CN102993519A - Cable sheath insulating material for field logging and preparation method of same - Google Patents
Cable sheath insulating material for field logging and preparation method of same Download PDFInfo
- Publication number
- CN102993519A CN102993519A CN2012104523555A CN201210452355A CN102993519A CN 102993519 A CN102993519 A CN 102993519A CN 2012104523555 A CN2012104523555 A CN 2012104523555A CN 201210452355 A CN201210452355 A CN 201210452355A CN 102993519 A CN102993519 A CN 102993519A
- Authority
- CN
- China
- Prior art keywords
- parts
- insulating material
- cable sheath
- calcium carbonate
- field logging
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a cable sheath insulating material for field logging and a preparation method of the cable sheath insulating material. The cable sheath insulating material comprises the following raw materials according to parts by weight: 97 to 102 parts of neoprene A90, 14 to 21 parts of Japanese JSR chemigum N220S, 19 to 26 parts of semi-reinforcing black N774, 2 to 3 parts of ferrocene, 1 to 2 parts of N, N'-m-phenylenedimaleimide, 31 to 36 parts of blanc fixe, 1 to 3 parts of anti-aging agent MB, 1 to 2 parts of 2-thiol benzimidazole, 5 to 9 parts of chlorcosane, 1 to 2 parts of accelerant DM, 0.8 to 1 part of ammonium trimolybdate, 19 to 29 parts of nanometer bauxite, 1 to 3 parts of polypropylene glycol adipate, 2 to 4 parts of zinc borate, 4 to 6 parts of epoxidized butyl ester, 0.8 to 1 part of zinc oxide, 2 to 3 parts of modified calcium carbonate, 1 to 2 parts of hexasulfide dipentamethylenethiuram, 1 to 1.2 parts of isopropyl tri(dioctyl pyrophosphoric acyloxy) titanate, and 2 to 3 parts of ammonium plyphosphate. The cable sheath insulating material for field logging, prepared by the invention, is excellent in physical performance, stable in dimension and low in percentage of contraction, and greatly reduces the pulling strength, the tearing strength and the resilience performance.
Description
Technical field
The present invention relates generally to a kind of rubber sleeve material and preparation method thereof, relates in particular to a kind of field logging cable jacket insulation material and preparation method thereof.
Background technology
The cable that field logging is used is owing to its Working environment is special, be in for a long time dirty down-hole, external world's corrosion that the oversheath of cable is subject to is more intense, also to bear comparatively frequently twisting and certain pulling force, therefore, mechanical property, water repelling property, ageing-resistant performance, corrosion resistance nature requirement to cable jacket are very high, and the jacket rubber of common cable can not satisfy the requirement in this particular job place, and often work-ing life is very short.
Summary of the invention
The object of the invention is exactly in order to remedy the defective of prior art, a kind of field logging cable jacket insulation material to be provided.
The present invention is achieved by the following technical solutions:
A kind of field logging cable jacket insulation material is characterized in that:
Chloroprene rubber A90 97-102, Japan JSR paracril N220S14-21, semi-reinforcing hydrocarbon black N774 19-26, ferrocene 2-3, N, a N '-penylene bismaleimides 1-2, blaue fixe 31-36, antioxidant MB 1-3,2-thiol group benzimidazolyl 1-2, clorafin 5-9, altax 1-2, three ammonium molybdate 0.8-1, nano aluminum alumina 19-29, hexanodioic acid propanediol polyester 1-3, zinc borate 2-4, epoxyoleic acid butyl ester 4-6, zinc oxide 0.8-1, modified calcium carbonate 2-3, six sulfuration di-penta methylene thiuram 1-2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 1-1.2, ammonium polyphosphate 2-3;
The preparation method of described modified calcium carbonate is: be that 1: 8-10 ratio is mixed in mass ratio with unslaked lime and boiling water, and digestion 4-5h, the resonance screen filter cleaner through 180 μ m further removes the gred through wet cyclone again, obtains Ca (OH)
2Suspension is at Ca (OH)
2Add the sequestrant b diammonium edta of its quality 5-8%, the magnesium chloride of its quality 8-12%, the tensio-active agent sodium polyphosphate of its quality 3-5% in the suspension, stir in the rear immigration carbonization reactor, pass into from CO
2The pure CO of steel cylinder
2With the air from air compressor machine, be mixed into and contain volume fraction 25～30%CO
2Gas react, stopped reaction when pH=6.5-7.0, with reaction mass through centrifugal, washing, dry, pulverize, cross 150-180 mesh sieves, get modified calcium carbonate.
A kind of field logging cable jacket insulation material preparation method may further comprise the steps:
(1) the chloroprene rubber A90 with above-mentioned weight part adds in the Banbury mixer, is to plasticate separately under 75-80 ℃ 8-10 minute in temperature, and then discharging is cooled to normal temperature;
(2) with Japanese JSR paracril N220S, the N of the chloroprene rubber behind the plastics and above-mentioned weight part, a N '-penylene bismaleimides, antioxidant MB, 2-thiol group benzimidazolyl, clorafin, ferrocene, altax, three ammonium molybdates mix and add Banbury mixer, are 85-90 ℃ in temperature and descend mixing 2-3 minute;
(3) add again semi-reinforcing hydrocarbon black N774, blaue fixe, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, ammonium polyphosphate, nano aluminum alumina, hexanodioic acid propanediol polyester, zinc borate, epoxyoleic acid butyl ester, the modified calcium carbonate of above-mentioned weight part, be under 85-90 ℃ in temperature, mixing 4-6 minute;
(4) add again above-mentioned weight part, six sulfuration di-penta methylene thiurams, zinc oxide, temperature be 55-60 ℃ lower mixing 2-3 minute, the discharging cooling namely gets described field logging with cable jacket insulation material.
Advantage of the present invention is:
The field logging that the present invention produces is excellent with cable jacket insulation material physical property, dimensional stabilizing, shrinking percentage is low, and product draws degree of promoting the strong, tearing toughness, screen resilience performance all greatly to improve, by rational collocation composition of raw materials, so that the insulating material compactness of producing is good, anti-outlet capacity is strong, and mechanical property is superior, can realize that elongation at break is greater than 300%, and oil resistant, ageing-resistant, corrosion-resistant, wear-resistant can satisfy the service requirements of field logging cable.
Embodiment
Embodiment 1
A kind of field logging cable jacket insulation material, it is comprised of following weight parts (kilogram) raw material:
Chloroprene rubber A90 102, Japanese JSR paracril N220S21, semi-reinforcing hydrocarbon black N774 26, ferrocene 2, N, a N '-penylene bismaleimides 2, blaue fixe 31-36, antioxidant MB 3,2-thiol group benzimidazolyl 1, clorafin 9, altax 2, three ammonium molybdates 1, nano aluminum alumina 29, hexanodioic acid propanediol polyester 3, zinc borate 4, epoxyoleic acid butyl ester 6, zinc oxide 0.8, modified calcium carbonate 2, six sulfuration di-penta methylene thiurams 2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 1.2, ammonium polyphosphate 3;
The preparation method of described modified calcium carbonate is: be that 1: 10 ratio is mixed in mass ratio with unslaked lime and boiling water, and digestion 5h, the resonance screen filter cleaner through 180 μ m further removes the gred through wet cyclone again, obtains Ca (OH)
2Suspension is at Ca (OH)
2Add the sequestrant b diammonium edta of its quality 8%, the magnesium chloride of its quality 12%, the tensio-active agent sodium polyphosphate of its quality 5% in the suspension, stir in the rear immigration carbonization reactor, pass into from CO
2The pure CO of steel cylinder
2With the air from air compressor machine, be mixed into and contain volume fraction 30%CO
2Gas react, stopped reaction when pH=7.0, with reaction mass through centrifugal, washing, dry, pulverize, cross 180 mesh sieves, get modified calcium carbonate.
The preparation method of the CABLE MATERIALS that a kind of used for wind power generation is low temperature resistant may further comprise the steps:
(1) the chloroprene rubber A90 with above-mentioned weight part adds in the Banbury mixer, is to plasticate separately under 80 ℃ 8 minutes in temperature, and then discharging is cooled to normal temperature;
(2) with Japanese JSR paracril N220S, the N of the chloroprene rubber behind the plastics and above-mentioned weight part, a N '-penylene bismaleimides, antioxidant MB, 2-thiol group benzimidazolyl 1-2, clorafin, ferrocene, altax, three ammonium molybdates mix and add Banbury mixer, are 90 ℃ in temperature and descend mixing 3 minutes;
(3) add again semi-reinforcing hydrocarbon black N774, blaue fixe, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, ammonium polyphosphate, nano aluminum alumina, hexanodioic acid propanediol polyester, zinc borate, epoxyoleic acid butyl ester, the modified calcium carbonate of above-mentioned weight part, be under 90 ℃ in temperature, mixing 6 minutes;
(4) add again above-mentioned weight part, six sulfuration di-penta methylene thiurams, zinc oxide, temperature be 60 ℃ lower mixing 3 minutes, the discharging cooling namely gets described field logging with cable jacket insulation material.
Technical indicator:
Claims (2)
1. a field logging is characterized in that it is comprised of the raw material of following weight parts with cable jacket insulation material:
Chloroprene rubber A90 97-102, Japan JSR paracril N220S14-21, semi-reinforcing hydrocarbon black N774 19-26, ferrocene 2-3, N, a N '-penylene bismaleimides 1-2, blaue fixe 31-36, antioxidant MB 1-3,2-thiol group benzimidazolyl 1-2, clorafin 5-9, altax 1-2, three ammonium molybdate 0.8-1, nano aluminum alumina 19-29, hexanodioic acid propanediol polyester 1-3, zinc borate 2-4, epoxyoleic acid butyl ester 4-6, zinc oxide 0.8-1, modified calcium carbonate 2-3, six sulfuration di-penta methylene thiuram 1-2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 1-1.2, ammonium polyphosphate 2-3;
The preparation method of described modified calcium carbonate is: be that 1: 8-10 ratio is mixed in mass ratio with unslaked lime and boiling water, and digestion 4-5h, the resonance screen filter cleaner through 180 μ m further removes the gred through wet cyclone again, obtains Ca (OH)
2Suspension is at Ca (OH)
2Add the sequestrant b diammonium edta of its quality 5-8%, the magnesium chloride of its quality 8-12%, the tensio-active agent sodium polyphosphate of its quality 3-5% in the suspension, stir in the rear immigration carbonization reactor, pass into from CO
2The pure CO of steel cylinder
2With the air from air compressor machine, be mixed into and contain volume fraction 25～30%CO
2Gas react, stopped reaction when pH=6.5-7.0, with reaction mass through centrifugal, washing, dry, pulverize, cross 150-180 mesh sieves, get modified calcium carbonate.
2. a field logging as claimed in claim 1 is characterized in that may further comprise the steps with cable jacket insulation material preparation method:
(1) the chloroprene rubber A90 with above-mentioned weight part adds in the Banbury mixer, is to plasticate separately under 75-80 ℃ 8-10 minute in temperature, and then discharging is cooled to normal temperature;
(2) with Japanese JSR paracril N220S, the N of the chloroprene rubber behind the plastics and above-mentioned weight part, a N '-penylene bismaleimides, antioxidant MB, 2-thiol group benzimidazolyl 1-2, clorafin, ferrocene, altax, three ammonium molybdates mix and add Banbury mixer, are 85-90 ℃ in temperature and descend mixing 2-3 minute;
(3) add again semi-reinforcing hydrocarbon black N774, blaue fixe, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, ammonium polyphosphate nano aluminum alumina, hexanodioic acid propanediol polyester, zinc borate, epoxyoleic acid butyl ester, the modified calcium carbonate of above-mentioned weight part, be under 85-90 ℃ in temperature, mixing 4-6 minute;
(4) add six of above-mentioned weight part again and vulcanize di-penta methylene thiurams, zinc oxide, be 55-60 ℃ in temperature and descended mixing 2-3 minute, the discharging cooling namely gets described field logging cable jacket insulation material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104523555A CN102993519A (en) | 2012-11-13 | 2012-11-13 | Cable sheath insulating material for field logging and preparation method of same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104523555A CN102993519A (en) | 2012-11-13 | 2012-11-13 | Cable sheath insulating material for field logging and preparation method of same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102993519A true CN102993519A (en) | 2013-03-27 |
Family
ID=47922665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012104523555A Pending CN102993519A (en) | 2012-11-13 | 2012-11-13 | Cable sheath insulating material for field logging and preparation method of same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102993519A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289277A (en) * | 2013-05-06 | 2013-09-11 | 安徽格林生态高分子材料技术有限公司 | Cable sheath material containing modified chloroprene rubber CR322 and preparation method thereof |
| CN103539980A (en) * | 2013-10-25 | 2014-01-29 | 安徽文峰电子科技集团有限公司 | Moisture-proof chemical reagent resistant modified nitrile rubber cable material |
| CN103540073A (en) * | 2013-10-25 | 2014-01-29 | 安徽文峰电子科技集团有限公司 | Modified heatproof anti-oxidation natural rubber cable material |
| CN103554697A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | Environment-friendly type oil-resistant high temperature-resistant rubber cable material |
| CN103788434A (en) * | 2014-01-16 | 2014-05-14 | 安徽复兴电缆集团有限公司 | High-strength and abrasion-proof cable sheath material |
| CN105524442A (en) * | 2015-12-17 | 2016-04-27 | 梅庆波 | Method for preparing unsaturated polyester composite material filled with modified calcium carbonate |
| CN105524309A (en) * | 2016-01-12 | 2016-04-27 | 芜湖航天特种电缆厂股份有限公司 | Environment-friendly filling material used for aerospace cable and preparation method thereof |
| CN109233023A (en) * | 2018-10-11 | 2019-01-18 | 无锡裕德电缆科技有限公司 | A kind of high performance cable insulating materials |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1624036A (en) * | 2003-12-30 | 2005-06-08 | 谢小丁 | Process for preparing magnetic oil saving rubber pipe |
| JP2006351322A (en) * | 2005-06-15 | 2006-12-28 | Hitachi Cable Ltd | Cable |
| CN101665597A (en) * | 2008-09-05 | 2010-03-10 | 上海五同同步带有限公司 | Rubber poly V-belt with safe polycyclic aromatic hydrocarbon content |
| CN101948576A (en) * | 2010-09-14 | 2011-01-19 | 十堰银森工贸有限公司 | Anti-cracking and anti-aging blend material for oil pipe of automobile |
| CN102286162A (en) * | 2011-06-20 | 2011-12-21 | 沈阳天荣电缆材料有限公司 | Preparation method of deep sea cable filling strip |
| CN102367298A (en) * | 2011-09-02 | 2012-03-07 | 芜湖禾田汽车工业有限公司 | High heat-resistant oil-resistant aging-resistant rubber and preparation method thereof |
| CN102372864A (en) * | 2011-06-28 | 2012-03-14 | 江苏远洋东泽电缆股份有限公司 | Signal flexible cable sheath material for underwater dredging bucket of dredger and production method thereof |
| CN102504367A (en) * | 2011-11-05 | 2012-06-20 | 天津鹏翎胶管股份有限公司 | Chemigum composition for preparing rubber flexible pipe |
-
2012
- 2012-11-13 CN CN2012104523555A patent/CN102993519A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1624036A (en) * | 2003-12-30 | 2005-06-08 | 谢小丁 | Process for preparing magnetic oil saving rubber pipe |
| JP2006351322A (en) * | 2005-06-15 | 2006-12-28 | Hitachi Cable Ltd | Cable |
| CN101665597A (en) * | 2008-09-05 | 2010-03-10 | 上海五同同步带有限公司 | Rubber poly V-belt with safe polycyclic aromatic hydrocarbon content |
| CN101948576A (en) * | 2010-09-14 | 2011-01-19 | 十堰银森工贸有限公司 | Anti-cracking and anti-aging blend material for oil pipe of automobile |
| CN102286162A (en) * | 2011-06-20 | 2011-12-21 | 沈阳天荣电缆材料有限公司 | Preparation method of deep sea cable filling strip |
| CN102372864A (en) * | 2011-06-28 | 2012-03-14 | 江苏远洋东泽电缆股份有限公司 | Signal flexible cable sheath material for underwater dredging bucket of dredger and production method thereof |
| CN102367298A (en) * | 2011-09-02 | 2012-03-07 | 芜湖禾田汽车工业有限公司 | High heat-resistant oil-resistant aging-resistant rubber and preparation method thereof |
| CN102504367A (en) * | 2011-11-05 | 2012-06-20 | 天津鹏翎胶管股份有限公司 | Chemigum composition for preparing rubber flexible pipe |
Non-Patent Citations (1)
| Title |
|---|
| 黄承亚: "《链状超细碳酸钙的合成研究》", 《无机盐工业》, 20 December 1995 (1995-12-20) * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289277A (en) * | 2013-05-06 | 2013-09-11 | 安徽格林生态高分子材料技术有限公司 | Cable sheath material containing modified chloroprene rubber CR322 and preparation method thereof |
| CN103289277B (en) * | 2013-05-06 | 2015-10-28 | 安徽格林生态高分子材料技术有限公司 | A kind of cable jacket material containing modified chloroprene rubber CR322 and preparation method thereof |
| CN103539980A (en) * | 2013-10-25 | 2014-01-29 | 安徽文峰电子科技集团有限公司 | Moisture-proof chemical reagent resistant modified nitrile rubber cable material |
| CN103540073A (en) * | 2013-10-25 | 2014-01-29 | 安徽文峰电子科技集团有限公司 | Modified heatproof anti-oxidation natural rubber cable material |
| CN103554697A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | Environment-friendly type oil-resistant high temperature-resistant rubber cable material |
| CN103788434A (en) * | 2014-01-16 | 2014-05-14 | 安徽复兴电缆集团有限公司 | High-strength and abrasion-proof cable sheath material |
| CN105524442A (en) * | 2015-12-17 | 2016-04-27 | 梅庆波 | Method for preparing unsaturated polyester composite material filled with modified calcium carbonate |
| CN105524309A (en) * | 2016-01-12 | 2016-04-27 | 芜湖航天特种电缆厂股份有限公司 | Environment-friendly filling material used for aerospace cable and preparation method thereof |
| CN109233023A (en) * | 2018-10-11 | 2019-01-18 | 无锡裕德电缆科技有限公司 | A kind of high performance cable insulating materials |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102993519A (en) | Cable sheath insulating material for field logging and preparation method of same | |
| CN102993518A (en) | Stretch-proof cable sheath insulation material and preparation method thereof | |
| CN102993521A (en) | Environmental-friendly termite-resistant cable sheath insulating material and method for preparing same | |
| CN102993523A (en) | Buoy communication cable sheath insulating material for ships and preparation method thereof | |
| CN103102544A (en) | Low-smoke zero-halogen flame-retardant cable material and preparation method thereof | |
| CN103102541A (en) | Low-smoke flame retardant cable material for locomotive and preparation method thereof | |
| CN103524930A (en) | Cold-resistant PVC sheath material for cable and preparation method thereof | |
| CN103694518A (en) | Oxidation resisting compounded rubber capacitor sealing ring and preparation method thereof | |
| CN104194198A (en) | Compound polyvinyl chloride rubber cable accessory material | |
| CN103539981A (en) | Multi-rubber blended ozone-resistant oil-resistant cable material | |
| CN103739900A (en) | Nitrile rubber acrylate rubber packing pad material and preparation method | |
| CN103601991A (en) | Novel environment protective sealing ring for capacitor and preparation method thereof | |
| CN103540073A (en) | Modified heatproof anti-oxidation natural rubber cable material | |
| CN103102543A (en) | Thermoplastic elastomer wire and cable material and preparation method thereof | |
| CN103540045A (en) | High-tensile power cord sheath material and preparation method thereof | |
| CN104945802A (en) | Buried high temperature resistance PVC-C cannula used for high voltage power cable | |
| CN103374156A (en) | High-strength cable sheath material and preparation method thereof | |
| CN103709533A (en) | Multi-rubber compounded sealing gasket material and preparation method thereof | |
| CN103709561A (en) | Mixed rubber capacitor sealing ring and preparation method therefor | |
| CN102993520A (en) | Spreader basket cable sheath insulation material for port machinery and preparation method thereof | |
| CN104086866A (en) | Special filler for high-strength anti-aging capacitor thin films and preparation method thereof | |
| CN103242574A (en) | Ageing resistant cable sheath material | |
| CN103756027B (en) | A kind of novel mixed rubber capacitor sealing ring and preparation method thereof | |
| CN103333380B (en) | A kind of Sun-proof cable sheath material | |
| CN105061932A (en) | Blended easily torn electric wire cable material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130327 |