CN103059209A - Weather-resistant resin for hot-stamping film and preparation method of resin - Google Patents
Weather-resistant resin for hot-stamping film and preparation method of resin Download PDFInfo
- Publication number
- CN103059209A CN103059209A CN2013100308770A CN201310030877A CN103059209A CN 103059209 A CN103059209 A CN 103059209A CN 2013100308770 A CN2013100308770 A CN 2013100308770A CN 201310030877 A CN201310030877 A CN 201310030877A CN 103059209 A CN103059209 A CN 103059209A
- Authority
- CN
- China
- Prior art keywords
- vinylformic acid
- preparation
- blocking film
- weathering resistance
- formulated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a weather-resistant resin for a hot-stamping film and a preparation method of the resin. The weather-resistant resin comprises the following compounds in parts by weight: 21-24 parts of acrylic hard monomers, 6-9 parts of acrylic soft monomers, 67-73 parts of solvents and 0.0135-0.066 parts of initiator; the preparation method comprises the following steps: (1) uniformly mixing all of the acrylic hard monomers and the acrylic soft monomers; (2) weighing 40% of the mixed monomers and 30% of the solvent in percentage by weight for uniformly mixing, heating up and reflowing the mixture in a reaction kettle; (3) weighing 40% of the solvent and 70% of the initiator in percentage by weight to mix with the residual monomers, dropping the mixture to the reaction kettle, controlling the reaction time between one hour and 1.5 hours, and keeping the reflow status to implement thermal insulation reaction for one hour to two hours after the dropping is completed; (4) weighing 30% of the solvent in percentage by weight to uniformly mix with the residual initiator, dropping the mixture to the reaction kettle, controlling the reaction time within the range of 0.5 hour and one hour, and keeping the reflow status to implement thermal insulation reaction for two hours to three hours after the dropping is completed; and (5) cooling and discharging to obtain the weather-resistant resin for the hot-stamping film.
Description
Technical field
The present invention relates to a kind of weathering resistance resin and preparation method thereof, relate in particular to a kind of blocking film weathering resistance resin and preparation method thereof.
Background technology
Blocking film is a kind ofly to be coated with the laminated film that parting agent, pigment, heat-sensitive resin form at plastics film, the coating of this film can be transferred on the printable fabric applying under certain temperature and the pressure, therefore, the thermoprint film can substitute now widely used silk screen printing, roll marks, spraying, brushing etc., and for example the application of furniture, electrical equipment surface color layer all can substitute with the thermoprint technology.The advantage of thermoprint technology is significantly to improve user's operating environment, is different from traditional printing technology in color is adhered to the process of transfer, does not have a large amount of VOC dischargings during thermoprint, does not also need to carry out ink setting.
At present, important component part heat-sensitive resin as blocking film mainly plays binding function, generally speaking, can select different resin systems to obtain best interlayer attachment fastness for different printable fabrics, at present common, be widely used at paper and made of cloth-based material such as cerul resin, urethane resin, polyvinyl chloride (PVC) RESINS etc.As everyone knows, it not is high especially for products such as general application scenario such as indoor furniture, electrical equipment, clothes the weather-resistant property of coating being required.But some particular application for example thermoprint material that adopts of license plate, traffic mark board, billboard require just high especially to the weathering resistance of heat-sensitive resin, therefore, this heat-sensitive resin also need satisfy the tolerance requirement of the factor such as impact, gasoline corrosion of outdoor complex conditions such as uviolizing, dust storm except the requirement that will satisfy adhesion property.
Summary of the invention
The present invention is directed to the tolerance requirement that can't satisfy outdoor complex conditions that exists in the prior art, provide a kind of and have that UV resistant irradiation, anti-blown sand performance are strong, the blocking film of the excellent performance of anti-the gasoline corrosion is with weathering resistance resin and preparation method thereof.
