CN103015257A - 一种自交联碳纳米纤维纸及其制备方法 - Google Patents
一种自交联碳纳米纤维纸及其制备方法 Download PDFInfo
- Publication number
- CN103015257A CN103015257A CN2012105433999A CN201210543399A CN103015257A CN 103015257 A CN103015257 A CN 103015257A CN 2012105433999 A CN2012105433999 A CN 2012105433999A CN 201210543399 A CN201210543399 A CN 201210543399A CN 103015257 A CN103015257 A CN 103015257A
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- China
- Prior art keywords
- carbon nano
- fiber
- carboxylated
- crosslinking
- aminated
- Prior art date
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 207
- 239000002134 carbon nanofiber Substances 0.000 title claims abstract description 161
- 238000004132 cross linking Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 27
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 12
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 238000005576 amination reaction Methods 0.000 claims abstract description 5
- 239000006185 dispersion Substances 0.000 claims description 47
- 239000007788 liquid Substances 0.000 claims description 46
- 238000003756 stirring Methods 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 18
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 14
- 239000012467 final product Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 13
- 239000002270 dispersing agent Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000002048 multi walled nanotube Substances 0.000 claims description 9
- 239000002109 single walled nanotube Substances 0.000 claims description 9
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims description 9
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 claims description 7
- 239000000853 adhesive Substances 0.000 claims description 7
- 230000001070 adhesive effect Effects 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 4
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 4
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical group OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- -1 fully stir Chemical compound 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims 2
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 13
- 239000004917 carbon fiber Substances 0.000 abstract description 13
- 125000003368 amide group Chemical group 0.000 abstract description 9
- 238000004458 analytical method Methods 0.000 abstract description 4
- 238000000840 electrochemical analysis Methods 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 abstract 2
- 239000008394 flocculating agent Substances 0.000 abstract 2
- 230000021523 carboxylation Effects 0.000 abstract 1
- 238000006473 carboxylation reaction Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 238000003828 vacuum filtration Methods 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 230000007935 neutral effect Effects 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000006250 one-dimensional material Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000011856 silicon-based particle Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
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Abstract
Description
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CN201210543399.9A CN103015257B (zh) | 2012-12-16 | 2012-12-16 | 一种自交联碳纳米纤维纸及其制备方法 |
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CN201210543399.9A CN103015257B (zh) | 2012-12-16 | 2012-12-16 | 一种自交联碳纳米纤维纸及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN103015257A true CN103015257A (zh) | 2013-04-03 |
CN103015257B CN103015257B (zh) | 2015-06-17 |
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CN201210543399.9A Active CN103015257B (zh) | 2012-12-16 | 2012-12-16 | 一种自交联碳纳米纤维纸及其制备方法 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1475437A (zh) * | 2003-07-31 | 2004-02-18 | 清华大学 | 一种碳纳米管纸的制备方法 |
CN102351165A (zh) * | 2011-06-23 | 2012-02-15 | 中国科学院苏州纳米技术与纳米仿生研究所 | 大面积自支撑碳纳米管纸及其制备方法 |
JP2012162810A (ja) * | 2011-02-03 | 2012-08-30 | Shinshu Univ | カーボンナノ構造物含有シートの製造方法 |
-
2012
- 2012-12-16 CN CN201210543399.9A patent/CN103015257B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1475437A (zh) * | 2003-07-31 | 2004-02-18 | 清华大学 | 一种碳纳米管纸的制备方法 |
JP2012162810A (ja) * | 2011-02-03 | 2012-08-30 | Shinshu Univ | カーボンナノ構造物含有シートの製造方法 |
CN102351165A (zh) * | 2011-06-23 | 2012-02-15 | 中国科学院苏州纳米技术与纳米仿生研究所 | 大面积自支撑碳纳米管纸及其制备方法 |
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CN103015257B (zh) | 2015-06-17 |
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Owner name: KUNMING NATAI ENERGY TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: XIAO HUI Effective date: 20130917 |
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C41 | Transfer of patent application or patent right or utility model | ||
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Effective date of registration: 20130917 Address after: 650091 Yunnan city of Kunming province high tech Zone Haiyuan A Road No. 1520 Building 2 floor, No. 215 Applicant after: Kunming Natai Energy Technology Co., Ltd. Address before: 650091 room 715, Tung Yi Road North, Yuantong Road, Wuhua District, Kunming, Yunnan Applicant before: Xiao Hui |
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C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 650091 Yunnan city of Kunming province high tech Zone Haiyuan A Road No. 1520 Building 2 floor, No. 215 Patentee after: KUNMING NATAI TECHNOLOGY CO., LTD. Address before: 650091 Yunnan city of Kunming province high tech Zone Haiyuan A Road No. 1520 Building 2 floor, No. 215 Patentee before: Kunming Natai Energy Technology Co., Ltd. |