CN102964105A - Citric acid gypsum hollow block and preparation method thereof - Google Patents

Citric acid gypsum hollow block and preparation method thereof Download PDF

Info

Publication number
CN102964105A
CN102964105A CN201110257130XA CN201110257130A CN102964105A CN 102964105 A CN102964105 A CN 102964105A CN 201110257130X A CN201110257130X A CN 201110257130XA CN 201110257130 A CN201110257130 A CN 201110257130A CN 102964105 A CN102964105 A CN 102964105A
Authority
CN
China
Prior art keywords
citric acid
gypsum
acid gypsum
building block
hollow block
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201110257130XA
Other languages
Chinese (zh)
Inventor
张庚福
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI SENKE NEW MATERIAL Co Ltd
Original Assignee
ANHUI SENKE NEW MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI SENKE NEW MATERIAL Co Ltd filed Critical ANHUI SENKE NEW MATERIAL Co Ltd
Priority to CN201110257130XA priority Critical patent/CN102964105A/en
Publication of CN102964105A publication Critical patent/CN102964105A/en
Pending legal-status Critical Current

Links

Landscapes

  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a citric acid gypsum hollow block and its preparation method. The citric acid gypsum hollow block comprises the following raw materials by weight: 59-69.95 parts of citric acid gypsum powder (beta type); 20-25 parts of desulfurized gypsum powder (beta type); 2-3 parts of a reinforcing agent; 8-12 parts of a neutralizer; and 0.05-1 part of a water reducer. The hollow block provided in the invention has an excellent color better (whiter than ordinary gypsum hollow blocks), is more conducive to wall decoration, and has the effects of light weight, waterproofness as well as thermal insulation. With all indexes meeting the JC/T698-2010 and GB6566-2001 building materials radionuclide limited standards of gypsum blocks, the hollow block is also in line with the requirements of low carbon, environmental protection, energy saving and consumption reduction, and recycling economy, and alleviates the environmental pollution problem to certain extent.

Description

A kind of citric acid gypsum holllow building block and preparation method thereof
Technical field:
The present invention relates generally to a kind of gypsum hollow block, relates in particular to a kind of citric acid gypsum holllow building block and preparation method thereof.
Background technology:
Gypsum hollow block generally is the novel internal partition wall materials for wall that utilizes plaster of Paris to produce, because low, the lightweight of its cost, waterproof, and meet low-carbon (LC), environmental protection, energy-saving and cost-reducing, make simple, high insulating effect, the advantage such as sturdy and durable is widely used in the buildings internal partition wall, so create a kind of dominant direction of utilizing new trade waste to become the gypsum hollow block development as main raw material.
Main raw material citric acid gypsum among the present invention, be produce when utilizing dull method to produce citric acid take terra alba as main industrial residue: citric acid gypsum.1 ton of citric acid of every production can obtain 1.5 tons of citric acid gypsums; Citric acid gypsum makes the semi-hydrated gypsum low strength of producing owing to contain certain remaining acid and organism (mycelium), and time of coagulation is elongated, utilizes difficulty; Can not get for a long time effectively utilizing and bulk deposition to environment.
Summary of the invention:
For solving an above-mentioned difficult problem, the invention provides a kind of citric acid gypsum holllow building block and preparation method thereof, it is main raw material that the contriver utilizes citric acid gypsum powder (β type) and other trade wastes, make in conjunction with other auxiliary materials, and in conjunction with new manufacture craft, so that the citric acid gypsum holllow building block that this prescription is produced is with lightweight, waterproof, the advantages such as insulation, and its indices all meets gypsum block JC/T698-2010 and the requirement of GB6566-2001 radioactive material nucleic limit standard, also meets in addition low-carbon (LC), environmental protection, energy-saving and cost-reducing, the requirement of recycling economy.
Technical scheme of the present invention is as follows:
A kind of citric acid gypsum holllow building block, raw material and weight part are:
Citric acid gypsum powder (β type): 59-69.95 part;
Desulfurization gypsum powder (β type): 20-25 part;
Toughener: 2-3 part;
Neutralizing agent: 8-12 part;
Water reducer: 0.05-1 part;
Ratio of water to material: 0.73-0.76 part.
Described toughener is blast furnace water quenching ore deposit quarrel powder, and described neutralizing agent is unslaked lime, and described water reducer is trimeric cyanamide.
Raw material and weight are preferably:
Citric acid gypsum powder (β type): 63-69.95 part;
Desulfurization gypsum powder (β type): 20-23 part;
Toughener: 2-3 part;
Neutralizing agent: 9-11 part;
Water reducer: 0.06-1 part;
Ratio of water to material: 0.74-0.76 part.
Its making step is as follows:
(1) batching: each raw material is prepared in proportion by self-measuring device;
(2) mass transport: each raw material is arrived the appointment storage tank by the e Foerderanlage automatic transport respectively;
(3) stir: designated ratio water is added first mixing drum, open stirrer, add the designated ratio retardant, again unclassified stores is dropped into mixing drum, stirred about 30 seconds;
(4) moulding: the slip after will stirring injects cavity forming, can obtain work in-process after about about 15 minutes, by mechanical manipulator work in-process is moved on the transport trolley platform again;
(5) piling, maintenance: piling (or the rear piling of oven dry) is carried out in the building block of work in-process citric acid gypsum, and natural curing, the maintenance fate is about 28 days;
(6) total inspection, warehouse-in.
The present invention is because its main raw material is citric acid gypsum powder etc., institute is so that product has: color and luster excellent (all whiter than common gypsum holllow building block), more be conducive to the powdering of body of wall, and the effect with lightweight, waterproof, insulation, and indices of the present invention all meets gypsum block JC/T698-2010 and the requirement of GB6566-2001 radioactive material nucleic limit standard; And meet the requirement of low-carbon (LC), environmental protection, energy-saving and cost-reducing, recycling economy, and alleviated to a certain extent problem of environmental pollution.
Embodiment:
Embodiment 1:
A kind of citric acid gypsum holllow building block, raw material and weight part are: citric acid gypsum powder (β type): 63.25 parts; Desulfurization gypsum powder (β type): 22 parts; Toughener: 2.5; Neutralizing agent part: 10.5 parts; Water reducer: 1 part; Ratio of water to material: 0.75 part.
Its making step is as follows:
(1) batching: each raw material is prepared in proportion by self-measuring device;
(2) mass transport: raw material is arrived the appointment storage tank by the e Foerderanlage automatic transport respectively;
(3) stir: designated ratio water is added first mixing drum, open stirrer, add the designated ratio retardant, again unclassified stores is dropped into mixing drum, stirred about 30 seconds;
(4) moulding: the slip after will stirring injects cavity forming, can obtain work in-process after about about 15 minutes, by mechanical manipulator work in-process is moved on the transport trolley platform again;
(5) piling, maintenance: piling (or the rear piling of oven dry) is carried out in the building block of work in-process citric acid gypsum, and natural curing, the maintenance fate is about 28 days;
(6) total inspection, warehouse-in: product is carried out final inspection, obtain finished lemon/lime acid gypsum hollow block, with qualified product packing, warehouse-in, for sale.

