CN103013305B - Cold-coating bi-component unsaturated polyester resin highway marking paint - Google Patents
Cold-coating bi-component unsaturated polyester resin highway marking paint Download PDFInfo
- Publication number
- CN103013305B CN103013305B CN201210563286.5A CN201210563286A CN103013305B CN 103013305 B CN103013305 B CN 103013305B CN 201210563286 A CN201210563286 A CN 201210563286A CN 103013305 B CN103013305 B CN 103013305B
- Authority
- CN
- China
- Prior art keywords
- parts
- unsaturated polyester
- component
- polyester resin
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention discloses cold-coating bi-component unsaturated polyester resin highway marking paint and a preparation method thereof. The method comprises the steps that phthalic anhydride, tetrahydrophthalic anhydride, maleic anhydride, trans-acid, glycol, propylene glycol, diglycol, pentaerythritol, linseed oil, tung oil, linoleic acid and eleostearic acid are used to generate unsaturated polyester; then unsaturated polyester is diluted into unsaturated polyester resin by styrene, methyl alcohol, butyl acrylate, methyl methacrylate, rosin and rosin acid; and a component A and a component B of the paint are prepared by taking unsaturated polyester resin obtained from the steps, titanium dioxide, talcum powder, precipitated barium sulfate, calcium, phosphorus, cobalt, vanadium, amine, an antifoaming agent, an anti-yellow agent, an anti-settling agent, methyl ethyl ketone peroxide, cyclohexanone peroxide and BPO (benzoyl peroxide) as raw materials. The highway marking paint has high temperature resistance, water resistance, friction resistance and the like, and is convenient to use.
Description
Technical field
The present invention relates to a kind of paint, particularly relate to a kind of cold spraying paint.
Background technology
Now a lot of building, equipment, road surface all need mopping, the requirement of paint is not quite similar.For highway graticule, owing to being positioned at outdoor environment, especially on highway, various severe physical environment be stood, need it to have the performances such as high temperature resistant, sun-resistant, resistance to rainwater, rub resistance, but highway marking paint of the prior art also exist shortcomings.In addition, before highway marking paint of the prior art sprays, need heating again, cause it to use inconvenience.Therefore researching and developing good, the easy to use highway marking paint of a kind of performance is the problem that this area researchist needs solution badly.
Summary of the invention
The invention discloses a kind of cold painting two-pack unsaturated polyester resin highway marking paint and preparation method thereof, the performances such as this highway marking paint is high temperature resistant, waterproof, rub resistance are good and easy to use.
The invention discloses a kind of cold painting two-pack unsaturated polyester resin highway marking paint, it comprises component A and B component, wherein,
Component A comprises unsaturated polyester resin 1555.5 parts, titanium dioxide 864 parts, talcum powder 345.6 parts, process white 259.2 parts, calcium 86.4 parts, 17.28 parts, phosphorus, cobalt 8.64 parts, vanadium 8.64 parts, amine 8.64 parts, defoamer 3.45 parts, anti-yellow agent 3.45 parts, anti-settling agent 3.45 parts;
B component comprises unsaturated polyester resin 1555.5 parts, titanium dioxide 864 parts, talcum powder 345.6 parts, process white 259.2 parts, calcium 86.4 parts, 17.28 parts, phosphorus, cobalt 8.64 parts, vanadium 8.64 parts, amine 8.64 parts, defoamer 3.45 parts, anti-yellow agent 3.45 parts, anti-settling agent 3.45 parts, methylethyl ketone peroxide 86.4 parts, cyclohexanone peroxide 86.4 parts, BPO 34.56 parts;
Wherein unsaturated polyester resin comprises phthalic anhydride 110 parts, tetrahydrophthalic anhydride 114 parts, cis-butenedioic anhydride 98 parts, sour regurgitation 102 parts, ethylene glycol 62 parts, propylene glycol 76 parts, glycol ether 106 parts, tetramethylolmethane 100 parts, oleum lini 66 parts, tung oil 48 parts, linolenic acid 68 parts, eleostearic acid 68 parts, vinylbenzene 320 parts, methyl alcohol 10 parts, butyl acrylate 50 parts, methyl methacrylate 50 parts, 200# solvent 150 parts, toluene 50 parts, dimethylbenzene 30 parts, rosin 30 parts, sylvic acid 20 parts.
