CN1030144C - High caloric value synthetic liquid fuel - Google Patents
High caloric value synthetic liquid fuel Download PDFInfo
- Publication number
- CN1030144C CN1030144C CN 93118756 CN93118756A CN1030144C CN 1030144 C CN1030144 C CN 1030144C CN 93118756 CN93118756 CN 93118756 CN 93118756 A CN93118756 A CN 93118756A CN 1030144 C CN1030144 C CN 1030144C
- Authority
- CN
- China
- Prior art keywords
- liquid fuel
- synthetic liquid
- oil
- ferrocene
- synthetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
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- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention relates to a synthetic liquid fuel which is prepared by the reaction of vegetable oil, methanol, 2, 6-di-tert-butyl-p-cresol, acetone, ferrocene, octanol, ethanol and diesel oil in a mixing mode. The high value of the synthetic liquid fuel is as high as 11000 calories/gram, and is higher than that of general synthetic fuel. The synthetic liquid fuel has the advantages of simple and stable synthetic process, and easy operation. In addition, the synthetic liquid fuel can be obtained by general-purpose equipment.
Description
The present invention relates to a kind of high-heat value synthetic liquid fuel, particularly a kind of is the synthetic liquid fuel of main composition with vegetables oil.
As everyone knows, many decades has been carried out in the research of synthetic liquid fuel at home and abroad, various schemes and measure have been proposed, though some are with industrialization, for example: the used gasification (adopting iron or cobalt agent to make catalyzer) of Jinzhou oil six factories is come the method for prepare liquid fuel at home, but all is difficult to promote its major cause complex manufacturing, the calorific value of liquid fuel is not high, shortcomings such as cost costliness.
The object of the present invention is to provide a kind of production technique easy, the synthetic liquid fuel of high heating value, can be mass-produced and on probation on heavy duty industrials such as various boilers, cement, pottery, casting, and State Standard Matter Research Centre's test, its calorific value is a kind of ideal industrial fuels up to 11000 card/grams.
Concrete measure of the present invention is as follows:
With vegetables oil for example Wood of Shinyleaf Yellowhorn wet goods a kind of and ethanol, 2.6-ditertbutylparacresol, acetone, octanol, diesel oil and ferrocene wherein mix and react, heat is emitted in reaction, controlled temperature is reacted into mixed solution between 45 ℃～60 ℃, and then adding methyl alcohol, mix, temperature is reduced to 20～30 ℃ and was formed in about 10 minutes, and the purpose that adds ferrocene is to make liquid fuel can burn fully, thereby the raising calorific value generally can reach 11000 card/grams.2.6-ditertbutylparacresol is as solvent the plant wet goods to be dissolved each other.
Concrete prescription is as follows: (weight part)
Vegetables oil 100, methyl alcohol 100～120,2.6-ditertbutylparacresol 0.04～0.06, acetone 0.14～0.16, octanol 12～15, ethanol 3～5, diesel oil 2～4, ferrocene 0.01～0.03.
Concrete technology is as follows:
With vegetables oil, 2.6-ditertbutylparacresol, acetone, octanol, ethanol, diesel oil, ferrocene totally 7 kinds of materials at room temperature mix in reactor and react, owing to be thermopositive reaction, so the temperature of material in reactor is controlled between 45 °～60 ℃ from the logical water coolant of chuck of reactor, about 0.5～1 hour of reaction times, general reaction mixture becomes light yellow and then adds methyl alcohol, continues to mix forming liquid fuel of the present invention in about about 10 minutes.
Following preference elaborates to the present invention, but does not limit the scope of the invention.
