CN103031054B - A kind of Antistatic, high-temperature-resandant andant explosion-proof coating and preparation method thereof - Google Patents

A kind of Antistatic, high-temperature-resandant andant explosion-proof coating and preparation method thereof Download PDF

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CN103031054B
CN103031054B CN201210590489.3A CN201210590489A CN103031054B CN 103031054 B CN103031054 B CN 103031054B CN 201210590489 A CN201210590489 A CN 201210590489A CN 103031054 B CN103031054 B CN 103031054B
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mixture
parts
temperature
antistatic
temperature resistant
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CN103031054A (en
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柳彩虹
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Hangzhou Liwei Chemical Coatings Co.,Ltd.
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Hangzhou Liwei Chemical Industrial Paint Co Ltd
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Abstract

The present invention relates to a kind of Antistatic, high-temperature-resandant andant explosion-proof coating, it is made up of mixture first and mixture second; Described mixture first comprises the component of following weight part: nano-level conducting mica powder 6-8 part, nanometer scale ceramics powder 8-10 part, diacetone alcohol 18 parts, 2 parts, static inhibitor; Described mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 56-62 part, silane coupling agent 1 part, high temperature resistant inorganic pigment 5 parts.The present invention compared with prior art, has the following advantages and effect: the high thermal resistance of this Antistatic, high-temperature-resandant andant explosion-proof coating paint film is good, and this coating can be widely used in the high-temperature corrosion environments such as thermal power plant, boiler, smelting.

Description

A kind of Antistatic, high-temperature-resandant andant explosion-proof coating and preparation method thereof
Technical field
The present invention relates to a kind of Antistatic, high-temperature-resandant andant explosion-proof coating, the invention still further relates to the preparation method of this coating.
Background technology
Traditional coating is in long-time dispersion or long-distance transport process, and due to dispersion, rock, electrostatic can be gathered in coating inside, if electrostatic can not be derived in time, runs up to and to a certain degree may cause combustion explosion.Traditional coating only devises high-temperature resistant organic silicon resin and high-temperature resisting pigment, and only has one paint film protection ground.
People devise antistatic coating to overcome electrostatic, as disclosed a kind of antistatic coating in the Chinese invention patent specification sheets of application publication number CN102690582A, described coating comprises: E-12 epoxy resin, vibrin, silicone resin, pigment and static inhibitor.Although also with the addition of static inhibitor in this antistatic coating, have certain effect of deriving electrostatic, if will reach desirable Hangzhoupro electrostatic efficiency, so the addition of static inhibitor can be relatively very large, thus make do not have advantage on cost.In general coating, static inhibitor is all generally with particle form distribution in coating, can not reach the dispersion of molecular level, make its antistatic effect not good.
And general antistatic coating with the addition of high-temperature resistant organic silicon resin and high-temperature resisting pigment, still only have one paint film protection ground.
Summary of the invention
The object of the invention is to overcome above shortcomings in prior art, and provide a kind of antistatic effect good, addition is low, and cost is low, the Antistatic, high-temperature-resandant andant explosion-proof coating that resistance to elevated temperatures is good.
The present invention's adopted technical scheme that solves the problem is: this Antistatic, high-temperature-resandant andant explosion-proof coating, and its special character is: be made up of mixture first and mixture second;
Described mixture first comprises the component of following weight part: nano-level conducting mica powder 6-8 part, nanometer scale ceramics powder 8-10 part, diacetone alcohol 18 parts, 2 parts, static inhibitor;
Described mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 56-62 part, silane coupling agent 1 part, high temperature resistant inorganic pigment 5 parts.
Present invention also offers the preparation method of this Antistatic, high-temperature-resandant andant explosion-proof coating, its special character is to comprise the following steps:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol ensures fully wetting, then adds static inhibitor, then with dispersion machine in speed be 800-1000r/min rotating speed under stir 5min to be uniformly dispersed, make mixture first;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1200-1400r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) by mixture first and the mixing of mixture second.
The present invention compared with prior art, has the following advantages and effect: the high thermal resistance of this Antistatic, high-temperature-resandant andant explosion-proof coating paint film is good, and this coating can be widely used in the high-temperature corrosion environments such as thermal power plant, boiler, smelting.
Antistatic, high-temperature-resandant andant explosion-proof coating of the present invention, static inhibitor and nano-level conducting mica powder is added in formula, the conductive network running through whole coating inside is formed by the functional groups of static inhibitor and nano mica particle, effectively can improve the electroconductibility of coating under liquid or solid state, thus the electrostatic energy of coating accumulated inside can be guided to the packaging container of metal of coating, then by packaging container of metal, electrostatic is caused external static conducting device.The amount of the static inhibitor that coating of the present invention adds and nano-level conducting mica powder can not produce obviously impact to paint film quality.
Antistatic, high-temperature-resandant andant explosion-proof coating of the present invention, devise two pipe protections, nanometer scale ceramics powder is with the addition of in formula, nanometer scale ceramics powder melts gradually in high temperature environments and can form the first layer enamel protective layer by emersion coating surface, enamel protective layer can strengthen the physical strength of film, thermostability, dielectric strength and prevent the erosion of liquid, gas, effectively can ensure that paint film can not cross thermal spalling under high temperature (800 DEG C) condition; And the rear second protective layer that formed of the solidification such as high-temperature resistant organic silicon resin, high temperature resistant inorganic pigment in coating of the present invention, twice protect system effectively improves the work-ing life of paint film.
Embodiment
Below by embodiment, the present invention is described in further detail, and following examples are explanation of the invention and the present invention is not limited to following examples.
Embodiment 1.
In the present embodiment, Antistatic, high-temperature-resandant andant explosion-proof coating is made up of mixture first and mixture second;
Mixture first comprises the component of following weight part: nano-level conducting mica powder 6 parts, 8 parts, nanometer scale ceramics powder, diacetone alcohol 18 parts, 2 parts, static inhibitor;
Mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 56 parts, silane coupling agent 1 part, high temperature resistant inorganic pigment 5 parts.
In the present embodiment, static inhibitor can select cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of Antistatic, high-temperature-resandant andant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol ensures fully wetting, then adds static inhibitor, then with dispersion machine in speed be 800r/min rotating speed under stir 5min to be uniformly dispersed, make mixture first;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1200r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) by mixture first and the mixing of mixture second.
Embodiment 2.
In the present embodiment, Antistatic, high-temperature-resandant andant explosion-proof coating is made up of mixture first and mixture second;
Mixture first comprises the component of following weight part: nano-level conducting mica powder 8 parts, 10 parts, nanometer scale ceramics powder, diacetone alcohol 18 parts, 2 parts, static inhibitor;
Mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 62 parts, silane coupling agent 1 part, high temperature resistant inorganic pigment 5 parts.
In the present embodiment, static inhibitor can select cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of Antistatic, high-temperature-resandant andant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol ensures fully wetting, then adds static inhibitor, then with dispersion machine in speed be 1000r/min rotating speed under stir 5min to be uniformly dispersed, make mixture first;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1400r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) by mixture first and the mixing of mixture second.
Embodiment 3.
In the present embodiment, Antistatic, high-temperature-resandant andant explosion-proof coating is made up of mixture first and mixture second;
Mixture first comprises the component of following weight part: nano-level conducting mica powder 7 parts, 9 parts, nanometer scale ceramics powder, diacetone alcohol 18 parts, 2 parts, static inhibitor;
Mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 59 parts, silane coupling agent 1 part, high temperature resistant inorganic pigment 5 parts.
In the present embodiment, static inhibitor can select cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of Antistatic, high-temperature-resandant andant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol ensures fully wetting, then adds static inhibitor, then with dispersion machine in speed be 900r/min rotating speed under stir 5min to be uniformly dispersed, make mixture first;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1300r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) by mixture first and the mixing of mixture second.
Embodiment 4.
In the present embodiment, Antistatic, high-temperature-resandant andant explosion-proof coating is made up of mixture first and mixture second;
Mixture first comprises the component of following weight part: nano-level conducting mica powder 6 parts, 10 parts, nanometer scale ceramics powder, diacetone alcohol 18 parts, 2 parts, static inhibitor;
Mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 62 parts, silane coupling agent 1 part, high temperature resistant inorganic pigment 5 parts.
In the present embodiment, static inhibitor can select cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of Antistatic, high-temperature-resandant andant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol ensures fully wetting, then adds static inhibitor, then with dispersion machine in speed be 1000r/min rotating speed under stir 5min to be uniformly dispersed, make mixture first;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1200r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) by mixture first and the mixing of mixture second.
Embodiment 5.
In the present embodiment, Antistatic, high-temperature-resandant andant explosion-proof coating is made up of mixture first and mixture second;
Mixture first comprises the component of following weight part: nano-level conducting mica powder 8 parts, 8 parts, nanometer scale ceramics powder, diacetone alcohol 18 parts, 2 parts, static inhibitor;
Mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 56 parts, silane coupling agent 1 part, high temperature resistant inorganic pigment 5 parts.
In the present embodiment, static inhibitor can select cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of Antistatic, high-temperature-resandant andant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol ensures fully wetting, then adds static inhibitor, then with dispersion machine in speed be 800r/min rotating speed under stir 5min to be uniformly dispersed, make mixture first;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1400r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) by mixture first and the mixing of mixture second.
Above content described in this specification sheets is only made for the present invention illustrating.Those skilled in the art can make various amendment or supplement or adopt similar mode to substitute to described specific embodiment; only otherwise depart from the content of specification sheets of the present invention or surmount this scope as defined in the claims, protection scope of the present invention all should be belonged to.

