CN103059663B - Ultra-durable self-cleaning reflective insulation simulation coating technical field - Google Patents
Ultra-durable self-cleaning reflective insulation simulation coating technical field Download PDFInfo
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- CN103059663B CN103059663B CN201210577700.8A CN201210577700A CN103059663B CN 103059663 B CN103059663 B CN 103059663B CN 201210577700 A CN201210577700 A CN 201210577700A CN 103059663 B CN103059663 B CN 103059663B
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Abstract
The present invention discloses an ultra-durable self-cleaning reflective insulation simulation coating. The ultra-durable self-cleaning reflective insulation simulation coating includes the following components: water, an antifreeze, a thickener, a wetting agent, a dispersing agent, an antifoaming agent, a multifunctional additive, a pH adjusting agent, a bactericide, rutile titanium dioxide, an environmentally-friendly colored mixed-phase inorganic pigment, a coalescing agent, a dry film fungicide, a self-cleaning additive, a modified fluorocarbon emulsion, a covering hollow micro-emulsion, high-strength hollow glass beads, and hollow ceramic micro powder. The environmentally-friendly colored mixed-phase inorganic pigment adopted in the coating has excellent durability, excellent infrared-reflection function, and excellent insulation and cooling, and environmental protection and energy saving effect; additionally, the pigment also has a function of simulating chlorophyll, so the coating can be used for simulation in national defense and military fields; and the coating of the present invention has excellent resistance to staining, yellowing, alkali, acid rain, and salt spray, and ultra-long weather resistance, ultra-long durability and self-cleaning function.
Description
Technical field
The present invention relates to a kind of chemistry painting industry field, be specifically related to a kind of super-durable automatically cleaning reflective insulation anti-counterfeit paint.
Background technology
Because the constant temperature of the outer surface of building shined upon for a long time raises, the temperature of the material of construction outside surfaces such as outer surface of building is cement, concrete, ceramic tile, metal, insulating brick can reach 40-50 DEG C, on color steel, water-proof material, temperature can reach 60 DEG C, reaches the temperature of boiling hot people.Under such outer surface of building high temperature, in habitat, the inevitable rising of the temperature of plant floor etc., live to normal human subject, material deposits, the safety of equipment all causes very large impact, likely can produce the great potential safety hazards such as blast, if temperature is too high, need cooling, cause the significant wastage of the energy simultaneously.
In order to reduce the thermal radiation of the sun, by improving the absorption of reflection minimizing to sunlight heat, therefore there is heat insulation, to reflect functions such as lowering the temperature, anticorrosion coating arise at the historic moment, become reducing sun heat radiation harm to a great extent in the urgent need to, these coating there are fabulous market outlook of painting industry.But there is certain toxicity in traditional reflective insulation material, and unstable chemcial property, not easily preserve for a long time, heat-reflecting heat-insulating performance in time and the change of environment and the defect of change etc.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency, provide a kind of feature of environmental protection good, there is good protection against the tide, waterproof, sound insulation, antifouling, anticorrosion, lasting automatically cleaning, and there is the super-durable automatically cleaning reflective insulation anti-counterfeit paint of anti-camouflage function and stable performance.
The object of the present invention is achieved like this: a kind of super-durable automatically cleaning reflective insulation anti-counterfeit paint, this coating by weight percentage composition comprises following component:
Water 10 ~ 30%
Frostproofer 1 ~ 5 %
Thickening material 1 ~ 5%
Wetting agent 0.5 ~ 3%
Dispersion agent 0.5 ~ 3%
Defoamer 0.3 ~ 3%
Multifunctional assistant, pH adjusting agent 0.5 ~ 3%
Sterilant 0.5 ~ 3%
Rutile titanium white powder 0 ~ 20%
Environment protection colour mixed phase mineral dye 5 ~ 20%
Film coalescence aid 1 ~ 3%
Dry film mould inhibitor 0.5 ~ 3%
Automatically cleaning auxiliary agent 1 ~ 2%
Fluorocarbon modified emulsion 30 ~ 50%
Opacifying property hollow microemulsion 5 ~ 15%
Hollow glass micropearl 5 ~ 25 %
Hollow ceramic micro mist 2 ~ 10%
Above-mentioned each component sum is 100%.
Preferred technical scheme is, described frostproofer is propylene glycol, and described thickening material is ACRYLIC EMULSION;
Described wetting agent is Triton X-100 (TRITON X-100), described dispersion agent (TRITON CF-10), and described defoamer is silica derivative (SN-154);
Described multifunctional assistant, pH adjusting agent are 2-amino-2-methyl isophthalic acid-propyl alcohol (AMP95);
Described sterilant is ACTICIDE HF, that is: 5-chloro-2-methyl-4-isothiazoline-3 ketone, the mixture of 2-methyl-4 isothiazoline-3-ketone and formaldehyde concentrated solution;
Described rutile titanium white powder is R902+, and it is through special surface process, has the light reflective properties of overlength weathering resistance, easily dispersion, high whiteness, high covering power and excellence;
Described environment protection colour mixed phase mineral dye has remarkable weather resistance, excellent reflected infrared function, has excellent heat insulation and heat control, the effect of environmental protection and energy saving; In addition this pigment also has imitative chlorophyll function, can be used for the anti-counterfeit paint field of national defense and military.
Described film coalescence aid is TEXANOL, that is: 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrates, and cohesiveness, the weathering resistance of improving coating are resistance to, scrubbing character and color developing, have good preservation stability simultaneously.
Described automatically cleaning auxiliary agent can be automatically cleaning auxiliary agent B YK-9131, and it act as hydrophobic and not dust suction, very easily clean by rain drop erosion, has the effect of " lasting automatically cleaning ";
Described fluorocarbon modified emulsion has splendid water tolerance and overlength weathering resistance, and anti-contamination, non yellowing, alkali resistant, Acid Rain, salt fog resistance, paint film are bright, plentiful, good fluidity.
Described opacifying property hollow microemulsion has hollow structure, its outer shell polymkeric substance is different from the specific refraction of the air in cavity to light, so incident optical energy is by effective scattering, thus the reflective insulation Be very effective of paint film is improved, the consumption of the larger hollow glass bead of particle diameter can be reduced simultaneously, the outward appearance of film is improved, there is excellent whiteness and good coating performance, can white pigment, uvioresistant additive and Feel Modifzers etc. be used as.
Described high strength hollow glass micropearl thermal conductivity is low, λ=0.023W/mK, and play the effect of well heat insulation and noise-reducing, have efficient fillibility, low oil absorption ferric, density is low, but particle diameter is comparatively large, and condition of surface is general.
Described hollow ceramic micro mist thermal conductivity is low, λ=0.023W/mK, and play the effect of well heat insulation and noise-reducing, efficient fillibility, low oil absorption ferric, density is higher, but particle diameter is little, and condition of surface is good.
The present invention is that the space hitech materials used by space shuttle transfers the brand-new coating of civilian one to.Its exploitation object is the worried problem in order to forever solve room reflections heat-insulation and heat-preservation.This coating, except having good protection against the tide, waterproof, sound insulation, antifouling, anticorrosion external decoration effect, also has very strong thermal insulation function, make house and container cool in summer and warm in winter.This reflective heat-insulation paint construction costs is low, be only 1/6 of benzene plate method external wall outer insulation construction costs, but effect is identical.By to the choose reasonable of component and allotment, obtained reflective heat-insulation paint tool has the following advantages:
(1) energy-conservation 40%.Containing using the opacifying property hollow microemulsion of superfine high strength of high-tech technology production, high strength hollow glass micropearl, hollow ceramic micro mist, thermal conductivity low in coating, λ=0.023W/mK, there is extremely strong thermal insulation function, to light and heat, there is very high blocking-up and reflex action; Environment protection colour mixed phase mineral dye has remarkable weather resistance, excellent reflected infrared function, has excellent heat insulation and heat control, the effect of environmental protection and energy saving; Sunlight and the baking of environment heat to buildings can be resisted during the broiling summer, room temp is significantly reduced, greatly reduces the using air-condition time, obviously reduce air-conditioning expense.In the winter time, the heat radiation of people and object, mainly carries out in far infrared radiation mode, if at interior of building or this High Efficiency Thermal reflective coating of outside employing, most of infrared radiation hot bakers ' can be reflected back indoor, reduce hot wall penetration loss more than 30% winter, reach effect cool in summer and warm in winter.Because this coating can save energy 40%, each domestic household can save electric power changes of air conditioners more than 500 yuan every year.
(2) super-durable.Coating adopts brand-new synthetic materials and technology; employ the fluorocarbon modified emulsion of super-durable, rutile titanium white powder, environment protection colour mixed phase mineral dye etc. and there is splendid anti-contamination, non yellowing, alkali resistant, Acid Rain, salt fog resistance and overlength weathering resistance, overlength weather resistance; use the protection face that rear formation one deck is pliable and tough; do not ftracture, non-scale, not efflorescence; life-span reaches more than 25 years; can architecture protection long-term effectively, even if when ponding is very heavy, still water-tight.
(3) preservative property are strong.Coating is not by animal urine, accumulator acid, SYNTHETIC OPTICAL WHITNER, deicing chemicals, 40% hydrochloric acid solution damage, acid-proof, alkali prevention, acid rain preventing.
(4) sound isolating and flame-retardant.Coating sound isolating and flame-retardant better performances, obviously reduces external noise, makes indoor quiet comfortable, and burning capable of blocking.
(5) there is imitative chlorophyll function, can be used for the false proof of national defense and military fields.
(6) lasting automatically cleaning.More hydrophobic and the not dust suction of the film that the interpolation of automatically cleaning auxiliary agent makes coating be formed, very easily clean by rain drop erosion, there is the effect of " lasting automatically cleaning ", make the reflective insulation of coating and anti-counterfeiting performance etc. more lasting and stable.
(7) totally nontoxic.Coating uses special formula, and water-borne coatings is nonpoisonous and tasteless, harmless to human and environment.
(8) use simply.Coating does not need dilution mediation just can use, and spray, roll, brush, decorative effect is better than general emulsion paint.
Embodiment
Below in conjunction with attached embodiment, the specific embodiment of the present invention is further described.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
embodiment one
A kind of super-durable automatically cleaning reflective insulation anti-counterfeit paint, this coating by weight percentage composition comprises following component:
Water 11.5%
Propylene glycol 4%
Acrylic thickener CR 1%
Wetting agent TRITON X-100 1.5%
Dispersion agent TRITON CF-10 1.5%
Defoamer SN-154 1%
Multifunctional assistant AMP95 0.5%
Sterilant ACTICIDE HF 1%
Film coalescence aid TEXANOL 2%
Dry film mould inhibitor ACTICDE EPW 1%
Automatically cleaning auxiliary agent B YK-9131 0
Fluorocarbon modified emulsion 30%
Opacifying property hollow microemulsion 15%
High strength hollow glass micropearl 25%
Hollow ceramic micro mist 5%
This coating is used as middle painting, and heat-proof quality is good.
embodiment two
A kind of super-durable automatically cleaning reflective insulation anti-counterfeit paint, this coating by weight percentage composition comprises following component:
Water 10%
Propylene glycol 5%
Acrylic thickener CR 1%
Wetting agent TRITON X-100 1 .5%
Dispersion agent TRITON CF-10 1%
Defoamer SN-154 1%
Multifunctional assistant AMP95 0.5%
Sterilant ACTICIDE HF 1%
Rutile titanium white powder R902+ 5%
Environment protection colour mixed phase mineral dye 5%
Film coalescence aid TEXANOL 12 carbon ester alcohol 2%
Dry film mould inhibitor ACTICDE EPW 1%
Automatically cleaning auxiliary agent B YK-9131 1%
Fluorocarbon modified emulsion 35%
Opacifying property hollow microemulsion 10%
High strength hollow glass micropearl 5%
Hollow ceramic micro mist 15%
This coating is used as face and is coated with, and false proof, reflective insulation performance is good, and outward appearance is good, lasting automatically cleaning.
embodiment three
A kind of super-durable automatically cleaning reflective insulation anti-counterfeit paint, this coating by weight percentage composition comprises following component:
Water 28%
Propylene glycol 5%
Acrylic thickener CR 5%
Wetting agent TRITON X-100 0.5%
Dispersion agent TRITON CF-10 0.5%
Defoamer SN-154 0.4%
Multifunctional assistant AMP95 0.5%
Sterilant ACTICIDE HF 0.6%
Rutile titanium white powder R902+ 9.5%
Environment protection colour mixed phase mineral dye 5%
Film coalescence aid TEXANOL 12 carbon ester alcohol 1%
Dry film mould inhibitor ACTICDE EPW 1%
Automatically cleaning auxiliary agent B YK-9131 1%
Fluorocarbon modified emulsion 30%
Opacifying property hollow microemulsion 5%
High strength hollow glass micropearl 5%
Hollow ceramic micro mist 2%
This coating is used as face and is coated with, and closure is good, and outward appearance is good, lasting automatically cleaning.
With coat can be applicable to the industries such as national defence, industry, agricultural, accumulating, building, health care any occasion needing reflective insulation (or cold insulation, insulation), military anti-camouflage and safety precaution on.
