CN103030841A - Novel foaming material - Google Patents

Novel foaming material Download PDF

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Publication number
CN103030841A
CN103030841A CN2012105935567A CN201210593556A CN103030841A CN 103030841 A CN103030841 A CN 103030841A CN 2012105935567 A CN2012105935567 A CN 2012105935567A CN 201210593556 A CN201210593556 A CN 201210593556A CN 103030841 A CN103030841 A CN 103030841A
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China
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mentioned
agent
foam material
novel foam
material according
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CN2012105935567A
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CN103030841B (en
Inventor
王星坤
李文胜
陈佳文
丁金造
魏昌山
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FUJIAN SANSD PLASTIC Co Ltd
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FUJIAN SANSD PLASTIC Co Ltd
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Priority to CN201210593556.7A priority Critical patent/CN103030841B/en
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Abstract

The invention discloses a novel foaming material which is prepared by taking pregelatinized starch as a matrix, adopting an assistant, and using a routine foaming process. As the foaming material takes the pregelatinized starch as the matrix, the pure bio-based foaming material can be completely degraded, has no destruction to the environment, and is nontoxic, odorless and completely environment-friendly.

Description

A kind of Novel foam material
Technical field
The present invention relates to a kind of foam material, specifically a kind of foam material that can be degradable.
Background technology
Existing foam material, general very difficult plastics of degrading, rubber, the resin etc. of adopting of its basic thing, the non-degradable foam material that is dropped in a large number brings serious pollution to environment.The inventor invents and has studied a kind of Novel foam material that can be degradable thus, satisfies this case and produces thus.
Summary of the invention
The purpose of this invention is to provide a kind of Novel foam material that can be degradable.
To achieve these goals, the present invention adopts following technical scheme:
A kind of Novel foam material, it is equipped with auxiliary agent take pre-gelatinization W-Gum as base-material, is prepared from by conventional foam process.
Above-mentioned auxiliary agent comprises linking agent, whipping agent and dispersion agent, and the weight proportion of above-mentioned base-material and above-mentioned auxiliary agent is:
Figure BDA00002688447800011
Above-mentioned auxiliary agent also comprises frothing aid, and the consumption of this frothing aid is the 28-40% of above-mentioned whipping agent weight.
Above-mentioned linking agent adopts peroxide cross-linking agent (DCP).
Above-mentioned whipping agent adopts Cellmic C 121 (AC whipping agent).
Above-mentioned frothing aid adopts zinc oxide or zinc carbonate.
Above-mentioned dispersion agent adopts stearic acid.
After adopting such scheme, Novel foam material of the present invention, take pre-gelatinization W-Gum as base-material, the foam material of this pure bio-based can be degradable, and environment is not produced destruction, and is nonpoisonous and tasteless, fully environmental protection.
Embodiment
A kind of Novel foam material of the present invention, it is equipped with auxiliary agent take pre-gelatinization W-Gum as base-material, is prepared from by conventional foam process.
Particularly, auxiliary agent comprises linking agent, whipping agent and dispersion agent, and the weight proportion of base-material (pre-gelatinization W-Gum) and auxiliary agent is:
In order to strengthen foaming effect, also can add frothing aid, the consumption of this frothing aid is the 28-40% of above-mentioned whipping agent weight.
Wherein, linking agent, whipping agent, dispersion agent and frothing aid can be selected as required, and in the present embodiment, linking agent adopts peroxide cross-linking agent (DCP); Whipping agent adopts Cellmic C 121 (AC whipping agent); Frothing aid adopts zinc oxide or zinc carbonate; Dispersion agent adopts stearic acid.
A kind of Novel foam material of the present invention, take pre-gelatinization W-Gum as base-material, the foam material of this pure bio-based, being embedded in can be degradable after three months in the soil, and environment is not produced destruction, nonpoisonous and tasteless, fully environmental protection.And product has preferably elasticity and physical strength, can satisfy saw, cuts, the various plastic working requirements such as bonding, stamping-out, can be used for the multiple fields such as pantofle, medical treatment product, household articles, food product pack.
A kind of Novel foam material of the present invention is by the technical process realization of batching-mixing-mill packing-slice-weighing-sulfuration-mould unloading cooling-foam sheet.
Particularly, realize as follows:
1, batching: the proportioning according to above-mentioned base-material and each above-mentioned auxiliary agent is prepared burden;
2, mix: adopt Banbury mixer or high-speed kneading machine, each raw material that step 1 is prepared drops in Banbury mixer (high-speed kneading machine) and mixes, temperature is controlled at the 90-100 degree, and basis of time equipment and technology parameter determines that generally and auxiliary agent softening with pre-gelatinization W-Gum mixes get final product fully;
3, mill packing: will put into through the raw material that step 2 mixes and thin bag in the mill, the mill temperature is controlled at the 90-95 degree, and various raw materials are uniformly dispersed, and obtains finely dispersed material;
4, slice weighing: will be pressed into sheet through the finely dispersed material of step 3 packing;
5, sulfuration: the material weighing of the sheet that step 4 is obtained is packed into and is carried out the pressurized, heated sulfuration in the vulcanizer mold, curing temperature 160-180 degree all can, curing time is determined according to mold thickness and temperature, gets final product after the sulfuration mould unloading out cools off.
A kind of Novel foam material of the present invention is also applicable to foam process such as injection foaming, second time of foaming.
Novel foam material of the present invention, it is as follows that property indices detects data:
Test event Test value Unit Testing method
Hardness 65 Degree ASTM-D2240
Proportion 0.15 g/cm3 ASTM-D297
Longitudinal pulling force 21.08 kgf/cm2 ASTM-D412
Lateral pull 20.2 kgf/cm2 ASTM-D412
The longitudinal extension rate 240 % ASTM-D412
The horizontal expansion rate 236 % ASTM-D412
Vertical tearing force 5.2 kg/cm ASTM-D412
Horizontal tearing force 5.04 kg/cm ASTM-D412
Shrinking percentage 1 % NIKE?G1

