CN103014451A - Aluminum material of zip-top two-sheet can body and production method thereof - Google Patents
Aluminum material of zip-top two-sheet can body and production method thereof Download PDFInfo
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Abstract
The invention discloses an aluminum material of a zip-top two-sheet can body and a production method thereof; the production process comprises casting, saw-cutting, face-milling, heating, hot continuous rolling and cold-rolling, wherein casted molten aluminum consists of the following chemical components by mass percentage: 0.17-0.23% of Si, 0.38-0.48% of Fe, 0.145-0.21% of Cu, 0.85-0.90% of Mn, 1.18-1.23% of Mg, not greater than 0.025% of Cr, not greater than 0.02% of Zn, not greater than 0.02% of Ti, not greater than 0.10% of other impurities each of which accounts for not greater than 0.03%, and the balance of Al; smelting temperature is at 720-750 DEG C; refining temperature is at 725-740 DEG C; and casting temperature is 660-700 DEGC. The cold-rolling process comprises the following steps of: by a five-stand cold continuous rolling production line, rolling an aluminum material from 2.2-2.5mm to 0.27-0.28mm in the first time of forming, and distributing reduction rates of the first to the fifth stands as: 25-35%, 25-38%, 25-38%, 30-50% and 35-50%. The production method disclosed by the invention not only guarantees the stable and qualified mechanical performance of the aluminum material of the zip-top two-sheet can body, but also shortens the production process and improves the production efficiency.
Description
Technical field
The present invention relates to aluminium alloy and make the field, specifically relate to a kind of easy-to-draw 2 tank can body aluminiums and production method thereof.
Background technology
The aluminium ring pull end production of China is progressively developed, and 3104 aluminium alloys have good development prospect as 2 materials that the tank can body is the most frequently used of preparation.Along with the attenuate of can body aluminium thickness, to the mechanical property proposition requirements at the higher level of can body aluminium; Domestic tank industry development processed simultaneously, the demand of can body aluminium increases, and the delivery of cargo cycle is also claimed.In order to improve material use efficiency and to enhance productivity, the finished product thickness thinning technique of 3104 aluminum alloy strips and minimizing hot rolling and cold rolling pass become study hotspot.
At present, adopt traditional single-stand cold-rolling machine to produce 3104 aluminum alloy strips, its technical process is: founding → sawing → mill face → homogenizing annealing → hot rolling → cold rolling 1 passage (50% draft) → cold rolling 2 passages (50% draft) → cold rolling 3 passages (50% draft) → finished product to shear.
When the tradition single-stand cold-rolling machine is produced 3104 aluminum alloy strip, 2.2 ~ 2.5mm is rolled to finished product 0.27 ~ 0.28mm need to be through three passages, aluminium about one 13 tons is only rolled up rolling time will 40 minutes, and single stand cold mill only has single Abrollhaspel, single reeling machine, upper and lower volume, threading also need other non-cutting time, therefore the mean consumption of a rolling volume is more than one hour, and production efficiency is lower.And in the processing of aluminium sheet band, traditional single-stand cold-rolling machine great majority use full oil to make cooling-lubricant, often cause firing accident because of broken belt.
Summary of the invention
Based on this, the invention provides a kind of production method of easy-to-draw 2 tank can body aluminiums.
A kind of production method of easy-to-draw 2 tank can body aluminiums, its Production Flow Chart comprise founding, sawing, mill face, heating, hot continuous rolling, cold rolling.
Wherein, the mass percent of the chemical composition of aluminium water is after the founding: Si0.17~0.23%, Fe0.38~0.48%, Cu0.145 ~ 0.21%, Mn0.85~0.90%, Mg1.18~1.23%, Cr≤0.025%, Zn≤0.02%, Ti≤0.02%, other impurity is single≤and 0.03%, add up to≤0.10%, all the other are Al; Smelting temperature is 720 ~ 750 ℃, 725 ~ 740 ℃ of refining temperatures, 660 ~ 700 ℃ of casting temps;
Described cold-rolling process is: adopt five frame cold continuous rolling production lines, 1 moulding is rolled down to 0.27 ~ 0.28mm with aluminium by 2.2 ~ 2.5mm, and the first frame to the five frame drafts are assigned as: 25 ~ 35% → 25 ~ 38% → 25 ~ 38% → 30 ~ 50% → 35 ~ 50%.
