CN103031704A - Felt proofing machine-washing finishing method for wool fabric - Google Patents
Felt proofing machine-washing finishing method for wool fabric Download PDFInfo
- Publication number
- CN103031704A CN103031704A CN2012105589850A CN201210558985A CN103031704A CN 103031704 A CN103031704 A CN 103031704A CN 2012105589850 A CN2012105589850 A CN 2012105589850A CN 201210558985 A CN201210558985 A CN 201210558985A CN 103031704 A CN103031704 A CN 103031704A
- Authority
- CN
- China
- Prior art keywords
- wool fabric
- wool
- minutes
- processing time
- protease
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Abstract
The invention discloses a felt proofing machine-washing finishing method for wool fabric. Under the effect of ultrasonic waves, the wool fabric is subjected to chlorination pretreatment to realize mild scale stripping treatment, and then the wool fabric is subjected to enzyme treatment to realize controlled scale stripping treatment under effect of the ultrasonic waves, so that the inside and outside uniformity of yarns of which the wool surface is subjected to scale stripping is effectively increased. The chlorination pretreatment is combined with the enzyme treatment, so that the longitudinal scale stripping uniformity of fibers is effectively increased, therefore the felt proofing effect of the wool fabric is achieved, and the machine-washing purpose of wool textiles is realized. Meanwhile, the reaction in the method is carried out in a scale layer, so that the damage on intercellular substances of the inner layers of the fibers is reduced, and the wearing performance and the durability of the wool textiles are increased.
Description
Technical field
The present invention relates to a kind of processing method of fabric, especially relate to a kind of felt proofing anti-shrink finish method of wool fabric.
Background technology
Wool is the important source material of textile industry, and it has a lot of good characteristics, strong such as good springiness, hygroscopicity, be difficult for staiing, warmth retention property is good, gloss is soft etc., these characteristics are subjected to people's favor deeply so that wool fabric has various individual styles.But felting easily occurs in wool fabric, the felting of wool fabric is mainly caused by the surperficial scale feature of wool, under cleaning function, " displacement " effect easily occurs in wool, thereby cause " gathering " effect of wool fibre, namely wool fibre follows the string and is curling, and wool fabric is tightened, and then cause the DIMENSIONAL STABILITY variation of wool fabric, have a strong impact on the outward appearance of wool fabric and wear performance.Therefore wool fabric need carry out corresponding chemistry dry-cleaning usually, or carries out the slight washing of the minimum heart, and can not " machine-wash ", and this and modern's life style is inadaptable.
The industry personnel lasts for a long time the research of wool fabric felt proofing.At present, main felt proofing processing method has both at home and abroad: divest scale and stop relatively moving of wool.The general scale that divests adopts chloridizing more, but there is following problem in it: 1) it is in order to reach the stripping squama of yarn internal fiber, certainly will be overweight to the processing of yam surface fiber, cause the inside and outside stripping of fiber squama inhomogeneous, thereby damaged yarn fibers, seriously affected the performance such as brute force, color of wool fabric; 2) it need adopt heavy dose of stripping squama agent to shell the squama processing, yet heavy dose of stripping squama agent is very large to the pollution of environment, is unfavorable for environmental protection.Current, also there is the combination of some new techniques and technique to process for the felt proofing of wool fabric, although these new technologies can reach the anti-felting effect of wool fabric, but yarn is inside and outside and vertically process inhomogeneous, particularly the stripping squama degree difference of outer fiber is very large in the yarn, thereby cause a lot of problems, such as on the brute force of wool fabric, tear, the impact of the physical property such as grammes per square metre is very large; Impact on the style of wool fabric, feel, degree comfortable and easy to wear is very large; Durability impact on wool fabric is very large; Dyeing impact on wool fabric is very large; The effect stability that felt proofing is processed and repeatability are poor etc.
Summary of the invention
Technical problem to be solved by this invention provides a kind of felt proofing anti-shrink finish method of wool fabric, its can the desquamation of Effective Raise wool surfaces the inside and outside uniformity of yarn and longitudinal uniformity, anti-felting effect not only can be improved, and the machine washable purpose can be realized.
