CN103045331B - Modified attapulgite rustic phase slow-release rust preventive oil and preparation method thereof - Google Patents
Modified attapulgite rustic phase slow-release rust preventive oil and preparation method thereof Download PDFInfo
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- CN103045331B CN103045331B CN201210547442.9A CN201210547442A CN103045331B CN 103045331 B CN103045331 B CN 103045331B CN 201210547442 A CN201210547442 A CN 201210547442A CN 103045331 B CN103045331 B CN 103045331B
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Abstract
The invention provides modified attapulgite rustic phase slow-release rust preventive oil. The oil is prepared by the following raw material comp onents in part by weight: 150 parts of solvent oil 120, 5 to 8 parts of rosin, 2 to 5 parts of zinc powder, 3 to 5 parts of sodium lauryl ether sulfate, 15 to 18 parts of liquefied paraffin, 3 to 5 parts of 3-aminopropyl trimethoxy silane, 10 to 15 parts of triethylene diamine, 10 to 13 parts of epoxidized soybean oil, 10 to 15 parts of dimethylbenzene, 5 to 8 parts of cross-linking agent TAIC, 1 to 2 parts of ferrocene, 3 to 6 parts of polyisobutene, 1 to 2 parts of N-phenyl-2-naphthylamine, 1 to 3 parts of benzotriazole, 1 to 2 parts of 2-aminoethyl heptadecenyl imidazoline, 1 to 2 parts of 1-hydroxy benzotriazole, 2 to 3 parts of zinc dialkyl dithiophosphate, 1 to 2 parts of sodium dodecyl benzene sulfonate, 5 to 7 parts of simethicone, 12 to 14 parts of epoxy tetrahydrogen dioctyl phthalate, 5 to 6 parts of film-forming resin and 1 to 2 parts of modified attapulgite. The gas phase rust preventive oil has excellent rust preventive performance and a remarkable contact rust resistant effect, so that the oil can be widely applied in the rust prevention for inner cavities or other contact or non-contact metal parts of mechanical equipment.
Description
Technical field
The present invention relates to a kind of volatile rust preventive oil, belong to metal rust preventing technical field.
Background technology
Corrosion of metal problem spreads all over national economy all trades and professions, and corrosion of metal meeting makes the performance of metal products and commodity value be subject to great infringement, even can cause significant trouble and make equipment scrapping.According to statistics, the direct economic loss causing due to corrosion of metal every year accounts for the 2%-4% of total value of production in national economy, calculate with China GDP18.23 trillion yuan Renminbi in 2005, the loss that China causes because of corrosion the whole year at least reaches more than 36,000,000,000 yuan, and its harm is very surprising.For avoiding corrosion, people have adopted multiple technologies and method to prevent the generation of metallic corrosion.Wherein, protecting metal products with slushing oil is one of current modal means of defence.But existing slushing oil is all made up of base oil and oil-soluble inhibitor, can only play the antirust function of contact, the position that does not reach slushing oil for those, can not form effective corrosion protection.And vapor phase inhibitor technology is one of current non contact metal rust-proofing method.It is to utilize vapour-phase inhibitor automatically to volatilize and give vent to anger at normal temperatures
Body forms protective membrane in metallic surface, plays the effect that suppresses metallic corrosion.During World War II, due to the antirust needs of armament equipment, vapor phase inhibitor technology starts application and development.For many years, many developed countries national defence and civilian aspect all adopt in a large number vapour-phase inhibitor to be used for metal rust preventing, product form has volatile rust prevention powder, volatile rust preventive paper, gas phase anti-tarnishing film, gas-phase anti-corrosion paint etc.At industrial circle, abroad vapour-phase inhibitor is widely used in antirust in metal product production, transport, use and storage process by some large enterprises.
The present invention, by base oil and the combination of a kind of oil soluble vapour-phase inhibitor, makes a kind of volatile rust preventive oil, because this slushing oil contains vapor phase inhibitor, thereby in the time of rust-proof seal, oil be stained with less than position also because the effect of vapor phase inhibitor is protected.At home, the antirust problem of the special gear box of engine, large-scale compressor etc. does not thoroughly solve always.