Claims (2)

1. an Antistatic, high-temperature-resandant andant explosion-proof coating, is characterized in that: be made up of mixture first and mixture second;
Described mixture first comprises the component of following weight part: nano-level conducting mica powder 6-8 part, nanometer scale ceramics powder 8-10 part, diacetone alcohol 18 parts, 2 parts, static inhibitor;
Described mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 56-62 part, silane coupling agent 1 part, high temperature resistant inorganic pigment 5 parts.
2. the preparation method of Antistatic, high-temperature-resandant andant explosion-proof coating according to claim 1, is characterized in that comprising the following steps:
1) nano-level conducting mica powder and nano-ceramic powder being soaked 2h with diacetone alcohol ensures fully wetting, then adds static inhibitor, then with dispersion machine in speed be 800-1000r/min rotating speed under stir 5min to be uniformly dispersed, make mixture first;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1200-1400r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) by mixture first and the mixing of mixture second.
CN201210590489.3A 2012-12-31 2012-12-31 A kind of Antistatic, high-temperature-resandant andant explosion-proof coating and preparation method thereof Active CN103031054B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107118660A (en) * 2017-06-06 2017-09-01 明光市泰丰新材料有限公司 A kind of emergency light fluorescent tube explosion-proof coating of heat conductive flame-retarding and preparation method thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107459908A (en) * 2017-08-25 2017-12-12 刘伟 A kind of explosion-proof coating of test tube glass and preparation method thereof
CN109337576B (en) * 2018-10-17 2021-01-15 北京亚创联华节能环保科技有限公司 Graphite electrode protective agent

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Publication number Priority date Publication date Assignee Title
CN2605457Y (en) * 2002-12-20 2004-03-03 中国石油天然气集团公司 High-temperature resistant silicone anti-corrosive layer heat-insulating pipe
CN101033369A (en) * 2007-04-19 2007-09-12 重庆三峡油漆股份有限公司 Semi-interpenetrating network structure double-component fire resistant paint
CN101113289A (en) * 2007-08-22 2008-01-30 王正堂 Anti-corrosion abrasion-resistant powder coating and method for making same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2605457Y (en) * 2002-12-20 2004-03-03 中国石油天然气集团公司 High-temperature resistant silicone anti-corrosive layer heat-insulating pipe
CN101033369A (en) * 2007-04-19 2007-09-12 重庆三峡油漆股份有限公司 Semi-interpenetrating network structure double-component fire resistant paint
CN101113289A (en) * 2007-08-22 2008-01-30 王正堂 Anti-corrosion abrasion-resistant powder coating and method for making same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107118660A (en) * 2017-06-06 2017-09-01 明光市泰丰新材料有限公司 A kind of emergency light fluorescent tube explosion-proof coating of heat conductive flame-retarding and preparation method thereof

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Address after: No. 226, Jingcheng Road, hengcun Town, Tonglu County, Hangzhou City, Zhejiang Province

Patentee after: Hangzhou Liwei Chemical Coatings Co.,Ltd.

Address before: No.19, xujiabu community, Chengdong village, hengcun Town, Tonglu County, Hangzhou City, Zhejiang Province

Patentee before: HANGZHOU LIWEI CHEMICAL INDUSTRIAL PAINT Co.,Ltd.