The present invention solves the problems of the technologies described above the technical scheme that adopts: a kind of felt proofing anti-shrink finish method of wool fabric is characterized in that may further comprise the steps:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: it is to carry out gentle chlorination preliminary treatment in 1～2% the chlorated liquid that wool fabric is immersed concentration; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 15～40kHz, and treatment temperature is 20～35 ℃, and the processing time is 10～50 minutes, the consumption of the chlorinating agent that adopts be wool fabric weight 1～2%;
2. reduction dechlorination is processed: add reductant and carry out the reduction dechlorination processing in being soaked with the chlorated liquid of wool fabric; Treatment conditions: the consumption of reductant be wool fabric weight 4～7%, pH value is adjusted to 6～8.5, treatment temperature is 20～35 ℃, the processing time is 20～60 minutes;
3. enzyme is processed under ul-trasonic irradiation: add protease and carry out the enzyme processing in the solution after 2. step is processed; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 15～40kHz, the consumption of protease be wool fabric weight 0.5～2.0%, pH value is adjusted to 6～8.5, treatment temperature is 30～55 ℃, the processing time is 30～60 minutes;
4. enzyme deactivation is processed: improve treatment temperature and make protease inactivation in the solution after 3. step is processed; Treatment conditions: treatment temperature is 50～80 ℃, and the processing time is 5～20 minutes;
5. oven dry.
The chlorinating agent of described step in 1. is Basolan 88.
The reductant of described step in 2. is sodium hydrogensulfite or sodium sulfite.
The protease of described step in 3. is Novi's letter protease.
Described step adds emulsifying agent in the enzyme deactivation processing procedure in 4. in the solution after 3. step is processed makes the reaction of protease more even.
Described emulsifying agent adopts non-ionic surface active agent.
Described non-ionic surface active agent is paregal O, and the concentration of described paregal O is for being 0.5～2 % of the weight of wool fabric.
The oven dry of described step in 5. finished in industrial cylinder baking oven, and bake out temperature and drying time are by thickness and the type decided of handled wool fabric.
When described wool fabric is the woven thick and heavy shell fabric of pure wool, described step 1. in the frequency of ultrasonic processor to be made as 15～40kHz, processing time be 30～50 minutes, 2. the middle processing time is 20～60 minutes to described step, the described step 3. frequency of middle ultrasonic processor is made as 15～40kHz, the consumption of protease be wool fabric weight 0.5～2.0%, the processing time is 30～60 minutes;
When described wool fabric is the woven slim underlinen fabric of pure wool, described step 1. in the frequency of ultrasonic processor to be made as 15～20kHz, processing time be 10～30 minutes, 2. the middle processing time is 20～40 minutes to described step, the described step 3. frequency of middle ultrasonic processor is made as 15～20kHz, the consumption of protease be wool fabric weight 0.5～1.0%, the processing time is 30～50 minutes.
Compared with prior art, the invention has the advantages that:
1) the inventive method is carried out the chlorination preliminary treatment to wool fabric first under ul-trasonic irradiation, realize gentle stripping squama processing, under ul-trasonic irradiation, wool fabric is carried out enzyme again and process the controlled stripping squama processing of realization, effectively improved the inside and outside uniformity of the yarn of wool surfaces desquamation, and the combination that chlorination preliminary treatment and enzyme are processed, effectively improve fiber and shelled longitudinally the squama uniformity, thereby reached the anti-felting effect of wool fabric, realized " machine washable " purpose of wool fabric, the simultaneously reaction in the inventive method is carried out at scale layer, reduced the damage to the cytoplasm of fiber internal layer, that has improved wool fabric wears performance and durability degree.
2) the inventive method has reduced pollution to environment, has reduced processing cost, has improved product quality, can be used for industrialization production.
3) the inventive method is applicable to all and has the fabric that the scale structure fiber is made, and the weaving structure of fabric can be knitted structure, machine-knitted structure and non-woven structure.
Description of drawings
Fig. 1 is the scanning electron microscope (SEM) photograph of surfoyl stripped shape condition in the yarn of the woven thick and heavy shell fabric of pure wool after the inventive method arrangement;
Fig. 2 is the scanning electron microscope (SEM) photograph of surfoyl stripped shape condition in the yarn of the woven thick and heavy shell fabric of pure wool after the processing of traditional chloridizing.
The specific embodiment
Embodiment is described in further detail the present invention below in conjunction with accompanying drawing.
Embodiment one:
To the woven thick and heavy shell fabric (yarn count: 40/3 * 40/2 of pure wool; Density: 148 * 192/10cm; Grammes per square metre: 355g/ m
2) carry out the processing of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: it is to carry out gentle chlorination preliminary treatment in 1.5% the chlorated liquid that wool fabric is immersed concentration; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 25kHz, and treatment temperature is 32 ℃, and the processing time is 40 minutes, the consumption of the chlorinating agent that adopts be wool fabric weight 1.6%.
In the present embodiment, ultrasonic processor adopts the ultrasonic processor of existing any maturation; Utilize the Basolan medicament as chlorinating agent (such as BAOLAN88(Basolan 88), a kind of organochlorine release type compound) scale layer on wool top layer is slowly degraded, so that the wool top layer becomes smooth, thereby so that wool fabric is soft, and can shrinkproof anti-balling-up.