Summary of the invention
The object of this invention is to provide a kind of attapulgite modified gas phase slowly-releasing slushing oil, this volatile rust preventive oil had both had the rust-preventing characteristic of slushing oil contact, had again the high-performance of vapour-phase inhibitor volatile rust prevention.The present invention can be widely used in the antirust for a long time of weaponry and civilian metallic substance, is mainly used in airtight inner chamber system.Various metals are had to antirust function more.
Technical scheme of the present invention is as follows:
A kind of attapulgite modified gas phase slowly-releasing slushing oil, is characterized in that, its feed composition by following weight part is prepared from:
No. 120 solvent oils 150, ferrocene 1-2, polyisobutene 3-6, N-phenyl-2-naphthylamine 1-2, benzotriazole 1-3,2-aminoethyl 17 alkenyl imidazoline 1-2,1-hydroxy benzo triazole 1-2, zinc dialkyl dithiophosphate 2-3, Sodium dodecylbenzene sulfonate 1-2, dimethyl silicone oil 5-7, epoxy tetrahydro-2-ethylhexyl phthalate 12-14, film-forming resin 5-6, attapulgite modified 1-2.
Described attapulgite modified gas phase slowly-releasing slushing oil, is characterized in that, its feed composition by following weight part is prepared from:
No. 120 solvent oils 150, ferrocene 1.5, polyisobutene 5, N-phenyl-2-naphthylamine 2, benzotriazole 2,2-aminoethyl 17 alkenyl imidazolines 1.5,1-hydroxy benzo triazole 1.5, zinc dialkyl dithiophosphate 2.5, Sodium dodecylbenzene sulfonate 1.5, dimethyl silicone oil 6, epoxy tetrahydro-2-ethylhexyl phthalate 13, film-forming resin 5.5, attapulgite modified 1.5.
Described attapulgite modified gas phase slowly-releasing slushing oil, is characterized in that: described film-forming resin is made according to the following steps:
(1) sodium lauryl tri(oxyethyl) sulfate, liquefied petrolatum, 3-aminopropyl trimethoxysilane, triethylene diamine, epoxy soybean oil, dimethylbenzene, linking agent TAIC are added to stainless steel cauldron, be warming up to 110 ± 5 DEG C, start to stir and add rosin, zinc powder, wherein, sodium lauryl tri(oxyethyl) sulfate: liquefied petrolatum: 3-aminopropyl trimethoxysilane: triethylene diamine: epoxy soybean oil: dimethylbenzene: linking agent TAIC: rosin: the mass ratio of zinc powder is: 3-5:15-18:3-5:10-15:10-13:10-15:5-8:5-8:2-5;
(2) be then warmed up to 205 ± 2 DEG C with 30-40 DEG C/h of speed;
(3) below acid number reaches 15mgKOH/g time, stop heating, put to dilution still;
(4) be cooled to 70 ± 5 DEG C to stir evenly and obtain film-forming resin.
Described attapulgite modified gas phase slowly-releasing slushing oil, is characterized in that: described attapulgite modifiedly make according to the following steps:
(1), attapulgite is used 15-20% dioxygen bubble after 2-3 hour, then by extremely neutrality of deionized water wash, is dried;
(2), in attapulgite, add and be equivalent to the aluminium hydrate powder of its weight 1-2%, the Sodium orthomolybdate of 2-3%, the linking agent TAC of 1-2%, high speed 4500-4800 rev/min of stirring, 20-30 minute, ovendry power is broken into 500-600 order powder.
The preparation method of attapulgite modified gas phase slowly-releasing slushing oil: be first prepared into film resin and attapulgite modified, then by formula requirement by various compositions mix and blend 30-40 minute at 80-90 DEG C, cooled and filtered.
Beneficial effect of the present invention:
This volatile rust preventive oil had both had the antirust characteristic of contact, had again the high-performance of vapour-phase inhibitor volatile rust prevention; This volatile rust preventive oil has rust inhibition to various metals such as gun-steel, A3 steel, 45# steel, 20# steel, brass, zinc-plated, chromium plating.
