CN102961955A - 一种甲醛清除剂及其制备方法 - Google Patents
一种甲醛清除剂及其制备方法 Download PDFInfo
- Publication number
- CN102961955A CN102961955A CN2012104827194A CN201210482719A CN102961955A CN 102961955 A CN102961955 A CN 102961955A CN 2012104827194 A CN2012104827194 A CN 2012104827194A CN 201210482719 A CN201210482719 A CN 201210482719A CN 102961955 A CN102961955 A CN 102961955A
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- CN
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- Prior art keywords
- formaldehyde
- melamine
- formaldehyde scavenger
- amino
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 230
- 239000002516 radical scavenger Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 47
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000007788 liquid Substances 0.000 claims abstract description 30
- 229920003180 amino resin Polymers 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 150000001412 amines Chemical class 0.000 claims abstract description 13
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 formaldehyde, alcohol amine Chemical class 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 18
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 150000002191 fatty alcohols Chemical class 0.000 claims description 10
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 claims description 5
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 5
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 claims description 2
- JCBPETKZIGVZRE-UHFFFAOYSA-N 2-aminobutan-1-ol Chemical compound CCC(N)CO JCBPETKZIGVZRE-UHFFFAOYSA-N 0.000 claims description 2
- BKMMTJMQCTUHRP-UHFFFAOYSA-N 2-aminopropan-1-ol Chemical compound CC(N)CO BKMMTJMQCTUHRP-UHFFFAOYSA-N 0.000 claims description 2
- BLFRQYKZFKYQLO-UHFFFAOYSA-N 4-aminobutan-1-ol Chemical compound NCCCCO BLFRQYKZFKYQLO-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920000136 polysorbate Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 238000010521 absorption reaction Methods 0.000 abstract description 6
- 239000006082 mold release agent Substances 0.000 abstract 3
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- 239000000243 solution Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 229940008099 dimethicone Drugs 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 206010067477 Cytogenetic abnormality Diseases 0.000 description 2
- 108020004414 DNA Proteins 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 208000031320 Teratogenesis Diseases 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 208000006673 asthma Diseases 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000315 carcinogenic Toxicity 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 235000005687 corn oil Nutrition 0.000 description 2
- 239000002285 corn oil Substances 0.000 description 2
- 230000004064 dysfunction Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 210000004185 liver Anatomy 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 229920002866 paraformaldehyde Polymers 0.000 description 2
- 210000003800 pharynx Anatomy 0.000 description 2
- 230000035935 pregnancy Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 208000011580 syndromic disease Diseases 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- 208000031404 Chromosome Aberrations Diseases 0.000 description 1
- 208000011359 Chromosome disease Diseases 0.000 description 1
- 208000014085 Chronic respiratory disease Diseases 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 102000053602 DNA Human genes 0.000 description 1
- 230000005778 DNA damage Effects 0.000 description 1
- 231100000277 DNA damage Toxicity 0.000 description 1
- 206010064571 Gene mutation Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 208000002454 Nasopharyngeal Carcinoma Diseases 0.000 description 1
- 206010061306 Nasopharyngeal cancer Diseases 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- 206010037423 Pulmonary oedema Diseases 0.000 description 1
- 206010047700 Vomiting Diseases 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000013566 allergen Substances 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- ZHNUHDYFZUAESO-OUBTZVSYSA-N aminoformaldehyde Chemical compound N[13CH]=O ZHNUHDYFZUAESO-OUBTZVSYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 208000024971 chromosomal disease Diseases 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000001900 immune effect Effects 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 239000003471 mutagenic agent Substances 0.000 description 1
- 231100000707 mutagenic chemical Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- 210000003928 nasal cavity Anatomy 0.000 description 1
- 210000001989 nasopharynx Anatomy 0.000 description 1
- 201000011216 nasopharynx carcinoma Diseases 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 208000005333 pulmonary edema Diseases 0.000 description 1
- 230000009325 pulmonary function Effects 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210482719.4A CN102961955B (zh) | 2012-11-26 | 2012-11-26 | 一种甲醛清除剂及其制备方法 |
Applications Claiming Priority (1)
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CN201210482719.4A CN102961955B (zh) | 2012-11-26 | 2012-11-26 | 一种甲醛清除剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102961955A true CN102961955A (zh) | 2013-03-13 |
CN102961955B CN102961955B (zh) | 2015-09-23 |
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CN201210482719.4A Expired - Fee Related CN102961955B (zh) | 2012-11-26 | 2012-11-26 | 一种甲醛清除剂及其制备方法 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106345273A (zh) * | 2016-08-23 | 2017-01-25 | 大工(青岛)新能源材料技术研究院有限公司 | 一种含有壳聚糖的微生物甲醛清除剂及其制备方法 |
CN107398152A (zh) * | 2017-07-03 | 2017-11-28 | 雄商(杭州)股权投资有限公司 | 甲醛清除剂及其制备方法 |
CN107952354A (zh) * | 2016-10-17 | 2018-04-24 | 秦素洁 | 一种用于吸收甲醛的液体材料及其制备方法 |
CN108744951A (zh) * | 2018-04-29 | 2018-11-06 | 广州长裕化工科技有限公司 | 一种室内除味剂及其制备方法与应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102399514A (zh) * | 2011-10-13 | 2012-04-04 | 北京林业大学 | 一种甲醛消除剂及其制备方法 |
CN102675574A (zh) * | 2012-04-12 | 2012-09-19 | 西南林业大学 | 一种共缩聚树脂型甲醛捕捉剂及其制备方法 |
CN102675575A (zh) * | 2012-04-28 | 2012-09-19 | 南通紫鑫实业有限公司 | 泡沫用三聚氰胺甲醛树脂的制备方法 |
-
2012
- 2012-11-26 CN CN201210482719.4A patent/CN102961955B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102399514A (zh) * | 2011-10-13 | 2012-04-04 | 北京林业大学 | 一种甲醛消除剂及其制备方法 |
CN102675574A (zh) * | 2012-04-12 | 2012-09-19 | 西南林业大学 | 一种共缩聚树脂型甲醛捕捉剂及其制备方法 |
CN102675575A (zh) * | 2012-04-28 | 2012-09-19 | 南通紫鑫实业有限公司 | 泡沫用三聚氰胺甲醛树脂的制备方法 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106345273A (zh) * | 2016-08-23 | 2017-01-25 | 大工(青岛)新能源材料技术研究院有限公司 | 一种含有壳聚糖的微生物甲醛清除剂及其制备方法 |
CN107952354A (zh) * | 2016-10-17 | 2018-04-24 | 秦素洁 | 一种用于吸收甲醛的液体材料及其制备方法 |
CN107398152A (zh) * | 2017-07-03 | 2017-11-28 | 雄商(杭州)股权投资有限公司 | 甲醛清除剂及其制备方法 |
CN108744951A (zh) * | 2018-04-29 | 2018-11-06 | 广州长裕化工科技有限公司 | 一种室内除味剂及其制备方法与应用 |
Also Published As
Publication number | Publication date |
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CN102961955B (zh) | 2015-09-23 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Che Chunling Inventor before: Che Chunling Inventor before: Lu Wei Inventor before: Lv Mingxia |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: CHE CHUNLING LU WEI LV MINGXIA TO: CHE CHUNLING |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20160308 Address after: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, No. 2 250100 Patentee after: Xinghuo Sci. & Tech. Research Inst., Jinan Dev. Zone Address before: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, No. 2 250100 Patentee before: Shandong Taide New Energy Co., Ltd. |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20161227 Address after: 510000 Guangdong Province, Guangzhou Baiyun District and the town of crow Lake Village Huaye Road No. 12 building 301 room 3 Patentee after: Guangdong Environmental Protection Technology Co., Ltd. Keerwei Address before: North Qilihe Road, Licheng District, Shandong city of Ji'nan Province, No. 2 250100 Patentee before: Jinan Development Zone Xinghuo Science and Technology Research Institute |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150923 Termination date: 20171126 |