At this, in the chlorination preprocessing process, utilize ultrasonic technology, not only can improve the pretreated efficient of wool surfaces, and can reduce the consumption of chlorinating agent, wool scale produces " opening " under hyperacoustic effect simultaneously, has effectively improved stripping squama effect.
In actual process, ultrasonic wave is processed also can be combined with gentle processing methods such as oxidation, plasma, ozone, laser and is realized gentle stripping squama.
2. reduction dechlorination is processed: add reductant and carry out the reduction dechlorination processing in being soaked with the chlorated liquid of wool fabric; Treatment conditions: the consumption of reductant be wool fabric weight 5.5%, pH value is adjusted to 7, treatment temperature is 28 ℃, the processing time is 40 minutes.
In the present embodiment, adopt sodium hydrogensulfite (NaHSO
3) or sodium sulfite (Na
2SO
3) as reductant, in order in and chlorinating agent.
3. enzyme is processed under ul-trasonic irradiation: add protease and carry out the enzyme processing in the solution after 2. step is processed; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 25kHz, the consumption of protease be wool fabric weight 1.0%, pH value is adjusted to 7, treatment temperature is 40 ℃, the processing time is 45 minutes.
Protease is a kind of have high catalytic efficiency and narrow spectrum biocatalyst of effect substrate height, and its catalytic condition is gentle (temperature is generally 30～60 ℃) quite, but Reusability, but discharging occurring in nature natural degradation.Wool fabric after the Protease Treatment has following characteristics and performance: the feel that obtains permanent soft; Gloss obviously improves; Anti-pilling property obviously improves.Therefore, adopting in the present invention the proteases on wool fabric to carry out enzyme processes.In the present embodiment, protease adopts the letter protease Savinase of Novi 16.
4. enzyme deactivation is processed: improve treatment temperature and make protease inactivation in the solution after 3. step is processed; Treatment conditions: treatment temperature is 60 ℃, and the processing time is 15 minutes.
In the present embodiment, can add emulsifying agent in the enzyme deactivation processing procedure in the solution after 3. step is processed makes the reaction of protease more even, as adopt paregal O in the non-ionic surface active agent, can improve the dispersiveness of protease behind the adding paregal O (concentration is 0.5～2 %), thereby so that the reaction of protease is more even.
5. oven dry, drying and processing is finished in industrial cylinder baking oven, and bake out temperature is relevant with thickness and the type of drying time and handled wool fabric.
Embodiment two:
To the woven thick and heavy shell fabric (yarn count: 40/3 * 40/2 of pure wool; Density: 148 * 192/10cm; Grammes per square metre: 355g/ m
2) carry out the processing of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: it is to carry out gentle chlorination preliminary treatment in 1% the chlorated liquid that wool fabric is immersed concentration; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 15kHz, and treatment temperature is 20 ℃, and the processing time is 30 minutes, the consumption of the chlorinating agent that adopts be wool fabric weight 1%.
2. reduction dechlorination is processed: add reductant and carry out the reduction dechlorination processing in being soaked with the chlorated liquid of wool fabric; Treatment conditions: the consumption of reductant be wool fabric weight 4%, pH value is adjusted to 6, treatment temperature is 20 ℃, the processing time is 60 minutes.
3. enzyme is processed under ul-trasonic irradiation: add protease and carry out the enzyme processing in the solution after 2. step is processed; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 15kHz, the consumption of protease be wool fabric weight 0.5%, pH value is adjusted to 6, treatment temperature is 30 ℃, the processing time is 60 minutes.
4. enzyme deactivation is processed: improve treatment temperature and make protease inactivation in the solution after 3. step is processed; Treatment conditions: treatment temperature is 50 ℃, and the processing time is 20 minutes.
In the present embodiment, can add emulsifying agent in the enzyme deactivation processing procedure in the solution after 3. step is processed makes the reaction of protease more even, as adopt paregal O in the non-ionic surface active agent, can improve the dispersiveness of protease behind the adding paregal O (concentration is 0.5～2 %), thereby so that the reaction of protease is more even.
5. oven dry, drying and processing is finished in industrial cylinder baking oven, and bake out temperature is relevant with thickness and the type of drying time and handled wool fabric.
Embodiment three:
To the woven thick and heavy shell fabric (yarn count: 40/3 * 40/2 of pure wool; Density: 148 * 192/10cm; Grammes per square metre: 355g/ m
2) carry out the processing of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: it is to carry out gentle chlorination preliminary treatment in 2% the chlorated liquid that wool fabric is immersed concentration; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 40kHz, and treatment temperature is 35 ℃, and the processing time is 50 minutes, the consumption of the chlorinating agent that adopts be wool fabric weight 2%.
