CN103031054A - Antistatic, high-temperature-resistant and explosion-proof coating and preparation method thereof - Google Patents

Antistatic, high-temperature-resistant and explosion-proof coating and preparation method thereof Download PDF

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Publication number
CN103031054A
CN103031054A CN2012105904893A CN201210590489A CN103031054A CN 103031054 A CN103031054 A CN 103031054A CN 2012105904893 A CN2012105904893 A CN 2012105904893A CN 201210590489 A CN201210590489 A CN 201210590489A CN 103031054 A CN103031054 A CN 103031054A
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mixture
parts
temperature resistant
high temperature
antistatic
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CN2012105904893A
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CN103031054B (en
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柳彩虹
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Hangzhou Liwei Chemical Coatings Co.,Ltd.
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Hangzhou Liwei Chemical Industrial Paint Co Ltd
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Abstract

The invention relates to an antistatic, high-temperature-resistant and explosion-proof coating which consists of a mixture A and a mixture B, wherein the mixture A comprises the following components in parts by weight: 6-8 parts of nano conductive mica powder, 8-10 parts of nano ceramic powder, 18 parts of diacetone alcohol, and 2 parts of an antistatic agent, and the mixture B comprises the following components in parts by weight: 56-62 parts of high-temperature-resistant silicone resin, 1 part of an silane coupling agent, and 5 parts of high-temperature-resistant inorganic pigment. Compared with the prior art, the coating has the following advantages and effects that the high-temperature resistance of a film of the antistatic, high-temperature-resistant and explosion-proof coating is good, and the coating can be widely applied to high-temperature corrosion environments such as thermal power plants, boilers and smelting.

Description

A kind of antistatic high temperature resistant explosion-proof coating and preparation method thereof
Technical field
The present invention relates to a kind of antistatic high temperature resistant explosion-proof coating, the invention still further relates to the preparation method of this coating.
Background technology
Traditional coating long-time disperse or the long-distance transport process in owing to disperseing, rocking, static can be gathered in coating inside, if static can not in time be derived, runs up to a certain degree and may cause combustion explosion.Traditional coating has only designed high-temperature resistant organic silicon resin and high-temperature resisting pigment, and only has paint film protection ground one.
People have designed antistatic coating in order to overcome static, disclose a kind of antistatic coating in the Chinese invention patent specification sheets such as application publication number CN 102690582 A, described coating comprises: E-12 Resins, epoxy, vibrin, silicone resin, pigment and static inhibitor.Although also added static inhibitor in this antistatic coating, have the effect of certain derivation static, if reach desirable Hangzhoupro electrostatic efficiency, the addition of static inhibitor can be relatively very large so, thereby so that do not have advantage at cost.In the general coating, static inhibitor generally all is to distribute with particle form in coating, can not reach the dispersion of molecular level, so that its antistatic effect is not good.
And the interpolation of general antistatic coating high-temperature resistant organic silicon resin and high-temperature resisting pigment, still only have one paint film protection ground.
Summary of the invention
The object of the invention is to overcome above shortcomings in the prior art, and provide a kind of antistatic effect good, addition is low, and cost is low, the antistatic high temperature resistant explosion-proof coating that resistance to elevated temperatures is good.
The present invention addresses the above problem the technical scheme that adopts: this antistatic high temperature resistant explosion-proof coating, and its special character is: be comprised of mixture first and mixture second;
Described mixture first comprises the component of following weight part: nano-level conducting mica powder 6-8 part, nanometer scale ceramics powder 8-10 part, 18 parts of diacetone alcohols, 2 parts in static inhibitor;
Described mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 56-62 part, 1 part of silane coupling agent, 5 parts of high temperature resistant inorganic pigment.
The present invention also provides the preparation method of this antistatic high temperature resistant explosion-proof coating, and its special character is may further comprise the steps:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol and guarantee fully wettingly, then add static inhibitor, is that stirring 5min makes the mixture first to be uniformly dispersed under the rotating speed of 800-1000r/min in speed with dispersion machine again;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1200-1400r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) mixture first and mixture second are mixed.
The present invention compared with prior art has the following advantages and effect: the high thermal resistance of this antistatic high temperature resistant explosion-proof coating paint film is good, and this coating can be widely used in the high temperature corrosive environments such as thermal power plant, boiler, smelting.
Antistatic high temperature resistant explosion-proof coating of the present invention, in prescription, add static inhibitor and nano-level conducting mica powder, functional groups by static inhibitor and nano mica particle forms the conductive network that runs through whole coating inside, can the electroconductibility of Effective Raise coating under the liquid or solid state, thereby the electrostatic energy of coating accumulated inside can be guided to the packaging container of metal of coating, by packaging container of metal static be caused external static conducting device again.The static inhibitor that coating of the present invention adds and the amount of nano-level conducting mica powder can not produce obviously impact to the paint film quality.
Antistatic high temperature resistant explosion-proof coating of the present invention, two pipe protections have been designed, in prescription, added the nanometer scale ceramics powder, the nanometer scale ceramics powder melts gradually under hot environment and can form the first layer enamel protective layer by the emersion coating surface, the enamel protective layer can strengthen physical strength, thermostability, the dielectric strength of filming and the erosion that prevents liquid, gas, can guarantee effectively that paint film can not cross thermal spalling under high temperature (800 ℃) condition; And forming the second protective layer after the curing such as the high-temperature resistant organic silicon resin in the coating of the present invention, high temperature resistant inorganic pigment, twice have been protected the system Effective Raise work-ing life of paint film.
Embodiment
The present invention is described in further detail below by embodiment, and following examples are explanation of the invention and the present invention is not limited to following examples.
Embodiment 1.
In the present embodiment, antistatic high temperature resistant explosion-proof coating is comprised of mixture first and mixture second;
The mixture first comprises the component of following weight part: 6 parts of nano-level conducting mica powders, 8 parts in nanometer scale ceramics powder, 18 parts of diacetone alcohols, 2 parts in static inhibitor;
Mixture second comprises the component of following weight part: 56 parts of high-temperature resistant organic silicon resins, 1 part of silane coupling agent, 5 parts of high temperature resistant inorganic pigment.
In the present embodiment, static inhibitor can be selected cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of antistatic high temperature resistant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol and guarantee fully wettingly, then add static inhibitor, is that stirring 5min makes the mixture first to be uniformly dispersed under the rotating speed of 800r/min in speed with dispersion machine again;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1200r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) mixture first and mixture second are mixed.
Embodiment 2.
In the present embodiment, antistatic high temperature resistant explosion-proof coating is comprised of mixture first and mixture second;
The mixture first comprises the component of following weight part: 8 parts of nano-level conducting mica powders, 10 parts in nanometer scale ceramics powder, 18 parts of diacetone alcohols, 2 parts in static inhibitor;
Mixture second comprises the component of following weight part: 62 parts of high-temperature resistant organic silicon resins, 1 part of silane coupling agent, 5 parts of high temperature resistant inorganic pigment.
In the present embodiment, static inhibitor can be selected cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of antistatic high temperature resistant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol and guarantee fully wettingly, then add static inhibitor, is that stirring 5min makes the mixture first to be uniformly dispersed under the rotating speed of 1000r/min in speed with dispersion machine again;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1400r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) mixture first and mixture second are mixed.
Embodiment 3.
In the present embodiment, antistatic high temperature resistant explosion-proof coating is comprised of mixture first and mixture second;
The mixture first comprises the component of following weight part: 7 parts of nano-level conducting mica powders, 9 parts in nanometer scale ceramics powder, 18 parts of diacetone alcohols, 2 parts in static inhibitor;
Mixture second comprises the component of following weight part: 59 parts of high-temperature resistant organic silicon resins, 1 part of silane coupling agent, 5 parts of high temperature resistant inorganic pigment.
In the present embodiment, static inhibitor can be selected cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of antistatic high temperature resistant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol and guarantee fully wettingly, then add static inhibitor, is that stirring 5min makes the mixture first to be uniformly dispersed under the rotating speed of 900r/min in speed with dispersion machine again;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1300r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) mixture first and mixture second are mixed.
Embodiment 4.
In the present embodiment, antistatic high temperature resistant explosion-proof coating is comprised of mixture first and mixture second;
The mixture first comprises the component of following weight part: 6 parts of nano-level conducting mica powders, 10 parts in nanometer scale ceramics powder, 18 parts of diacetone alcohols, 2 parts in static inhibitor;
Mixture second comprises the component of following weight part: 62 parts of high-temperature resistant organic silicon resins, 1 part of silane coupling agent, 5 parts of high temperature resistant inorganic pigment.
In the present embodiment, static inhibitor can be selected cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of antistatic high temperature resistant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol and guarantee fully wettingly, then add static inhibitor, is that stirring 5min makes the mixture first to be uniformly dispersed under the rotating speed of 1000r/min in speed with dispersion machine again;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1200r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) mixture first and mixture second are mixed.
Embodiment 5.
In the present embodiment, antistatic high temperature resistant explosion-proof coating is comprised of mixture first and mixture second;
The mixture first comprises the component of following weight part: 8 parts of nano-level conducting mica powders, 8 parts in nanometer scale ceramics powder, 18 parts of diacetone alcohols, 2 parts in static inhibitor;
Mixture second comprises the component of following weight part: 56 parts of high-temperature resistant organic silicon resins, 1 part of silane coupling agent, 5 parts of high temperature resistant inorganic pigment.
In the present embodiment, static inhibitor can be selected cationic level Four ammonium compound.
In the present embodiment, the PMX silane coupling agent that silane coupling agent can select Dow corning to produce.
In the present embodiment, the preparation method of antistatic high temperature resistant explosion-proof coating is:
1) nano-level conducting mica powder and nanometer scale ceramics powder being soaked 2h with diacetone alcohol and guarantee fully wettingly, then add static inhibitor, is that stirring 5min makes the mixture first to be uniformly dispersed under the rotating speed of 800r/min in speed with dispersion machine again;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1400r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) mixture first and mixture second are mixed.
Above content described in this specification sheets only is made for the present invention illustrating.Those skilled in the art can make various modifications or replenish or adopt similar mode to substitute described specific embodiment; only otherwise depart from the content of specification sheets of the present invention or surmount this scope as defined in the claims, all should belong to protection scope of the present invention.

Claims (2)

1. an antistatic high temperature resistant explosion-proof coating is characterized in that: be comprised of mixture first and mixture second;
Described mixture first comprises the component of following weight part: nano-level conducting mica powder 6-8 part, nanometer scale ceramics powder 8-10 part, 18 parts of diacetone alcohols, 2 parts in static inhibitor;
Described mixture second comprises the component of following weight part: high-temperature resistant organic silicon resin 56-62 part, 1 part of silane coupling agent, 5 parts of high temperature resistant inorganic pigment.
2. the preparation method of antistatic high temperature resistant explosion-proof coating according to claim 1 is characterized in that may further comprise the steps:
1) nano-level conducting mica powder and nano-ceramic powder being soaked 2h with diacetone alcohol and guarantee fully wettingly, then add static inhibitor, is that stirring 5min makes the mixture first to be uniformly dispersed under the rotating speed of 800-1000r/min in speed with dispersion machine again;
2) high-temperature resistant organic silicon resin and silane coupling agent are stirred 5min under the rotating speed of 1200-1400r/min, then add high temperature resistant inorganic pigment, stir 10min, make mixture second;
3) mixture first and mixture second are mixed.
CN201210590489.3A 2012-12-31 2012-12-31 A kind of Antistatic, high-temperature-resandant andant explosion-proof coating and preparation method thereof Active CN103031054B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107459908A (en) * 2017-08-25 2017-12-12 刘伟 A kind of explosion-proof coating of test tube glass and preparation method thereof
CN109337576A (en) * 2018-10-17 2019-02-15 北京亚创联华节能环保科技有限公司 A kind of graphite electrode protective agent

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107118660A (en) * 2017-06-06 2017-09-01 明光市泰丰新材料有限公司 A kind of emergency light fluorescent tube explosion-proof coating of heat conductive flame-retarding and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2605457Y (en) * 2002-12-20 2004-03-03 中国石油天然气集团公司 High-temperature resistant silicone anti-corrosive layer heat-insulating pipe
CN101033369A (en) * 2007-04-19 2007-09-12 重庆三峡油漆股份有限公司 Semi-interpenetrating network structure double-component fire resistant paint
CN101113289A (en) * 2007-08-22 2008-01-30 王正堂 Anti-corrosion abrasion-resistant powder coating and method for making same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2605457Y (en) * 2002-12-20 2004-03-03 中国石油天然气集团公司 High-temperature resistant silicone anti-corrosive layer heat-insulating pipe
CN101033369A (en) * 2007-04-19 2007-09-12 重庆三峡油漆股份有限公司 Semi-interpenetrating network structure double-component fire resistant paint
CN101113289A (en) * 2007-08-22 2008-01-30 王正堂 Anti-corrosion abrasion-resistant powder coating and method for making same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107459908A (en) * 2017-08-25 2017-12-12 刘伟 A kind of explosion-proof coating of test tube glass and preparation method thereof
CN109337576A (en) * 2018-10-17 2019-02-15 北京亚创联华节能环保科技有限公司 A kind of graphite electrode protective agent

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Address after: No. 226, Jingcheng Road, hengcun Town, Tonglu County, Hangzhou City, Zhejiang Province

Patentee after: Hangzhou Liwei Chemical Coatings Co.,Ltd.

Address before: No.19, xujiabu community, Chengdong village, hengcun Town, Tonglu County, Hangzhou City, Zhejiang Province

Patentee before: HANGZHOU LIWEI CHEMICAL INDUSTRIAL PAINT Co.,Ltd.