Example 1: add 100 kilograms of shinyleaf yellowhorn oils in the reactor that the paddle volume is 500 liters in general having, 2.6-0.05 kilogram of ditertbutylparacresol, 0.15 kilogram in acetone, 13 kilograms of octanols, 4 kilograms of ethanol, 3 kilograms of diesel oil, 0.02 kilogram of ferrocene, start the logical water coolant of stirred autoclave chuck, control reaction temperature is 48 ℃ ± 2 ℃, and after 40 minutes, reaction solution becomes light yellow, and then adding methyl alcohol 120 kg, continue stirring and formed synthetic liquid fuel of the present invention by analysis in 10 minutes, calorific value 11,000 cards/in, 55 ℃ of flash-points do not have black smoke during 60 ℃ of burnings of burning-point.
Example 2: except that replacing the shinyleaf yellowhorn oil with Semen Maydis oil, all the other conditions are identical with example 1, and the analytical results of the synthetic liquid fuel oil that makes is calorific value 9,000 card/grams, 57 ℃ of flash-points, 61 ℃ of burning-points.There is not black smoke during burning.
Advantage of the present invention:
1. the calorific value of synthetic liquid fuel is up to 11,000 cards/gram, than general synthetic liquid fuel height.
2. technology is simple, can adopt common apparatus.
Claims (2)
1, a kind of synthetic liquid fuel is characterized in that it being the prescription that adopts following raw materials according:
(weight part)
Shinyleaf yellowhorn oil or Semen Maydis oil 100
Methyl alcohol 100～120
2.6-ditertbutylparacresol 0.04～0.06
Acetone 0.14～0.16
Octanol 12～15
Ethanol 3～5
Diesel oil 2～4
Ferrocene 0.01～0.03
2, a kind of method for making of synthetic liquid fuel is characterized in that:
(a) add Wood of Shinyleaf Yellowhorn or Semen Maydis oil, 2.6-ditertbutylparacresol, acetone, octanol, ethanol, diesel oil and ferrocene in general reactor, temperature is controlled between 45 °～60 ℃, reacts to become light yellow mixed solution in 0.5～1 hour.
(b) in the mixed solution of (a), add methyl alcohol again, continuing to stir 10 minutes temperature is 20～30 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93118756 CN1030144C (en) | 1993-10-28 | 1993-10-28 | High caloric value synthetic liquid fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93118756 CN1030144C (en) | 1993-10-28 | 1993-10-28 | High caloric value synthetic liquid fuel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1084876A CN1084876A (en) | 1994-04-06 |
| CN1030144C true CN1030144C (en) | 1995-10-25 |
Family
ID=4992633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93118756 Expired - Fee Related CN1030144C (en) | 1993-10-28 | 1993-10-28 | High caloric value synthetic liquid fuel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1030144C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053920C (en) * | 1998-08-28 | 2000-06-28 | 胡忠 | High-heat value synthetic liquid fuel |
| CN1308420C (en) * | 2004-01-06 | 2007-04-04 | 李冠峰 | Biological-flux diesel alcohol blended fuel |
| CN101368114B (en) * | 2008-10-10 | 2012-05-02 | 上海龙津石油有限公司 | Emulsified diesel oil for automobile |
| CN102559293A (en) * | 2010-12-20 | 2012-07-11 | 段兴林 | Multi-element anti-phase composite diesel oil |
| ITRM20110317A1 (en) * | 2011-06-17 | 2012-12-18 | Enea Floris | PROCESS METHOD AND FORMULATIONS FOR THE PRODUCTION OF A VEGETABLE OIL-BASED BIOFUEL PRODUCT ALSO EXHAUSTED REGENERATED AND / OR GENETICALLY MODIFIED ALGAE AND MICRO-ALGAE AND / OR OIL FROM WHICH DERIVED ADDED TO PRIMARY AND / OR SECONDARY AND / OR |
| CN104673413B (en) * | 2015-02-10 | 2017-02-22 | 许明华 | liquid ecological gas and preparation method thereof |
-
1993
- 1993-10-28 CN CN 93118756 patent/CN1030144C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1084876A (en) | 1994-04-06 |
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Legal Events
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|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |