CN102974837A - Preparation method of flaky nano silver powder - Google Patents
Preparation method of flaky nano silver powder Download PDFInfo
- Publication number
- CN102974837A CN102974837A CN2012105009111A CN201210500911A CN102974837A CN 102974837 A CN102974837 A CN 102974837A CN 2012105009111 A CN2012105009111 A CN 2012105009111A CN 201210500911 A CN201210500911 A CN 201210500911A CN 102974837 A CN102974837 A CN 102974837A
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- Prior art keywords
- silver
- salt
- preparation
- nano silver
- silver powder
- Prior art date
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000000843 powder Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 14
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical group [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 6
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 6
- 239000012266 salt solution Substances 0.000 claims abstract description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 4
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 3
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 3
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 claims abstract description 3
- 229940071536 silver acetate Drugs 0.000 claims abstract description 3
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 claims abstract description 3
- 229910000367 silver sulfate Inorganic materials 0.000 claims abstract description 3
- 229940010514 ammonium ferrous sulfate Drugs 0.000 claims abstract 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- ZLXPLDLEBORRPT-UHFFFAOYSA-M [NH4+].[Fe+].[O-]S([O-])(=O)=O Chemical group [NH4+].[Fe+].[O-]S([O-])(=O)=O ZLXPLDLEBORRPT-UHFFFAOYSA-M 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 20
- 230000035484 reaction time Effects 0.000 abstract description 4
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 abstract description 3
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical group [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 10
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 6
- 229920003081 Povidone K 30 Polymers 0.000 description 6
- 238000006722 reduction reaction Methods 0.000 description 6
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000012279 sodium borohydride Substances 0.000 description 3
- 229910000033 sodium borohydride Inorganic materials 0.000 description 3
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical group OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002135 nanosheet Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 241000792859 Enema Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- -1 Silver salt Silver nitrate Silver nitrate Silver nitrate Silver sulfate Silver acetate Chemical compound 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000000090 biomarker Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000013872 defecation Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007920 enema Substances 0.000 description 1
- 229940095399 enema Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000829 suppository Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 230000010512 thermal transition Effects 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
Silver salt | Silver nitrate | Silver nitrate | Silver nitrate | Silver sulfate | Silver acetate |
Surfactant | PVP-K30 | PEG-10000 | SDS | PVP-K30 | CTAB |
Ferrous salt | Six ferrous sulfate hydrate ammoniums | Green vitriol | Six ferrous sulfate hydrate ammoniums | Green vitriol | Six ferrous sulfate hydrate ammoniums |
? | Embodiment 1 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 |
Silver nitrate | 0.20g | 0.20g | 0.20g | 0.20g | 2.00g | 2.00g | 2.00g |
PVP-K30 | 0.04g | 0.01g | 0.02g | 0.40g | 0.10g | 0.04g | 0.40g |
Six ferrous sulfate hydrate ammoniums | 0.40g | 0.80g | 0.20g | 0.10g | 2.00g | 4.00g | 7.00g |
Reaction temperature | 60℃ | 40℃ | 20℃ | 50℃ | 80℃ | 0℃ | 60℃ |
Reaction time | 30min | 28min | 35min | 30min | 32min | 25min | 30min |
Claims (9)
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CN201210500911.1A CN102974837B (en) | 2012-11-29 | 2012-11-29 | The preparation method of flaky nanometer silver powder |
CN201510815965.0A CN105268993B (en) | 2012-11-29 | 2012-11-29 | A method of preparing flaky nanometer silver powder |
CN201510819711.6A CN105290420B (en) | 2012-11-29 | 2012-11-29 | Method for preparing flaky nano silver powder |
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CN201210500911.1A CN102974837B (en) | 2012-11-29 | 2012-11-29 | The preparation method of flaky nanometer silver powder |
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CN201510819711.6A Division CN105290420B (en) | 2012-11-29 | 2012-11-29 | Method for preparing flaky nano silver powder |
CN201510815965.0A Division CN105268993B (en) | 2012-11-29 | 2012-11-29 | A method of preparing flaky nanometer silver powder |
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CN102974837A true CN102974837A (en) | 2013-03-20 |
CN102974837B CN102974837B (en) | 2016-01-06 |
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CN201510815965.0A Active CN105268993B (en) | 2012-11-29 | 2012-11-29 | A method of preparing flaky nanometer silver powder |
CN201210500911.1A Active CN102974837B (en) | 2012-11-29 | 2012-11-29 | The preparation method of flaky nanometer silver powder |
CN201510819711.6A Active CN105290420B (en) | 2012-11-29 | 2012-11-29 | Method for preparing flaky nano silver powder |
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Cited By (13)
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CN103521777A (en) * | 2013-10-11 | 2014-01-22 | 南京邮电大学 | Method for preparing two-dimensional silver nanosheets of different shapes |
CN104551007A (en) * | 2015-01-13 | 2015-04-29 | 山东大学 | Large-scale preparation method of silver nano-sheets |
CN104934097A (en) * | 2014-03-17 | 2015-09-23 | 常宝公司 | A conductive paste composition for a flexible substrate and a method for producing the same |
CN105050755A (en) * | 2013-06-25 | 2015-11-11 | 化研科技株式会社 | Flake-like silver powder, conductive paste, and method for producing flake-like silver powder |
CN105127448A (en) * | 2015-09-25 | 2015-12-09 | 合肥工业大学 | Room-temperature preparation method for nano silver sheet with ultra-large area |
CN106623963A (en) * | 2016-09-12 | 2017-05-10 | 贵研铂业股份有限公司 | Flaky ultra-fine and spherical mixing silver powder with adjustable proportion and preparation method thereof |
CN108655414A (en) * | 2018-06-11 | 2018-10-16 | 合肥学院 | Simple method for rapidly and massively preparing two-dimensional Ag micro-nano material |
CN110449598A (en) * | 2019-09-06 | 2019-11-15 | 辽宁星空新能源发展有限公司 | A kind of method that rapid precipitation prepares two-dimensional metallic silver simple substance nanometer sheet |
CN112355321A (en) * | 2020-10-09 | 2021-02-12 | 肇庆市华师大光电产业研究院 | Preparation method of kelp-like silver structure |
CN112475310A (en) * | 2020-10-16 | 2021-03-12 | 湖南诺尔得材料科技有限公司 | Preparation method of silver powder with narrow particle size distribution |
CN114042929A (en) * | 2021-10-26 | 2022-02-15 | 西安交通大学 | High-concentration silver nano-micron sheet and synthesis method thereof |
CN115488347A (en) * | 2022-09-09 | 2022-12-20 | 淮阴师范学院 | Preparation method of multilayer silver nanosheet |
CN117659785A (en) * | 2023-12-21 | 2024-03-08 | 广州翔铭环保新材料有限公司 | Antibacterial coating for automotive interiors and preparation method thereof |
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CN111496269A (en) * | 2020-05-21 | 2020-08-07 | 广州大学附属中学 | Nano silver and preparation method and application thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101569935A (en) * | 2009-06-05 | 2009-11-04 | 中国乐凯胶片集团公司 | Preparation method for flaky micro-silver powder |
CN102161103A (en) * | 2011-03-02 | 2011-08-24 | 中南大学 | Micrometer-level piece-shaped nano silver powder and preparation method |
CN102699341A (en) * | 2012-04-26 | 2012-10-03 | 蔡雄辉 | Wet-chemical preparation method for silver micro/nanowires |
CN102764897A (en) * | 2012-08-09 | 2012-11-07 | 深圳市圣龙特电子有限公司 | Method for preparing submicron silver powder for electro-conductive paste |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3992197A (en) * | 1975-03-18 | 1976-11-16 | Wetzold Paul W | Silver crystals and production thereof |
SU1488134A1 (en) * | 1987-11-17 | 1989-06-23 | Предприятие П/Я А-3481 | Method of producing silver powder |
JP2006045655A (en) * | 2004-08-09 | 2006-02-16 | Mitsubishi Materials Corp | Silver nanoparticle and production method therefor |
CN100443222C (en) * | 2006-11-16 | 2008-12-17 | 中国科学院长春应用化学研究所 | Method for preparing Nano silver piece |
CN101310899B (en) * | 2008-03-18 | 2010-12-08 | 江苏工业学院 | Method for preparing silver nano-wire in large batch |
CN101327521B (en) * | 2008-07-28 | 2011-01-26 | 华中科技大学 | Wet chemical preparation method containing spherical silver powder |
CN101823153A (en) * | 2009-03-06 | 2010-09-08 | 五邑大学 | Technology for preparing flake nano silver with overlarge area |
CN101890504B (en) * | 2010-07-07 | 2012-06-27 | 江苏技术师范学院 | Preparation method of flaky nano copper powder |
CN101947655B (en) * | 2010-10-25 | 2012-07-25 | 江苏技术师范学院 | Preparation method of triangular silver nanosheet |
-
2012
- 2012-11-29 CN CN201510815965.0A patent/CN105268993B/en active Active
- 2012-11-29 CN CN201210500911.1A patent/CN102974837B/en active Active
- 2012-11-29 CN CN201510819711.6A patent/CN105290420B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101569935A (en) * | 2009-06-05 | 2009-11-04 | 中国乐凯胶片集团公司 | Preparation method for flaky micro-silver powder |
CN102161103A (en) * | 2011-03-02 | 2011-08-24 | 中南大学 | Micrometer-level piece-shaped nano silver powder and preparation method |
CN102699341A (en) * | 2012-04-26 | 2012-10-03 | 蔡雄辉 | Wet-chemical preparation method for silver micro/nanowires |
CN102764897A (en) * | 2012-08-09 | 2012-11-07 | 深圳市圣龙特电子有限公司 | Method for preparing submicron silver powder for electro-conductive paste |
Non-Patent Citations (4)
Title |
---|
CAI XIONGHUIA等: "Preparation of microsized silver crystals with different morphologies by a wet-chemical method", 《RARE METALS》, vol. 29, no. 4, 31 August 2010 (2010-08-31), pages 407 - 412 * |
王辉等: "微米级球形银粉的可控制备", 《材料导报》, vol. 25, 31 May 2011 (2011-05-31) * |
董维国等: "微细银粉的制备与应用", 《材料与冶金学报》, vol. 1, no. 03, 30 September 2002 (2002-09-30) * |
谈发堂等: "模板法制备纳米片状银粉的粒径与形貌控制", 《材料导报》, vol. 20, no. 04, 30 April 2006 (2006-04-30), pages 102 - 105 * |
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CN112475310B (en) * | 2020-10-16 | 2022-12-20 | 湖南中伟新银材料科技有限公司 | Preparation method of silver powder with narrow particle size distribution |
CN114042929A (en) * | 2021-10-26 | 2022-02-15 | 西安交通大学 | High-concentration silver nano-micron sheet and synthesis method thereof |
CN115488347A (en) * | 2022-09-09 | 2022-12-20 | 淮阴师范学院 | Preparation method of multilayer silver nanosheet |
CN115488347B (en) * | 2022-09-09 | 2024-01-26 | 淮阴师范学院 | Preparation method of multilayer silver nano-sheet |
CN117659785A (en) * | 2023-12-21 | 2024-03-08 | 广州翔铭环保新材料有限公司 | Antibacterial coating for automotive interiors and preparation method thereof |
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Also Published As
Publication number | Publication date |
---|---|
CN105268993B (en) | 2019-01-25 |
CN105290420A (en) | 2016-02-03 |
CN102974837B (en) | 2016-01-06 |
CN105268993A (en) | 2016-01-27 |
CN105290420B (en) | 2017-11-21 |
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