2. reduction dechlorination is processed: add reductant and carry out the reduction dechlorination processing in being soaked with the chlorated liquid of wool fabric; Treatment conditions: the consumption of reductant be wool fabric weight 7%, pH value is adjusted to 8.5, treatment temperature is 35 ℃, the processing time is 20 minutes.
3. enzyme is processed under ul-trasonic irradiation: add protease and carry out the enzyme processing in the solution after 2. step is processed; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 40kHz, the consumption of protease be wool fabric weight 2.0%, pH value is adjusted to 8.5, treatment temperature is 55 ℃, the processing time is 30 minutes.
4. enzyme deactivation is processed: improve treatment temperature and make protease inactivation in the solution after 3. step is processed; Treatment conditions: treatment temperature is 80 ℃, and the processing time is 5 minutes;
In the present embodiment, can add emulsifying agent in the enzyme deactivation processing procedure in the solution after 3. step is processed makes the reaction of protease more even, as adopt paregal O in the non-ionic surface active agent, can improve the dispersiveness of protease behind the adding paregal O (concentration is 0.5～2 %), thereby so that the reaction of protease is more even.
5. oven dry, drying and processing is finished in industrial cylinder baking oven, and bake out temperature is relevant with thickness and the type of drying time and handled wool fabric.
Embodiment four:
To the woven slim underlinen fabric (yarn count: 72/2 of pure wool; Density: 258 * 211/10cm; Grammes per square metre: 210g/m
2) carry out the processing of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: it is to carry out gentle chlorination preliminary treatment in 1.5% the chlorated liquid that wool fabric is immersed concentration; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 18kHz, and treatment temperature is 25 ℃, and the processing time is 20 minutes, the consumption of the chlorinating agent that adopts be wool fabric weight 1.5%.
2. reduction dechlorination is processed: add reductant and carry out the reduction dechlorination processing in being soaked with the chlorated liquid of wool fabric; Treatment conditions: the consumption of reductant be wool fabric weight 5%, pH value is adjusted to 7, treatment temperature is 25 ℃, the processing time is 30 minutes.
3. enzyme is processed under ul-trasonic irradiation: add protease and carry out the enzyme processing in the solution after 2. step is processed; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 18kHz, the consumption of protease be wool fabric weight 0.8%, pH value is adjusted to 7, treatment temperature is 40 ℃, the processing time is 40 minutes.
4. enzyme deactivation is processed: improve treatment temperature and make protease inactivation in the solution after 3. step is processed; Treatment conditions: treatment temperature is 65 ℃, and the processing time is 15 minutes.
5. oven dry, drying and processing is finished in industrial cylinder baking oven, and bake out temperature is relevant with thickness and the type of drying time and handled wool fabric.
Embodiment five:
To the woven slim underlinen fabric (yarn count: 72/2 of pure wool; Density: 258 * 211/10cm; Grammes per square metre: 210g/m
2) carry out the processing of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: it is to carry out gentle chlorination preliminary treatment in 1% the chlorated liquid that wool fabric is immersed concentration; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 15kHz, and treatment temperature is 20 ℃, and the processing time is 30 minutes, the consumption of the chlorinating agent that adopts be wool fabric weight 1%.
2. reduction dechlorination is processed: add reductant and carry out the reduction dechlorination processing in being soaked with the chlorated liquid of wool fabric; Treatment conditions: the consumption of reductant be wool fabric weight 4%, pH value is adjusted to 6, treatment temperature is 20 ℃, the processing time is 40 minutes.
3. enzyme is processed under ul-trasonic irradiation: add protease and carry out the enzyme processing in the solution after 2. step is processed; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 15kHz, the consumption of protease be wool fabric weight 0.5%, pH value is adjusted to 6, treatment temperature is 30 ℃, the processing time is 50 minutes.
4. enzyme deactivation is processed: improve treatment temperature and make protease inactivation in the solution after 3. step is processed; Treatment conditions: treatment temperature is 50 ℃, and the processing time is 20 minutes.
5. oven dry, drying and processing is finished in industrial cylinder baking oven, and bake out temperature is relevant with thickness and the type of drying time and handled wool fabric.
Embodiment six:
To the woven slim underlinen fabric (yarn count: 72/2 of pure wool; Density: 258 * 211/10cm; Grammes per square metre: 210g/m
2) carry out the processing of felt proofing anti-shrink finish, concrete processing procedure is:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: it is to carry out gentle chlorination preliminary treatment in 2% the chlorated liquid that wool fabric is immersed concentration; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 20kHz, and treatment temperature is 35 ℃, and the processing time is 10 minutes, the consumption of the chlorinating agent that adopts be wool fabric weight 2%.