Main applicable object is:
Tubing system: comprise high and low temperature pipeline; Running water pipe, transition pipeline, oxygen and freonll-11 pipeline; The thermal insulation of pipeline for giving wind for air conditioner (heat insulation, insulation, cold insulation) and condensation-proof; The cold insulation of refrigerator, refrigerator-freezer.
Equipment and container: comprise boiler, kiln, chemical device; Oil & gas equipment, petrochemical equipment, roasting plant, heating installation, refrigerating apparatus, heat recovery equipment, metallurgy and mechanical means, electrical equipment, medical facilities, transit equipment, transport container, interchanger, fuel tank, oil tank, basin, dangerous goods container, freezer, the thermal insulation of refrigerator car etc. and prevent condensation.
Personal protection: the surface for machinery equipment or other high/low temperature place is adiabatic, prevents personnel's injury (as boiler exterior wall) produced owing to touching high/low temperature.
National defense and military fields: for anti-camouflage and the reflective insulation protection of responsive military installations.
Architectural and other: can be used as heat-insulation and heat-preservation, moisture-proof barrier.On industrial premises and covil construction, the place that car, ship, freight container and other needs are adiabatic uses.And have waterproof, corrosion-resisting function.The heat preservation energy-saving in automobile, train, compartment; It is heat insulation that low-temperature floor radiant heating substitutes vinylbenzene plate, and the heat insulation thermal insulation such as plastics, paulin uses.
Be suitable for effect citing:
Steel plate silo, freezer---peripheral protective surface spraying 0.3-0.5mm, top, storehouse maximum temperature declines 21.6 DEG C, and can protective environment steam on the impact of warehouse peripheral protective, the generation hindering moisture condensation phenomenon, energy-conservation more than 30%.
Propylene Spherical Tanks, oil tank---outside surface spraying 0.3-0.5mm, upper face temperature decline nearly 20 DEG C, do not occur that temperature is more than 50 DEG C, phenomenon, reduce temperature lowering water dripping to the corrosion of tank body outside surface, play certain provide protection.
Building, factory roof---roof spraying 0.4-0.6 mm, under the envrionment temperature of 32 DEG C, the maximum decline of roof temperature 18.1 DEG C, period at sunshine (10:00-7:00) on average declines 15.65 DEG C, attenuation multiple improves 53.9%, time delay increases by 19.75%, greatly reduces the sensation of solar heat baking.
Boats and ships, vehicle, compartment---box outer surface spraying 0.45-0.5mm, surface temperature declines nearly 20 DEG C, and the temperature inside the box declines more than 3 DEG C, does not feel baking in railway carriage.
Pipeline and valve---95 DEG C of hot-water lines spray 3.0-3.5mm to the outside surface with valve, and surface temperature drops to 30 DEG C.
Various annealing furnace and process furnace---outside surface spraying 0.4-0.5mm, surface temperature drops to 72.4 DEG C from 84.2 DEG C, reduces calorific loss more than 31%, seals touch surface without the serious sensation of scalding of burning with hand.
The material that low temperature exchange column---outside surface only sprays 0.6---1.0mm is thick, can reduce loss of refrigeration capacity more than 50%, not occur condensation, possess protection against the tide/preservative effect simultaneously.
Low-temperature (low temperature) vessel---outside surface spraying 0.4-0.5mm, can effectively suppress the sun, greatly, the impact of environmental radiation heat on equipment.
Oil storage (gas) tank---storage tank outside surface spraying 0.4-0.5 mm, surface temperature declines at most more than 20 DEG C, and top top temperature is not more than 50 DEG C.Reduce oil gas breathing loss and trickle cooling.
Building constructions---external spray 0.3-0.5mm, forms a protective guard, keeps inside buildings heat or cold air, and summer, top layer did not toast sultry in the past, and condensation seldom appears in cold interior walls in winter.
National defense and military fields---external spray 0.3-0.5mm, forms a protective guard, has excellent antiforge function, can also effectively suppress the sun, greatly, the impact of environmental radiation heat.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (6)
1. a super-durable automatically cleaning reflective insulation anti-counterfeit paint, is characterized in that, described coating by weight percentage composition comprises following component:
Water 10 ~ 30%
Frostproofer 1 ~ 5 %
Thickening material 1 ~ 5%
Wetting agent 0.5 ~ 3%
Dispersion agent 0.5 ~ 3%
Defoamer 0.3 ~ 3%
Multifunctional assistant, pH adjusting agent 0.5 ~ 3%
Sterilant 0.5 ~ 3%
Rutile titanium white powder 0 ~ 20%
Environment protection colour mixed phase mineral dye 5 ~ 20%
Film coalescence aid 1 ~ 3%
Dry film mould inhibitor 0.5 ~ 3%
Automatically cleaning auxiliary agent 1 ~ 2%
Fluorocarbon modified emulsion 30 ~ 50%
Opacifying property hollow microemulsion 5 ~ 15%
High strength hollow glass micropearl 5 ~ 25 %
Hollow ceramic micro mist 2 ~ 10%
Above-mentioned each component sum is 100%.
2. super-durable automatically cleaning reflective insulation anti-counterfeit paint as claimed in claim 1, it is characterized in that, described frostproofer is propylene glycol, and described thickening material is ACRYLIC EMULSION.
3. super-durable automatically cleaning reflective insulation anti-counterfeit paint as claimed in claim 1, it is characterized in that, described wetting agent is Triton X-100, and described defoamer is silica derivative.
4. super-durable automatically cleaning reflective insulation anti-counterfeit paint as claimed in claim 1, it is characterized in that, described multifunctional assistant, pH adjusting agent are 2-amino-2-methyl isophthalic acid-propyl alcohol.
5. super-durable automatically cleaning reflective insulation anti-counterfeit paint as claimed in claim 1, it is characterized in that, described sterilant is 5-chloro-2-methyl-4-isothiazoline-3 ketone, the mixture of 2-methyl-4 isothiazoline-3-ketone and formaldehyde concentrated solution.
6. super-durable automatically cleaning reflective insulation anti-counterfeit paint as claimed in claim 1, it is characterized in that, described film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate.
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104710892A (en) * | 2013-12-16 | 2015-06-17 | 苏州大乘环保建材有限公司 | Elastic self-cleaning reflective thermal-insulating coating |
| CN103709847A (en) * | 2013-12-26 | 2014-04-09 | 深圳市嘉达高科产业发展有限公司 | Colored reflective heat-insulating paint based on modified titanium white and preparation method thereof |
| CN104403476A (en) * | 2014-11-28 | 2015-03-11 | 安徽省金盾涂料有限责任公司 | Self-cleaning antibacterial fluorocarbon coating |
| CN104592823B (en) * | 2015-02-03 | 2016-09-21 | 安徽工业大学 | nickel acid bismuth nano-wire multifunctional coating |
| CN105219144A (en) * | 2015-09-22 | 2016-01-06 | 亚士漆(上海)有限公司 | Silicon clad nano titanium dioxide and preparation method thereof and reflective heat-insulation paint |
| CN105176233B (en) * | 2015-10-21 | 2017-12-22 | 南京旭羽睿材料科技有限公司 | High-strength anti-corrosion heat-barrier material of height for yard piping and preparation method thereof |
| CN106752526B (en) * | 2016-12-23 | 2020-03-17 | 沈阳化工研究院有限公司 | Water-based light-reflection industrial heat-insulating coating and preparation method thereof |
| CN111593568B (en) * | 2020-06-02 | 2021-06-22 | 北京建筑材料科学研究总院有限公司 | Alkali-resistant flame-retardant waterproof vapor-barrier agent and film for building with ultralow energy consumption and preparation method thereof |
| CN112812690A (en) * | 2020-06-11 | 2021-05-18 | 湖南国彩新材料有限公司 | Novel waterproof heat-preservation heat-insulation coating |
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| CN1986664A (en) * | 2005-12-19 | 2007-06-27 | 深圳市海川实业股份有限公司 | Water-base reflecting heat-islating paint |
| CN102585626A (en) * | 2011-12-12 | 2012-07-18 | 深圳市广田环保涂料有限公司 | Water-based fluorocarbon heat insulation coating and preparation method |
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- 2012-12-27 CN CN201210577700.8A patent/CN103059663B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986664A (en) * | 2005-12-19 | 2007-06-27 | 深圳市海川实业股份有限公司 | Water-base reflecting heat-islating paint |
| CN102585626A (en) * | 2011-12-12 | 2012-07-18 | 深圳市广田环保涂料有限公司 | Water-based fluorocarbon heat insulation coating and preparation method |
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Address after: 214400 Jiangsu city of Wuxi province Jiangyin Lingang New City Shen Gang Cun Zhang Jia pad No. 128 innovation Applicant after: JIANGYIN TIANBANG PAINT LIMITED BY SHARE LTD Address before: 214400 Jiangsu city of Wuxi province Jiangyin Lingang New City Shen Gang Cun Zhang Jia pad No. 128 innovation Applicant before: Jiangyin Tianbang Coating Chemical Industry Co., Ltd. |
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