Claims (7)

1. Novel foam material, it is characterized in that: it is equipped with auxiliary agent take pre-gelatinization W-Gum as base-material, is prepared from by conventional foam process.
2. a kind of Novel foam material according to claim 1, it is characterized in that: above-mentioned auxiliary agent comprises linking agent, whipping agent and dispersion agent, the weight proportion of above-mentioned base-material and above-mentioned auxiliary agent is:
Figure FDA00002688447700011
3. a kind of Novel foam material according to claim 2, it is characterized in that: above-mentioned auxiliary agent also comprises frothing aid, the consumption of this frothing aid is the 28-40% of above-mentioned whipping agent weight.
4. a kind of Novel foam material according to claim 2 is characterized in that: above-mentioned linking agent employing peroxide cross-linking agent.
5. a kind of Novel foam material according to claim 2 is characterized in that: above-mentioned whipping agent employing Cellmic C 121.
6. a kind of Novel foam material according to claim 2 is characterized in that: above-mentioned frothing aid employing zinc oxide or zinc carbonate.
7. a kind of Novel foam material according to claim 2 is characterized in that: above-mentioned dispersion agent employing stearic acid.
CN201210593556.7A 2012-12-29 2012-12-29 A kind of Novel foam material Active CN103030841B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210593556.7A CN103030841B (en) 2012-12-29 2012-12-29 A kind of Novel foam material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210593556.7A CN103030841B (en) 2012-12-29 2012-12-29 A kind of Novel foam material

Publications (2)

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CN103030841A true CN103030841A (en) 2013-04-10
CN103030841B CN103030841B (en) 2016-02-03

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1583850A (en) * 2003-08-21 2005-02-23 朱秀刚 Preparing method for plant plastics
CN1970611A (en) * 2006-08-02 2007-05-30 福州大学 Process for preparing EVA/PE/starch composite foam material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1583850A (en) * 2003-08-21 2005-02-23 朱秀刚 Preparing method for plant plastics
CN1970611A (en) * 2006-08-02 2007-05-30 福州大学 Process for preparing EVA/PE/starch composite foam material

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Inventor after: Ding Fangmei

Inventor after: Ding Zhimeng

Inventor before: Wang Xingkun

Inventor before: Li Wensheng

Inventor before: Chen Jiawen

Inventor before: Ding Jinzao

Inventor before: Wei Changshan