CN103031704B - A kind of felt proofing anti-shrink finish method of wool fabric - Google Patents
A kind of felt proofing anti-shrink finish method of wool fabric Download PDFInfo
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Abstract
The invention discloses a kind of felt proofing anti-shrink finish method of wool fabric, it first carries out chlorination preliminary treatment to wool fabric under ul-trasonic irradiation, realize gentle stripping squama process, under ul-trasonic irradiation, ferment treatment is carried out to wool fabric again and realize the process of controlled stripping squama, effectively improve the inside and outside uniformity of the yarn of wool surfaces desquamation, and the combination of chlorination preliminary treatment and ferment treatment, effectively improve the stripping squama uniformity of fiber longitudinal direction, thus reach the anti-felting effect of wool fabric, achieve " machine washable " object of wool fabric, reaction simultaneously in the inventive method is carried out at scale layer, reduce the damage of the cytoplasm to fiber internal layer, what improve wool fabric wears performance and durability degree.
Description
Technical field
The present invention relates to a kind of processing method of fabric, especially relate to a kind of felt proofing anti-shrink finish method of wool fabric.
Background technology
Wool is the important source material of textile industry, and it has a lot of good characteristic, as good springiness, hygroscopicity stain by force, not easily, warmth retention property is good, gloss is soft, these characteristics make wool fabric have various individual style, the dark favor by people.But easily there is felting in wool fabric, the felting of wool fabric causes primarily of the surface scale feature of wool, under cleaning function, effect that wool easily occurs " displacement ", thus cause " gathering " effect of wool fibre, namely wool fibre follows the string and curling, and wool fabric is tightened, and then cause the DIMENSIONAL STABILITY of wool fabric to be deteriorated, have a strong impact on the outward appearance of wool fabric and wear performance.Therefore wool fabric need carry out corresponding chemistry dry-cleaning usually, or carries out the slight washing of the minimum heart, and can not " machine-wash ", and the life style of this and modern is inadaptable.
The research of industry personnel to wool fabric felt proofing lasts for a long time.At present, main both at home and abroad shrinkproofing treatment method has: the relative movement divesting scale and prevention wool.General divests scale many employings chloridizing, but there is following problem in it: 1) it is in order to reach the stripping squama of yarn interior fiber, certainly will be overweight to the process of yam surface fiber, cause fiber inside and outside stripping squama uneven, thus damaged yarn fibers, seriously have impact on the performances such as the brute force of wool fabric, color; 2) it need adopt heavy dose of stripping squama agent to carry out the process of stripping squama, but the stripping squama agent of heavy dose is very large to the pollution of environment, is unfavorable for environmental protection.Current, also the shrinkproofing treatment of combination for wool fabric of some new techniques and technique is had, although these new technologies can reach the anti-felting effect of wool fabric, but yarn is inside and outside and longitudinally process is uneven, particularly in yarn, the stripping squama degree difference of outer fiber is very large, thus cause a lot of problem, such as on the brute force of wool fabric, tear, the impact of the physical property such as grammes per square metre is very large; Very large on the impact of the style of wool fabric, feel, wearing comfort; Very large on the durability impact of wool fabric; Very large on the dyeing impact of wool fabric; The effect stability of shrinkproofing treatment and repeatability difference etc.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of felt proofing anti-shrink finish method of wool fabric, uniformity and longitudinal uniformity inside and outside its yarn that effectively can improve wool surfaces desquamation, can not only anti-felting effect be improved, and machine washable object can be realized.
The present invention solves the problems of the technologies described above adopted technical scheme: a kind of felt proofing anti-shrink finish method of wool fabric, is characterized in that comprising the following steps:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: wool fabric being immersed concentration is carry out gentle chlorination preliminary treatment in the chlorated liquid of 1 ~ 2%; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 15 ~ 40kHz, treatment temperature is 20 ~ 35 DEG C, and the processing time is 10 ~ 50 minutes, and the consumption of the chlorinating agent adopted is 1 ~ 2% of the weight of wool fabric;
2. reduction dechlorination process: add reductant and carry out reduction dechlorination process in the chlorated liquid being soaked with wool fabric; Treatment conditions: the consumption of reductant is 4 ~ 7% of the weight of wool fabric, and pH value is adjusted to 6 ~ 8.5, treatment temperature is 20 ~ 35 DEG C, and the processing time is 20 ~ 60 minutes;
3. ferment treatment under ul-trasonic irradiation: add protease in the solution after 2. processing through step and carry out ferment treatment; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 15 ~ 40kHz, the consumption of protease is 0.5 ~ 2.0% of the weight of wool fabric, and pH value is adjusted to 6 ~ 8.5, and treatment temperature is 30 ~ 55 DEG C, and the processing time is 30 ~ 60 minutes;
4. enzyme deactivation process: raising treatment temperature makes the protease inactivation in the solution after 3. step processes; Treatment conditions: treatment temperature is 50 ~ 80 DEG C, the processing time is 5 ~ 20 minutes;
5. dry.
Described step 1. in chlorinating agent be Basolan 88.
Described step 2. in reductant be sodium hydrogensulfite or sodium sulfite.
Described step 3. in protease be Novi letter protease.
Described step 4. in add emulsifying agent in solution in enzyme deactivation processing procedure after 3. processing through step and make the reaction of protease more even.
Described emulsifying agent adopts non-ionic surface active agent.
Described non-ionic surface active agent is paregal O, and the concentration of described paregal O is 0.5 ~ 2 % of the weight for wool fabric.
Described step 5. in oven dry complete in industrial roller oven, bake out temperature and drying time are by the thickness of handled wool fabric and type decided.
When described wool fabric is pure wool woven Heavy fabric, described step 1. in the frequency of ultrasonic processor is set to 15 ~ 40kHz, the processing time is 30 ~ 50 minutes, 2. the middle processing time is 20 ~ 60 minutes to described step, described step 3. in the frequency of ultrasonic processor be set to 15 ~ 40kHz, the consumption of protease is 0.5 ~ 2.0% of the weight of wool fabric, and the processing time is 30 ~ 60 minutes;
When described wool fabric is pure wool woven slim underlinen fabric, described step 1. in the frequency of ultrasonic processor is set to 15 ~ 20kHz, the processing time is 10 ~ 30 minutes, 2. the middle processing time is 20 ~ 40 minutes to described step, described step 3. in the frequency of ultrasonic processor be set to 15 ~ 20kHz, the consumption of protease is 0.5 ~ 1.0% of the weight of wool fabric, and the processing time is 30 ~ 50 minutes.
Compared with prior art, the invention has the advantages that:
1) the inventive method first carries out chlorination preliminary treatment to wool fabric under ul-trasonic irradiation, realize gentle stripping squama process, under ul-trasonic irradiation, ferment treatment is carried out to wool fabric again and realize the process of controlled stripping squama, effectively improve the inside and outside uniformity of the yarn of wool surfaces desquamation, and the combination of chlorination preliminary treatment and ferment treatment, effectively improve the stripping squama uniformity of fiber longitudinal direction, thus reach the anti-felting effect of wool fabric, achieve " machine washable " object of wool fabric, reaction simultaneously in the inventive method is carried out at scale layer, reduce the damage of the cytoplasm to fiber internal layer, what improve wool fabric wears performance and durability degree.
2) the inventive method reduces pollution to environment, reduces processing cost, improves product quality, can be used for industrialization and produces.
3) the inventive method is applicable to all fabrics having scale structure fiber and make, and the weaving structure of fabric can be knitted structure, machine-knitted structure and non-woven structure.
Accompanying drawing explanation
Fig. 1 be the woven Heavy fabric of pure wool after the inventive method arranges yarn in the scanning electron microscope (SEM) photograph of surfoyl stripped shape condition;
Fig. 2 be the woven Heavy fabric of pure wool after the processing of traditional chloridizing yarn in the scanning electron microscope (SEM) photograph of surfoyl stripped shape condition.
Detailed description of the invention
Below in conjunction with accompanying drawing embodiment, the present invention is described in further detail.
Embodiment one:
To the woven Heavy fabric of pure wool (yarn count: 40/3 × 40/2; Density: 148 × 192/10cm; Grammes per square metre: 355g/ m
2) carry out the process of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: wool fabric being immersed concentration is carry out gentle chlorination preliminary treatment in the chlorated liquid of 1.5%; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 25kHz, treatment temperature is 32 DEG C, and the processing time is 40 minutes, and the consumption of the chlorinating agent adopted is 1.6% of the weight of wool fabric.
In the present embodiment, ultrasonic processor adopts the ultrasonic processor of existing any maturation; Utilize Basolan medicament as chlorinating agent (such as BAOLAN88(Basolan 88), a kind of organochlorine release type compound) scale layer on wool top layer is slowly degraded, make wool top layer become smooth, thus make wool fabric soft, and can shrinkproof anti-pilling.
At this, in chlorination preprocessing process, make use of ultrasonic technology, the pretreated efficiency of wool surfaces can not only be improved, and the consumption of chlorinating agent can be reduced, wool scale produces " opening " under hyperacoustic effect simultaneously, effectively improves stripping squama effect.
In actual process, ultrasonic wave process also can be combined with the gentle processing method such as oxidation, plasma, ozone, laser and realize gentlely shelling squama.
2. reduction dechlorination process: add reductant and carry out reduction dechlorination process in the chlorated liquid being soaked with wool fabric; Treatment conditions: the consumption of reductant is 5.5% of the weight of wool fabric, and pH value is adjusted to 7, treatment temperature is 28 DEG C, and the processing time is 40 minutes.
In the present embodiment, sodium hydrogensulfite (NaHSO is adopted
3) or sodium sulfite (Na
2sO
3) as reductant, in order in and chlorinating agent.
3. ferment treatment under ul-trasonic irradiation: add protease in the solution after 2. processing through step and carry out ferment treatment; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 25kHz, the consumption of protease is 1.0% of the weight of wool fabric, and pH value is adjusted to 7, and treatment temperature is 40 DEG C, and the processing time is 45 minutes.
Protease is a kind of biocatalyst with high catalytic efficiency and substrate specificity high specificity, its catalytic condition quite gentle (temperature is generally 30 ~ 60 DEG C), can Reusability, and discharge occurring in nature can natural degradation.Wool fabric after Protease Treatment has following characteristics and performance: the feel obtaining permanent soft; Gloss significantly improves; Anti-pilling property obviously improves.Therefore, proteases on wool fabric is adopted to carry out ferment treatment in the present invention.In the present embodiment, protease adopts Novi letter protease Savinase 16.
4. enzyme deactivation process: raising treatment temperature makes the protease inactivation in the solution after 3. step processes; Treatment conditions: treatment temperature is 60 DEG C, the processing time is 15 minutes.
In the present embodiment, can add emulsifying agent in solution after 3. processing through step in enzyme deactivation processing procedure makes the reaction of protease more even, as adopted the paregal O in non-ionic surface active agent, the dispersiveness of protease can be improved after adding paregal O (concentration is 0.5 ~ 2 %), thus make the reaction of protease more even.
5. dry, drying and processing completes in industrial roller oven, and thickness and the type of bake out temperature and drying time and handled wool fabric are relevant.
Embodiment two:
To the woven Heavy fabric of pure wool (yarn count: 40/3 × 40/2; Density: 148 × 192/10cm; Grammes per square metre: 355g/ m
2) carry out the process of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: wool fabric being immersed concentration is carry out gentle chlorination preliminary treatment in the chlorated liquid of 1%; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 15kHz, treatment temperature is 20 DEG C, and the processing time is 30 minutes, and the consumption of the chlorinating agent adopted is 1% of the weight of wool fabric.
2. reduction dechlorination process: add reductant and carry out reduction dechlorination process in the chlorated liquid being soaked with wool fabric; Treatment conditions: the consumption of reductant is 4% of the weight of wool fabric, and pH value is adjusted to 6, treatment temperature is 20 DEG C, and the processing time is 60 minutes.
3. ferment treatment under ul-trasonic irradiation: add protease in the solution after 2. processing through step and carry out ferment treatment; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 15kHz, the consumption of protease is 0.5% of the weight of wool fabric, and pH value is adjusted to 6, and treatment temperature is 30 DEG C, and the processing time is 60 minutes.
4. enzyme deactivation process: raising treatment temperature makes the protease inactivation in the solution after 3. step processes; Treatment conditions: treatment temperature is 50 DEG C, the processing time is 20 minutes.
In the present embodiment, can add emulsifying agent in solution after 3. processing through step in enzyme deactivation processing procedure makes the reaction of protease more even, as adopted the paregal O in non-ionic surface active agent, the dispersiveness of protease can be improved after adding paregal O (concentration is 0.5 ~ 2 %), thus make the reaction of protease more even.
5. dry, drying and processing completes in industrial roller oven, and thickness and the type of bake out temperature and drying time and handled wool fabric are relevant.
Embodiment three:
To the woven Heavy fabric of pure wool (yarn count: 40/3 × 40/2; Density: 148 × 192/10cm; Grammes per square metre: 355g/ m
2) carry out the process of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: wool fabric being immersed concentration is carry out gentle chlorination preliminary treatment in the chlorated liquid of 2%; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 40kHz, treatment temperature is 35 DEG C, and the processing time is 50 minutes, and the consumption of the chlorinating agent adopted is 2% of the weight of wool fabric.
2. reduction dechlorination process: add reductant and carry out reduction dechlorination process in the chlorated liquid being soaked with wool fabric; Treatment conditions: the consumption of reductant is 7% of the weight of wool fabric, and pH value is adjusted to 8.5, treatment temperature is 35 DEG C, and the processing time is 20 minutes.
3. ferment treatment under ul-trasonic irradiation: add protease in the solution after 2. processing through step and carry out ferment treatment; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 40kHz, the consumption of protease is 2.0% of the weight of wool fabric, and pH value is adjusted to 8.5, and treatment temperature is 55 DEG C, and the processing time is 30 minutes.
4. enzyme deactivation process: raising treatment temperature makes the protease inactivation in the solution after 3. step processes; Treatment conditions: treatment temperature is 80 DEG C, the processing time is 5 minutes;
In the present embodiment, can add emulsifying agent in solution after 3. processing through step in enzyme deactivation processing procedure makes the reaction of protease more even, as adopted the paregal O in non-ionic surface active agent, the dispersiveness of protease can be improved after adding paregal O (concentration is 0.5 ~ 2 %), thus make the reaction of protease more even.
5. dry, drying and processing completes in industrial roller oven, and thickness and the type of bake out temperature and drying time and handled wool fabric are relevant.
Embodiment four:
To the woven slim underlinen fabric (yarn count: 72/2 of pure wool; Density: 258 × 211/10cm; Grammes per square metre: 210g/m
2) carry out the process of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: wool fabric being immersed concentration is carry out gentle chlorination preliminary treatment in the chlorated liquid of 1.5%; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 18kHz, treatment temperature is 25 DEG C, and the processing time is 20 minutes, and the consumption of the chlorinating agent adopted is 1.5% of the weight of wool fabric.
2. reduction dechlorination process: add reductant and carry out reduction dechlorination process in the chlorated liquid being soaked with wool fabric; Treatment conditions: the consumption of reductant is 5% of the weight of wool fabric, and pH value is adjusted to 7, treatment temperature is 25 DEG C, and the processing time is 30 minutes.
3. ferment treatment under ul-trasonic irradiation: add protease in the solution after 2. processing through step and carry out ferment treatment; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 18kHz, the consumption of protease is 0.8% of the weight of wool fabric, and pH value is adjusted to 7, and treatment temperature is 40 DEG C, and the processing time is 40 minutes.
4. enzyme deactivation process: raising treatment temperature makes the protease inactivation in the solution after 3. step processes; Treatment conditions: treatment temperature is 65 DEG C, the processing time is 15 minutes.
5. dry, drying and processing completes in industrial roller oven, and thickness and the type of bake out temperature and drying time and handled wool fabric are relevant.
Embodiment five:
To the woven slim underlinen fabric (yarn count: 72/2 of pure wool; Density: 258 × 211/10cm; Grammes per square metre: 210g/m
2) carry out the process of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: wool fabric being immersed concentration is carry out gentle chlorination preliminary treatment in the chlorated liquid of 1%; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 15kHz, treatment temperature is 20 DEG C, and the processing time is 30 minutes, and the consumption of the chlorinating agent adopted is 1% of the weight of wool fabric.
2. reduction dechlorination process: add reductant and carry out reduction dechlorination process in the chlorated liquid being soaked with wool fabric; Treatment conditions: the consumption of reductant is 4% of the weight of wool fabric, and pH value is adjusted to 6, treatment temperature is 20 DEG C, and the processing time is 40 minutes.
3. ferment treatment under ul-trasonic irradiation: add protease in the solution after 2. processing through step and carry out ferment treatment; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 15kHz, the consumption of protease is 0.5% of the weight of wool fabric, and pH value is adjusted to 6, and treatment temperature is 30 DEG C, and the processing time is 50 minutes.
4. enzyme deactivation process: raising treatment temperature makes the protease inactivation in the solution after 3. step processes; Treatment conditions: treatment temperature is 50 DEG C, the processing time is 20 minutes.
5. dry, drying and processing completes in industrial roller oven, and thickness and the type of bake out temperature and drying time and handled wool fabric are relevant.
Embodiment six:
To the woven slim underlinen fabric (yarn count: 72/2 of pure wool; Density: 258 × 211/10cm; Grammes per square metre: 210g/m
2) carry out the process of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: wool fabric being immersed concentration is carry out gentle chlorination preliminary treatment in the chlorated liquid of 2%; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 20kHz, treatment temperature is 35 DEG C, and the processing time is 10 minutes, and the consumption of the chlorinating agent adopted is 2% of the weight of wool fabric.
2. reduction dechlorination process: add reductant and carry out reduction dechlorination process in the chlorated liquid being soaked with wool fabric; Treatment conditions: the consumption of reductant is 7% of the weight of wool fabric, and pH value is adjusted to 8.5, treatment temperature is 35 DEG C, and the processing time is 20 minutes.
3. ferment treatment under ul-trasonic irradiation: add protease in the solution after 2. processing through step and carry out ferment treatment; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 20kHz, the consumption of protease is 1.0% of the weight of wool fabric, and pH value is adjusted to 8.5, and treatment temperature is 55 DEG C, and the processing time is 30 minutes.
4. enzyme deactivation process: raising treatment temperature makes the protease inactivation in the solution after 3. step processes; Treatment conditions: treatment temperature is 80 DEG C, the processing time is 8 minutes.
5. dry, drying and processing completes in industrial roller oven, and thickness and the type of bake out temperature and drying time and handled wool fabric are relevant.
Contrast each embodiment above-mentioned, known for slim wool fabric, the frequency of ultrasonic processor, processing time in chlorination preprocessing process, processing time in reduction dechlorination process, the reduction that the consumption of the frequency of ultrasonic processor, processing time, enzyme all should be suitable relative to Heavy fabric in ferment treatment.
For validity and the feasibility of the inventive method are described, to the woven Heavy fabric of the pure wool (yarn count: 40/3 × 40/2 after the inventive method arrangement; Density: 148 × 192/10cm; Grammes per square metre: 355g/ m
2) and test carrying out washing under the washing test condition of the woven Heavy fabric of pure wool at International Wool Secretariat TM31 after the processing of traditional chloridizing, experimental result is as listed in table 1.
The washing result of the pure wool woven Heavy fabric of table 1 after the inventive method arranges and the woven Heavy fabric of pure wool after the processing of traditional chloridizing
As can be seen from Table 1, the maximum length of the woven Heavy fabric of pure wool after the inventive method arranges and shrinkage in width rate for being no more than 3%, fracture strength loss late is no more than 10%, and change color is not obvious, utilize the use amount (for barlan element 88) of chlorinating agent during the pure wool of the inventive method process woven Heavy fabric to be no more than 2% simultaneously, and the use amount (for barlan element 88) of chlorinating agent, more than 5%, illustrates that the inventive method effectively can reduce the pollution to environment during traditional pure wool of chloridizing process woven Heavy fabric.
Fig. 1 give through the inventive method arrange after the woven Heavy fabric of pure wool yarn in surfoyl stripped shape condition (scanning electron microscope (SEM) photograph), Fig. 2 give through traditional chloridizing processing after the woven Heavy fabric of pure wool yarn in surfoyl stripped shape condition (scanning electron microscope (SEM) photograph), comparison diagram 1 and Fig. 2, can find out through the inventive method arrange after the woven Heavy fabric of pure wool yarn in surfoyl peel off more even.
Claims (8)
1. a felt proofing anti-shrink finish method for wool fabric, is characterized in that comprising the following steps:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: wool fabric being immersed concentration is carry out gentle chlorination preliminary treatment in the chlorated liquid of 1 ~ 2%; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 15 ~ 40kHz, treatment temperature is 20 ~ 35 DEG C, and the processing time is 10 ~ 50 minutes, and the consumption of the chlorinating agent adopted is 1 ~ 2% of the weight of wool fabric;
2. reduction dechlorination process: add reductant and carry out reduction dechlorination process in the chlorated liquid being soaked with wool fabric; Treatment conditions: the consumption of reductant is 4 ~ 7% of the weight of wool fabric, and pH value is adjusted to 6 ~ 8.5, treatment temperature is 20 ~ 35 DEG C, and the processing time is 20 ~ 60 minutes;
3. ferment treatment under ul-trasonic irradiation: add protease in the solution after 2. processing through step and carry out ferment treatment; Treatment conditions: the frequency of the ultrasonic processor adopted is set to 15 ~ 40kHz, the consumption of protease is 0.5 ~ 2.0% of the weight of wool fabric, and pH value is adjusted to 6 ~ 8.5, and treatment temperature is 30 ~ 55 DEG C, and the processing time is 30 ~ 60 minutes;
4. enzyme deactivation process: raising treatment temperature makes the protease inactivation in the solution after 3. step processes; Treatment conditions: treatment temperature is 50 ~ 80 DEG C, the processing time is 5 ~ 20 minutes;
Described step 4. in add emulsifying agent in solution in enzyme deactivation processing procedure after 3. processing through step and make the reaction of protease more even;
5. dry.
2. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 1, is characterized in that the chlorinating agent during described step is 1. Basolan 88.
3. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 1 and 2, is characterized in that the reductant during described step is 2. sodium hydrogensulfite or sodium sulfite.
4. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 3, is characterized in that the protease during described step is 3. Novi's letter protease.
5. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 1, is characterized in that described emulsifying agent adopts non-ionic surface active agent.
6. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 5, is characterized in that described non-ionic surface active agent is paregal O, and the concentration of described paregal O is 0.5 ~ 2% of the weight for wool fabric.
7. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 6, it is characterized in that the oven dry during described step 5. completes in industrial roller oven, bake out temperature and drying time are by the thickness of handled wool fabric and type decided.
8. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 7, when it is characterized in that described wool fabric is the woven Heavy fabric of pure wool, described step 1. in the frequency of ultrasonic processor is set to 15 ~ 40kHz, the processing time is 30 ~ 50 minutes, 2. the middle processing time is 20 ~ 60 minutes to described step, described step 3. in the frequency of ultrasonic processor be set to 15 ~ 40kHz, the consumption of protease is 0.5 ~ 2.0% of the weight of wool fabric, and the processing time is 30 ~ 60 minutes;
When described wool fabric is pure wool woven slim underlinen fabric, described step 1. in the frequency of ultrasonic processor is set to 15 ~ 20kHz, the processing time is 10 ~ 30 minutes, 2. the middle processing time is 20 ~ 40 minutes to described step, described step 3. in the frequency of ultrasonic processor be set to 15 ~ 20kHz, the consumption of protease is 0.5 ~ 1.0% of the weight of wool fabric, and the processing time is 30 ~ 50 minutes.
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| CN111962293B (en) * | 2020-08-18 | 2022-10-21 | 浙江曙丰毛纺织科技股份有限公司 | Processing technology of blended wool graphene wool fabric |
| CN112095259A (en) * | 2020-08-21 | 2020-12-18 | 常熟市新光毛条处理有限公司 | Continuous treatment process of Basolan wool tops |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6242059B1 (en) * | 1998-12-18 | 2001-06-05 | Bayer Aktiengesellschaft | Nonfelting wool and antifelt finishing process |
| CN101666041A (en) * | 2009-09-17 | 2010-03-10 | 宁波雅戈尔毛纺织染整有限公司 | Manufacturing method of all-wool thick black spinning fabrics |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0203522D0 (en) * | 2002-02-14 | 2002-04-03 | Prec Process Textiles Ltd | Treating proteinaceous material |
-
2012
- 2012-12-20 CN CN201210558985.0A patent/CN103031704B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6242059B1 (en) * | 1998-12-18 | 2001-06-05 | Bayer Aktiengesellschaft | Nonfelting wool and antifelt finishing process |
| CN101666041A (en) * | 2009-09-17 | 2010-03-10 | 宁波雅戈尔毛纺织染整有限公司 | Manufacturing method of all-wool thick black spinning fabrics |
Non-Patent Citations (3)
| Title |
|---|
| 前处理在羊毛针织物蛋白酶防毡缩整理中的作用;樊增禄等;《毛纺科技》;20020830(第4期);第25页右栏最后一段，26页左栏1-5段 * |
| 蛋白酶在羊毛丝光防毡缩整理中的应用研究;吴婵娟等;《毛纺科技》;20010830(第4期);第36-40页 * |
| 超声波协同酶复合整理改善毛织物防缩性的研究;李霞等;《毛纺科技》;20070705(第3期);第19页右栏3-4、7段，20页左栏第2段，右栏第一段 * |
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