Claims (4)

1. citric acid gypsum holllow building block, it is characterized in that: raw material and weight part are:
Citric acid gypsum powder (β type): 59-69.95 part;
Desulfurization gypsum powder (β type): 20-25 part;
Toughener: 2-3 part;
Neutralizing agent: 8-12 part;
Water reducer: 0.05-1 part;
Ratio of water to material: 0.73-0.76 part.
2. a kind of citric acid gypsum holllow building block as claimed in claim 1 is characterized in that: described toughener is blast furnace water quenching ore deposit quarrel powder, and described neutralizing agent is unslaked lime, and described water reducer is trimeric cyanamide.
3. a kind of citric acid gypsum holllow building block as claimed in claim 1, it is characterized in that: raw material and weight part are preferably:
Citric acid gypsum powder (β type): 63-69.95 part;
Desulfurization gypsum powder (β type): 20-23 part;
Toughener: 23 parts;
Neutralizing agent: 9-11 part;
Water reducer: 0.06-1 part;
Ratio of water to material: 0.74-0.76 part.
4. citric acid gypsum holllow building block preparation method, it is characterized in that: preparation process is as follows:
(1) batching: each raw material is prepared in proportion by self-measuring device;
(2) mass transport: each raw material is arrived the appointment storage tank by the e Foerderanlage automatic transport respectively;
(3) stir: designated ratio water is added first mixing drum, open stirrer, add the designated ratio retardant, again unclassified stores is dropped into mixing drum, stirred about 30 seconds;
(4) moulding: the slip after will stirring injects cavity forming, can obtain work in-process after about about 15 minutes;
(5) piling, maintenance: piling (or the rear piling of oven dry) is carried out in the building block of work in-process citric acid gypsum, and natural curing, the maintenance fate is about 28 days;
(6) total inspection, warehouse-in.
CN201110257130XA 2011-09-01 2011-09-01 Citric acid gypsum hollow block and preparation method thereof Pending CN102964105A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110257130XA CN102964105A (en) 2011-09-01 2011-09-01 Citric acid gypsum hollow block and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110257130XA CN102964105A (en) 2011-09-01 2011-09-01 Citric acid gypsum hollow block and preparation method thereof

Publications (1)

Publication Number Publication Date
CN102964105A true CN102964105A (en) 2013-03-13