Utilize the once shaped of five frame cold continuous rollings energy the hot-rolled billet of 2.2 ~ 2.5mm to be rolled down to the advantage of 0.27 ~ 0.28mm aluminium thickness, rolling time is only with the finished product volume that just can finish in about 12 minutes about one 13 tons, and five frame cold continuous rollings have two Abrollhaspels, two reeling machines, can carry out in the machine operation of rolling non-cutting time of upper and lower volume, need not wait in addition, therefore the time of an actual volume consumption only is about 12 minutes, it is 1/5th of single chassis, greatly shorten the Production Flow Chart of can body aluminium sheet band, enhance productivity.
Among some embodiment, in described heating steps, ingot casting turns 510 ~ 520 ℃ of insulations 2 ~ 3 hours 600 ~ 610 ℃ of lower insulations 8 ~ 10 hours therein.
Among some embodiment, in described hot-rolled step, use the 1+5 hot rolling line therein, 1 reversing rougher adds 1 five frame hot continuous rolling production line; Hot rolled coil thickness 2.2 ~ 2.5mm, 330 ~ 350 ℃ of hot finishing temperatures.
Therein among some embodiment, in the aluminium water after the described founding content of Mg be 1.20 ~ 1.22%, Mg content in this scope the time performance of aluminium more stable.
In described cold rolling step, five frame cold continuous rollings adopt base oil (mineral oil is main) that certain viscosity, acid number, saponification value are arranged and additive (organic acid, alcohol, ester and polymkeric substance etc.) as oil phase, deionized water carries out Cooling and Lubricator as the oil-water mixture of water, and S 1~S4 frame employing oil phase concentration expressed in percentage by volume is 2 ~ 10% oil-water mixture; S5 frame employing oil phase concentration expressed in percentage by volume is 10 ~ 20% oil-water mixture; The injection flow of single chassis oil-water mixture is 400 ~ 900L/min, and temperature is 50~65 ℃.Aluminium product outlet speed 〉=1200m/min.Oil-water mixture has good lubrication and cooling effect, thereby can obtain best template, surface quality and higher finished product temperature (finished product temperature 〉=150 ℃), and can prevent the firing accident that the rolling broken belt of similar complete oily formula causes.
Aluminum alloy for pop-top can body band YS/T435-2000 stipulates that 3104 chemical compositions (mass percent) scope is Si≤0.6%, Fe≤0.8%, Cu0.05 ~ 0.25%, Mn0.8 ~ 1.4%, Mg0.8 ~ 1.4%, Zn≤0.25%, Ti≤0.1%, V≤0.05%, Ca≤0.05%, other impurity is single≤and 0.05%, add up to≤0.15%.According to mechanical property requirements and the thickness requirement of can body aluminium alloy, the present invention is optimized adjustment to aluminium alloy contained chemical composition and content thereof.The present invention obtains more excellent performance, will strictly control Si, Fe, Cu content, compares industry standard and requires higher.Mg content is the important chemical element that determines the can body Mechanical Properties of Aluminum Alloys, so Mg content span of control directly affects the process control ability of product mechanical property.
The maximum solid solution degree of Fe in aluminium only is 0.04%, so Fe mainly forms compound and supersaturated solid solution in aluminium.During Fe content<0.20% and Mn form (FeMn) Al
6Compound, Fe content>0.7% can produce thick Fe primary phase, and compound increases in the alloy, easily generates the processability that a large amount of frangible compounds reduce aluminium, can significantly fall low-alloyed mechanical property and processing performance.But refinement recrystal grain when Fe content is 0.38~0.48%, the mechanical property of Effective Raise aluminium and forming ability.