In order to solve the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of blocking film preparation method of weathering resistance resin is characterized in that comprising the composition preparation of following weight proportion:
Hard monomer 21-24,
Soft monomer 6-9,
Solvent 67-73,
Initiator 0.0135-0.066;
Preparation process is as follows:
(1) takes by weighing vinylformic acid hard monomer and the vinylformic acid soft monomer of above-mentioned weight ratio, all mix;
(2) take by weighing 40% of the total monomer weight that mixed in the above-mentioned steps (1), take by weighing above-mentioned weight of solvent than 30% of total amount, mix, enter reactor and be heated to backflow;
(3) take by weighing above-mentioned weight of solvent than total amount 40%, take by weighing above-mentioned initiator weight ratio total amount 70% with after step (2) takes by weighing whole monomers of remainder mix, be added drop-wise in the described reactor of step (2), time for adding is 1-1.5 hour, keeps the reflux state insulation reaction after being added dropwise to complete 1-2 hour again;
(4) take by weighing weight of solvent than 30% of total amount, with will after above-mentioned steps (3) take by weighing, mix by whole initiators of remainder, be added drop-wise in the described reactor of step (3), time for adding is 0.5-1 hour, keeps the reflux state insulation reaction after being added dropwise to complete 2-3 hour again;
(5) cooling discharging namely gets a kind of blocking film weathering resistance resin.
Prepare blocking film weathering resistance resin by above-mentioned steps, owing to adopt reaction step by step, can avoid discharging amount of heat, explosion caused danger; In the control reaction times step by step, can better control molecular weight and the second-order transition temperature of resin, thereby make the weathering resistance of resin and tack good.
As preferably, above-mentioned a kind of blocking film is with the preparation method of weathering resistance resin, and described initiator weight is the 0.056%-0.182% of vinylformic acid hard monomer and vinylformic acid soft monomer total amount.Select the initiator in the above-mentioned scope, monomer conversion is best, and the properties of resin is excellent, is embodied in: the anti-blown sand performance is strong, the excellent performance of anti-gasoline corrosion the, UV resistant irradiation; Initiator weighs less than 0.056% of vinylformic acid hard monomer and vinylformic acid soft monomer total amount, and reaction not exclusively; Initiator weight is higher than 0.182% of vinylformic acid hard monomer and vinylformic acid soft monomer total amount, can cause the waste of initiator, and cost increases.
As preferably, above-mentioned a kind of blocking film is with the preparation method of weathering resistance resin, and described initiator is benzoyl peroxide.Select this initiator, can make the reaction of monomer more complete, effectively control reaction efficiency.Initiator also can be selected azo-bis-isobutyl cyanide or azo two cyanogen in different heptan.
As preferably, above-mentioned a kind of blocking film preparation method of weathering resistance resin, described solvent is that the formulated in combination of any one or two kinds of components in toluene or the methyl iso-butyl ketone (MIBK) forms, and the weight ratio of the formulated in combination of described toluene and two kinds of components of methyl iso-butyl ketone (MIBK) is 1: 1 to 3: 1.Select above-mentioned solvent or its combination, can effectively control the temperature of reaction of monomer, reduce reaction system viscosity, it is fully reacted.Solvent also can be selected the combination of vinyl acetic monomer or N-BUTYL ACETATE or vinyl acetic monomer and toluene, or N-BUTYL ACETATE and two kinds of components of toluene are formulated.
As preferably, above-mentioned a kind of blocking film is with the preparation method of weathering resistance resin, and described vinylformic acid hard monomer comprises any in methyl methacrylate or β-dimethyl-aminoethylmethacrylate or the vinylbenzene.
As preferably, above-mentioned a kind of blocking film preparation method of weathering resistance resin, described vinylformic acid hard monomer is that the formulated in combination of methyl methacrylate and two kinds of components of β-dimethyl-aminoethylmethacrylate forms, and the weight ratio of the formulated in combination of described methyl methacrylate and two kinds of components of β-dimethyl-aminoethylmethacrylate is 4: 1 to 7: 1.