2. reduction dechlorination is processed: add reductant and carry out the reduction dechlorination processing in being soaked with the chlorated liquid of wool fabric; Treatment conditions: the consumption of reductant be wool fabric weight 7%, pH value is adjusted to 8.5, treatment temperature is 35 ℃, the processing time is 20 minutes.
3. enzyme is processed under ul-trasonic irradiation: add protease and carry out the enzyme processing in the solution after 2. step is processed; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 20kHz, the consumption of protease be wool fabric weight 1.0%, pH value is adjusted to 8.5, treatment temperature is 55 ℃, the processing time is 30 minutes.
4. enzyme deactivation is processed: improve treatment temperature and make protease inactivation in the solution after 3. step is processed; Treatment conditions: treatment temperature is 80 ℃, and the processing time is 8 minutes.
5. oven dry, drying and processing is finished in industrial cylinder baking oven, and bake out temperature is relevant with thickness and the type of drying time and handled wool fabric.
Contrast above-mentioned each embodiment, as can be known for slim wool fabric, the frequency of ultrasonic processor, processing time in the chlorination preprocessing process, processing time in reduction dechlorination is processed, the reduction that the consumption of the frequency of ultrasonic processor, processing time, enzyme all should be suitable with respect to thick and heavy shell fabric in enzyme is processed.
Be validity and the feasibility of explanation the inventive method, to the woven thick and heavy shell fabric (yarn count: 40/3 * 40/2 of pure wool after the inventive method arrangement; Density: 148 * 192/10cm; Grammes per square metre: 355g/ m
2) and to wash experiment under the washing test condition of the woven thick and heavy shell fabric of pure wool at the TM31 of International Wool Secretariat after traditional chloridizing processing, experimental result such as table 1 are listed.
Table 1 is through the washing result of the woven thick and heavy shell fabric of pure wool after the inventive method arrangement and the woven thick and heavy shell fabric of pure wool after traditional chloridizing processing
As can be seen from Table 1, the maximum length of the woven thick and heavy shell fabric of pure wool after the inventive method arrangement and shrinkage in width rate for be no more than 3%, the fracture strength loss late is no more than 10%, and change color is not obvious, the use amount (take barlan element 88 as example) of chlorinating agent is no more than 2% when utilizing simultaneously the inventive method to process the woven thick and heavy shell fabric of pure wool, and the use amount (take barlan element 88 as example) of traditional chloridizing chlorinating agent when processing the woven thick and heavy shell fabric of pure wool surpasses 5%, illustrates that the inventive method can effectively reduce the pollution to environment.
Fig. 1 has provided surfoyl stripped shape condition (scanning electron microscope (SEM) photograph) in the yarn of the woven thick and heavy shell fabric of pure wool after the inventive method arrangement, Fig. 2 has provided surfoyl stripped shape condition (scanning electron microscope (SEM) photograph) in the yarn of the woven thick and heavy shell fabric of pure wool after the processing of traditional chloridizing, comparison diagram 1 and Fig. 2 can find out that surfoyl is peeled off more even in the yarn of the woven thick and heavy shell fabric of pure wool after the inventive method arrangement.
Claims (9)
1. the felt proofing anti-shrink finish method of a wool fabric is characterized in that may further comprise the steps:
1. gentle chlorination preliminary treatment under ul-trasonic irradiation: it is to carry out gentle chlorination preliminary treatment in 1～2% the chlorated liquid that wool fabric is immersed concentration; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 15～40kHz, and treatment temperature is 20～35 ℃, and the processing time is 10～50 minutes, the consumption of the chlorinating agent that adopts be wool fabric weight 1～2%;
2. reduction dechlorination is processed: add reductant and carry out the reduction dechlorination processing in being soaked with the chlorated liquid of wool fabric; Treatment conditions: the consumption of reductant be wool fabric weight 4～7%, pH value is adjusted to 6～8.5, treatment temperature is 20～35 ℃, the processing time is 20～60 minutes;
3. enzyme is processed under ul-trasonic irradiation: add protease and carry out the enzyme processing in the solution after 2. step is processed; Treatment conditions: the frequency of the ultrasonic processor that adopts is made as 15～40kHz, the consumption of protease be wool fabric weight 0.5～2.0%, pH value is adjusted to 6～8.5, treatment temperature is 30～55 ℃, the processing time is 30～60 minutes;
4. enzyme deactivation is processed: improve treatment temperature and make protease inactivation in the solution after 3. step is processed; Treatment conditions: treatment temperature is 50～80 ℃, and the processing time is 5～20 minutes;
5. oven dry.
2. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 1 is characterized in that the chlorinating agent during described step 1. is Basolan 88.
3. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 1 and 2 is characterized in that the reductant during described step 2. is sodium hydrogensulfite or sodium sulfite.
4. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 3 is characterized in that the protease during described step 3. is Novi's letter protease.
5. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 4 is characterized in that adding emulsifying agent in the enzyme deactivation processing procedure in the solution after 3. step is processed during described step 4. makes the reaction of protease more even.
6. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 5 is characterized in that described emulsifying agent adopts non-ionic surface active agent.
7. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 6 is characterized in that described non-ionic surface active agent is paregal O, and the concentration of described paregal O is for being 0.5～2 % of the weight of wool fabric.
8. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 7, it is characterized in that the oven dry during described step 5. finishes in industrial cylinder baking oven, bake out temperature and drying time are by thickness and the type decided of handled wool fabric.
9. the felt proofing anti-shrink finish method of a kind of wool fabric according to claim 8, when it is characterized in that described wool fabric is the woven thick and heavy shell fabric of pure wool, described step 1. in the frequency of ultrasonic processor to be made as 15～40kHz, processing time be 30～50 minutes, 2. the middle processing time is 20～60 minutes to described step, the described step 3. frequency of middle ultrasonic processor is made as 15～40kHz, the consumption of protease be wool fabric weight 0.5～2.0%, the processing time is 30～60 minutes;
When described wool fabric is the woven slim underlinen fabric of pure wool, described step 1. in the frequency of ultrasonic processor to be made as 15～20kHz, processing time be 10～30 minutes, 2. the middle processing time is 20～40 minutes to described step, the described step 3. frequency of middle ultrasonic processor is made as 15～20kHz, the consumption of protease be wool fabric weight 0.5～1.0%, the processing time is 30～50 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210558985.0A CN103031704B (en) | 2012-12-20 | 2012-12-20 | A kind of felt proofing anti-shrink finish method of wool fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210558985.0A CN103031704B (en) | 2012-12-20 | 2012-12-20 | A kind of felt proofing anti-shrink finish method of wool fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103031704A true CN103031704A (en) | 2013-04-10 |
| CN103031704B CN103031704B (en) | 2015-08-26 |
Family
ID=48019071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210558985.0A Active CN103031704B (en) | 2012-12-20 | 2012-12-20 | A kind of felt proofing anti-shrink finish method of wool fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103031704B (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103266476A (en) * | 2013-06-13 | 2013-08-28 | 太仓协大申泰羊毛衫有限公司 | Treatment method for preventing shrinkage of woollen sweater |
| CN103321060A (en) * | 2013-05-03 | 2013-09-25 | 蚌埠市惠利纺织有限责任公司 | Production process capable of washing threads |
| CN103696237A (en) * | 2013-09-12 | 2014-04-02 | 浙江新澳纺织股份有限公司 | Basolan wool treatment method |
| CN103924439A (en) * | 2014-04-25 | 2014-07-16 | 江南大学 | Method for protease-method wool felt-proofing treatment by using ultrasonic technology |
| CN104611935A (en) * | 2015-02-03 | 2015-05-13 | 湖州市菱湖重兆金辉丝织厂 | Felt proofing method for wool fabrics |
| CN105463666A (en) * | 2015-12-15 | 2016-04-06 | 桐乡市濮院毛针织技术服务中心 | Cool, light and thin wool combined fabric |
| CN105506978A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Enzymatic shrinkproof mercerizing method of wool yarns |
| CN105544201A (en) * | 2015-12-30 | 2016-05-04 | 江阴市长泾花园毛纺织有限公司 | Production method of mercerized wool air layer fabric |
| CN105908485A (en) * | 2016-05-30 | 2016-08-31 | 长兴锦桥纺织有限公司 | Preparation method of children's underwear blended fabric |
| CN106012548A (en) * | 2016-05-30 | 2016-10-12 | 长兴锦桥纺织有限公司 | Method for preparing environment-friendly wool and silkworm protein fiber blended yarn |
| CN106012493A (en) * | 2016-05-30 | 2016-10-12 | 长兴锦桥纺织有限公司 | Environmentally-friendly antibiotic wool treatment technology |
| CN107119445A (en) * | 2017-06-23 | 2017-09-01 | 沙洲职业工学院 | A kind of worsted fabric shiinkproof finish method |
| CN107447320A (en) * | 2017-09-23 | 2017-12-08 | 江苏箭鹿毛纺股份有限公司 | A kind of machine washable velvet apple machine knitting yarn and its production technology |
| CN109736093A (en) * | 2018-11-22 | 2019-05-10 | 江阴兴吴呢绒科技有限公司 | A kind of felt-proofing finishing method of machine washable wool fabric |
| CN109853248A (en) * | 2018-12-29 | 2019-06-07 | 浙江米皇羊绒股份有限公司 | A kind of biological enzyme synergistic supersonic wave anti-felting method |
| CN111286972A (en) * | 2020-02-05 | 2020-06-16 | 上海恋轩实业有限公司 | Shrink-proof and crease-resistant process for worsted cashmere fabric |
| CN111560690A (en) * | 2020-05-13 | 2020-08-21 | 杭州悦仕达新材料科技有限公司 | Flame-retardant elastic textile fabric and processing method thereof |
| CN111850773A (en) * | 2020-08-13 | 2020-10-30 | 嘉兴市华盛达时装股份有限公司 | Machine-washable wool fabric processing technology |
| CN111962293A (en) * | 2020-08-18 | 2020-11-20 | 浙江曙丰毛纺织科技股份有限公司 | Processing technology of blended wool graphene wool fabric |
| CN112095259A (en) * | 2020-08-21 | 2020-12-18 | 常熟市新光毛条处理有限公司 | Continuous treatment process of Basolan wool tops |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6242059B1 (en) * | 1998-12-18 | 2001-06-05 | Bayer Aktiengesellschaft | Nonfelting wool and antifelt finishing process |
| WO2003069051A1 (en) * | 2002-02-14 | 2003-08-21 | Precision Processes Textiles Limited | Treating proteinaceous materials |
| CN101666041A (en) * | 2009-09-17 | 2010-03-10 | 宁波雅戈尔毛纺织染整有限公司 | Manufacturing method of all-wool thick black spinning fabrics |
-
2012
- 2012-12-20 CN CN201210558985.0A patent/CN103031704B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6242059B1 (en) * | 1998-12-18 | 2001-06-05 | Bayer Aktiengesellschaft | Nonfelting wool and antifelt finishing process |
| WO2003069051A1 (en) * | 2002-02-14 | 2003-08-21 | Precision Processes Textiles Limited | Treating proteinaceous materials |
| CN101666041A (en) * | 2009-09-17 | 2010-03-10 | 宁波雅戈尔毛纺织染整有限公司 | Manufacturing method of all-wool thick black spinning fabrics |
Non-Patent Citations (4)
| Title |
|---|
| 吴婵娟等: "蛋白酶在羊毛丝光防毡缩整理中的应用研究", 《毛纺科技》 * |
| 李霞等: "超声波协同酶复合整理改善毛织物防缩性的研究", 《毛纺科技》 * |
| 樊增禄等: "前处理在羊毛针织物蛋白酶防毡缩整理中的作用", 《毛纺科技》 * |
| 马晓光: "《纺织品物理机械染整》", 30 June 2002, 中国纺织出版社 * |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103321060A (en) * | 2013-05-03 | 2013-09-25 | 蚌埠市惠利纺织有限责任公司 | Production process capable of washing threads |
| CN103266476A (en) * | 2013-06-13 | 2013-08-28 | 太仓协大申泰羊毛衫有限公司 | Treatment method for preventing shrinkage of woollen sweater |
| CN103696237A (en) * | 2013-09-12 | 2014-04-02 | 浙江新澳纺织股份有限公司 | Basolan wool treatment method |
| CN103924439A (en) * | 2014-04-25 | 2014-07-16 | 江南大学 | Method for protease-method wool felt-proofing treatment by using ultrasonic technology |
| CN104611935A (en) * | 2015-02-03 | 2015-05-13 | 湖州市菱湖重兆金辉丝织厂 | Felt proofing method for wool fabrics |
| CN105463666A (en) * | 2015-12-15 | 2016-04-06 | 桐乡市濮院毛针织技术服务中心 | Cool, light and thin wool combined fabric |
| CN105506978A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Enzymatic shrinkproof mercerizing method of wool yarns |
| CN105544201A (en) * | 2015-12-30 | 2016-05-04 | 江阴市长泾花园毛纺织有限公司 | Production method of mercerized wool air layer fabric |
| CN106012493A (en) * | 2016-05-30 | 2016-10-12 | 长兴锦桥纺织有限公司 | Environmentally-friendly antibiotic wool treatment technology |
| CN106012548A (en) * | 2016-05-30 | 2016-10-12 | 长兴锦桥纺织有限公司 | Method for preparing environment-friendly wool and silkworm protein fiber blended yarn |
| CN105908485A (en) * | 2016-05-30 | 2016-08-31 | 长兴锦桥纺织有限公司 | Preparation method of children's underwear blended fabric |
| CN107119445A (en) * | 2017-06-23 | 2017-09-01 | 沙洲职业工学院 | A kind of worsted fabric shiinkproof finish method |
