CN103011463A - 一种去除污水中锆的方法 - Google Patents
一种去除污水中锆的方法 Download PDFInfo
- Publication number
- CN103011463A CN103011463A CN2012105954445A CN201210595444A CN103011463A CN 103011463 A CN103011463 A CN 103011463A CN 2012105954445 A CN2012105954445 A CN 2012105954445A CN 201210595444 A CN201210595444 A CN 201210595444A CN 103011463 A CN103011463 A CN 103011463A
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- CN
- China
- Prior art keywords
- zirconium
- waste water
- organic
- sewage
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 229910052726 zirconium Inorganic materials 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000010865 sewage Substances 0.000 title claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000000919 ceramic Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000007524 organic acids Chemical class 0.000 claims abstract description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 8
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims abstract description 7
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims abstract description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 7
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000005979 Citrus limon Nutrition 0.000 claims abstract description 3
- 244000248349 Citrus limon Species 0.000 claims abstract description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract description 3
- 239000002351 wastewater Substances 0.000 claims description 37
- 239000000126 substance Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000012856 packing Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000008399 tap water Substances 0.000 claims description 6
- 235000020679 tap water Nutrition 0.000 claims description 6
- 238000005189 flocculation Methods 0.000 claims description 5
- 230000016615 flocculation Effects 0.000 claims description 5
- 239000013049 sediment Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 238000011282 treatment Methods 0.000 abstract description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 abstract 1
- KPGXRSRHYNQIFN-UHFFFAOYSA-N 2-oxoglutaric acid Chemical compound OC(=O)CCC(=O)C(O)=O KPGXRSRHYNQIFN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract 1
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 235000011090 malic acid Nutrition 0.000 abstract 1
- 239000001630 malic acid Substances 0.000 abstract 1
- ZUVVLBGWTRIOFH-UHFFFAOYSA-N methyl 4-methyl-2-[(4-methylphenyl)sulfonylamino]pentanoate Chemical compound COC(=O)C(CC(C)C)NS(=O)(=O)C1=CC=C(C)C=C1 ZUVVLBGWTRIOFH-UHFFFAOYSA-N 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical group 0.000 description 3
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- JJWSNOOGIUMOEE-UHFFFAOYSA-N Monomethylmercury Chemical compound [Hg]C JJWSNOOGIUMOEE-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000005442 atmospheric precipitation Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 210000001218 blood-brain barrier Anatomy 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001079 digestive effect Effects 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 238000004162 soil erosion Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- HAIMOVORXAUUQK-UHFFFAOYSA-J zirconium(iv) hydroxide Chemical group [OH-].[OH-].[OH-].[OH-].[Zr+4] HAIMOVORXAUUQK-UHFFFAOYSA-J 0.000 description 1
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201210595444.5A CN103011463B (zh) | 2012-12-07 | 2012-12-07 | 一种去除污水中锆的方法 |
Applications Claiming Priority (1)
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CN201210595444.5A CN103011463B (zh) | 2012-12-07 | 2012-12-07 | 一种去除污水中锆的方法 |
Publications (2)
Publication Number | Publication Date |
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CN103011463A true CN103011463A (zh) | 2013-04-03 |
CN103011463B CN103011463B (zh) | 2014-01-08 |
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Family Applications (1)
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CN201210595444.5A Expired - Fee Related CN103011463B (zh) | 2012-12-07 | 2012-12-07 | 一种去除污水中锆的方法 |
Country Status (1)
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CN (1) | CN103011463B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103739108A (zh) * | 2013-06-24 | 2014-04-23 | 四川海普流体技术有限公司 | 一种污水处理工艺中加入添加剂的方法 |
CN104140169A (zh) * | 2014-07-18 | 2014-11-12 | 常州大学 | 一种去除线路板蚀刻废水中硒离子的方法 |
CN106379984A (zh) * | 2016-11-18 | 2017-02-08 | 郑州丽福爱生物技术有限公司 | 一种城镇污水处理药剂及其制备工艺 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1336329A (zh) * | 2001-04-03 | 2002-02-20 | 柳云珍 | 生产锆系列产品中碱熔料或烧结料水洗产生的污水处理工艺 |
CN101161834A (zh) * | 2006-10-09 | 2008-04-16 | 冯云善 | 从11#煤层酸水中分离矿物的方法 |
CN101234765A (zh) * | 2007-01-31 | 2008-08-06 | 北京有色金属研究总院 | 碱熔锆英石生产氧氯化锆中废碱液的回收利用方法 |
CN202449939U (zh) * | 2012-02-21 | 2012-09-26 | 山东神州锆业有限公司 | 一种污水处理装置 |
US8287738B2 (en) * | 2009-04-21 | 2012-10-16 | E I Du Pont De Nemours And Company | Process for removing impurities from iron chloride solutions |
-
2012
- 2012-12-07 CN CN201210595444.5A patent/CN103011463B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1336329A (zh) * | 2001-04-03 | 2002-02-20 | 柳云珍 | 生产锆系列产品中碱熔料或烧结料水洗产生的污水处理工艺 |
CN101161834A (zh) * | 2006-10-09 | 2008-04-16 | 冯云善 | 从11#煤层酸水中分离矿物的方法 |
CN101234765A (zh) * | 2007-01-31 | 2008-08-06 | 北京有色金属研究总院 | 碱熔锆英石生产氧氯化锆中废碱液的回收利用方法 |
US8287738B2 (en) * | 2009-04-21 | 2012-10-16 | E I Du Pont De Nemours And Company | Process for removing impurities from iron chloride solutions |
CN202449939U (zh) * | 2012-02-21 | 2012-09-26 | 山东神州锆业有限公司 | 一种污水处理装置 |
Non-Patent Citations (3)
Title |
---|
孙亚光等: "氯氧化锆生产排放废水废渣处理技术研究", 《稀有金属快报》 * |
罗新文等: "氧氯化锆生产过程的污染治理", 《中国材料进展》 * |
黄凯等: "硅胶吸附去除高放废液中锆的研究进展", 《核科学与工程》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103739108A (zh) * | 2013-06-24 | 2014-04-23 | 四川海普流体技术有限公司 | 一种污水处理工艺中加入添加剂的方法 |
CN103739108B (zh) * | 2013-06-24 | 2016-03-02 | 四川海普流体技术有限公司 | 一种污水处理工艺中加入添加剂的方法 |
CN104140169A (zh) * | 2014-07-18 | 2014-11-12 | 常州大学 | 一种去除线路板蚀刻废水中硒离子的方法 |
CN106379984A (zh) * | 2016-11-18 | 2017-02-08 | 郑州丽福爱生物技术有限公司 | 一种城镇污水处理药剂及其制备工艺 |
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Publication number | Publication date |
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CN103011463B (zh) | 2014-01-08 |
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Legal Events
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PB01 | Publication | ||
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SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Lei Chunsheng Inventor before: Wang Wei |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: WANG WEI TO: LEI CHUNSHENG |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20171115 Address after: 226531, No. 18 Shi Zhuang Road, Shi Zhuang Town, Nantong City, Jiangsu, Rugao Patentee after: Rugao Linjiang Construction Investment Co., Ltd. Address before: Changzhou Road, Wujin District 213164 Gehu Lake in Jiangsu province No. 1 Patentee before: Changzhou University |
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TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140108 Termination date: 20181207 |
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CF01 | Termination of patent right due to non-payment of annual fee |