As preferably, above-mentioned a kind of blocking film preparation method of weathering resistance resin, described vinylformic acid hard monomer is that the formulated in combination of methyl methacrylate and two kinds of components of vinylbenzene forms, and the weight ratio of the formulated in combination of described methyl methacrylate and two kinds of components of vinylbenzene is 10:1 to 15:1.
Select aforesaid propylene acid hard monomer or its combination, can make the weathering resistance of resin, anti-deformation behavior, solvent resistance better.
As preferably, above-mentioned a kind of blocking film preparation method of weathering resistance resin, described vinylformic acid soft monomer is that the formulated in combination of any or any two component in butyl methacrylate or methyl acrylate or the vinyl acetate forms, the weight ratio of the formulated in combination of described butyl methacrylate and two kinds of components of methyl acrylate is 3:1 to 5:1, the weight ratio of the formulated in combination of described butyl methacrylate and two kinds of components of vinyl acetate is 5:1 to 8:1, and the weight ratio of the formulated in combination of described methyl acrylate and two kinds of components of vinyl acetate is 4:3 to 7:3.Select the aching and limp monomer of aforesaid propylene or its combination, can make the snappiness of resin, ductility better, improve simultaneously its attachment fastness.
A kind of blocking film weathering resistance resin prepares gained by above-mentioned any blocking film with the preparation method of weathering resistance resin.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail, but they are not limitations of the present invention:
Embodiment 1
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
21 parts of vinylformic acid hard monomers, 6 parts of vinylformic acid soft monomers, 67 parts of solvents, 0.0135 part of initiator, preparation process is as follows:
(1) takes by weighing vinylformic acid hard monomer and the vinylformic acid soft monomer of above-mentioned weight ratio, all mix;
(2) take by weighing 40% of the total monomer weight that mixed in the above-mentioned steps (1), take by weighing above-mentioned weight of solvent than 30% of total amount, mix, enter reactor and be heated to backflow;
(3) take by weighing above-mentioned weight of solvent than total amount 40%, take by weighing above-mentioned initiator weight ratio total amount 70% with after step (2) takes by weighing whole monomers of remainder mix, be added drop-wise in the described reactor of step (2), time for adding is 1-1.5 hour, keeps the reflux state insulation reaction after being added dropwise to complete 1-2 hour again;
(4) take by weighing weight of solvent than 30% of total amount, with will after above-mentioned steps (3) take by weighing, mix by whole initiators of remainder, be added drop-wise in the described reactor of step (3), time for adding is 0.5-1 hour, keeps the reflux state insulation reaction after being added dropwise to complete 2-3 hour again;
(5) cooling discharging namely gets a kind of blocking film weathering resistance resin.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 2
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
21 parts of vinylformic acid hard monomers, 9 parts of vinylformic acid soft monomers, 73 parts of solvents, 0.066 part of initiator.
Solvent is the combination of toluene and methyl iso-butyl ketone (MIBK), and two kinds of component weight ratios are controlled at 1:1 to 3:1 and prepare.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 3
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
24 parts of vinylformic acid hard monomers, 9 parts of vinylformic acid soft monomers, 73 parts of solvents, 0.066 part of initiator.
The vinylformic acid hard monomer is that the formulated in combination of methyl methacrylate and two kinds of components of β-dimethyl-aminoethylmethacrylate forms, and the weight ratio of the formulated in combination of described methyl methacrylate and two kinds of components of β-dimethyl-aminoethylmethacrylate is controlled at 4:1 to 7:1.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 4
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
24 parts of vinylformic acid hard monomers, 6 parts of vinylformic acid soft monomers, 67 parts of solvents, 0.0135 part of initiator.
The vinylformic acid hard monomer is that the formulated in combination of methyl methacrylate and two kinds of components of vinylbenzene forms, and the weight ratio of the formulated in combination of described methyl methacrylate and two kinds of components of vinylbenzene is controlled at 10:1 to 15:1.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 5
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
22 parts of vinylformic acid hard monomers, 7 parts of vinylformic acid soft monomers, 70 parts of solvents, 0.0135 part of initiator.
The vinylformic acid soft monomer is that the formulated in combination of butyl methacrylate and two kinds of components of methyl acrylate forms, and the weight ratio of the formulated in combination of described butyl methacrylate and two kinds of components of methyl acrylate is controlled at 3:1 to 5:1.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
Embodiment 6
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
23 parts of vinylformic acid hard monomers, 8 parts of vinylformic acid soft monomers, 71 parts of solvents, 0.04 part of initiator.
The vinylformic acid soft monomer is that the formulated in combination of butyl methacrylate and two kinds of components of vinyl acetate forms, and the weight ratio of the formulated in combination of described butyl methacrylate and two kinds of components of vinyl acetate is controlled at 5:1 to 8:1.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
Embodiment 7
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
24 parts of vinylformic acid hard monomers, 6 parts of vinylformic acid soft monomers, 73 parts of solvents, 0.066 part of initiator.
The vinylformic acid soft monomer is that the formulated in combination of methyl acrylate and two kinds of components of vinyl acetate forms, and the weight ratio of the formulated in combination of described methyl acrylate and two kinds of components of vinyl acetate is controlled at 4:3 to 7:3.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
Embodiment 8
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
24 parts of vinylformic acid hard monomers, 9 parts of vinylformic acid soft monomers, 67 parts of solvents, 0.066 part of initiator.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 9
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
21 parts of vinylformic acid hard monomers, 9 parts of vinylformic acid soft monomers, 67 parts of solvents, 0.02 part of initiator.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 10
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
21 parts of vinylformic acid hard monomers, 6 parts of vinylformic acid soft monomers, 73 parts of solvents, 0.0135 part of initiator.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 11
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
24 parts of vinylformic acid hard monomers, 9 parts of vinylformic acid soft monomers, 73 parts of solvents, 0.0135 part of initiator.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 12
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
21 parts of vinylformic acid hard monomers, 6 parts of vinylformic acid soft monomers, 67 parts of solvents, 0.066 part of initiator.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 13
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
21 parts of vinylformic acid hard monomers, 6 parts of vinylformic acid soft monomers, 73 parts of solvents, 0.015 part of initiator.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid hard monomer is preferably selected methyl methacrylate or β-dimethyl-aminoethylmethacrylate or vinylbenzene.
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
Embodiment 14
A kind of blocking film preparation method of weathering resistance resin comprises the composition preparation of following weight proportion:
24 parts of vinylformic acid hard monomers, 6 parts of vinylformic acid soft monomers, 67 parts of solvents, 0.06 part of initiator.
The vinylformic acid hard monomer is that the formulated in combination of methyl methacrylate and two kinds of components of vinylbenzene forms, and the weight ratio of the formulated in combination of described methyl methacrylate and two kinds of components of vinylbenzene is controlled at 10:1 to 15:1.
The proportioning of other component and implementation step are with above-mentioned embodiment 1.
Initiator is preferably benzoyl peroxide.
Solvent is preferably selected toluene or methyl iso-butyl ketone (MIBK).
The vinylformic acid soft monomer is preferably selected butyl methacrylate or methyl acrylate or vinyl acetate.
In a word, the above only is preferred embodiment of the present invention, and all equalizations of doing according to the scope of the present patent application patent change and modify, and all should belong to covering scope of the present invention.
Claims (9)
1. a blocking film is characterized in that: comprise the composition preparation of following weight proportion with the preparation method of weathering resistance resin:
Vinylformic acid hard monomer 21-24,
Vinylformic acid soft monomer 6-9,
Solvent 67-73,
Initiator 0.0135-0.066;
Preparation process is as follows:
(1) takes by weighing vinylformic acid hard monomer and the vinylformic acid soft monomer of above-mentioned weight ratio, all mix;
(2) take by weighing 40% of the total monomer weight that mixed in the above-mentioned steps (1), take by weighing above-mentioned weight of solvent than 30% of total amount, mix, enter reactor and be heated to backflow;
(3) take by weighing above-mentioned weight of solvent than total amount 40%, take by weighing 70% of above-mentioned initiator weight ratio total amount, with take by weighing through step (2) after whole monomers of remainder mix, be added drop-wise in the described reactor of step (2), time for adding is 1-1.5 hour, keeps the reflux state insulation reaction after being added dropwise to complete 1-2 hour again;
(4) take by weighing weight of solvent than 30% of total amount, with will after above-mentioned steps (3) take by weighing, mix by whole initiators of remainder, be added drop-wise in the described reactor of step (3), time for adding is 0.5-1 hour, keeps the reflux state insulation reaction after being added dropwise to complete 2-3 hour again;
(5) cooling discharging namely gets a kind of blocking film weathering resistance resin.
2. a kind of blocking film according to claim 1 is with the preparation method of weathering resistance resin, and it is characterized in that: described initiator weight is the 0.056%-0.182% of vinylformic acid hard monomer and vinylformic acid soft monomer total amount.
3. a kind of blocking film according to claim 1 is with the preparation method of weathering resistance resin, and it is characterized in that: described initiator is benzoyl peroxide.
4. a kind of blocking film according to claim 1 is with the preparation method of weathering resistance resin, it is characterized in that: described solvent is that the formulated in combination of any one or two kinds of components in toluene or the methyl iso-butyl ketone (MIBK) forms, and the weight ratio of the formulated in combination of described toluene and two kinds of components of methyl iso-butyl ketone (MIBK) is 1: 1 to 3: 1.
5. a kind of blocking film according to claim 1 is with the preparation method of weathering resistance resin, and it is characterized in that: described vinylformic acid hard monomer comprises any in methyl methacrylate or β-dimethyl-aminoethylmethacrylate or the vinylbenzene.
6. a kind of blocking film according to claim 1 is with the preparation method of weathering resistance resin, it is characterized in that: described vinylformic acid hard monomer is that the formulated in combination of methyl methacrylate and two kinds of components of β-dimethyl-aminoethylmethacrylate forms, and the weight ratio of the formulated in combination of described methyl methacrylate and two kinds of components of β-dimethyl-aminoethylmethacrylate is 4: 1 to 7: 1.
7. a kind of blocking film according to claim 1 is with the preparation method of weathering resistance resin, it is characterized in that: described vinylformic acid hard monomer is that the formulated in combination of methyl methacrylate and two kinds of components of vinylbenzene forms, and the weight ratio of the formulated in combination of described methyl methacrylate and two kinds of components of vinylbenzene is 10:1 to 15:1.
8. a kind of blocking film according to claim 1 is with the preparation method of weathering resistance resin, it is characterized in that: described vinylformic acid soft monomer is that the formulated in combination of any or any two component in butyl methacrylate or methyl acrylate or the vinyl acetate forms, the weight ratio of the formulated in combination of described butyl methacrylate and two kinds of components of methyl acrylate is 3:1 to 5:1, the weight ratio of the formulated in combination of described butyl methacrylate and two kinds of components of vinyl acetate is 5:1 to 8:1, and the weight ratio of the formulated in combination of described methyl acrylate and two kinds of components of vinyl acetate is 4:3 to 7:3.
9. blocking film weathering resistance resin, it is characterized in that: the preparation method with the weathering resistance resin makes by any blocking film among the claim 1-8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310030877.0A CN103059209B (en) | 2013-01-28 | 2013-01-28 | Weather-resistant resin for hot-stamping film and preparation method of resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310030877.0A CN103059209B (en) | 2013-01-28 | 2013-01-28 | Weather-resistant resin for hot-stamping film and preparation method of resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103059209A true CN103059209A (en) | 2013-04-24 |
| CN103059209B CN103059209B (en) | 2015-04-15 |
Family
ID=48102129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310030877.0A Active CN103059209B (en) | 2013-01-28 | 2013-01-28 | Weather-resistant resin for hot-stamping film and preparation method of resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103059209B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694933A (en) * | 2013-12-09 | 2014-04-02 | 佛山市南海高拓包装材料有限公司 | Acrylic ester modified adhesive, preparation method thereof and application method of benzene-free hot melt adhesive |
| CN104004476A (en) * | 2014-05-13 | 2014-08-27 | 佛山市南海高拓包装材料有限公司 | Adhesive for electrochemical aluminium hot stamping and preparation method thereof and electrochemical aluminium |
| CN107384263A (en) * | 2017-08-18 | 2017-11-24 | 佛山市永恒达新材料科技有限公司 | The adhesive of high durable, high-adhesive-strength |
| CN108102021A (en) * | 2017-12-30 | 2018-06-01 | 张义群 | Highlighted thermoprint packing box glazing transfer membrane and its manufacture craft |
| CN109651559A (en) * | 2018-12-11 | 2019-04-19 | 上海绘兰材料科技有限公司 | A kind of release-free scalds cloth anodized aluminium acrylic resin and its preparation method and application |
| CN110435320A (en) * | 2019-08-14 | 2019-11-12 | 河南科技大学 | A kind of no-solvent type heat transfer film for soft infusion bag and its production technology |
| CN115340833A (en) * | 2021-12-02 | 2022-11-15 | 广东邦固化学科技有限公司 | Environment-friendly water-based gum for tipping paper hot stamping film for high-speed stamping and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106893534A (en) * | 2017-03-02 | 2017-06-27 | 浙江龙游道明光学有限公司 | For road sign reflective membrane hot soarfing from pressure sensitive adhesive and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050217789A1 (en) * | 2001-12-07 | 2005-10-06 | Axel Eckstein | Hot melt acrylic pressure sensitive adhesive and use thereof |
| CN101280165A (en) * | 2008-05-21 | 2008-10-08 | 山东福源聚氨酯工业有限公司 | Hot-transfer thermoprinting adhesive for electrical aluminum |
-
2013
- 2013-01-28 CN CN201310030877.0A patent/CN103059209B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050217789A1 (en) * | 2001-12-07 | 2005-10-06 | Axel Eckstein | Hot melt acrylic pressure sensitive adhesive and use thereof |
| CN101280165A (en) * | 2008-05-21 | 2008-10-08 | 山东福源聚氨酯工业有限公司 | Hot-transfer thermoprinting adhesive for electrical aluminum |
Non-Patent Citations (2)
| Title |
|---|
| 林旭荣等: ""溶剂型热熔转印胶的研制"", 《厦门大学学报（自然科学版）》 * |
| 潘祖仁: "《高分子化学》", 30 June 1997, 化学工业出版社 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694933A (en) * | 2013-12-09 | 2014-04-02 | 佛山市南海高拓包装材料有限公司 | Acrylic ester modified adhesive, preparation method thereof and application method of benzene-free hot melt adhesive |
| CN103694933B (en) * | 2013-12-09 | 2016-02-10 | 佛山市南海高拓包装材料有限公司 | A kind of acrylate modified glue and preparation method and without benzene hot melt adhesive and application method |
| CN104004476A (en) * | 2014-05-13 | 2014-08-27 | 佛山市南海高拓包装材料有限公司 | Adhesive for electrochemical aluminium hot stamping and preparation method thereof and electrochemical aluminium |
| CN104004476B (en) * | 2014-05-13 | 2017-07-07 | 佛山市南海高拓包装材料有限公司 | Adhesive for electrochemical aluminium thermoprinting and preparation method thereof and anodized aluminium |
| CN107384263A (en) * | 2017-08-18 | 2017-11-24 | 佛山市永恒达新材料科技有限公司 | The adhesive of high durable, high-adhesive-strength |
| CN108102021A (en) * | 2017-12-30 | 2018-06-01 | 张义群 | Highlighted thermoprint packing box glazing transfer membrane and its manufacture craft |
| CN109651559A (en) * | 2018-12-11 | 2019-04-19 | 上海绘兰材料科技有限公司 | A kind of release-free scalds cloth anodized aluminium acrylic resin and its preparation method and application |
| CN109651559B (en) * | 2018-12-11 | 2021-11-09 | 上海绘兰材料科技有限公司 | Acrylic resin for release-free ironing cloth electrochemical aluminum and preparation method and application thereof |
| CN110435320A (en) * | 2019-08-14 | 2019-11-12 | 河南科技大学 | A kind of no-solvent type heat transfer film for soft infusion bag and its production technology |
| CN110435320B (en) * | 2019-08-14 | 2021-08-03 | 河南科技大学 | Production process of heat transfer film for solvent-free infusion soft bag |
| CN115340833A (en) * | 2021-12-02 | 2022-11-15 | 广东邦固化学科技有限公司 | Environment-friendly water-based gum for tipping paper hot stamping film for high-speed stamping and preparation method thereof |
| CN115340833B (en) * | 2021-12-02 | 2023-11-10 | 广东邦固化学科技有限公司 | Environment-friendly aqueous back glue for tipping paper thermoprinting film for high-speed ironing and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103059209B (en) | 2015-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103059209B (en) | Weather-resistant resin for hot-stamping film and preparation method of resin | |
| CN103468179B (en) | Casting polypropylene protection film pressure-sensitive adhesive, casting polypropylene protection film and their preparation methods | |
| CN101654604B (en) | Composition of acrylic pressure-sensitive adhesive and surface finishing material comprising the same | |
| CN103788901B (en) | High temperature resistant pressure sensitive adhesive adhesive composition, preparation method and double-faced adhesive tape | |
| CN108136632A (en) | Decorating film and its manufacturing method and decorated molded article | |
| CN102351979B (en) | Acrylic resin coating liquid for alumite coloring layer and preparation method thereof | |
| US20180142118A1 (en) | Low-voc-emission waterborne coating having high hardness and good adhesion and process for producing the same | |
| CN102643591B (en) | Resin composition for thermal transfer protection layer, thermal transfer film using resin composition and thermal transfer method | |
| CN104178017A (en) | Optical-thermal double-solidified baikeding for tinplate and coating method thereof | |
| CA2466611C (en) | Heat-curable resin composition | |
| CN101679796B (en) | Method for applying corrosion protection coatings to metal surfaces | |
| CN103524667A (en) | Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof | |
| CN104877446B (en) | A kind of ultraviolet hot dual cure glass ink and preparation method thereof | |
| CN101925642A (en) | Method for producing coated rubber particles and coated rubber particles | |
| TW201842126A (en) | Adhesive composition and adhesive sheet | |
| CN104479507A (en) | Ultraviolet-cured resin composition and application thereof as solder resist | |
| CN104004476A (en) | Adhesive for electrochemical aluminium hot stamping and preparation method thereof and electrochemical aluminium | |
| CN103937377A (en) | Low gloss ultraviolet curing coating | |
| CN104263311B (en) | UV (ultraviolet) cold stamping glue | |
| CN101497680B (en) | Alcohol water-soluble copolymer resin, preparation and application thereof | |
| CN104356924A (en) | Ultraviolet curing coating | |
| CN101440248A (en) | Preparation of epoxy acroleic acid anticorrosive paint | |
| CN104910758A (en) | High-strength antibacterial ultraviolet-curable coating | |
| CN104672394A (en) | Polystyrene-polyurethane-unsaturated polyester copolymer and preparation method thereof | |
| CN105566582A (en) | Preparation method of aqueous anti-corrosive epoxy resin acrylate emulsion |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: ZHEJIANG LONGYOU DAOMING OPTICAL CO., LTD. Free format text: FORMER OWNER: DAOMING OPTICS + CHEMICALS CO., LTD. Effective date: 20150714 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20150714 Address after: 324400, No. 7 Xingye Road, Chengnan industrial town, Donghua street, Longyou County, Zhejiang, Quzhou Patentee after: Zhejiang Longyou Daoming Optical Co., Ltd. Address before: 321300, No. 1 Yingbin Road, No. 3, elephant Pearl Industrial Zone, Jinhua, Zhejiang, Yongkang Patentee before: Zhejiang Daoming Optics & Chemical Co., Ltd. |