CN103031048A - Low solar-energy absorbing energy-saving coating for ship - Google Patents
Low solar-energy absorbing energy-saving coating for ship Download PDFInfo
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- CN103031048A CN103031048A CN2012105425418A CN201210542541A CN103031048A CN 103031048 A CN103031048 A CN 103031048A CN 2012105425418 A CN2012105425418 A CN 2012105425418A CN 201210542541 A CN201210542541 A CN 201210542541A CN 103031048 A CN103031048 A CN 103031048A
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Abstract
The invention discloses a low solar-energy absorbing energy-saving coating for a ship. The coating is characterized by comprising an anti-corrosive primer, a heat-reflective finish and a heat-insulating intermediate coating, wherein the heat-reflective finish comprises a group A and a group B; the group A comprises the following components: 40-50% of polyhydroxy acrylic resin, 25-35% of rutile titanium dioxide, 8-15% of other pigments and fillers, 8-15% of solvent, and 2-5% of auxiliary; the group B comprises the component: aliphatic polyisocyanate; the heat-insulating intermediate coating comprises a group A and a group B; the group A comprises the following components: 25-35% of epoxy resin, 10-15% of hollow glass beads, 20-30% of other pigments and fillers, 20-30% of solvent and 2-5% of auxiliary; and the group B comprises the following components: low-molecular polyamide resin and a solvent. The coating system comprises three layers, can reduce adsorption of outer walls of the ship to sunlight irradiation energy, reduce temperature rising in the cabin, improve the security of petroleum storage and transportation, and can prevent corrosion, reduce temperature and save energy in the construction industry.
Description
Technical field
The present invention relates to a kind of coating technology, particularly a kind of naval vessel is with hanging down the energy-saving coating of solar absorption.
Background technology
When global construction industry, petroleum industry, transport trade, weapon industry etc. developed rapidly, environment-friendly temperature-reducing, raising production security aspect more and more received domestic and international personage's concern.The research of external various cooling coatings is very active at present, a lot of fields have been widely used in, be applied to the space shuttle heat-insulation and heat-preservation such as U.S.'s shield energy-saving coatings, make filler with the hollow ceramic microballon, this class coating can make coated article (such as the house) internal temperature greatly reduce, obviously reduce air-conditioning and take (saving energy 40%), have simultaneously preferably corrosion protection, fire-retardant, water-proof function concurrently, safety non-toxic has been widely used in oil gas storage tank, the building construction roof of the states such as the U.S., Japan, Malaysia and Singapore.The heat insulation C16 of the council of U.S. ASTM has also formulated C1483 standard (heat-reflecting insulating coating), all technical, testing method to heat reflection coatings have been made regulation, indicate " heat-reflecting heat-insulating protective system " formally accepted by the U.S. and given application in association area, such as steel construction, external wall etc.In addition, people's huge fund the lower the temperature research of coating or cooling material and beginning commercialization are all thrown by the country such as Japanese, Italian.It is reported, after Japan comes into effect and corrects energy law (rationally using the relevant law of the energy), each associated companies is all accelerating to carry out solar energy shielding coating, adiabatic coating, all coat solar energy shielding coating on the factory roof such as major companies such as Matsushita Electric Industries and rising sun building coatings, Japanese special coating company with soundproof technology then emphasis promotes and has the solar energy shielding coating that mixes anti-sound function, Japan is after correcting the energy law release, and the prospect of solar energy shielding coating is particularly good.Shipbuilding industry aspect, the heat reflection type ship shell finish paint of IP company are applied on more than 100 naval vessel, the whole world.The report of domestic, cooling coating energy-conservation about developing in recent years quantity increases to some extent, has development HC solar energy shielding protective system to be used for the petroleum product storage tank such as North China petrochemical buildings material factory; The morning twilight coating company limited development of changzhou is used for the heat reflection coatings of building roof and metope; Lanzhou coating Research Institute is used for the coating on rocket liquid oxygen storage tank surface, raises vaporization of liquid oxygen, reflectivity about 75% to prevent tank temperature.The heat reflection coatings home products of covil construction is more, existing industry internal standard: JG/T235-2008, and its solar energy reflection ratio to heat reflection coatings, hemispherical emissivity, the heat insulation temperature difference and the decay of the heat insulation temperature difference have proposed index request.