embodiment:
Embodiment
Attapulgite modified gas phase slowly-releasing slushing oil, its feed composition by following weight part is prepared from:
No. 120 solvent oils 150, ferrocene 1.5, polyisobutene 5, N-phenyl-2-naphthylamine 2, benzotriazole 2,2-aminoethyl 17 alkenyl imidazolines 1.5,1-hydroxy benzo triazole 1.5, zinc dialkyl dithiophosphate 2.5, Sodium dodecylbenzene sulfonate 1.5, dimethyl silicone oil 6, epoxy tetrahydro-2-ethylhexyl phthalate 13, film-forming resin 5.5, attapulgite modified 1.5;
Preparation method:
1, the preparation of film-forming resin:
(1) get 4 parts of sodium lauryl tri(oxyethyl) sulfates, 16 parts of liquefied petrolatums, 4 parts of 3-aminopropyl trimethoxysilane, 13 parts of triethylene diamines, 12 parts of epoxy soybean oils, 14 parts of dimethylbenzene, 7 parts of linking agent TAIC and add stainless steel cauldron, be warming up to 110 ± 5 DEG C, start stirring and add 4 parts of rosin, 3 parts of zinc powders;
(2) be then warmed up to 205 ± 2 DEG C with 30-40 DEG C/h of speed;
(3) below acid number reaches 15mgKOH/g time, stop heating, put to dilution still;
(4) be cooled to 70 ± 5 DEG C to stir evenly and obtain film-forming resin.
2, attapulgite modified preparation, make according to the following steps:
(1), attapulgite is used 15-20% dioxygen bubble after 2-3 hour, then by extremely neutrality of deionized water wash, is dried;
(2), in attapulgite, add and be equivalent to the aluminium hydrate powder of its weight 1-2%, the Sodium orthomolybdate of 2-3%, the linking agent TAC of 1-2%, high speed 4500-4800 rev/min of stirring, 20-30 minute, ovendry power is broken into 500-600 order powder.
3, the preparation of volatile rust preventive oil finished product
By formula requirement, by various components mix and blend 30-40 minute at 80-90 DEG C, cooled and filtered, makes volatile rust preventive oil finished product.
testing data
1, the performance of the volatile rust preventive oil to above-described embodiment detects, result table 1.
The technical indicator of table 1 volatile rust preventive oil
| Project | Result | Testing standard |
| The test of salt water logging pool | Qualified | SH/T0025-1999 |
| Humid heat test (10d) | Qualified | GB/T2361-1992 |
2, the slushing oil performance test of volatile rust preventive oil
(1) static state does not contact accelerated test
By the volatile rust preventive oil of the present invention of 5ml and 10ml, be placed in small beaker respectively, the method processing that metal testing plate (50mm × 25mm × 2mm) is specified by GB/T4879-1999 is placed in device, room temperature teleblem 24h, and electrolyte solution is respectively containing HCO
s-1000mg/L, SO
4 2-2500mg/L, C1
-1500mg/L, puts into large burning bosom, and electrolyte solution is remained to 40 DEG C.In addition, do not put slushing oil as blank test.Test-results is shown in Table 2.
table 2 static state does not contact accelerated test result
All there is corrosion without the steel class test piece 1h of slushing oil as shown in Table 2, also there is variable color and corrosion in brass, zinc-plated, chromium plating 2h, and when having 5ml slushing oil of the present invention, no matter be all to rise appreciably the test piece of steel class or antirust time of other test piece, and rust-proof effect is more obvious when having 10ml slushing oil of the present invention.This slushing oil of the present invention has volatile rust prevention effect.Thereby do not contact accelerated test by static state, show that volatile rust preventive oil of the present invention has good rust-proof effect to many metals.
(2) salt fog cabinet accelerated corrosion test
Test method is with reference to GJBI45A-1993 and SH/T0081-1991.After the method that three metal testing plate 50mm × 25mm × 2mm are specified by GB/T4879-1999 is processed, stand-by.To shake uniform 500ml slushing oil sample, remove specimen surface bubble, and adjust its temperature in (23 ± 3) DEG C, clean test piece is vertically immersed to 1min with suspension hook, then mention extension on the top of the shelf with the speed of about 100mm/min, then test piece is hung over to relative humidity below 70%, temperature (23 ± 3) DEG C, drains 24h without direct sunlight and the little clean place that ventilates.And then get three same metal testing plates and do blank test, the oil of blank test is No. 120 solvent oils.