The invention also discloses a kind of preparation method of cold painting two-pack unsaturated polyester resin highway marking paint, it comprises the steps:
(1) prepare unsaturated polyester resin, it comprises the steps:
With phthalic anhydride 110 parts, tetrahydrophthalic anhydride 114 parts, cis-butenedioic anhydride 98 parts, sour regurgitation 102 parts, ethylene glycol 62 parts, propylene glycol 76 parts, glycol ether 106 parts, tetramethylolmethane 100 parts, oleum lini 66 parts, tung oil 48 parts, linolenic acid 68 parts and eleostearic acid 68 parts with high temperature under protection of inert gas through condensation reaction, generate unsaturated polyester; Wherein said high temperature is preferably 240 DEG C;
By above-mentioned unsaturated polyester vinylbenzene 320 parts, methyl alcohol 10 parts, butyl acrylate 50 parts, methyl methacrylate 50 parts, 200# solvent 150 parts, toluene 50 parts, dimethylbenzene 30 parts, rosin 30 parts and sylvic acid 20 parts are diluted to unsaturated polyester resin at low temperatures; Wherein said low temperature is preferably 50 DEG C;
(2) unsaturated polyester resin obtained in step (1) is prepared component A and B component as raw material, wherein,
The method preparing component A is:
By unsaturated polyester resin 1555.5 parts, titanium dioxide 864 parts, talcum powder 345.6 parts, process white 259.2 parts, calcium 86.4 parts, 17.28 parts, phosphorus, cobalt 8.64 parts, vanadium 8.64 parts, amine 8.64 parts, defoamer 3.45 parts, anti-yellow agent 3.45 parts and anti-settling agent 3.45 parts add dispersion tank, fully stir, be uniformly dispersed, with 200# solvent 150 parts, toluene 50 parts, dimethylbenzene 30 parts, vinylbenzene 320 parts adjustment viscosity, obtained component A paint.
The method preparing B component is:
By unsaturated polyester resin 1555.5 parts, titanium dioxide 864 parts, talcum powder 345.6 parts, process white 259.2 parts, calcium 86.4 parts, 17.28 parts, phosphorus, cobalt 8.64 parts, vanadium 8.64 parts, amine 8.64 parts, defoamer 3.45 parts, anti-yellow agent 3.45 parts, anti-settling agent 3.45 parts, methylethyl ketone peroxide 86.4 parts, cyclohexanone peroxide 86.4 parts and BPO 34.56 parts add dispersion tank, fully stir, be uniformly dispersed, with 200# solvent 150 parts, toluene 50 parts, dimethylbenzene 30 parts, vinylbenzene 320 parts adjustment viscosity, obtained B component paint.
Embodiment
The preparation method of cold painting two-pack unsaturated polyester resin highway marking paint of the present invention, it comprises the steps:
First, unsaturated polyester resin is prepared:
Prepare raw material: phthalic anhydride 110 grams, tetrahydrophthalic anhydride 114 grams, cis-butenedioic anhydride 98 grams, sour regurgitation 102 grams, ethylene glycol 62 grams, propylene glycol 76 grams, glycol ether 106 grams, tetramethylolmethane 100 grams, oleum lini 66 grams, tung oil 48 grams, linolenic acid 68 grams, eleostearic acid 68 grams, vinylbenzene 320 grams, methyl alcohol 10 grams, butyl acrylate 50 grams, methyl methacrylate 50 grams, 200# solvent 150 grams, toluene 50 grams, dimethylbenzene 30 grams, rosin 30 grams, sylvic acid 20 grams.
The method preparing unsaturated polyester resin comprises the steps:
By the phthalic anhydride of said components, tetrahydrophthalic anhydride, cis-butenedioic anhydride, sour regurgitation, ethylene glycol, propylene glycol, glycol ether, tetramethylolmethane, oleum lini, tung oil, linolenic acid, eleostearic acid with high temperature under protection of inert gas through condensation reaction, generate unsaturated polyester; Wherein high temperature is preferably 240 DEG C;
By the vinylbenzene of above-mentioned unsaturated polyester said components, methyl alcohol, butyl acrylate, methyl methacrylate, rosin, sylvic acid is diluted to unsaturated polyester resin at low temperatures; Wherein low temperature is preferably 50 DEG C.