The boats and ships aspect, the units such as Inst. of Marine Chemical Engineering, Shanghai kairine have succeeded in developing has heat reflection type sea grey shell finish paint, has obtained application on the naval vessel.The patent No. is that ZL2009's 1 0137811.5 " grey shell finish paint in a kind of low solar absorbing energy-saving type " patent has been carried out patent application for finish paint, but about the naval vessel that formed by heat reflection finish paint, heat insulation middle layer and the rust-proofing primer domestic report that there is not yet of patent with the low energy-saving coating system of solar absorption.
Summary of the invention
Technical problem to be solved by this invention provides a kind of naval vessel with hanging down the energy-saving coating of solar absorption, be used in ship hull and the superstructure, thereby reduce the naval vessel outer wall to the absorption of solar light irradiation energy, reduce the raising of room temp, improve crewman's Life and job condition, save a large amount of cooling expenses, promote China naval vessel to the energy-conserving and environment-protective future development; Solve because boats and ships are subjected to sunlight exposure for a long time on the sea problem of excess Temperature in the cabin.
For the purpose that realizes solving the problems of the technologies described above, the present invention has adopted following technical scheme:
A kind of naval vessel of the present invention comprises rust-proofing primer, heat reflection finish paint, heat insulation intermediate coat with the low energy-saving coating of solar absorption, includes the first and second components, and rust-proofing primer is common commercially available epoxy zinc rich primer or epoxy micaceous iron oxide rustproof paint, wherein
The mass percent of the first component of heat reflection finish paint consists of:
Poly-hydroxy acrylic resin: 40～50%;
Rutile type Titanium Dioxide: 25～35%;
Other face, filler: 8～15%;
Solvent 8～15%;
Auxiliary agent 2～5%;
The second component of heat reflection finish paint is aliphatic polymeric isocyanate, its technical indicator :-NCO content is 16.5%(wt); The first and second constituent masses are than being 7:1～6:1
The mass percent of the first component of heat insulation intermediate coat consists of:
Resins, epoxy: 25～35%;
Hollow glass micropearl: 10～15%;
Other face, filler: 20～30%;
Solvent: 20～30%;
Auxiliary agent: 2～5%;
The mass percent of the second component of heat insulation intermediate coat consists of:
The low molecule pa resin of amine value 230 ~ 240 mgKOH/g: 40～60%;
The low molecule pa resin of amine value 200 ~ 240 mgKOH/g: 20～30%;
Solvent: 20～30%;
The first and second constituent masses are than being 3.5:1～2.5:1;
The coat-thickness that rust-proofing primer, heat reflection finish paint and heat insulation intermediate coat require:
Rust-proofing primer build: 50 μ m ± 10 μ m;
Heat insulation intermediate coat build: 200 ~ 300 μ m;
Heat reflection finish paint build: 80 μ m ± 10 μ m.
Concrete, the poly-hydroxy acrylic resin technical indicator of described heat reflection finish paint first component is hydroxyl value: 80 ± 5 mgKOH/g, solid part: 60 ~ 65%.
The mixture that other face of described heat reflection finish paint first component, filler specifically refer to light calcium carbonate or the two arbitrary proportion of calcined kaolin.
The solvent of described heat reflection finish paint first component is the mixture of dimethylbenzene and the two arbitrary proportion of N-BUTYL ACETATE.
The auxiliary agent of described heat reflection finish paint first component specifically refers to dispersion agent, wetting agent, defoamer, thixotropic agent.Wherein dispersion agent is for being fit to the multi-functional dispersion agent of oleoresin system, and such as the BYK110 of Bayer etc., consumption is generally 0.2% ~ 0.5% of coating total amount; Defoamer is generally selected 6800 of oiliness polyurethane system defoamer such as the modest company of moral, and consumption is generally 1 ~ 1.5% of resin total amount; Thixotropic agent is generally selected the organobentonite class, 0.5% ~ 1% of the about coating total amount of consumption.
The aliphatic polymeric isocyanate of described heat reflection finish paint component B is preferably six methyne polyisocyanates, technical indicator: NCO content: 16.5%.
Concrete, the oxirane value of the Resins, epoxy of the first component of described heat insulation intermediate coat is: 0.48 ~ 0.52mol(100g)
-1
The hollow glass micropearl technical indicator of the first component of described heat insulation intermediate coat is: oil number 0.4 ~ 0.5g/cm
3, particle diameter is 10 ~ 120 μ m.
Other face of the first component of described heat insulation intermediate coat, filler specifically refer to the mixture of Feldspar Powder, mica powder, titanium dioxide arbitrary proportion.
The solvent of the first component of described heat insulation intermediate coat is the mixture of dimethylbenzene, propyl carbinol or epoxy active diluent arbitrary proportion.
The auxiliary agent of the first component of described heat insulation intermediate coat specifically refers to dispersion agent, thixotropic agent, defoamer, adhesion promoter, wherein general selection of dispersion agent is fit to the multi-functional dispersion agent of oleoresin system such as the BYK110 of Bayer etc., and consumption is generally 0.2% ~ 0.5% of coating total amount; Defoamer is generally selected 6800 of oleoresin system defoamer such as the modest company of moral, and consumption is generally 1 ~ 1.5% of resin total amount; Thixotropic agent is generally selected the Ultra of organobentonite class or German arkema, 0.5% ~ 1.5% of the about coating total amount of consumption, adhesion promoter: epoxy group(ing) coupling agent such as KH560,05 ~ 1% of the about coating total amount of consumption.
The low molecule pa resin of amine value 230 ~ 240 mgKOH/g of the second component of described heat insulation intermediate coat is polyamide resin 6060.This 6060 is the polyamide resin industry universal trade mark.
The low molecule pa resin of about 200 ~ 240 mgKOH/g of amine value of the second component of described heat insulation intermediate coat is polyamide resin 650.This 650 is the polyamide resin industry universal trade mark.
The solvent of the second component of described heat insulation intermediate coat is the mixture of dimethylbenzene, propyl carbinol arbitrary proportion.
These technical schemes also can make up mutually or combination, thereby reach better technique effect.
See Table 1 concrete the composition.
Table 1 reflection finish paint and heat insulation intermediate coat proportioning (mass percent)
In order to make coating have preferably low sun absorptive character, technical scheme principle of the present invention is:
⑴ will reflect, mechanism of heat insulation combines, and realize preferably cooling-down effect of coating system.As finish paint, thermal insulating coating is as the middle layer with heat reflection coatings, and rust-inhibiting paint makes coating system multiple functional as bottom, has the performances such as antirust, heat insulation, weather-proof and heat reflection.
⑵ heat reflection finish paint with weathering resistance preferably the poly-hydroxy acrylic resin as base-material, take Rutile type Titanium Dioxide as main face, filler, add the filler that the high particle diameter of a small amount of cost performance and titanium dioxide approach, improve the Rutile type Titanium Dioxide agglomeration, use sand milling technique and prepare the finish paint with good weather resisteant energy, the model test result shows to have higher solar reflectance.
⑶ adopt resistance to pressure, and better the hollow glass microbead of cracky is not as the main stuffing in coating system middle layer, and as base-material, the heat insulation middle layer for preparing has had good effect of heat insulation with Resins, epoxy with better adhesion effect.
A kind of naval vessel of the present invention is with hanging down the energy-saving coating of solar absorption, and its preparation method comprises:
1, heat reflection finish paint preparation technology
Front preparation feeds intake:
With the face such as Rutile type Titanium Dioxide, filler according to the accurate weighing of the requirement of turnout, be positioned over separately in the pallet of dried and clean, the Electric heat oven of putting into temperature and be 105 ± 2 ℃ is dried, drying time 4h, it is for subsequent use behind the naturally cooling face such as titanium dioxide, filler to be packed respectively sealing, and identifies accordingly.
First component production technological process is seen Fig. 1.
The component B production technological process is seen Fig. 2.
2, heat insulation intermediate coat preparation technology
Front preparation feeds intake:
Glass microballon and other color stuffings according to the accurate weighing of the requirement of turnout, are positioned over separately in the pallet of dried and clean, and identify accordingly.
First component production technological process is seen Fig. 3.
The component B production technological process is seen Fig. 4.
The key technical indexes of product of the present invention sees Table 2.
Table 2 naval vessel low solar absorbing energy-saving type coating the key technical indexes
By adopting technique scheme, the present invention has following beneficial effect:
A kind of naval vessel of the present invention is made of three layers of rust-proofing primer, heat insulation intermediate coat and heat reflection finish paints with the energy-saving coating system of low solar absorption, be applied to the above shell of boats and ships waterline and superstructure outside surface, can reduce the naval vessel outer wall to the absorption of solar light irradiation energy, reduce the raising of temperature in the cabin, improve crewman's Life and job condition, save a large amount of cooling expenses; Also can use in petrochemical industry accumulating industry, as be coated on tank wagon, large-scale oil storage tank outside surface, freight container outside surface, the security of the storages such as raising petrochemical industry accumulating; Can use in construction industry, be coated on steel structural roof, can play effect anticorrosion, cooling energy-saving.
Description of drawings
Fig. 1 is heat reflection finish paint first component production technological process.
Fig. 2 is heat reflection finish paint component B production technological process.
Fig. 3 is heat insulation intermediate coat first component production technological process.
Fig. 4 is heat insulation intermediate coat component B production technological process.
Embodiment
Below in conjunction with drawings and Examples this patent is further explained.But the protection domain of this patent is not limited to concrete embodiment.
Naval vessel of the present invention all is two component chemical reaction type coating with the heat reflection finish paint in the low energy-saving coating system of solar absorption and heat insulation intermediate coat, coating is mainly with two component high pressure airless spray equipment sprayings, heat reflection finish paint per pass application build is 40 μ m, recommends application 2 roads; Heat insulation intermediate coat per pass application build is 100 μ m, recommends application 2 to 3 roads.Condition of cure is ambient cure, surface drying: 3h; Do solid work: 24h.
Embodiment and products thereof detected result sees Table 3～table 8.
Table 3: embodiment 1
Wherein, 2210 is the poly-hydroxy acrylic resin.
The product detected result of table 4 embodiment 1
Table 5 embodiment 2
The product detected result of table 6 embodiment 2
Table 7 embodiment 3
The product detected result of table 8 embodiment 3
Annotate: epoxy active diluent NC-513 production firm: U.S. Ka Delai; 706 production firms: E.I.Du Pont Company; 6800: the modest company of Taiwan moral; HD-3: the large chemical industry in sea, Qingdao.
Claims (9)
1. a naval vessel is with hanging down the energy-saving coating of solar absorption, and it is characterized in that: comprise rust-proofing primer, heat reflection finish paint, heat insulation intermediate coat, include the first and second components, rust-proofing primer is epoxy zinc rich primer or epoxy micaceous iron oxide rustproof paint, wherein
The mass percent of the first component of heat reflection finish paint consists of:
Poly-hydroxy acrylic resin: 40～50%;
Rutile type Titanium Dioxide: 25～35%;
Other face, filler: 8～15%;
Solvent 8～15%;
Auxiliary agent 2～5%;
The second component of heat reflection finish paint is aliphatic polymeric isocyanate, its technical indicator :-NCO content is 16.5%(wt); The first and second constituent masses are than being 7:1～6:1;
The mass percent of the first component of heat insulation intermediate coat consists of:
Resins, epoxy: 25～35%;
Hollow glass micropearl: 10～15%;
Other face, filler: 20～30%;
Solvent: 20～30%;
Auxiliary agent: 2～5%;
The mass percent of the second component of heat insulation intermediate coat consists of:
The low molecule pa resin of amine value 230 ~ 240 mgKOH/g: 40～60%;
The low molecule pa resin of amine value 200 ~ 240 mgKOH/g: 20～30%;
Solvent: 20～30%;
The first and second constituent masses are than being 3.5:1～2.5:1;
The coat-thickness of rust-proofing primer, heat reflection finish paint and heat insulation intermediate coat is:
Rust-proofing primer build: 50 μ m ± 10 μ m;
Heat insulation intermediate coat build: 200 ~ 300 μ m;
Heat reflection finish paint build: 80 μ m ± 10 μ m;
Wherein, other face of heat reflection finish paint first component, filler specifically refer to the mixture of light calcium carbonate and the two arbitrary proportion of calcined kaolin;
The auxiliary agent of heat reflection finish paint first component refers to dispersion agent, defoamer, thixotropic agent;
Other face of the first component of heat insulation intermediate coat, filler specifically refer to the mixture of Feldspar Powder, mica powder, titanium dioxide arbitrary proportion;
The auxiliary agent of the first component of heat insulation intermediate coat specifically refers to dispersion agent, thixotropic agent, defoamer, adhesion promoter.
2. described naval vessel is with hanging down the energy-saving coating of solar absorption according to claim 1, and it is characterized in that: the poly-hydroxy acrylic resin technical indicator of described heat reflection finish paint first component is hydroxyl value: 80 ± 5 mgKOH/g, solid part: 60 ~ 65%.
3. described naval vessel is with hanging down the energy-saving coating of solar absorption according to claim 1, and it is characterized in that: the solvent of the first component of described heat reflection finish paint is dimethylbenzene, N-BUTYL ACETATE; Dispersion agent is for being fit to the multi-functional dispersion agent of oleoresin system, and consumption is 0.2% ~ 0.5% of coating total amount; Defoamer is oiliness polyurethane system defoamer, and consumption is 1 ~ 1.5% of resin total amount; Thixotropic agent is organobentonite, and consumption is 0.5% ~ 1% of coating total amount.
4. described naval vessel is with hanging down the energy-saving coating of solar absorption according to claim 1, and it is characterized in that: described aliphatic polymeric isocyanate is six methyne polyisocyanates, its NCO content: 16.5%.
5. described naval vessel is with hanging down the energy-saving coating of solar absorption according to claim 1, and it is characterized in that: the oxirane value of the Resins, epoxy of the first component of described heat insulation intermediate coat is: 0.48 ~ 0.52mol(100g)
-1
6. described naval vessel is with hanging down the energy-saving coating of solar absorption according to claim 1, and it is characterized in that: described hollow glass micropearl technical indicator and requirement are: oil number: 0.4 ~ 0.5g/cm
3, particle diameter is 10 ~ 120 μ m.
7. described naval vessel is with hanging down the energy-saving coating of solar absorption according to claim 1, and it is characterized in that: the solvent of the first component of described heat insulation intermediate coat is the mixture of dimethylbenzene, propyl carbinol or epoxy active diluent arbitrary proportion; Other face, the filler of the first component of heat insulation intermediate coat refers to the mixture of Feldspar Powder, mica powder, titanium dioxide arbitrary proportion.
8. described naval vessel is with hanging down the energy-saving coating of solar absorption according to claim 1, and it is characterized in that: the low molecule pa resin of amine value 230 ~ 240 mgKOH/g of the second component of described heat insulation intermediate coat is 6060 low molecule pa resins; The low molecule pa resin of amine value 200 ~ 240 mgKOH/g is 650 low molecule pa resins.
According to claim 1 described naval vessel with the low energy-saving coating of solar absorption, it is characterized in that: the auxiliary agent of the first component of described heat insulation intermediate coat is dispersion agent, thixotropic agent, defoamer, adhesion promoter, wherein dispersion agent is for being fit to the dispersion agent of oleoresin system, and consumption is 0.2% ~ 0.5% of coating total amount; Defoamer is oleoresin system defoamer, and consumption is 1 ~ 1.5% of resin total amount; Thixotropic agent is organobentonite, and consumption is 0.5% ~ 1.5% of coating total amount, and adhesion promoter is the epoxy group(ing) coupling agent, 0.5 ~ 1% of the about coating total amount of consumption.
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| CN103965742A (en) * | 2014-04-29 | 2014-08-06 | 厦门双瑞船舶涂料有限公司 | Epoxy connecting paint used as transition layerfor rust prevention and pollution prevention of part below ship water line |
| CN104817950A (en) * | 2015-05-19 | 2015-08-05 | 太仓市金新涂料有限公司 | Energy-saving and environment-friendly roller coating paint for printing plate and application method of energy-saving and environment-friendly roller coating paint |
| CN104910755A (en) * | 2015-05-29 | 2015-09-16 | 中国船舶重工集团公司第七二五研究所 | Preparation and application method of dark-colored heat-reflective ship deck coating |
| CN104985891A (en) * | 2013-11-14 | 2015-10-21 | 德邦新材料有限公司 | Coating material with characteristics of efficiency, energy saving, heat shield, cooling and corrosion resistance |
| CN105086750A (en) * | 2015-08-07 | 2015-11-25 | 西北工业大学 | Heavy anti-corrosion coating system and preparing method thereof |
| CN107544614A (en) * | 2017-09-28 | 2018-01-05 | 柳州凡科技有限公司 | A kind of accounting abacus of favorable rust preventing effect |
| CN109337497B (en) * | 2018-10-11 | 2020-12-08 | 宁波瑞凌新能源材料研究院有限公司 | Environment-friendly cooling and refrigerating coating |
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| CN104985891A (en) * | 2013-11-14 | 2015-10-21 | 德邦新材料有限公司 | Coating material with characteristics of efficiency, energy saving, heat shield, cooling and corrosion resistance |
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| CN107544614A (en) * | 2017-09-28 | 2018-01-05 | 柳州凡科技有限公司 | A kind of accounting abacus of favorable rust preventing effect |
| CN109337497B (en) * | 2018-10-11 | 2020-12-08 | 宁波瑞凌新能源材料研究院有限公司 | Environment-friendly cooling and refrigerating coating |
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Application publication date: 20130410 |