Summary of the invention
The purpose of this invention is to provide a kind of nuclear power generating sets member chrome-plated process.
The technical solution used in the present invention is:
Nuclear power generating sets member chrome-plated process comprises following treatment step: plating front surface treatment step, chromium plating treatment step and plating rear surface treatment step,
Described plating front surface treatment step is:
A, oil removal treatment: part is put into cleaned 10-20 minute in the acetone solution of 100% concentration until clean, be neutral with flushing with clean water again, then artificial scrub;
B, frock protection: according to the difference of part shape, and the requirement at coating position, select corresponding tooling device and supplementary anode equipment to install, to protect non-coating especially, and clean with flushing with clean water;
C, acid activation process: the part that upper step is obtained puts into that activation was neutral with flushing with clean water after 1-2 minute in the groove of the sulfuric acid liquid that fills 5% concentration;
Described chromium plating treatment step is: the part that will handle well in above-mentioned steps is put into 50 ℃-60 ℃ tank preheating 3-10 minute, electroplate liquid is heated to 50 ℃-60 ℃ again, puts into plating piece, and current density is 20-46A/dm
2, rush current density is 50-70 A/dm
2, adopt the staged power supply, the chromium plating time is 25-30 minute;
Described plating rear surface treatment step is: use again with after the flushing with clean water cleaning 〉=hot water injection 10-30 second of 80 ℃, be neutrality with pure water rinsing again after, remove frock, washing dries up and gets final product.
Warm up time in the described chromium plating treatment step, the thickness according to the part wall changed, and 1 centimetre of the every increase of thickness then heating needs to increase by 1 minute.
The composition of described electroplate liquid is chromic acid, sulfuric acid, trivalent chromium and iron contamination, and the mass concentration ratio between described chromic acid, sulfuric acid, trivalent chromium, the iron contamination is (200-300): (2.2-3.5): (1-5): (1-7.5).
Determine according to distance and the thickness of coating of anode and cathode the heat-up time of the electroplate liquid in the described chromium plating treatment step.
Advantage of the present invention is: the good uniformity of the part coating that this chrome-plated process is made; bonding force is strong; compactness is good; superpower wear-resisting and erosion resistance is arranged; can reach the coating standard of nuclear three generation products; in frock protection process; the tooling device of selecting reaches smooth smooth effect without sharp trace to the junction between coating and the non-coating; when making the even Zai of inner bore of part thickness of coating Du Chrome, adopts supplementary anode equipment the staged power supply; can make coating uniformity good and bonding force is strong; proportioning in the electroplate liquid between each composition is so that the bonding force that part reaches in the process of chromium plating is strong; smooth finish is good; erosion resistance is good; the effect that coating hardness is high.
Embodiment
Embodiment 1
Nuclear power generating sets member chrome-plated process of the present invention comprises following treatment step: plating front surface treatment step, chromium plating treatment step and plating rear surface treatment step,
Plating front surface treatment step is:
A, oil removal treatment: part is put into cleaned 10 minutes in the acetone solution of 100% concentration until clean, be neutral with flushing with clean water again, then artificial scrub;
B, frock protection: according to the difference of part shape, and the requirement at coating position, select corresponding tooling device and supplementary anode equipment to install, to protect non-coating especially, and clean with flushing with clean water;
C, acid activation process: the part that upper step is obtained puts into that activation was neutral with flushing with clean water after 1 minute in the groove of the sulfuric acid liquid that fills 5% concentration;
The chromium plating treatment step is: the part that will handle well in above-mentioned steps is put into 50 ℃ tank preheating 3 minutes, electroplate liquid is heated to 50 ℃ again, and electroplate liquid is by chromic acid 200g/L, sulfuric acid 2.2g/L, trivalent chromium 1g/L and iron contamination 1g/L form, and put into plating piece, and current density is 20A/dm
2, rush current density is 50A/dm
2, adopt the staged power supply, the chromium plating time is 25 minutes;
Plating rear surface treatment step is: with the hot water injection 10 seconds who uses again 80 ℃ after the flushing with clean water cleaning, be neutrality with pure water rinsing again after, remove frock, washing dries up and gets final product.
Embodiment 2
Nuclear power generating sets member chrome-plated process of the present invention comprises following treatment step: plating front surface treatment step, chromium plating treatment step and plating rear surface treatment step,
Plating front surface treatment step is:
A, oil removal treatment: part is put into cleaned 15 minutes in the acetone solution of 100% concentration until clean, be neutral with flushing with clean water again, then artificial scrub;
B, frock protection: according to the difference of part shape, and the requirement at coating position, select corresponding tooling device and supplementary anode equipment to install, to protect non-coating especially, and clean with flushing with clean water;
C, acid activation process: the part that upper step is obtained puts into that activation was neutral with flushing with clean water after 2 minutes in the groove of the sulfuric acid liquid that fills 5% concentration;
The chromium plating treatment step is: the part that will handle well in above-mentioned steps is put into 55 ℃ tank preheating 7 minutes, electroplate liquid is heated to 55 ℃ again, electroplate liquid is comprised of chromic acid 250g/L, sulfuric acid 2.8g/L, trivalent chromium 2.5g/L and iron contamination 3.5g/L, puts into plating piece, and current density is 30A/dm
2, rush current density is 60A/dm
2, adopt the staged power supply, the chromium plating time is 28 minutes;
Plating rear surface treatment step is: with the hot water injection 20 seconds who uses again 90 ℃ after the flushing with clean water cleaning, be neutrality with pure water rinsing again after, remove frock, washing dries up and gets final product.
Embodiment 3
Nuclear power generating sets member chrome-plated process of the present invention comprises following treatment step: plating front surface treatment step, chromium plating treatment step and plating rear surface treatment step,
Plating front surface treatment step is:
A, oil removal treatment: part is put into cleaned 20 minutes in the acetone solution of 100% concentration until clean, be neutral with flushing with clean water again, then artificial scrub;
B, frock protection: according to the difference of part shape, and the requirement at coating position, select corresponding tooling device and supplementary anode equipment to install, to protect non-coating especially, and clean with flushing with clean water;
C, acid activation process: the part that upper step is obtained puts into that activation was neutral with flushing with clean water after 2 minutes in the groove of the sulfuric acid liquid that fills 5% concentration;
The chromium plating treatment step is: the part that will handle well in above-mentioned steps is put into 60 ℃ tank preheating 10 minutes, electroplate liquid is heated to 60 ℃ again, electroplate liquid is by chromic acid 300g/L, sulfuric acid 3.5g/L, trivalent chromium 5g/L), iron contamination 7.5g/L forms, and puts into plating piece, current density is 46A/dm
2, rush current density is 70 A/dm
2, adopt the staged power supply, the chromium plating time is 30 minutes;
Plating rear surface treatment step is: with using again 95 ℃ hot water injection 10-30 second after the flushing with clean water cleaning, be neutrality with pure water rinsing again after, remove frock, washing dries up and gets final product.