The syntheti c route of the method is:
Phthalic anhydride, tetrahydrophthalic anhydride, cis-butenedioic anhydride, sour regurgitation, ethylene glycol, propylene glycol, glycol ether, tetramethylolmethane, oleum lini, tung oil, linolenic acid, eleostearic acid, heat 240 DEG C---> tests endpoint acid number, viscosity, qualified---> cooling DEG C---> vinylbenzene, methyl alcohol, butyl acrylate, methyl methacrylate, rosin, sylvic acid, dilution, test viscosity, admittedly containing qualified, lower the temperature 25 DEG C, packaging discharging.
Then the unsaturated polyester resin prepared using aforesaid method prepares component A and B component as one of raw material, and the raw material wherein preparing component A and B component comprises respectively:
Unsaturated polyester resin 1555.5 grams, titanium dioxide 864 grams, talcum powder 345.6 grams, process white 259.2 grams, calcium 86.4 grams, 17.28 grams, phosphorus, cobalt 8.64 grams, vanadium 8.64 grams, amine 8.64 grams, defoamer 3.45 grams, anti-yellow agent 3.45 grams, anti-settling agent 3.45 grams;
Unsaturated polyester resin 1555.5 grams, titanium dioxide 864 grams, talcum powder 345.6 grams, process white 259.2 grams, calcium 86.4 grams, 17.28 grams, phosphorus, cobalt 8.64 grams, vanadium 8.64 grams, amine 8.64 grams, defoamer 3.45 grams, anti-yellow agent 3.45 grams, anti-settling agent 3.45 grams, methylethyl ketone peroxide 86.4 grams, cyclohexanone peroxide 86.4 grams, BPO 34.56 grams.
The method preparing component A is:
By above-mentioned raw materials: unsaturated polyester resin, titanium dioxide, talcum powder, process white, calcium, phosphorus, cobalt, vanadium, amine, defoamer, anti-yellow agent, anti-settling agent, raw material adds dispersion tank in proportion, fully stirs, be uniformly dispersed, with 200# solvent 150g, toluene 50g, dimethylbenzene 30g, vinylbenzene 320g adjust viscosity, obtained component A paint.
The method preparing B component is:
By unsaturated polyester resin, titanium dioxide, talcum powder, process white, calcium, phosphorus, cobalt, vanadium, amine, defoamer, anti-yellow agent, anti-settling agent, raw material adds dispersion tank in proportion, fully stirs, and is uniformly dispersed, and adds methylethyl ketone peroxide, methylethyl ketone peroxide and BPO, with 200# solvent 150g, toluene 50g, dimethylbenzene 30g, vinylbenzene 320g adjust viscosity, obtained B component paint.
The products characteristics of cold painting two-pack unsaturated polyester resin highway marking paint of the present invention uses specific equipment, the namely direct cold spraying of special dual-component highway marking equipment, does not need heating, easy to use.Component A fully must mix outward at rifle when spraying with B component.
Claims (2)
1. a cold painting two-pack unsaturated polyester resin highway marking paint, is characterized in that, comprise component A and B component, wherein,
Described component A comprises unsaturated polyester resin 1555.5 parts, titanium dioxide 864 parts, talcum powder 345.6 parts, process white 259.2 parts, calcium 86.4 parts, 17.28 parts, phosphorus, cobalt 8.64 parts, vanadium 8.64 parts, amine 8.64 parts, defoamer 3.45 parts, anti-yellow agent 3.45 parts, anti-settling agent 3.45 parts;
Described B component comprises unsaturated polyester resin 1555.5 parts, titanium dioxide 864 parts, talcum powder 345.6 parts, process white 259.2 parts, calcium 86.4 parts, 17.28 parts, phosphorus, cobalt 8.64 parts, vanadium 8.64 parts, amine 8.64 parts, defoamer 3.45 parts, anti-yellow agent 3.45 parts, anti-settling agent 3.45 parts, methylethyl ketone peroxide 86.4 parts, cyclohexanone peroxide 86.4 parts, BPO34.56 part;
Wherein, described unsaturated polyester resin comprises phthalic anhydride 110 parts, tetrahydrophthalic anhydride 114 parts, cis-butenedioic anhydride 98 parts, sour regurgitation 102 parts, ethylene glycol 62 parts, propylene glycol 76 parts, glycol ether 106 parts, tetramethylolmethane 100 parts, oleum lini 66 parts, tung oil 48 parts, linolenic acid 68 parts, eleostearic acid 68 parts, vinylbenzene 320 parts, methyl alcohol 10 parts, butyl acrylate 50 parts, methyl methacrylate 50 parts, 200# solvent 150 parts, toluene 50 parts, dimethylbenzene 30 parts, rosin 30 parts, sylvic acid 20 parts.