The spraying salts solution of test use is 5% sodium chloride solution, and test temperature is 35 DEG C, spraying 3min, and interval 5min, salt fog sinkability is 1～2ml(80cm
2h).Test-results is shown in Table 3,
As shown in Table 3, the transformer that does not add oil soluble vapour-phase inhibitor compares, and this slushing oil has fine contact rust-proof effect, and salt spray corrosion resistance is better, and various metals is all had to good effect.
table 3 salt fog cabinet accelerated corrosion test result
Conclusion: do not contact accelerated test and salt fog cabinet accelerated corrosion test by static state, show that this volatile rust preventive oil has good antirust, there is again excellent contact rust-proof effect, thereby it can be widely used in the antirust of the inner chambers such as mechanical means or other contact or non-contacting metal.
Claims (3)
1. an attapulgite modified gas phase slowly-releasing slushing oil, is characterized in that, its feed composition by following weight part is prepared from:
No. 120 solvent oils 150, ferrocene 1-2, polyisobutene 3-6, N-phenyl-2-naphthylamine 1-2, benzotriazole 1-3,2-aminoethyl 17 alkenyl imidazoline 1-2,1-hydroxy benzo triazole 1-2, zinc dialkyl dithiophosphate 2-3, Sodium dodecylbenzene sulfonate 1-2, dimethyl silicone oil 5-7, epoxy tetrahydro-2-ethylhexyl phthalate 12-14, film-forming resin 5-6, attapulgite modified 1-2;
Described film-forming resin is made according to the following steps:
(1) sodium lauryl tri(oxyethyl) sulfate, liquefied petrolatum, 3-aminopropyl trimethoxysilane, triethylene diamine, epoxy soybean oil, dimethylbenzene, linking agent TAIC are added to stainless steel cauldron, be warming up to 110 ± 5 DEG C, start to stir and add rosin, zinc powder, wherein, sodium lauryl tri(oxyethyl) sulfate: liquefied petrolatum: 3-aminopropyl trimethoxysilane: triethylene diamine: epoxy soybean oil: dimethylbenzene: linking agent TAIC: rosin: the mass ratio of zinc powder is: 3-5:15-18:3-5:10-15:10-13:10-15:5-8:5-8:2-5;
(2) be then warmed up to 205 ± 2 DEG C with 30-40 DEG C/h of speed;
(3) below acid number reaches 15mgKOH/g time, stop heating, put to dilution still;
(4) be cooled to 70 ± 5 DEG C to stir evenly and obtain film-forming resin;
Described attapulgite modifiedly make according to the following steps:
(1), attapulgite is used 15-20% dioxygen bubble after 2-3 hour, then by extremely neutrality of deionized water wash, is dried;
(2), in attapulgite, add and be equivalent to the aluminium hydrate powder of its weight 1-2%, the Sodium orthomolybdate of 2-3%, the linking agent TAC of 1-2%, high speed 4500-4800 rev/min of stirring, 20-30 minute, ovendry power is broken into 500-600 order powder.
2. attapulgite modified gas phase slowly-releasing slushing oil according to claim 1, is characterized in that, its feed composition by following weight part is prepared from:
No. 120 solvent oils 150, ferrocene 1.5, polyisobutene 5, N-phenyl-2-naphthylamine 2, benzotriazole 2,2-aminoethyl 17 alkenyl imidazolines 1.5,1-hydroxy benzo triazole 1.5, zinc dialkyl dithiophosphate 2.5, Sodium dodecylbenzene sulfonate 1.5, dimethyl silicone oil 6, epoxy tetrahydro-2-ethylhexyl phthalate 13, film-forming resin 5.5, attapulgite modified 1.5.
3. the preparation method of attapulgite modified gas phase slowly-releasing slushing oil according to claim 1, it is characterized in that: be first prepared into film resin and attapulgite modified, then by formula requirement by various components mix and blend 30-40 minute at 80-90 DEG C, cooled and filtered.
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| CN201210547442.9A CN103045331B (en) | 2012-12-17 | 2012-12-17 | Modified attapulgite rustic phase slow-release rust preventive oil and preparation method thereof |
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Effective date of registration: 20170512 Address after: 226200, Jiangsu Province, Nantong City, Qidong City North Pole village five sets Patentee after: Qidong Fuzhou vegetable and fruit professional cooperatives Address before: 244000 Datong industry and Trade Park, economic development zone, Tongling suburbs, Anhui Patentee before: Tongling Dongfang Mingning Machine Co., Ltd. |
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