Family

ID=47794576

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110257130XA Pending CN102964105A (en) 2011-09-01 2011-09-01 Citric acid gypsum hollow block and preparation method thereof

Country Status (1)

Country Link
CN (1) CN102964105A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467057A (en) * 2013-10-09 2013-12-25 漳州正霸建材科技有限公司 Self-heat-preservation damp-proof gypsum block and manufacturing method thereof
CN103819163A (en) * 2014-02-25 2014-05-28 上海宇培特种建材有限公司 Lightweight gypsum block and its preparation method
CN104016651A (en) * 2014-06-19 2014-09-03 安徽森科新材料有限公司 Manufacturing method for producing gypsum hollow building block from hemihydrate phosphogypsum waste slag
CN110482890A (en) * 2019-09-26 2019-11-22 江苏一夫科技股份有限公司 A kind of Modified Citric Acid semi-hydrated gypsum and its preparation method and application
CN111187050A (en) * 2018-11-14 2020-05-22 北新集团建材股份有限公司 Gypsum board and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101265067A (en) * 2008-04-28 2008-09-17 长沙归一建材科技有限公司 Water-resisting high-strength gypsum-base concrete brick or building block, and producing method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101265067A (en) * 2008-04-28 2008-09-17 长沙归一建材科技有限公司 Water-resisting high-strength gypsum-base concrete brick or building block, and producing method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467057A (en) * 2013-10-09 2013-12-25 漳州正霸建材科技有限公司 Self-heat-preservation damp-proof gypsum block and manufacturing method thereof
CN103467057B (en) * 2013-10-09 2015-10-14 福建正霸新材料股份有限公司 Moistureproof gypsum block of a kind of self-heat conserving and preparation method thereof
CN103819163A (en) * 2014-02-25 2014-05-28 上海宇培特种建材有限公司 Lightweight gypsum block and its preparation method
CN104016651A (en) * 2014-06-19 2014-09-03 安徽森科新材料有限公司 Manufacturing method for producing gypsum hollow building block from hemihydrate phosphogypsum waste slag
CN111187050A (en) * 2018-11-14 2020-05-22 北新集团建材股份有限公司 Gypsum board and preparation method thereof
CN111187050B (en) * 2018-11-14 2021-04-27 北新集团建材股份有限公司 Gypsum board and preparation method thereof
CN110482890A (en) * 2019-09-26 2019-11-22 江苏一夫科技股份有限公司 A kind of Modified Citric Acid semi-hydrated gypsum and its preparation method and application
CN110482890B (en) * 2019-09-26 2020-12-01 江苏一夫科技股份有限公司 Modified citric acid semi-hydrated gypsum and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN102863189B (en) Preparation technique of waste residue composite light-weight thermal-insulation wallboard
CN102964105A (en) Citric acid gypsum hollow block and preparation method thereof
CN107188442B (en) A kind of trade waste base geological polymer and preparation method thereof
CN101614051A (en) Water-tolerant gypsum hollow building block and production method thereof
CN102765918B (en) Method for manufacturing aerated building blocks by doped navajoite tailings
CN100488908C (en) Method for modifying pre-processing titanium gypsum
CN103739251B (en) Light wallboard and preparation method thereof
CN103896535A (en) Light-weight partition wall board blended with pharmaceutical waste salt residues and preparation method of light-weight partition wall board
CN104649643A (en) Modified desulfurized gypsum based slurry for permanent composite heat preservation formwork
CN102531664A (en) Fluorgypsum hollow building block and preparation method thereof
CN102173674A (en) Light concrete composite wallboard and production technology thereof
CN104016651B (en) Manufacturing method for producing gypsum hollow building block from hemihydrate phosphogypsum waste slag
CN103979845B (en) A kind of water-proof concrete and preparation method thereof
CN102964104B (en) Nickel gypsum hollow block and preparation method thereof
CN103613352A (en) Burning-free brick production method
CN109437699A (en) A method of using composite compaction technique and slag, coal ash for manufacturing for cementitious material
CN104211368B (en) A kind of light-weight hollow-brick and preparation method thereof
CN102452823A (en) Novel wall material prepared by using tailings from zinc smelting, and preparation method thereof
CN107814545A (en) A kind of plaster of Paris building block and preparation method thereof
CN107721222A (en) A kind of novel phosphoric acid magnesium cement of no retarder
CN104211369A (en) Environmentally-friendly hollow brick and preparation method thereof
CN103102051B (en) Method for preparing calcium ferrite steelmaking slag former by use of galvanizing sludge
CN104929304A (en) Production method of light-weight partition wall board
CN104045368A (en) Method for producing aerated building block by using doping blast furnace slag
CN104045371A (en) Method for producing aerated building block used for oxidation furnace by using doping iron ore tailings

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20130313