CN103030171B - Method for preparing modified zinc oxide - Google Patents
Method for preparing modified zinc oxide Download PDFInfo
- Publication number
- CN103030171B CN103030171B CN201210548654.9A CN201210548654A CN103030171B CN 103030171 B CN103030171 B CN 103030171B CN 201210548654 A CN201210548654 A CN 201210548654A CN 103030171 B CN103030171 B CN 103030171B
- Authority
- CN
- China
- Prior art keywords
- zinc oxide
- bismuth
- oxide
- zinc
- modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000011787 zinc oxide Substances 0.000 claims abstract description 37
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 34
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 30
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 229910000416 bismuth oxide Inorganic materials 0.000 claims abstract description 12
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 6
- PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical compound [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 17
- 238000002360 preparation method Methods 0.000 claims description 17
- 238000000498 ball milling Methods 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 5
- 238000007669 thermal treatment Methods 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 229940049676 bismuth hydroxide Drugs 0.000 claims description 2
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 claims description 2
- 238000001149 thermolysis Methods 0.000 claims description 2
- 239000011701 zinc Substances 0.000 abstract description 21
- 229910052725 zinc Inorganic materials 0.000 abstract description 21
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 239000002243 precursor Substances 0.000 abstract 2
- 239000010405 anode material Substances 0.000 abstract 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 abstract 1
- 238000005979 thermal decomposition reaction Methods 0.000 abstract 1
- 235000014692 zinc oxide Nutrition 0.000 description 27
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 4
- 229910052797 bismuth Inorganic materials 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 210000001787 dendrite Anatomy 0.000 description 3
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 229940105847 calamine Drugs 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 229910052864 hemimorphite Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- CPYIZQLXMGRKSW-UHFFFAOYSA-N zinc;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+3].[Fe+3].[Zn+2] CPYIZQLXMGRKSW-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000022131 cell cycle Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201210548654.9A CN103030171B (en) | 2012-12-17 | 2012-12-17 | Method for preparing modified zinc oxide |
Applications Claiming Priority (1)
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CN201210548654.9A CN103030171B (en) | 2012-12-17 | 2012-12-17 | Method for preparing modified zinc oxide |
Publications (2)
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CN103030171A CN103030171A (en) | 2013-04-10 |
CN103030171B true CN103030171B (en) | 2014-05-28 |
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CN201210548654.9A Active CN103030171B (en) | 2012-12-17 | 2012-12-17 | Method for preparing modified zinc oxide |
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Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3016199B1 (en) | 2013-06-28 | 2019-01-09 | Positec Power Tools (Suzhou) Co., Ltd | Electrolytic solution and battery |
EP3200265A4 (en) | 2014-09-26 | 2018-04-04 | Positec Power Tools (Suzhou) Co., Ltd | Battery, battery pack and continuous power supply |
CN107039645B (en) * | 2017-04-11 | 2020-01-31 | 宁波富邦电池有限公司 | Primary alkaline battery negative electrode material and preparation method thereof |
CN107265494B (en) * | 2017-06-06 | 2019-04-02 | 安徽锦华氧化锌有限公司 | A kind of modified nano zinc oxide |
CN107394117A (en) * | 2017-06-09 | 2017-11-24 | 安徽零度新能源科技有限公司 | A kind of electrode of lithium cell |
CN107130147A (en) * | 2017-06-22 | 2017-09-05 | 合肥市闵葵电力工程有限公司 | The aluminium alloy conductor material and preparation method of a kind of high conductivity |
CN107338672A (en) * | 2017-07-15 | 2017-11-10 | 合肥皖水信息科技有限公司 | A kind of electro-photographic paper with good humidity resistance |
CN107474419A (en) * | 2017-09-26 | 2017-12-15 | 安徽斯威达建材科技有限公司 | A kind of polystyrene fire-retardant heat insulation plate |
CN108767215B (en) * | 2018-05-15 | 2021-03-26 | 华中科技大学 | Material for inhibiting zinc dendrite and preparation method and application thereof |
CN109112003B (en) * | 2018-09-28 | 2021-08-06 | 广州市加茜亚化妆品有限公司 | Washing gel bead for dish-washing machine and preparation method |
CN109592705A (en) * | 2019-01-02 | 2019-04-09 | 东莞理工学院 | A kind of no-solvent synthesis process of zinc oxide and application |
CN110066109B (en) * | 2019-05-28 | 2022-02-22 | 江西陶瓷工艺美术职业技术学院 | Flux for antique pigment and application method thereof |
CN111387351A (en) * | 2020-03-25 | 2020-07-10 | 济源市鲁泰纳米材料有限公司 | Surface-coated nano zinc oxide powder and preparation method thereof |
CN116835973B (en) * | 2023-06-16 | 2024-06-04 | 华中科技大学 | Bismuth oxide coated zinc oxide powder and preparation method and application thereof |
Family Cites Families (6)
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GB792644A (en) * | 1954-12-22 | 1958-04-02 | Exxon Research Engineering Co | Improvements in or relating to catalytic dehydrogenation of secondary alcohols to ketones |
US3778743A (en) * | 1973-02-23 | 1973-12-11 | Matsushita Electric Ind Co Ltd | Voltage-nonlinear resistors |
US5039452A (en) * | 1986-10-16 | 1991-08-13 | Raychem Corporation | Metal oxide varistors, precursor powder compositions and methods for preparing same |
CN1011839B (en) * | 1988-02-02 | 1991-02-27 | 西安交通大学 | Production method of zinc oxide resistor chip |
CN1569616A (en) * | 2003-07-22 | 2005-01-26 | 西南科技大学 | Hydrothermal fluid process for preparation of doped zinc oxide powder |
CN101533908B (en) * | 2009-04-02 | 2011-07-20 | 浙江理工大学 | Alkaline zinc-based secondary battery cathode material and preparation method thereof |
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CN103030171A (en) | 2013-04-10 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for preparing modified zinc oxide Effective date of registration: 20150104 Granted publication date: 20140528 Pledgee: Bank of Beijing Limited by Share Ltd Changsha branch Pledgor: Hu'nan Fengri Power and Electric Co., Ltd. Registration number: 2014430000027 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20160218 Granted publication date: 20140528 Pledgee: Bank of Beijing Limited by Share Ltd Changsha branch Pledgor: Hu'nan Fengri Power and Electric Co., Ltd. Registration number: 2014430000027 |
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PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for preparing modified zinc oxide Effective date of registration: 20170222 Granted publication date: 20140528 Pledgee: Bank of Changsha Limited by Share Ltd Liuyang branch Pledgor: Hu'nan Fengri Power and Electric Co., Ltd. Registration number: 2017430000008 |
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PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20190301 Granted publication date: 20140528 Pledgee: Bank of Changsha Limited by Share Ltd Liuyang branch Pledgor: Hu'nan Fengri Power and Electric Co., Ltd. Registration number: 2017430000008 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for preparing modified zinc oxide Effective date of registration: 20190318 Granted publication date: 20140528 Pledgee: Bank of Changsha Limited by Share Ltd Liuyang branch Pledgor: Hu'nan Fengri Power and Electric Co., Ltd. Registration number: 2019430000022 |
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Date of cancellation: 20201208 Granted publication date: 20140528 Pledgee: Bank of Changsha Limited by Share Ltd. Liuyang branch Pledgor: HUNAN FENGRI ELECTRIC GROUP Co.,Ltd. Registration number: 2019430000022 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of modified zinc oxide Effective date of registration: 20201222 Granted publication date: 20140528 Pledgee: Bank of Changsha Limited by Share Ltd. Liuyang branch Pledgor: HUNAN FENGRI ELECTRIC GROUP Co.,Ltd. Registration number: Y2020430000042 |
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