composition of attraction of the present invention fly, various known additives also are useful as synergist, age resistor, antidecomposition agent, bactericide, fungicide, accidental picked-up prophylactic etc.Other known attractant also can be used in combination.
The example of useful synergist is N-(2-ethylhexyl) dicyclo [2,2,1]-5-heptene-2,3-dicarboximide, 6-(propyl group piperonyl) butyl Ka Biji ether etc.The example of useful antiager is butylated hydroxy anisole, dibutyl hydroxy toluene, vitamin e, oryzanol etc.The example of useful antidecomposition agent is a phenyl glycidyl ether etc.As everyone knows, the mode that these reagent can be used always is used, and also can be used in combination.
The example of useful bactericide is salicylic acid, benzoic acid, sorbic acid, to a chloro-meta-xylene phenol, 2-(4 '-thienyl) benzimidazole etc.The example of useful fungicide is α-bromocinnamaldehyde, N-dimethyl-N-phenyl-N '-(fluorine dichloromethyl) sulfo-sulfonamide etc.The tincture that the useful accidental example that absorbs prophylactic is a capsicum, the bitter basis of Japan, chloramphenicol etc.Can suitably determine the usage ratio of these reagent.For example, the consumption of accidental picked-up prophylactic can be about 0.1～3% (weight) of prepared preparation.
The example of the attractant that can combine with the composition of attraction fly of the present invention is the picked-up-attractive substance that comprises the material of protein and/or carbohydrate containing, for example milk powder, egg powder, pupa powder, whale baking soda, meat broth, albumin, globulin, amino acid (as proline), malt extract, caramel, vanillin, whey, flour, yeast, glucose, sucrose, maltose, monose and disaccharides.The example of the attractant that other is useful is terpineol, farnesol, geraniol, acetic acid, isovaleric acid, trimethylamine, indoles, send aliphatic mono class, the pancreatin of pyridine, benzyl carbinol, ammonium carbonate, scatol, formaldehyde, hexa, aminoquinoxaline, papain, butyric acid, isopentyl aldehyde, ethamine, chlorination alkene polyalcohol.The consumption of these attractants can suitably be determined, but needn't limit especially.
Optimum implementation of the present invention comprises a kind of poison bait compositions, wherein be combined with at least a pyrethrins and kill agent, allethrin), 3-phenoxy benzyl cis/trans chrysanthemum monocarboxylate (common name: phenothrin) and 3-phenoxy benzyl cis/trans-3-(2 this insecticide is selected from (5-benzyl-3-furyl) methyl d-cis/trans chrysanthemum monocarboxylate, and (custom is:, the 2-dichloroethylene)-2,2-dinethyl cyclopropane carboxylic acid ester (common name: permethrin).
Usually, poison bait compositions comprises a kind of food of stining food with confession fly impregnated with insecticides or that combine with insecticide.In order to obtain gratifying result, this poison bait compositions must satisfy following requirement.At first, selected insecticide component is minimum the repulsion to fly.The second, this poison bait must have physics and/or the chemical method that attracts fly.The 3rd, the sense of taste of this poison bait must have sufficient attraction to lure the fly picked-up poison bait that is attracted into.The 4th, before fly was detested poison bait or toxigenicity symptom in some mode, fly must have been taken in enough fatal dosage.These requirements are not independently, but married each other.If this poison bait compositions can not satisfy these any one in requiring, then the effect of this poison bait reduces and the result that produced can not be satisfactory greatly.
The insecticide component of at present known poison bait compositions only limits to some organic phosphors or carbamate pesticide, and pyrethroid insectide seldom uses.Usually, known pyrethroid insectide can produce a kind of significant down effect to growing up fly (hereinafter only being called " fly ") snap action, because this insecticide enters by skin or oral cavity in the body of fly and be very fast to nervous system generation effect.Therefore, the application of this insecticides only limits to the mouth breathing road and contacts with skin.Utilize above-mentioned feature, pyrethroid insectide not only can be used for fly, and can dosage form be used for mosquito, cockroach etc. as repel mosquito agent (stomatodeum), repel mosquito electricity cover (the same), aerosol (stomatodeum contacts with skin), fumigant maybe can be vaporized composition (the same) etc.Yet they were not used for stomatodeum with the form of insecticide poison bait compositions.
For example, once reported in J.Keiding " Paint-on-Baits " laboratory test in Denmark's insect infection experiment yearbook in 1978 is reported and attempt to control insect by stomatodeum with pyrethroid insectide, but this report explanation, the poison bait that combines pyrethroid insectide can not reach gratifying result.In view of present scientific information, promptly pyrethroid insectide can not absorbed by insect, and the result who is reported is seemingly rational.And, recently report, 2,2-dimethyl-3-(β, β-dichloroethylene) cyclopropane-carboxylic acid alpha-cyano-3-phenoxy group-4-fluorobenzene ester, a kind of pyrethroid insectide is effective (referring to the clear 59-78111 of unexamined Japanese patent gazette) to the poison bait of fly.Yet, this report explanation, having only above-claimed cpd is effectively, and other pyrethroid insectide is not suitable for poison bait.Therefore, it is generally acknowledged in this area at present that pyrethroid insectide has the activity of repelling insect, if but its effectiveness of oral administration absorption back is lower.
Yet, our research shows, if the composition of attraction of the present invention fly combines at least a in above-mentioned three kinds of pyrethroid compounds and is used as poison bait compositions, though then be that oral administration is taken in, this pyrethroid compound still has strong insecticidal effect to fly, and, said composition can attract fly effectively and can not cause any detest, and said composition can lure that the fly that is attracted absorbs the poison bait of lethal dose on one's own initiative, very doggedly into, has therefore reached high control efficiency.
The attractant of luring fly picked-up poison bait compositions of the present invention into is added said composition.Illustrational attractant can be used as this attractant.Absorb-lure attractant and be a kind of material that itself can be eaten by fly.Useful carrier is edible material preferably, for example Icing Sugar.Analysis for soybean powder, flour, starch etc.The consumption that absorbs-lure attractant and/or be used as the Edible material of carrier is at least 70% (weight) of said composition.
Above-mentioned pyrethroid insectide compound can use separately, and perhaps their at least two kinds can be used in combination, and its consumption is 0.1～15% (weight) of said composition, is preferably 0.3～10% (weight), the particularly preferred allethrin that is to use.
The consumption of sex pheromone is about 0.01～15% (weight) of said composition, is preferably about 0.02～4% (weight).Though the usage ratio of pyrethroid compound and sex pheromone is limited particularly and can select in very wide scope, and the ratio of the former with the latter (weight ratio) is generally about 1: 0.001-1 is preferably about 1: 0.005-0.5.
Can use and described this poison bait compositions of identical additive preparation.Can be with all components being made granular preparation with described identical method.
Attraction composition of the present invention can the primary particles form uses, and for example the film, sheet material, plate, ball, gengon etc. of paper, fabric and synthetic resin, timber or metal are gone up and used perhaps to adhere to a kind of suitable substrates.
As fly control or agent for killing the same, if the composition of attraction fly of the present invention prepares with the agrochemical of wherein combination, then said composition can be used for the fly some places that haunt by placing, spray or adhering to, as crop growth field, orchard, greenhouse, vinyl factory building, livestock canopy, poultry room, granary, kitchen, residential houses etc.If composition of the present invention does not contain agrochemical, then said composition can be used for these places with other suitable combination such as insecticidal preparation.The consumption of said composition can be according to method of using and local and suitable determining.For example, when using the composition of attraction fly of the present invention by spraying, its consumption is that 1mg is at least contained in every square metre of relevant place, preferably is about 3～10mg reactive compound.
Can be tame Nuscidae such as housefly, false stable fly, matting chela fly and Ophyra leucostoma by the example of the fly of the composition attraction of attraction fly of the present invention; Fanniinae; Family's Calliphoridae such as calliphorid, Aldrichina grahami, lucilia sericata, mercerising cupreous fly, gold fly, Lucilia illustris, chrysomyia megacephala and black flowerfly; Family's Flesh flies such as Sarcophaga peregrina and Parasarcophaga similis; Family fruit bat such as fruit bat and Drosophila virilis; Family's Piophilidae such as Piophila casei; Family's Scopeumatidae such as yellow class fly; Dromyzidae of family such as Stenodryomyza formosa; Family's Phoridae such as Megaselic scalaris; Deng.
With the following example the present invention is described in more detail.
Embodiment 11. Icing Sugar 60g2. pigment 0.8g3. cis-9-tricosene 15mg (1.5mll% (weight) acetone soln) are the equal amount of mixture 100ml5. adhesive 7ml (aqueous solution of 20% (weight) gum Arabic) of methyl alcohol and acetone 4.
Said components 1 to 5 by mixing together, is desolventized with rotary evaporator (50 ℃) steaming, and this mixture sieves with the 2mm screen cloth.The part that granularity is excessive is crushed to particle.Spray the aqueous solution of adhesive again.The particle that particle mean size is about 2mm is fully mediated and made to the gained mixture under pressure.Make this granulate mixture at room temperature leave standstill at least 12 hours and drying and obtain a kind of granular preparation.Obtain attracting the composition 1a to 1m of fly in this way.
The concentration of the cis of these formulation samples-9-tricosene is 0.025% (weight).
The formulation samples of gained is pressed JISZ8721 and is detected color.Table 1 has provided the result.
Table 1
Preparation pigment preparation color
1a tartrazines No4 6YR
1b fluorescein sodium K (202-1) 2Y
1c naphthol yellow S 3Y
1d fluorescein 1YR
1e quinoline yellow SS 10YR
1f fast yellow 3G 7YR
1g fluorescein (sodium) is 2Y (202-2)
The yellow G 5YR of 1h biphenyl
1i tropeolin G 5Y
1j hansa yellow 3Y
No. 5 yellow 9R of 1k
1l sunset yellow F 1YR
No. 4 yellow 1.5R of 1m
Embodiment 2
With with embodiment 1 in identical method prepare the particulate composition 2a to 2m that insecticide concentration is the attraction fly of 1% (weight), the methomyl (S-methyl N-(methylamino formyloxy) sulfo-acetimidate carbamate pesticide, the product of E.I.Du Pont Company) that different is uses 600mg in addition is as another kind of insect disinfestation component.
The color of finding prepared each formulation samples is all identical with the color of respective sample among the sample 1a to 1m (seeing Table 1) of embodiment 1.
Attraction effect with prepared preparation in the following method test implementation example 2.
Test I
Weight respectively for the preparation of 60g places some glass plates (diameter 15.5cm) respectively, is lined up a circle to these dishes then on the floor of laboratory, the distance of each interval is about 30cm.Housefly is put into laboratory.Through behind the preset time, detect the fly number that kills in each dish.
According to the effect of recently assessing every kind preparation attraction fly of the fly number that kills in the plate that preparation is housed with the fly sum that in laboratory, kills (i.e. the summation of the fly number that in all dishes, kills).
Test II
With with test among the I identical method assessment preparation attract the effect of fly, different is that weight is respectively placed plastic cup respectively for the preparation of 10g, and these cups are come be placed on outdoor glass box (on the floor of 1.45m * 1.4m), the distance of each interval is about 20cm.
Result of the test is shown in table 2 (test I) and table 3 (test II).
Table 2
Preparation number is to the attraction effect (%) of fly
2a 1
2b 3
2c 2
2d 28
2e 3
2f 4
2g 4
2h 4
2i 3
2j 3
2k 30
2l 11
2m 3
Contrast 1
Table 3
Preparation number is to the attraction effect % of fly
2a 3
2b 2
2c 1
2d 16
2e 4
2f 5
2g 5
2h 3
2i 3
2j 5
2k 28
2l 21
2m 3
Contrast 1
Embodiment 3
With with embodiment 2 in the preparation of identical method attract the Pesticidal combination of fly, different is to use 0.08% (weight) or the yellow F of 1.3% (weight) setting sun.With testing the effect that method test gained preparation identical among the I attracts fly with embodiment 2.Table 4 has provided result of the test.
Table 4 preparation paint color attracts fly
Effect (%)
Yellow F 1.3 1YR 16 of yellow F 0.08 1YR of title concentration (wt%) the 3a setting sun 12 3b setting sun
Embodiment 4
Pigment (fluorescein) 1g
Insecticide (permethrin) 1g
Cis-9-tricosene 25mg
Incremental agent 100mg
With the pigment of specified quantitative, cis-9-tricosene (form with the 1ml hexane solution is used) and Icing Sugar by mixing together; the gained solid mixture is crushed; by fully mediating granulation and at room temperature dry under pressure behind the spraying adding 20% gum Arabic mixture.
The insecticidal fogging that will be dissolved in acetone then is to prepared mixture, and spray amount is the 15ml/50g mixture.This mixture fully supportted mix, desolvate by wherein removing, obtain the composition of attraction fly of the present invention with rotary evaporator (50 ℃).Said composition will be called " invention 4a ".
Comparative example 1
Prepare a kind of Comparative composition that attracts fly in order to method identical among the embodiment 4, its color is identical with the composition of embodiment 4 with particle mean size, and different is not use cis-9-tricosene.Said composition will be called " contrast 4b ".
Comparative example 2
By mixing together, pulverize and drying obtain the Comparative composition of a kind of attraction fly of powder type then with component utilized among the embodiment 4.Said composition will be called " contrast 4c ".
Attraction-insecticidal test
Test the attraction-insecticidal activity of the attractant sample of above-mentioned preparation in order to following method to fly, weight is respectively put into the deep bid that some internal diameters are 15cm respectively for the sample of 20g, these dishes are arranged in laboratory (on 4 * 3 * 2.6m) the floor, and in laboratory, put into about 140～150 flies.Counted the fly number that kills in each dish after on-test in 1～2 hour.Each sample is repeated above-mentioned test 4 times, assess its activity according to the mean value of gained.
Table 5 has provided its activity of test.
Table 5
Tested number sample attraction-insecticidal activity (fly number) 1 invention 4a 69.1 2 row are than 4b 9.1 3 contrast 4c 2.9
According to table 5, have the invention 4a of same composition and contrast comparison shows that between the 4c, the activity of invention 4a is very excellent.This is the feature of said preparation, promptly by the given specified particle size of granulation.Aspect this effect, preparation of the present invention also is better than not containing the contrast 4b of cis-9-tricosene greatly.Therefore, this result of the test shows that this attracts effect owing to using cis-9-tricosene and specific granularity significantly.
Embodiment 5
Insecticide (methomyl, S-methyl N-(first
The base carbamoyloxy) 2g sulfo-acetimidate)
Cis-9-tricosene 50mg
Icing Sugar 100g
Antiager (BHT, 2,6-di-t-butyl toluene) 2g
Fluorescein 1g
Icing Sugar and cis-9-tricosene (form with the 1ml hexane solution is used) are in the same place by mixing; obtain solid mixture; then with its crushing; fully mediate behind the aqueous solution by spraying adding 20% gum Arabic; granulation to particle mean size is 2mm under pressure, and at room temperature dry.
The above-mentioned insecticidal fogging that then will be dissolved in acetone is to this granulate mixture, and spray amount is the 15ml/50g mixture.This mixture is fully stirred, desolvate from wherein removing, obtain the composition of attraction fly of the present invention with rotary evaporator (50 ℃).Said composition will be called " invention 5a ".
Comparative example 3
With with embodiment 5 in identical method prepare a kind of Comparative composition that attracts fly, its color is identical with above-mentioned composition with particle mean size, different is without cis-9-tricosene, said composition will be called, contrast 5b ".
Attraction-insecticidal test
Adopting weight be the sample of 20g respectively, use with embodiment 4 in identical method, test the composition sample that makes in these embodiments.Table 6 has provided result of the test.To each sample repeated test 5 times, assess its activity according to the mean value of gained.
Table 6
Tested number sample attraction-insecticidal activity (fly number) 1 invention 5a 43.3 2 contrast 5b 10.4
Embodiment 6-11
With with embodiment 4 in identical method, the preparation of listed component has varigrained attraction composition of the present invention in the use table 7.
In the table 7 to the following meaning of the used symbology of some component.
Pigment
A-1: setting sun Huang
The A-2:2 Huang
A-3: fluorescein
Insecticide
B-1: permethrin
B-2:Chrysron-Forte (compound name: 5-benzyl-3-furyl methyl d-cis/trans chrysanthemum monocarboxylate)
B-3: phenothrin (table 7 is seen the literary composition back)
With with embodiment 4 in the test of identical method in these embodiments the composition sample of the present invention of preparation to attraction-insecticidal activity of fly.The resulting result of each sample is equally matched with the acquired result of composition of the present invention.
Embodiment 12-17
With with embodiment 4 in identical method prepare some attractions-desinsection particulate composition, its particle mean size is 2mm, its color is identical with the composition of embodiment 4, different is replaces cis-9-tricosene with listed sex pheromone in the tabulation 8 down.
Table 8
The embodiment sex pheromone
12 9-tricosenes
13 10-methyl-9-tricosene
14 cis-2-methyl-8-two dodecylenes
15 cis-9-two dodecylenes
16 cis-8-two dodecylenes
17 cis-10-tricosene
With with embodiment 4 in the composition of identical method test gained.Therefore, the effect that the present composition obtained among the attraction effect of finding each composition and the embodiment 4 is identical.
Embodiment 18
With 0.6g (5-benzyl-3-furyl) methyl d-cis/trans chrysanthemum monocarboxylate (hereinafter referred to as " compd A "), 1.04g5 Huang, 0.1g cis-9-tricosene, 60g Icing Sugar and 20g pupa powder are in the same place by mixing.Remove from this mixture with rotary evaporator (50 ℃) and to desolvate.This mixture sieves with the 2mm screen cloth, and the part that granularity is excessive further is milled to particle.Adding the mixed-powder that will so obtain behind the 1.2mlAmlycolH (binder aqueous solution) by spraying fully pinches and is incorporated in that granulation to particle mean size is 2mm under the pressure.This granulate mixture was descended dry 4 hours at 40 ℃, obtain poison bait compositions of the present invention.
Embodiment 19
With with embodiment 18 in identical method prepare poison bait compositions of the present invention, different is to use 40g pupa powder.
Embodiment 20
With with embodiment 18 in identical method prepare poison bait compositions of the present invention, different is replaces Icing Sugar and with 5g meat broth replacement pupa powder with 10g flour and 30g glucose.
Embodiment 21
With with embodiment 18 in identical method prepare poison bait compositions of the present invention, different is to replace compd A with permethrin.
Embodiment 22
With with embodiment 18 in identical method prepare poison bait compositions of the present invention, different is to replace compd A with phenothrin.
Test case
The poison bait compositions that each 2g makes in embodiment 18,21 and 22 is put into the plastic cup (KP-430) that contains 100 male adult flies.Knock down the result through detecting after the regular hour.Table 9 has provided this result.
Table 9
Embodiment knocks down
After 5 minutes after 24 hours
18 100 100
21 100 100
22 100 100
Table 7
Implement cis two insecticide pigment Icing Sugar granularity colors
13 carbon title consumption title consumption consumption (umber) example alkene consumptions (umber) (umber) (mm)
(umber) 6 0.025 B-1 1.0 A-1 1.0 97.975 1.5 1YR 7 0.025 B-2 1.0 A-2 1.0 97.975 1.5 9R 8 0.025 B-3 1.0 A-3 1.0 97.975 1.5 1YR 9 0.025 B-1 3.0 A-1 3.0 97.975 3.0 1YR 10 0.025 B-2 3.0 A-1 3.0 97.975 3.0 1YR 11 0.025 B-3 3.0 A-1 3.0 97.975 3.0 1YR
Claims (9)
1. composition that attracts fly is characterized in that:
A) contain at least a sex pheromone as the compound that attracts fly, this sex pheromone is selected from 9-tricosene, cis-9-tricosene, 10-methyl-9-tricosene, cis-2-methyl-8-two dodecylenes, cis-9-two dodecylenes, cis-8-two dodecylenes and cis-10-tricosene.
B) its color is the yellowish red color of 2.5R～2.5YR, and
(c) be the granular preparation form that particle mean size is about 0.5～5mm.
2. according to the composition of claim 1, wherein said sex pheromone is cis-9-tricosene.
3. according to the composition of claim 1, wherein said Color Range is 7.5R～2.5YR.
4. according to the composition of claim 1, wherein said particle mean size is about 1～3mm.
5. according to the composition of claim 1, wherein contain a kind of pesticide compound.
6. according to the composition of claim 5, wherein said pesticide compound is a pyrethroid.
7. according to the composition of claim 6, wherein said pesticide compound is to be selected from following at least a compound: 5-benzyl-3-furyl methyl-d cis/trans chrysanthemum monocarboxylate, 3-phenoxy benzyl cis/trans chrysanthemum monocarboxylate and 3-phenoxy benzyl cis/trans-3-(2, the 2-dichloroethylene)-2,2-dinethyl cyclopropane carboxylic acid salt.
8. according to the composition of claim 7, wherein said pesticide compound is 5-benzyl-3-furyl methyl d-cis/trans chrysanthemum monocarboxylate.
9. according to the composition of claim 7 or 8, wherein contain a kind of picked-up-inducing substance and be used as the malicious erbium of fly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86108161 CN1030680C (en) | 1985-07-18 | 1986-11-29 | Composition for attracting flies |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60158835A JPS6219504A (en) | 1985-07-18 | 1985-07-18 | Attractant for fly |
| CN 86108161 CN1030680C (en) | 1985-07-18 | 1986-11-29 | Composition for attracting flies |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86108161A CN86108161A (en) | 1988-06-08 |
| CN1030680C true CN1030680C (en) | 1996-01-17 |
Family
ID=25742266
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 86108161 Expired - Fee Related CN1030680C (en) | 1985-07-18 | 1986-11-29 | Composition for attracting flies |
Country Status (1)
| Country | Link |
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| CN (1) | CN1030680C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5656286B2 (en) * | 2009-12-28 | 2015-01-21 | 住友化学株式会社 | Fly attractant and method for attracting and controlling flies |
| CN102388913B (en) * | 2011-09-23 | 2014-08-13 | 湖北省农业科学院果树茶叶研究所 | Chip for trapping and killing citrus fruit fly, and preparation method thereof |
| CN102499242B (en) * | 2011-11-02 | 2013-05-08 | 云南农业大学 | Piophila casei attractant |
| CN103155917B (en) * | 2013-03-26 | 2014-08-20 | 德清科中杰生物科技有限公司 | Housefly attractant |
| US9877487B2 (en) * | 2013-07-22 | 2018-01-30 | Emekatech, Llc | Compositions for effective fly population suppression |
| CN104982433A (en) * | 2015-06-23 | 2015-10-21 | 潍坊友容实业有限公司 | Injurious insect attractant and application thereof in cape gooseberry saline-alkali soil planting |
| BE1024239B1 (en) * | 2016-05-30 | 2018-01-09 | Globachem Nv | USE OF 9-TRICOSEEN TO COMBAT DROSOPHILA SUZUKII (SUZUKI'S FRUIT FLY) |
| CN106614576A (en) * | 2016-10-28 | 2017-05-10 | 广州翼鲲植物保护有限公司 | Fly attractant |
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1986
- 1986-11-29 CN CN 86108161 patent/CN1030680C/en not_active Expired - Fee Related
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