2. a preparation method for cold painting two-pack unsaturated polyester resin highway marking paint, described highway marking paint comprises component A and B component, it is characterized in that, described preparation method comprises the steps:
(1) prepare unsaturated polyester resin, it comprises the steps:
With phthalic anhydride 110 parts, tetrahydrophthalic anhydride 114 parts, cis-butenedioic anhydride 98 parts, sour regurgitation 102 parts, ethylene glycol 62 parts, propylene glycol 76 parts, glycol ether 106 parts, tetramethylolmethane 100 parts, oleum lini 66 parts, tung oil 48 parts, linolenic acid 68 parts and eleostearic acid 68 parts with high temperature under protection of inert gas through condensation reaction, generate unsaturated polyester; Wherein said high temperature is preferably 240 DEG C;
By above-mentioned unsaturated polyester vinylbenzene 320 parts, methyl alcohol 10 parts, butyl acrylate 50 parts, methyl methacrylate 50 parts, 200# solvent 150 parts, toluene 50 parts, dimethylbenzene 30 parts, rosin 30 parts and sylvic acid 20 parts are diluted to unsaturated polyester resin at low temperatures; Wherein said low temperature is preferably 50 DEG C;
(2) unsaturated polyester resin obtained in step (1) is prepared component A and B component as raw material, wherein,
The method preparing component A is:
By unsaturated polyester resin 1555.5 parts, titanium dioxide 864 parts, talcum powder 345.6 parts, process white 259.2 parts, calcium 86.4 parts, 17.28 parts, phosphorus, cobalt 8.64 parts, vanadium 8.64 parts, amine 8.64 parts, defoamer 3.45 parts, anti-yellow agent 3.45 parts and anti-settling agent 3.45 parts add dispersion tank, fully stir, be uniformly dispersed, with 200# solvent 150 parts, toluene 50 parts, dimethylbenzene 30 parts, vinylbenzene 320 parts adjustment viscosity, obtained component A paint;
The method preparing B component is:
By unsaturated polyester resin 1555.5 parts, titanium dioxide 864 parts, talcum powder 345.6 parts, process white 259.2 parts, calcium 86.4 parts, 17.28 parts, phosphorus, cobalt 8.64 parts, vanadium 8.64 parts, amine 8.64 parts, defoamer 3.45 parts, anti-yellow agent 3.45 parts, anti-settling agent 3.45 parts, methylethyl ketone peroxide 86.4 parts, cyclohexanone peroxide 86.4 parts and BPO34.56 part add dispersion tank, fully stir, be uniformly dispersed, with 200# solvent 150 parts, toluene 50 parts, dimethylbenzene 30 parts, vinylbenzene 320 parts adjustment viscosity, obtained B component paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210563286.5A CN103013305B (en) | 2012-12-24 | 2012-12-24 | Cold-coating bi-component unsaturated polyester resin highway marking paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210563286.5A CN103013305B (en) | 2012-12-24 | 2012-12-24 | Cold-coating bi-component unsaturated polyester resin highway marking paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103013305A CN103013305A (en) | 2013-04-03 |
| CN103013305B true CN103013305B (en) | 2015-03-18 |
Family
ID=47962434
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210563286.5A Expired - Fee Related CN103013305B (en) | 2012-12-24 | 2012-12-24 | Cold-coating bi-component unsaturated polyester resin highway marking paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103013305B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103360924A (en) * | 2013-06-26 | 2013-10-23 | 南京市荣达树脂有限公司 | Unsaturated polyester wear-resistant paint |
| CN103360923A (en) * | 2013-06-26 | 2013-10-23 | 南京市荣达树脂有限公司 | Preparation method of unsaturated polyester wear-resistant paint |
| CN104194588B (en) * | 2014-08-28 | 2016-06-29 | 苏州洛特兰新材料科技有限公司 | Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery |
| CN106065209A (en) * | 2016-08-05 | 2016-11-02 | 天津市津海特种涂料装饰有限公司 | A kind of solvent-free paint marking of super abrasive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5712053A (en) * | 1980-06-25 | 1982-01-21 | Dainippon Toryo Co Ltd | Corrosion-resisting lining composition |
| CN102134439A (en) * | 2011-02-25 | 2011-07-27 | 上海富臣化工有限公司 | Low-temperature baking polyurethane (PU) plastic cement paint and preparation method thereof |
| CN102140300A (en) * | 2011-02-21 | 2011-08-03 | 陈希锴 | Quick-drying unsaturated polyester resin marking coating and preparation method thereof |
-
2012
- 2012-12-24 CN CN201210563286.5A patent/CN103013305B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5712053A (en) * | 1980-06-25 | 1982-01-21 | Dainippon Toryo Co Ltd | Corrosion-resisting lining composition |
| CN102140300A (en) * | 2011-02-21 | 2011-08-03 | 陈希锴 | Quick-drying unsaturated polyester resin marking coating and preparation method thereof |
| CN102134439A (en) * | 2011-02-25 | 2011-07-27 | 上海富臣化工有限公司 | Low-temperature baking polyurethane (PU) plastic cement paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103013305A (en) | 2013-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104086701B (en) | The preparation method of the alkali solubility epoxy acrylic UV resin of high temperature resistant resistance to xanthochromia | |
| CN103013305B (en) | Cold-coating bi-component unsaturated polyester resin highway marking paint | |
| CN104479087B (en) | A kind of quick-dry type water-base epoxy ester lotion and its preparation method and application | |
| CN103554379B (en) | Aqueous acrylic acid-modified alkyd resin and preparation method thereof | |
| CN102746761B (en) | Aqueous alkyd acrylic resin paint and preparation method thereof | |
| CN103421170B (en) | Epoxy-acrylics modified water dispersible alkyd and Synthesis and applications thereof | |
| CN102190786B (en) | Dull polyester resin and preparation method thereof | |
| CN103554461A (en) | Epoxy modified alkyd resin and its high hardness fast reaction coating | |
| CN103319700A (en) | Maleic anhydride oil modified aqueous alkyd resin, and environmentally-friendly paint prepared through using it | |
| CN105764934A (en) | Low viscosity, water-borne, acrylic modified alkyd dispersion and method of production the same | |
| CN103360575A (en) | Aqueous organic salt modified epoxy ester resin, and preparation method and application thereof | |
| CN103642020A (en) | Modified polyester resin as well as coating and application thereof | |
| CN106967352A (en) | A kind of positive non-ion aqueous epoxy ester emulsion and preparation method and application | |
| CN103980804A (en) | Method for forming dual-layer coating | |
| CN103923241B (en) | AB block type pigment dispersing agent and preparation method thereof | |
| CN103906577A (en) | Method for forming multilayer coating film | |
| CN107216776B (en) | A kind of photo-thermal dual curable composition of insulating coating and its application | |
| CN104395416A (en) | Aluminum wheel primer coat composition | |
| CN105949439B (en) | A kind of preparation method of watersoluble modified epoxy resin | |
| CN107267013A (en) | A kind of environment-friendly type road gage mark coating | |
| CN106221569A (en) | A kind of high adhesion force acrylic resin paint and preparation method thereof | |
| CN106085157A (en) | A kind of method preparing cryogenic curing resin | |
| CN103342939A (en) | Water-soluble epoxy ester antirust paint | |
| CN102898884B (en) | Environment-friendly cashew amine epoxy curing agent for low volatile organic compound (VOC) anticorrosive coating and preparation method for curing agent | |
| US10513566B2 (en) | Epoxidized oil and resin compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150318 Termination date: 20201224 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |