The particieboard that a kind of low formaldehyde discharges
Technical field
The present invention relates to the particieboard that a kind of low formaldehyde discharges, belong to the Wood-based Panel Production field.
Technical background
The kind of wood-based plate has a lot, and wherein the performance of particieboard and medium density fibre board (MDF) compare favourably, and cost is lower, has obtained developing rapidly in China.Along with the fast development of national economy and the raising of people's environmental consciousness, people have higher requirement to security and the feature of environmental protection of material.The invention provides the particieboard that a kind of low formaldehyde discharges, significantly reduction of formaldehyde emission.
Summary of the invention
The purpose of this invention is to provide the particieboard that a kind of low formaldehyde discharges, significantly reduction of formaldehyde emission.
For realizing above purpose, the particieboard that a kind of low formaldehyde of the present invention discharges, comprise up and down top layer, sandwich layer, the top layer is the cotton stalk wood shavings of equal in quality and the wood shavings that mix of black pine wood shavings, sandwich layer is textile bar wood shavings, the water content of wood shavings is 5%-7%, and the wood shavings mass ratio of top layer and sandwich layer is 70:30-40:60; The top layer applies Lauxite (UF resin), and applied amount is the 8%-10% of top layer wood shavings quality, and sandwich layer applies isocyanide ester adhesive (MDI), and applied amount is the 3%-5% of sandwich layer wood shavings quality.
The beneficial effect that the present invention produces is that the present invention takes following measures to reduce the burst size of methanal of particieboard:
One, particieboard of the present invention top layer is the cotton stalk wood shavings of equal in quality and the wood shavings that mix of black pine wood shavings, sandwich layer is textile bar wood shavings, cotton stalk has significant aldehydes removal effect, and sandwich layer of the present invention is textile bar wood shavings, in hot pressing, formaldehyde is to the sandwich layer transmission, and the cotton stalk and the formaldehyde that are conducive to sandwich layer fully react, and reduces the burst size of formaldehyde.
Two, particieboard sandwich layer of the present invention adopts MDI to replace the UF resin, reduce the source that produces free formaldehyde, while MDI is reduction of formaldehyde emission effectively, and improves internal bond strength, and sandwich layer wood shavings quality proportion is higher, and then burst size of methanal is lower, internal bond strength is higher.Because in hot pressing, the heat on top layer by steam to the sandwich layer transmission, formaldehyde along with steam also to the sandwich layer transmission, the MDI of a part of formaldehyde and sandwich layer reacts away, thereby reduces the burst size of formaldehyde.
Three, to control the moisture content of wood shavings be 5%-7% in the present invention, in the identical situation of other conditions, the wood shavings moisture content in above-mentioned scope constantly, burst size of methanal is low, physical and mechanical property all satisfies national standard.If the wood shavings moisture content is high, then in the hot-press solidifying process, the humidity of plank inside raises, higher humidity can be accelerated the hydrolysis of methyl ether key, methylol, hemiacetal, hydrolysis has produced free formaldehyde, and this part formaldehyde not necessarily all discharges in hot pressing, if produce formaldehydogenic amount more than the increment that discharges in the hot pressing, the free formaldehyde that then remains in the plate is also many, becomes so the formaldehyde behind the plate to discharge also thereupon more.
Embodiment
Embodiment 1:
The particieboard that a kind of low formaldehyde discharges comprises up and down top layer, sandwich layer, and the top layer is the cotton stalk wood shavings of equal in quality and the wood shavings that mix of black pine wood shavings, and sandwich layer is textile bar wood shavings, and the water content of wood shavings is 5%, and the wood shavings mass ratio of top layer and sandwich layer is 70:30; The top layer applies the UF resin, and applied amount is 8% of top layer wood shavings quality, and sandwich layer applies MDI, and applied amount is 3% of sandwich layer wood shavings quality.
Embodiment 2:
The particieboard that a kind of low formaldehyde discharges comprises up and down top layer, sandwich layer, and the top layer is the cotton stalk wood shavings of equal in quality and the wood shavings that mix of black pine wood shavings, and sandwich layer is textile bar wood shavings, and the water content of wood shavings is 6%, and the wood shavings mass ratio of top layer and sandwich layer is 60:40; The top layer applies the UF resin, and applied amount is 9% of top layer wood shavings quality, and sandwich layer applies MDI, and applied amount is 4% of sandwich layer wood shavings quality.
Embodiment 3:
The particieboard that a kind of low formaldehyde discharges comprises up and down top layer, sandwich layer, and the top layer is the cotton stalk wood shavings of equal in quality and the wood shavings that mix of black pine wood shavings, and sandwich layer is textile bar wood shavings, and the water content of wood shavings is 7%, and the wood shavings mass ratio of top layer and sandwich layer is 50:50; The top layer applies the UF resin, and applied amount is 10% of top layer wood shavings quality, and sandwich layer applies MDI, and applied amount is 5% of sandwich layer wood shavings quality.
Embodiment 4:
The particieboard that a kind of low formaldehyde discharges comprises up and down top layer, sandwich layer, and the top layer is the cotton stalk wood shavings of equal in quality and the wood shavings that mix of black pine wood shavings, and sandwich layer is textile bar wood shavings, and the water content of wood shavings is 5%, and the wood shavings mass ratio of top layer and sandwich layer is 40:60; The top layer applies the UF resin, and applied amount is 9% of top layer wood shavings quality, and sandwich layer applies MDI, and applied amount is 4% of sandwich layer wood shavings quality.
The burst size of methanal of the particieboard of each embodiment and the data of physical and mechanical property are as shown in table 1.
The burst size of methanal of the particieboard that each embodiment of table 1 produces and the data of physical and mechanical property