The maxima solubility of Si in aluminium is 1.65%.Si is associated at Al-Mn-Fe and can impels a crystallization compound to be converted into the α phase in the gold.α can improve the deformability of stretching attenuate mutually in the production process of pop can, and Si also forms Mg with Mg simultaneously
2Si precipitated phase and aluminium intensity is improved, so the content of Si needs>0.1%.But the intensity that can make aluminium when Si content surpasses 0.5% is too high and the deep drawability of hot rolling performance and aluminium and stretching attenuate performance meeting variation.Si content 0.17~0.23% can guarantee that aluminium intensity can improve again deep-draw and the stretching attenuate deformability of aluminium among the present invention.
Cu can significantly improve the tensile strength of aluminium.Cu content 0.145 ~ 0.21% can be guaranteed pop can when baking among the present invention, because the age hardening effect of Cu is offset a part and replied the softening strength decreased that causes, thereby makes the aluminium strength degradation seldom.
The Mg of content 1.18~1.23% forms sosoloid in 3104 aluminium alloys, can improve the aluminium mechanical property, the intensity of Effective Raise aluminium.
Compared with prior art, the present invention has following beneficial effect:
The time of (1) adopting the 3104 aluminium volume of cold rolling one 13 tons of five frames to consume only is about 12 minutes, approximately 1/5th of single chassis, shorten the production operation time, and raise the efficiency.
Cutting head cutting tail repeatedly when (2) having avoided single chassis to produce reduces waste of material, improves yield rate.
(3) machine number of times in the minimizing is being compared the probability that has reduced surface quality defect when producing under the equal conditions with single chassis.
(4) the aluminium stable components that adopts the alloying constituent among the present invention to cast can reach the industry standard requirement, and the mechanical property of energy Effective Raise aluminium, reduces the earing rate of aluminium, thus deep drawability and stretching attenuate deformability when reaching the preparation pop can.
(5) five frame cold continuous rollings adopt unique water based systems (oil-water mixture) to carry out Cooling and Lubricator, can avoid the bad strip surface chromatic aberration problem that causes of separate lubrication, and can prevent the firing accident that the rolling broken belt of similar complete oily formula causes.
Embodiment
Describe the present invention in detail below in conjunction with specific embodiment.
Embodiment 1
The alloy state of the described easy-to-draw 2 tank can body aluminiums of the present embodiment: 3104H19; Finished product thickness: 0.275mm; Its Production Flow Chart comprises: and founding → saw mills → and homogenizing processing → hot rolling → cold rolling → finishing is cut edge, pre-oiling → packing, and the concrete technology parameter is as follows:
(1) founding
The mass percent of the chemical composition of aluminium water is after the founding: Si0.2056%, Fe0.4207%, Cu0.1636%, Mn0.8889%, Mg1.2141%, Cr0.0080%, Zn0.0180%, Ti0.0123%, Al97.0678%; Smelting temperature is 735 ℃, 728 ℃ of refining temperatures, 684 ℃ of casting temps.
(2) homogenizing is processed (heating): ingot casting turns 510 ~ 520 ℃ of insulations 2 ~ 3 hours 600 ~ 610 ℃ of lower insulations 8 ~ 10 hours.
(3) hot rolling: use the 1+5 hot rolling line, 1 reversing rougher adds 1 five frame hot continuous rolling production line; Hot roughing 590mm → 21.11mm, hot continuous rolling exit thickness: 2.5mm, 345 ℃ of hot rolled coil coiling temperatures.
(4) cold rolling: adopt five frame cold continuous rolling production lines, 1 moulding is rolled down to 0.275mm with aluminium by 2.5mm.Five frame cold continuous rollings adopt oil-water mixture to come lubrication and cooling, and oil phase concentration, oil mixing with water flow quantity in the exit thickness of five frames, percentage pass reduction, the oil-water mixture (raw material is provided by producer of Total France) are as shown in table 1.Aluminium product outlet speed 1320m/min, 152 ℃ of finished product temperature, free of surface defects.
The exit thickness of five frames of table 1, percentage pass reduction, oil phase concentration, oil mixing with water flow quantity
Frame | S1 | S2 | S3 | S4 | S5 |
Exit thickness/mm | 1.658 | 1.046 | 0.653 | 0.439 | 0.275 |
Percentage pass reduction/% | 33.7 | 36.9 | 37.6 | 32.8 | 37.4 |
Oil phase concentration/% | 3 | 3 | 3 | 3 | 10 |
Oil mixing with water flow quantity/Lmin -1 | 550 | 650 | 650 | 600 | 700 |
(5) finishing: according to customer requirement, utilize slitter that cold rolling aluminium is trimmed to satisfactory width and aluminium is carried out the precoating oil treatment.
(6) packing
The end properties of easy-to-draw 2 tank can body aluminiums that employing embodiment 1 production obtains is as shown in table 2.
The mechanical property that table 2 embodiment 1 produces the aluminium that obtains
Embodiment 2
The alloy state of the described easy-to-draw 2 tank can body aluminiums of the present embodiment: 3104H19; Finished product thickness: 0.275mm; Its Production Flow Chart comprises: and founding → saw mills → and homogenizing processing → hot rolling → cold rolling → finishing is cut edge, pre-oiling → packing, and the concrete technology parameter is as follows:
(1) founding
The mass percent of the chemical composition of aluminium water is after the founding: Si0.2287%, Fe0.4654%, Cu0.2054%, Mn0.8872%, Mg1.2265%, Ti0.0123%, Cr0.0001%, Zn0.0101%, Al96.9633%; Smelting temperature is 730 ℃, 728 ℃ of refining temperatures, 687 ℃ of casting temps.
(2) homogenizing is processed (heating): ingot casting turns 510 ~ 520 ℃ of insulations 2 ~ 3 hours 600 ~ 610 ℃ of lower insulations 8 ~ 10 hours.
(3) hot rolling: use the 1+5 hot rolling line, 1 reversing rougher adds 1 five frame hot continuous rolling production line; Hot roughing 590mm → 21.11mm, hot continuous rolling exit thickness: 2.48mm, 348 ℃ of hot rolled coil coiling temperatures.
(4) cold rolling: adopt five frame cold continuous rolling production lines, 1 moulding is rolled down to 0.275mm with aluminium by 2.48mm.Five frame cold continuous rollings adopt oil-water mixture to come lubrication and cooling, and oil phase concentration, oil mixing with water flow quantity in the exit thickness of five frames, percentage pass reduction, the oil-water mixture are as shown in table 3.Aluminium product outlet speed 1260m/min, 154 ℃ of finished product temperature, free of surface defects.
The exit thickness of five frames of table 3, percentage pass reduction, oil phase concentration, oil mixing with water flow quantity
Frame | S1 | S2 | S3 | S4 | S5 |
Exit thickness/mm | 1.846 | 1.378 | 0.985 | 0.523 | 0.275 |
Percentage pass reduction/% | 25.6 | 25.4 | 28.5 | 46.9 | 47.4 |
Oil phase concentration/% | 5 | 5 | 5 | 5 | 20 |
Oil mixing with water flow quantity/Lmin -1 | 410 | 450 | 500 | 800 | 860 |
(5) finishing: according to customer requirement, utilize slitter that cold rolling aluminium is trimmed to satisfactory width and aluminium is carried out the precoating oil treatment.
(6) packing
The end properties of easy-to-draw 2 tank can body aluminiums that employing embodiment 2 productions obtain is as shown in table 4.
The mechanical property that table 8 embodiment 2 produces the aluminium that obtains
Embodiment 3
The alloy state of the described easy-to-draw 2 tank can body aluminiums of the present embodiment: 3104H19; Finished product thickness: 0.275mm; Its Production Flow Chart comprises: and founding → saw mills → and homogenizing processing → hot rolling → cold rolling → finishing is cut edge, pre-oiling → packing, and the concrete technology parameter is as follows:
(1) founding
The mass percent of the chemical composition of aluminium water is after the founding: Si0.1857%, Fe0.3929%, Cu0.1525%, Mn0.8603%, Mg1.1986%, Ti0.0161%, Cr0.0010%, Zn0.0110%, Al97.1809%; Smelting temperature is 735 ℃, 730 ℃ of refining temperatures, 689 ℃ of casting temps.
(2) homogenizing is processed (heating): ingot casting turns 510 ~ 520 ℃ of insulations 2 ~ 3 hours 600 ~ 610 ℃ of lower insulations 8 ~ 10 hours.
(3) hot rolling: use the 1+5 hot rolling line, 1 reversing rougher adds 1 five frame hot continuous rolling production line; Hot roughing 590mm → 21.11mm, hot continuous rolling exit thickness: 2.19mm, 345 ℃ of hot rolled coil coiling temperatures.
(4) cold rolling: adopt five frame cold continuous rolling production lines, 1 moulding is rolled down to 0.275mm with aluminium by 2.19mm.Five frame cold continuous rollings adopt oil-water mixture to come lubrication and cooling, and oil phase concentration, oil mixing with water flow quantity in the exit thickness of five frames, percentage pass reduction, the oil-water mixture are as shown in table 5.Aluminium product outlet speed 1360m/min, 155 ℃ of finished product temperature, free of surface defects.
The exit thickness of five frames of table 5, percentage pass reduction, oil phase concentration, oil mixing with water flow quantity
Frame | S1 | S2 | S3 | S4 | S5 |
Exit thickness/mm | 1.564 | 1.127 | 0.720 | 0.462 | 0.275 |
Percentage pass reduction/% | 28.6 | 27.9 | 36.1 | 35.8 | 40.5 |
Oil phase concentration/% | 8 | 8 | 8 | 8 | 15 |
Oil mixing with water flow quantity/Lmin -1 | 500 | 500 | 650 | 650 | 750 |
(5) finishing: according to customer requirement, utilize slitter that cold rolling aluminium is trimmed to satisfactory width and aluminium is carried out the precoating oil treatment.
(6) packing
The end properties of easy-to-draw 2 tank can body aluminiums that employing embodiment 3 productions obtain is as shown in table 6.
The mechanical property that table 6 embodiment 3 produces the aluminium that obtains
Above three embodiment, the easy-to-draw 2 tank can body aluminium finished products that prepare can satisfy the industry standard requirement, and the surface is without defectives such as scuffing, oil mark, greasy dirt, striped, aberration, roll marks, embossing.Tensile strength and the yield strength of embodiment 1 resulting aluminium all meet the industry standard requirement, and mechanical property can be not higher or on the low side, and the earing rate of aluminium is lower than embodiment 2 and 3 among the embodiment 1, the deep-draw ability when more being conducive to tank processed.
Compared with prior art, the most outstanding improvement of the present invention is to adopt five frame cold continuous rolling production lines to carry out cold rolling process, in order to illustrate that cold rolling process of the present invention compares than the cold rolling process of traditional method, significantly improved production efficiency and yield rate, carried out following test example.
Comparative experimental example 1
Finish from the founding to the hot-rolled process, time consumption, energy consumption and the yield rate of embodiment 1 and comparative experimental example 1 are consistent, and coil weight is 13195kg behind the hot-rolled process, and thickness is 2.5mm, and width is 1542mm.Table 7 is embodiment 1 and the time consumption and yield rate comparing result of comparative experimental example 1 at cold rolling process.
Table 7 embodiment 1 and the time consumption and yield rate contrast of comparative experimental example 1 at cold rolling process
Because 6 roller single-stand cold-rolling machines only have an Abrollhaspel and a reeling machine, can not be rolled when carrying out the work such as material loading, blanking, threading, fortune volume, therefore will inevitably consume certain non-cutting time; And 5 frames have two Abrollhaspels and two reeling machines, the back works such as material loading, blanking, fortune volume can independently be carried out in the operation of rolling, can influence of rolled, and provide surge time by Multi-layer material-storing cabinet, a upper coiled strip tail by being welded together, does not need again threading with next coiled strip head, and at outlet automatic shearing bundling, thereby therefore realization continuous rolling can save the production time greatly.
As can be known from Table 7, only from the cold rolling process contrast, the time consumption of five frame cold continuous rollings is 18.0% of 6 roller single chassis only, and yield rate has improved 4.9%, can greatly enhance productivity and yield rate in the scale production of can body aluminium.
Comparative experimental example 2
Embodiment 2 and comparative experimental example 2 finish from the founding to the hot-rolled process that consumption, energy consumption and yield rate are consistent at that time, and coil weight is 12970kg behind the hot-rolled process, and thickness is 2.48mm, and width is 1240mm.Table 8 is embodiment 2 and the time consumption and yield rate comparing result of comparative experimental example 2 at cold rolling process.
Table 8 embodiment 2 and the time consumption and yield rate contrast of comparative experimental example 2 at cold rolling process
As can be known from Table 8, only from the cold rolling process contrast, the time consumption of five frame cold continuous rollings is 18.7% of 6 roller single chassis only, and yield rate has improved 4.0%, can greatly enhance productivity and yield rate in the scale production of can body aluminium.
Comparative experimental example 3
Embodiment 3 and comparative experimental example 3 finish from the founding to the hot-rolled process that consumption, energy consumption and yield rate are consistent at that time, and coil weight is 12925kg behind the hot-rolled process, and thickness is 2.19mm, and width is 1541mm.Table 9 is embodiment 3 and the time consumption and yield rate comparing result of comparative experimental example 3 at cold rolling process.
Table 9 embodiment 3 and the time consumption and yield rate contrast of comparative experimental example 3 at cold rolling process
As can be known from Table 9, only from the cold rolling process contrast, the time consumption of five frame cold continuous rollings is 18.6% of 6 roller single chassis only, and yield rate has improved 4.9%, can greatly enhance productivity and yield rate in the scale production of can body aluminium.
Above three test examples show: contrast single stand cold mill, but five frame cold continuous rolling Effective Raise production efficiencys, and improve the aluminium yield rate.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (6)
1. the production method of easy-to-draw 2 tank can body aluminiums is characterized in that, its Production Flow Chart comprises founding, sawing, mills face, heating, hot continuous rolling, cold rolling;
Wherein, the mass percent of the chemical composition of aluminium water is Si0.17~0.23%, Fe0.38~0.48%, Cu0.145 ~ 0.21%, Mn0.85~0.90%, Mg1.18~1.23%, Cr≤0.025%, Zn≤0.02%, Ti≤0.02%, other impurity after the founding single≤0.03%, add up to≤0.10%, all the other are Al; Smelting temperature is 720 ~ 750 ℃, 725 ~ 740 ℃ of refining temperatures, 660 ~ 700 ℃ of casting temps;
Described cold-rolling process is: adopt five frame cold continuous rolling production lines, 1 moulding is rolled down to 0.27 ~ 0.28mm with aluminium by 2.2mm ~ 2.5mm, and the first frame to the five frame drafts are assigned as: 25 ~ 35% → 25 ~ 38% → 25 ~ 38% → 30 ~ 50% → 35 ~ 50%.
2. the production method of easy-to-draw 2 tank can body aluminiums according to claim 1 is characterized in that, in described heating steps, ingot casting turns 510 ~ 520 ℃ of insulations 2 ~ 3 hours 600 ~ 610 ℃ of lower insulations 8 ~ 10 hours.
3. the production method of easy-to-draw 2 tank can body aluminiums according to claim 1 is characterized in that, in described hot-rolled step, uses the 1+5 hot rolling line, and 1 reversing rougher adds 1 five frame hot continuous rolling production line; Hot rolled coil thickness 2.2 ~ 2.5mm, 330 ~ 350 ℃ of hot finishing temperatures.
4. the production method of easy-to-draw 2 tank can body aluminiums according to claim 1 is characterized in that, exportation of aluminum products speed 〉=1200m/min, finished product temperature 〉=150 ℃.
5. the production method of each described easy-to-draw 2 tank can body aluminiums is characterized in that according to claim 1-4, and the content of Mg is 1.20 ~ 1.22% in the aluminium water after the described founding.
6. easy-to-draw 2 tank can body aluminiums of obtaining of each described production method production of claim 1-5.
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