| CN107447320A (en) * | 2017-09-23 | 2017-12-08 | 江苏箭鹿毛纺股份有限公司 | A kind of machine washable velvet apple machine knitting yarn and its production technology |
| CN109736093A (en) * | 2018-11-22 | 2019-05-10 | 江阴兴吴呢绒科技有限公司 | A kind of felt-proofing finishing method of machine washable wool fabric |
| CN109853248A (en) * | 2018-12-29 | 2019-06-07 | 浙江米皇羊绒股份有限公司 | A kind of biological enzyme synergistic supersonic wave anti-felting method |
| CN111286972A (en) * | 2020-02-05 | 2020-06-16 | 上海恋轩实业有限公司 | Shrink-proof and crease-resistant process for worsted cashmere fabric |
| CN111560690A (en) * | 2020-05-13 | 2020-08-21 | 杭州悦仕达新材料科技有限公司 | Flame-retardant elastic textile fabric and processing method thereof |
| CN111850773A (en) * | 2020-08-13 | 2020-10-30 | 嘉兴市华盛达时装股份有限公司 | Machine-washable wool fabric processing technology |
| CN111962293A (en) * | 2020-08-18 | 2020-11-20 | 浙江曙丰毛纺织科技股份有限公司 | Processing technology of blended wool graphene wool fabric |
| CN112095259A (en) * | 2020-08-21 | 2020-12-18 | 常熟市新光毛条处理有限公司 | Continuous treatment process of Basolan wool tops |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103031704B (en) | 2015-08-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103031704B (en) | A kind of felt proofing anti-shrink finish method of wool fabric | |
| CN101424040B (en) | Wool fiber modification treatment method | |
| CN102965959B (en) | Wool refining treating fluid and treating method | |
| CN103924439A (en) | Method for protease-method wool felt-proofing treatment by using ultrasonic technology | |
| CN101929078B (en) | Shrink-proof treatment method for cashmere fibres | |
| WO2016127951A1 (en) | Process and device for chlorine-free shrinkproof treatment of wool raw material and article thereof | |
| EP0635078B1 (en) | A process for defuzzing and depilling cellulosic fabrics | |
| WO2018177442A1 (en) | Extra-long cowhide collagen fiber, and manufacturing method and use thereof | |
| CN105177989A (en) | Anti-crease and anti-shrink finishing process for wool fabric | |
| CN105544201A (en) | Production method of mercerized wool air layer fabric | |
| JPH08503752A (en) | Method for treating cellulose fabric using cellulase | |
| CN1483877A (en) | High-count bamboo-fibril fabric. and dyeing-finishing technological method thereof | |
| CN106661824B (en) | Method for producing spinning fibrilia and spinning fibrilia | |
| CN102505502A (en) | Short-process dyeing pretreatment technology for ramee | |
| CN105544211B (en) | A kind of the tatting non-ironing face fabric and its processing method of the smooth feel of softness | |
| CN103938396A (en) | Clothing ironing-free finishing process | |
| Rehman et al. | Revolution of biotechnology in finishing sector of textile | |
| CN106012493B (en) | A kind of Environmentally-frieantibacterial antibacterial wool treatment process | |
| CN101240504A (en) | Technique for manufacturing soft jean | |
| EP1141473A1 (en) | Improved cellulase treatments for fabric | |
| JPH04281063A (en) | Improvement of touch of cellulosic fiber fabric | |
| CN103835141A (en) | Cellulase water washing method for jean textile | |
| CN103806263A (en) | Shrink resistant processing method of cashmere yarn | |
| Singh et al. | Recent advances in chemical processing of natural and synthetic textiles | |
| CN103850117A (en) | Deformation-preventing finishing method for cashmere fibers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SHENGZHOU YOUNGOR WOOL TEXTILE CO., LTD. Free format text: FORMER OWNER: NINGBO YOUNGOR WOOL TEXTILE DYEING + FINISHING CO., LTD. Effective date: 20141215 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 315153 NINGBO, ZHEJIANG PROVINCE TO: 312400 SHAOXING, ZHEJIANG PROVINCE |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20141215 Address after: 312400 Chengdong District, Shengzhou Economic Development Zone, Zhejiang Applicant after: Shengzhou Younger Woolen Textile Co., Ltd Address before: Yinxian Avenue West Section 315153 in Zhejiang province Ningbo City No. 1 Applicant before: Ningbo Youngor Wool Weaving Dyeing & Finishing Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |