CN102943204A - Yield strength 1100MPa level engineering machinery non-quenched and tempered hot rolled strip and preparation method thereof - Google Patents

Yield strength 1100MPa level engineering machinery non-quenched and tempered hot rolled strip and preparation method thereof Download PDF

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CN102943204A
CN102943204A CN2012104914898A CN201210491489A CN102943204A CN 102943204 A CN102943204 A CN 102943204A CN 2012104914898 A CN2012104914898 A CN 2012104914898A CN 201210491489 A CN201210491489 A CN 201210491489A CN 102943204 A CN102943204 A CN 102943204A
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衣海龙
刘振宇
吴迪
王国栋
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Northeastern University China
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Abstract

The invention belongs to the technical field of metallurgy and in particular to a yield strength 1100MPa level engineering machinery non-quenched and tempered hot rolled strip and a preparation method thereof. The chemical components of the yield strength 1100MPa level engineering machinery non-quenched and tempered hot rolled strip comprises, by weight, C 0.06-0.12%, Si 0.10-0.30%, Mn 1.60-2.00%, Nb 0.00-0.04%, V 0.00-0.04%, Ti 0.15-0.20%, Ni 0.4-0.80%, Mo 0.20-0.60%, P<0.012%, S<0.01%, and the balance Fe. The yield strength is greater than or equals to 1100MPa, the tensile strength is greater than or equals to 1180MPa, and percentage elongation after fracture is greater than or equals to 11%. The yield strength 1100MPa level engineering machinery non-quenched and tempered hot rolled strip is designed by adopting low carbon components, and by reasonably adding microalloy elements and controlled rolling and controlled cooling technology, production yield strength is greater than or equals to 1100MPa, the tensile strength is greater than or equals to 1180MPa, and percentage elongation after fracture is not lower than 11%. Simultaneously, structure steel strips is provided with good usability, the metallographic structure is bainite/ martensitic structures which are small in grain, cost capable of being reduced no less than 300 yuan per ton, and great economic benefit can be generated.

Description

屈服强度1100MPa级工程机械用非调质态热轧带钢及制备方法Non-quenched and tempered hot-rolled strip steel for construction machinery with a yield strength of 1100MPa and its preparation method

技术领域 technical field

本发明属于冶金技术领域,特别涉及一种屈服强度1100MPa级工程机械用非调质态热轧带钢及制备方法。 The invention belongs to the technical field of metallurgy, and in particular relates to a non-quenched and tempered hot-rolled steel strip for engineering machinery with a yield strength of 1100 MPa and a preparation method thereof.

背景技术 Background technique

随着工程机械行业的发展,对强度级别在900MPa以上的高强钢的需求越来越急迫,同时,为了节省资源、节约能源及保护环境,迫切需要研发强度水平更高的高品质钢材。目前,高强钢的强度级别从屈服强度900MPa到屈服强度在1100MPa以上,整体上来说,对强度、韧性和焊接使用性能的综合要求越来越高。 With the development of the construction machinery industry, the demand for high-strength steel with a strength level above 900MPa is becoming more and more urgent. At the same time, in order to save resources, save energy and protect the environment, it is urgent to develop high-quality steel with higher strength. At present, the strength level of high-strength steel ranges from a yield strength of 900MPa to a yield strength of more than 1100MPa. Generally speaking, the comprehensive requirements for strength, toughness and welding performance are getting higher and higher.

国外学者Koo等人,采用低C高Mn,通过添加Nb、V、Ni、Mo、B等合金元素,通过控轧在线淬火方法制备了抗拉强度超过930MPa的中厚板钢材,钢板显微组织具有一定比例的板条马氏体。Tamehiro等人采用低C,高Mn-Ni-Mo化学成分开发了热轧高强度钢,并认为要使抗拉强度超过950MPa,钢板显微组织中必须含有90%以上的马氏体,因此,成分设计上添加了大量的Ni和Mo元素,合金成本较高国内康永林、郑华、姚连登等学者针对高强度的低碳贝氏体进行了细致研究, 通过Nb、Ti、Ni、Mo、B等合金元素的添加,通过形成铌钛析出强化结合贝氏体组织的相变强化使钢材具有更好的成形性能和低温韧性,从成分设计上,采用了大量的Nb、Ni和Mo等贵重合金元素,因此,生产成本较高。目前,国外瑞典SSAB、日本、芬兰及国内的舞阳、湘钢、南钢、宝钢等各大钢厂实际生产的900MPa级的热轧高强钢都不同程度地添加了高附加值的Mo、Cr、Ni等合金元素,且生产工艺为热轧+调质处理,调质工艺的处理过程为,首先将热轧后的钢板加热到高温奥氏体区或两相区,温度为850~950℃,在此温度下保温30~60min不等,然后淬火,将淬火后的钢板进行400~600℃回火处理,显微组织以回火马氏体为主。对于屈服强度为1100MPa的高强度钢板来说, Foreign scholars Koo et al., used low C and high Mn, added Nb, V, Ni, Mo, B and other alloying elements, and prepared medium-thick plate steel with a tensile strength exceeding 930 MPa through controlled rolling and on-line quenching. The microstructure of the steel plate Has a certain proportion of lath martensite. Tamehiro et al. developed hot-rolled high-strength steel with low C and high Mn-Ni-Mo chemical composition, and believed that to make the tensile strength exceed 950MPa, the microstructure of the steel plate must contain more than 90% martensite. Therefore, A large amount of Ni and Mo elements are added in the composition design, and the cost of the alloy is relatively high . Domestic scholars such as Kang Yonglin, Zheng Hua, Yao Liandeng have conducted detailed research on high-strength low-carbon bainite, through the addition of alloying elements such as Nb, Ti, Ni, Mo, B, and the formation of niobium-titanium precipitation to strengthen bonded bainite The phase transformation strengthening of the structure makes the steel have better formability and low temperature toughness. In terms of composition design, a large amount of precious alloying elements such as Nb, Ni, and Mo are used, so the production cost is relatively high. At present, the 900MPa hot-rolled high-strength steel actually produced by SSAB in Sweden, Japan, Finland, and domestic Wuyang, Hunan Iron and Steel, Nangang, Baosteel and other major steel plants have added high value-added Mo, Cr, Alloying elements such as Ni, and the production process is hot rolling + quenching and tempering treatment. The treatment process of the quenching and tempering process is to first heat the hot-rolled steel plate to the high-temperature austenite zone or two-phase zone at a temperature of 850-950°C. Keep warm at this temperature for 30-60 minutes, then quench, and temper the quenched steel plate at 400-600 °C, and the microstructure is mainly tempered martensite. For a high-strength steel plate with a yield strength of 1100MPa,

赵四新、姜洪生等阐述了一种热处理高强钢,其成分特点为 C:0.15~0.25%、Si:0.10~0.50%、Mn:0.60~1.20%、P≤0.013%、S≤0.003%、Cr:0.20~0.55%、Mo:0.20~0.70%、Ni:0.60~2.00%、Nb:0~0.07%、V:0~0.07%、B:0.0006~0.0025%、Al:0.01~0.08%、Ti:0.003~0.06%、H≤0.00018%、N≤0.0040%、O≤0.0030%,采用淬火加回火热处理,获得回火马氏体组织。潘辉、郭佳、朱国森等阐述了一种1100-1200MPa的热处理高强钢,其化学成分特点为:C:0.15~0.18%;Si:0.20-0.25%;Mn:0.85~1.25%;Cr:0.20~0.60%;Mo:0.45~0.65%;V:0.035~0.060%;Nb:0.015~0.020%;Ni:0~0.55%;Cu:0~0.035%;Al:0.01~0.06%;P:≤0.015%;S:≤0.01%;N:≤0.008%,其工艺特点为将铸坯加热至1150~1250℃,终轧温度为860~920℃;卷取温度为650~750℃;淬火加热温度为880~930℃,保温时间为20~90min,回火加热温度为100~450℃,保温时间大于90min,缓冷或空冷至室温。 孙全社、张爱文等阐述了一种屈服强度1100MPa以上超高强度钢板,其成分特点为C 0.10~0.20%;Si≤0.6%;Mn 0.5~2.5%;Al≤0.03%;N 0.001~0.006 %;B 0~0.0025%;Ca 0~0.006%;P≤0.015%;S≤0.005%;Ni 0.2~ 1.2%、Cr 0~0.8%、Cu 0~0.5%和Mo 0~0.6%中的一种或几种以上; Ti 0.01~0.03%、V 0~0.1%和Nb 0.01~0.1%中的一种或几种以上;其工艺路线为在线淬火+离线回火。 Zhao Sixin, Jiang Hongsheng, etc. described a heat-treated high-strength steel whose composition characteristics are C: 0.15~0.25%, Si: 0.10~0.50%, Mn: 0.60~1.20%, P≤0.013%, S≤0.003%, Cr: 0.20 ~0.55%, Mo: 0.20~0.70%, Ni: 0.60~2.00%, Nb: 0~0.07%, V: 0~0.07%, B: 0.0006~0.0025%, Al: 0.01~0.08%, Ti: 0.003~ 0.06%, H≤0.00018%, N≤0.0040%, O≤0.0030%, adopt quenching and tempering heat treatment to obtain tempered martensite structure. Pan Hui, Guo Jia, Zhu Guosen, etc. described a heat-treated high-strength steel of 1100-1200MPa, whose chemical composition characteristics are: C: 0.15-0.18%; Si: 0.20-0.25%; Mn: 0.85-1.25%; ~0.60%; Mo: 0.45~0.65%; V: 0.035~0.060%; Nb: 0.015~0.020%; Ni: 0~0.55%; Cu: 0~0.035%; Al: 0.01~0.06%; %; S: ≤0.01%; N: ≤0.008%. The process features are heating the billet to 1150-1250°C, finishing rolling temperature is 860-920°C; coiling temperature is 650-750°C; quenching heating temperature is 880~930℃, holding time is 20~90min, tempering heating temperature is 100~450℃, holding time is more than 90min, slow cooling or air cooling to room temperature. Sun Quanshe, Zhang Aiwen, etc. described an ultra-high-strength steel plate with a yield strength of 1100MPa or more, and its composition characteristics are C 0.10-0.20%; Si≤0.6%; Mn 0.5-2.5%; Al≤0.03%; N 0.001-0.006%; B 0~0.0025%; Ca 0~0.006%; P≤0.015%; S≤0.005%; Ni 0.2~1.2%, Cr 0~0.8%, Cu 0~0.5% and Mo 0~0.6% or Several or more; One or more of Ti 0.01-0.03%, V 0-0.1% and Nb 0.01-0.1%; the process route is online quenching + offline tempering.

综上所述,对于强度级别在1100MPa以上的超高强钢来说,其成分设计和工艺设计都较为复杂,从成分设计来说,都加入了大量的合金元素,而对于生产工艺来说,均采用较为复杂的热处理工艺,获得以贝氏体或回火马氏体组织的1100MPa级高强钢。 To sum up, for ultra-high-strength steel with a strength level above 1100MPa, its composition design and process design are relatively complicated. A more complicated heat treatment process is used to obtain 1100MPa grade high-strength steel with bainite or tempered martensite structure.

发明内容 Contents of the invention

针对以上技术问题,本发明提供一种屈服强度1100MPa级工程机械用非调质态热轧带钢及制备方法,目的是通过合理的成分设计,以及通过控轧控冷工艺使带钢的屈服强度高于1100MPa,省去复杂的热处理工艺,简化生产流程,代替同一级别调质态的热轧钢板或低级别的低合金高强度钢。 In view of the above technical problems, the present invention provides a non-quenched and tempered hot-rolled steel strip for engineering machinery with a yield strength of 1100MPa and a preparation method, the purpose of which is to increase the yield strength of the strip steel through reasonable composition design and controlled rolling and cooling process. Higher than 1100MPa, eliminating the complicated heat treatment process, simplifying the production process, and replacing the same level of quenched and tempered hot-rolled steel plate or low-level low-alloy high-strength steel.

本发明的屈服强度1100MPa级工程机械用非调质态热轧带钢的化学成分按重量百分比为:C 0.06~0.12%,Si 0.10~0.30%,Mn 1.60~2.00%,Nb 0.00~0.04%,V 0.00~0.04%,Ti 0.15~0.20%,Ni 0.4~0.80%,Mo 0.20~0.60%,P<0.012%,S<0.01%,余量为铁Fe,其屈服强度≥1100MPa,抗拉强度≥1180MPa,断后伸长率≥11%。 The chemical composition of the non-quenched and tempered hot-rolled steel strip for construction machinery with a yield strength of 1100MPa according to the present invention is: C 0.06-0.12%, Si 0.10-0.30%, Mn 1.60-2.00%, Nb 0.00-0.04%, V 0.00~0.04%, Ti 0.15~0.20%, Ni 0.4~0.80%, Mo 0.20~0.60%, P<0.012%, S<0.01%, the balance is iron Fe, its yield strength ≥ 1100MPa, tensile strength ≥ 1180MPa, elongation after break ≥ 11%.

本发明的制备方法按以下步骤进行: Preparation method of the present invention carries out according to the following steps:

(1)按设定成分冶炼钢水并铸成铸坯,设定成分按重量百分比为C0.06~0.12%,Si 0.10~0.30%,Mn 1.60~2.00%,Nb 0.00~0.04%,V0.00~0.04%,Ti 0.15~0.20%,Ni 0.4~0.80%,Mo 0.20~0.60%,P<0.012%,S<0.01%,余量为铁Fe,铸坯厚度为220~250mm; (1) Smelt molten steel according to the set composition and cast it into a slab. The set composition is C0.06~0.12% by weight, Si 0.10~0.30%, Mn 1.60~2.00%, Nb 0.00~0.04%, V0.00 ~0.04%, Ti 0.15~0.20%, Ni 0.4~0.80%, Mo 0.20~0.60%, P<0.012%, S<0.01%, the balance is iron Fe, and the thickness of the slab is 220~250mm;

(2)将铸坯加热至1220~1250℃,进行5~7道次粗轧,粗轧开轧温度为1120~1170℃,终轧温度为980~1070℃,获得厚度为38~58mm的中间坯; (2) Heat the billet to 1220~1250°C, carry out rough rolling for 5~7 passes, the starting temperature of rough rolling is 1120~1170°C, and the finishing rolling temperature is 980~1070°C to obtain the intermediate thickness of 38~58mm. Blank;

(3)对中间坯进行5~7道次精轧,精轧开轧温度为950~1020℃,终轧温度为800~880℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为2~6mm; (3) Perform 5-7 passes of finishing rolling on the intermediate billet, the starting temperature of finishing rolling is 950-1020°C, the finishing rolling temperature is 800-880°C, and the reduction of each pass of finishing rolling is controlled at 15-40%. The strip thickness after finishing rolling is 2~6mm;

(4)精轧后以15~60℃/s的速度将带钢冷却至200~400℃,进行卷取,获得热轧带钢产品,其屈服强度≥1100MPa,抗拉强度≥1180MPa,断后伸长率≥11%。 (4) After finishing rolling, the steel strip is cooled to 200-400℃ at a speed of 15-60℃/s, and coiled to obtain hot-rolled steel strip products, with yield strength ≥ 1100MPa, tensile strength ≥ 1180MPa, elongation after fracture Length ≥ 11%.

本发明是采用低碳成分设计,通过合理添加微合金元素和控轧控冷工艺,生产屈服强度大于1100MPa,抗拉强度大于1180MPa,断后伸长率不低于11%,同时具有良好使用性能的结构钢带,其金相组织为晶粒较为细小的贝氏体/马氏体组织。 The present invention adopts low-carbon composition design, through reasonable addition of micro-alloy elements and controlled rolling and controlled cooling process, the yield strength is greater than 1100MPa, the tensile strength is greater than 1180MPa, the elongation after fracture is not less than 11%, and has good performance. Structural steel strip, its metallographic structure is bainite/martensite structure with relatively fine grains.

本发明中钢种成分的设置考虑了以下几点: The setting of steel type composition among the present invention has considered following points:

C对强化钢板是有效的,但同时降低了其成型性及焊接性,这些性能对其使用性能来说是必不可少的,因此碳的含量控制在低碳钢范围内;Mn能够通过固溶强化及相变强化来有效的提高钢材的性能,但同时会降低其点焊能力及电镀能力,考虑到高强钢板的实际使用性能要求,所以锰的含量控制在2%以下;Si和P能提高钢材的强度,但同时会降低钢材的电镀能力,所以他们的含量控制的很低;为了在低碳钢的基础上,将屈服强度提高到1100MPa以上,添加了大量的微合金元素钛,利用微合金元素钛的析出强化作用有效提高实验钢的性能,添加Mo合金元素,抑制了高温阶段铁素体组织的相变,提高了钢材的淬透性,有利于形成低温相变产物-贝氏体、马氏体等。 C is effective for strengthening the steel plate, but at the same time reduces its formability and weldability, these properties are essential for its performance, so the carbon content is controlled within the range of low carbon steel; Mn can pass solid solution Strengthening and phase transformation strengthening can effectively improve the performance of steel, but at the same time it will reduce its spot welding ability and electroplating ability. Considering the actual performance requirements of high-strength steel plates, the content of manganese is controlled below 2%; Si and P can improve The strength of the steel, but at the same time will reduce the plating ability of the steel, so their content is controlled very low; in order to increase the yield strength to above 1100MPa on the basis of low carbon steel, a large amount of microalloying element titanium is added. The precipitation strengthening effect of the alloying element titanium effectively improves the performance of the experimental steel, and the addition of Mo alloying elements inhibits the phase transformation of the ferrite structure at high temperature, improves the hardenability of the steel, and is conducive to the formation of low-temperature phase transformation products - bainite , Martensite, etc.

本发明制备屈服强度1100MPa级的非调质态热轧带钢采用的是TMCP(热机械控制过程),依据是:通过高温区的奥氏体再结晶控制轧制,充分细化奥氏体晶粒;精轧终轧温度控制在800~880℃,使轧制过程中产生较大的累积应变;通过轧后快速冷却及适度温度的卷取,得到细化的贝氏体及马氏体的复相组织; The present invention uses TMCP (Thermo-Mechanical Control Process) to prepare the non-quenched and tempered hot-rolled steel strip with a yield strength of 1100MPa. grains; the finishing rolling temperature is controlled at 800~880°C, so that a large cumulative strain is generated during the rolling process; through rapid cooling after rolling and coiling at a moderate temperature, refined bainite and martensite are obtained. Complex tissue;

本发明对屈服强度1100MPa级非调质态热轧带钢提供了一种新的生产工艺路线,取消了目前生产该级别钢材的调质热处理工艺,实现了工艺的减量化,产品的组织为贝氏体/马氏体组织,细化的贝氏体/马氏体组织使材料具有较高的力学性能及良好的塑性,同时,由于成分设计上碳含量较低,材料的焊接性能得到很大改善。 The present invention provides a new production process route for non-quenched and tempered hot-rolled strip steel with a yield strength of 1100 MPa, cancels the current quenched and tempered heat treatment process for producing this level of steel, and realizes the reduction of the process. The structure of the product is Bainite/martensite structure, the refined bainite/martensite structure makes the material have high mechanical properties and good plasticity. At the same time, due to the low carbon content in the composition design, the welding performance of the material is greatly improved. Big improvement.

本发明热轧带钢与同强度级别的热处理高强度钢相比具有如下优点: Compared with the heat-treated high-strength steel of the same strength level, the hot-rolled steel strip of the present invention has the following advantages:

(1)本发明热轧带钢由于取消了调质热处理工艺,实现了工艺的减量化,大大降低了生产成本,采用本发明热轧带钢,每吨可降低成本不少于300元,可以产生很大的经济效益。 (1) Since the hot-rolled steel strip of the present invention cancels the quenching and tempering heat treatment process, the reduction of the process is realized, and the production cost is greatly reduced. By adopting the hot-rolled steel strip of the present invention, the cost can be reduced by no less than 300 yuan per ton. Can produce great economic benefits.

(2)本发明热轧带钢成分设计上采用低碳成分路线,在保证力学性能要求的基础上,产品具有较好的焊接性能,有效降低焊接预热温度,降低了焊接的成本及难度。 (2) The composition design of the hot-rolled steel strip of the present invention adopts a low-carbon composition route. On the basis of ensuring the mechanical performance requirements, the product has better welding performance, effectively reduces the welding preheating temperature, and reduces the cost and difficulty of welding.

附图说明 Description of drawings

图1为本发明实施例1制备的热轧带钢产品的金相组织图。 FIG. 1 is a metallographic structure diagram of a hot-rolled steel strip product prepared in Example 1 of the present invention.

具体实施方式 Detailed ways

本发明实施例中采用的轧机为2250mm热连轧机。 The rolling mill adopted in the embodiment of the present invention is a 2250mm hot continuous rolling mill.

实施例1 Example 1

按设定成分在150吨转炉中冶炼钢水,并连铸成铸坯,其设定成分按重量百分比为C 0.06 %,Si 0.20%,Mn 1.60%,Nb 0.02%,V 0.04%,Ti 0.15%,Ni 0.4%,Mo 0.20%,P<0.012%,S<0.01%,余量为铁Fe,铸坯厚度为220mm。 Molten steel is smelted in a 150-ton converter according to the set composition, and continuously cast into billets. The set composition is C 0.06%, Si 0.20%, Mn 1.60%, Nb 0.02%, V 0.04%, Ti 0.15% by weight , Ni 0.4%, Mo 0.20%, P<0.012%, S<0.01%, the balance is iron Fe, and the thickness of the slab is 220mm.

将铸坯加热至1250℃,进行粗轧,粗轧过程为5道次,粗轧开轧温度为1170℃,粗轧终轧温度为1070℃,获得厚度为38mm的中间坯。 The cast slab was heated to 1250°C for rough rolling, the rough rolling process was 5 passes, the rough rolling start temperature was 1170°C, and the rough rolling finish rolling temperature was 1070°C to obtain an intermediate slab with a thickness of 38mm.

将中间坯进行精轧,精轧过程为7道次,精轧开轧温度为980℃,二轧温度为950℃,三轧温度为930℃,四轧温度为890℃,五轧温度为850℃,六轧温度为820℃,终轧温度为800℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为2mm。 Finish rolling of the intermediate billet, the finishing rolling process is 7 passes, the starting temperature of the finishing rolling is 980°C, the temperature of the second rolling is 950°C, the temperature of the third rolling is 930°C, the temperature of the fourth rolling is 890°C, and the temperature of the fifth rolling is 850°C ℃, the sixth rolling temperature is 820 ℃, the final rolling temperature is 800 ℃, the reduction of each pass of finishing rolling is controlled at 15~40%, and the strip thickness after finishing rolling is 2mm.

精轧后以60℃/s的速度水冷至300℃,通过卷取机卷取,获得成分按重量百分比为C 0.06 %,Si 0.20%,Mn 1.60%,Nb 0.02%,V 0.04%,Ti 0.15%,Ni 0.4%,Mo 0.20%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,其金相组织如图1所示,组织为细小的贝氏体/马氏体,力学性能测试结果为:屈服强度1150MPa,抗拉强度1250 MPa,断后伸长率12%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 300°C at a speed of 60°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.06%, Si 0.20%, Mn 1.60%, Nb 0.02%, V 0.04%, Ti 0.15 %, Ni 0.4%, Mo 0.20%, P<0.012%, S<0.01%, and the balance is iron Fe. The metallographic structure of the finished hot-rolled strip steel is shown in Figure 1, and the structure is fine bainite/ Martensite, the mechanical performance test results are: yield strength 1150MPa, tensile strength 1250MPa, elongation after fracture 12%, cold bending test (B=35, d=2a) qualified.

实施例2 Example 2

铸坯的制备方法及成分同实施例1,铸坯厚度为250mm。 The preparation method and composition of the slab are the same as in Example 1, and the thickness of the slab is 250mm.

粗轧过程同实施例1,获得厚度为58mm的中间坯。 The rough rolling process was the same as in Example 1, and an intermediate billet with a thickness of 58 mm was obtained.

将中间坯进行精轧,精轧过程为6道次,精轧开轧温度为950℃,二轧温度为930℃,三轧温度为910℃,四轧温度为880℃,五轧温度为850℃,终轧温度为830℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为6mm。 The intermediate billet is finished rolling, the finishing rolling process is 6 passes, the starting temperature of the finishing rolling is 950°C, the temperature of the second rolling is 930°C, the temperature of the third rolling is 910°C, the temperature of the fourth rolling is 880°C, and the temperature of the fifth rolling is 850°C ℃, the finish rolling temperature is 830 ℃, the reduction in each pass of finish rolling is controlled at 15~40%, and the strip thickness after finish rolling is 6mm.

精轧后以35℃/s的速度水冷至400℃,通过卷取机卷取,获得成分按重量百分比为C 0.06 %,Si 0.20%,Mn 1.60%,Nb 0.02%,V 0.04%,Ti 0.15%,Ni 0.4%,Mo 0.20%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,力学性能测试结果为:屈服强度1100MPa,抗拉强度1185MPa,断后伸长率11.5%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 400°C at a speed of 35°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.06%, Si 0.20%, Mn 1.60%, Nb 0.02%, V 0.04%, Ti 0.15 %, Ni 0.4%, Mo 0.20%, P<0.012%, S<0.01%, the balance is the finished hot-rolled steel strip of iron Fe, the mechanical property test results are: yield strength 1100MPa, tensile strength 1185MPa, elongation after fracture The rate is 11.5%, and the cold bending test (B=35, d=2a) is qualified.

实施例3 Example 3

铸坯的制备方法及成分同实施例1,铸坯厚度为240mm。 The preparation method and composition of the slab are the same as in Example 1, and the thickness of the slab is 240mm.

粗轧过程同实施例1,获得厚度为45mm的中间坯。 The rough rolling process was the same as in Example 1, and an intermediate billet with a thickness of 45 mm was obtained.

将中间坯进行精轧,精轧过程为5道次,精轧开轧温度为1020℃,二轧温度为980℃,三轧温度为920℃,四轧温度为900℃,终轧温度为880℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为4mm。 The intermediate billet is finished rolling, the finishing rolling process is 5 passes, the finishing rolling temperature is 1020°C, the second rolling temperature is 980°C, the third rolling temperature is 920°C, the fourth rolling temperature is 900°C, and the final rolling temperature is 880°C ℃, the reduction in each pass of finish rolling is controlled at 15~40%, and the strip thickness after finish rolling is 4mm.

精轧后以15℃/s的速度水冷至200℃,通过卷取机卷取,获得成分按重量百分比为C 0.06 %,Si 0.20%,Mn 1.60%,Nb 0.02%,V 0.04%,Ti 0.15%,Ni 0.4%,Mo 0.20%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,对应的力学性能测试结果为:屈服强度1120MPa,抗拉强度1190MPa,断后伸长率12%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 200°C at a speed of 15°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.06%, Si 0.20%, Mn 1.60%, Nb 0.02%, V 0.04%, Ti 0.15 %, Ni 0.4%, Mo 0.20%, P<0.012%, S<0.01%, and the balance is the finished hot-rolled steel strip of iron Fe. The corresponding mechanical performance test results are: yield strength 1120MPa, tensile strength 1190MPa, after fracture The elongation is 12%, and the cold bending test (B=35, d=2a) is qualified.

实施例4 Example 4

按设定成分在150吨转炉中冶炼钢水,并连铸成铸坯,其成分按重量百分比为C 0.08%,Si 0.10 %,Mn 2.00%,Nb 0.00 %,V0.00 %,Ti 0.20 %,Ni 0.80%,Mo 0.60%,P<0.012%,S<0.01%,余量为铁Fe,铸坯厚度为220mm。 Molten steel is smelted in a 150-ton converter according to the set composition, and continuously cast into a billet. The composition is C 0.08%, Si 0.10%, Mn 2.00%, Nb 0.00%, V0.00%, Ti 0.20%, Ni 0.80%, Mo 0.60%, P<0.012%, S<0.01%, the balance is iron Fe, and the thickness of the slab is 220mm.

将铸坯加热至1220℃,进行粗轧,粗轧过程为7道次,粗轧开轧温度为1150℃,轧温度为1000℃,获得厚度为38mm的中间坯。 The cast slab was heated to 1220°C for rough rolling, the rough rolling process was 7 passes, the rough rolling start temperature was 1150°C, and the final rolling temperature was 1000°C to obtain an intermediate slab with a thickness of 38mm.

将中间坯进行精轧,精轧过程为5道次,精轧开轧温度为1020℃,二轧温度为970℃,三轧温度为940℃,四轧温度为910℃,终轧温度为880℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为2mm。 Finish rolling of the intermediate billet, the finishing rolling process is 5 passes, the finishing rolling temperature is 1020°C, the second rolling temperature is 970°C, the third rolling temperature is 940°C, the fourth rolling temperature is 910°C, and the final rolling temperature is 880°C ℃, the reduction in each pass of finish rolling is controlled at 15~40%, and the strip thickness after finish rolling is 2mm.

精轧后以60℃/s的速度水冷至400℃,通过卷取机卷取,获得成分按重量百分比为C 0.08%,Si 0.10 %,Mn 2.00%,Nb 0.00 %,V 0.00 %,Ti 0.20 %,Ni 0.80%,Mo 0.60%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,力学性能测试结果为:屈服强度1110MPa,抗拉强度1190MPa,断后伸长率11%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 400°C at a speed of 60°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.08%, Si 0.10%, Mn 2.00%, Nb 0.00%, V 0.00%, Ti 0.20 %, Ni 0.80%, Mo 0.60%, P<0.012%, S<0.01%, the balance is the finished hot-rolled steel strip of iron Fe, the mechanical property test results are: yield strength 1110MPa, tensile strength 1190MPa, elongation after fracture The rate is 11%, and the cold bending test (B=35, d=2a) is qualified.

实施例5 Example 5

铸坯的制备方法及成分同实施例4,铸坯厚度为230mm。 The preparation method and composition of the slab are the same as in Example 4, and the thickness of the slab is 230mm.

粗轧过程同实施例4,获得厚度为45mm的中间坯。 The rough rolling process was the same as in Example 4, and an intermediate billet with a thickness of 45 mm was obtained.

将中间坯进行精轧,精轧过程为6道次,精轧开轧温度为970℃,二轧温度为950℃,三轧温度为920℃,四轧温度为880℃,五轧温度为840℃,终轧温度为820℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为4mm。 Finish rolling of the intermediate billet, the finishing rolling process is 6 passes, the starting temperature of the finishing rolling is 970°C, the temperature of the second rolling is 950°C, the temperature of the third rolling is 920°C, the temperature of the fourth rolling is 880°C, and the temperature of the fifth rolling is 840°C ℃, the final rolling temperature is 820 ℃, the reduction of each pass of finishing rolling is controlled at 15~40%, and the strip thickness after finishing rolling is 4mm.

精轧后以30℃/s的速度水冷至350℃,通过卷取机卷取,获得成分按重量百分比为C 0.08%,Si 0.10 %,Mn 2.00%,Nb 0.00 %,V 0.00 %,Ti 0.20 %,Ni 0.80%,Mo 0.60%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,力学性能测试结果为:屈服强度1100MPa,抗拉强度1180 MPa,断后伸长率11.5%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 350°C at a speed of 30°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.08%, Si 0.10%, Mn 2.00%, Nb 0.00%, V 0.00%, Ti 0.20 %, Ni 0.80%, Mo 0.60%, P<0.012%, S<0.01%, the balance is the finished hot-rolled steel strip of iron Fe, the mechanical property test results are: yield strength 1100MPa, tensile strength 1180MPa, elongation after fracture The elongation rate is 11.5%, and the cold bending test (B=35, d=2a) is qualified.

实施例6 Example 6

铸坯的制备方法及成分同实施例4,铸坯厚度为240mm。 The preparation method and composition of the slab are the same as in Example 4, and the thickness of the slab is 240mm.

粗轧过程同实施例4,获得厚度为58mm的中间坯。 The rough rolling process was the same as in Example 4, and an intermediate billet with a thickness of 58 mm was obtained.

将中间坯进行精轧,精轧过程为5道次,精轧开轧温度为950℃,二轧温度为930℃,三轧温度为900℃,四轧温度为850℃,终轧温度为800℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为6mm。 The intermediate billet is subjected to finish rolling, the finish rolling process is 5 passes, the finish rolling start temperature is 950°C, the second rolling temperature is 930°C, the third rolling temperature is 900°C, the fourth rolling temperature is 850°C, and the final rolling temperature is 800°C ℃, the reduction in each pass of finish rolling is controlled at 15~40%, and the strip thickness after finish rolling is 6mm.

精轧后以15℃/s的速度水冷至200℃,通过卷取机卷取,获得成分按重量百分比为C 0.08%,Si 0.10 %,Mn 2.00%,Nb 0.00 %,V 0.00 %,Ti 0.20 %,Ni 0.80%,Mo 0.60%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,力学性能测试结果为:屈服强度1100MPa,抗拉强度1200 MPa,断后伸长率11.5%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 200°C at a speed of 15°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.08%, Si 0.10%, Mn 2.00%, Nb 0.00%, V 0.00%, Ti 0.20 %, Ni 0.80%, Mo 0.60%, P<0.012%, S<0.01%, the balance is the finished hot-rolled steel strip of iron Fe, the mechanical property test results are: yield strength 1100MPa, tensile strength 1200MPa, elongation after fracture The elongation rate is 11.5%, and the cold bending test (B=35, d=2a) is qualified.

实施例7 Example 7

按设定成分在150吨转炉中冶炼钢水,并连铸成铸坯,其成分按重量百分比为C 0.12%,Si 0.30%,Mn 1.80 %,Nb 0.04%,V 0.02%,Ti 0.18%,Ni 0.60%,Mo 0.40%,P<0.012%,S<0.01%,余量为铁Fe,铸坯厚度为240mm。 Molten steel is smelted in a 150-ton converter according to the set composition, and continuously cast into a billet. The composition is C 0.12%, Si 0.30%, Mn 1.80%, Nb 0.04%, V 0.02%, Ti 0.18%, Ni 0.60%, Mo 0.40%, P<0.012%, S<0.01%, the balance is iron Fe, and the thickness of the slab is 240mm.

将铸坯加热至1240℃,进行粗轧,粗轧过程为6道次,粗轧开轧温度为1120℃,轧温度为980℃,获得厚度为42mm的中间坯。 The cast slab was heated to 1240°C for rough rolling, the rough rolling process was 6 passes, the rough rolling start temperature was 1120°C, and the final rolling temperature was 980°C to obtain an intermediate slab with a thickness of 42mm.

将中间坯进行精轧,精轧过程为7道次,精轧开轧温度为1000℃,二轧温度为970℃,三轧温度为940℃,四轧温度为900℃,五轧温度为860℃,六轧温度为820℃,终轧温度为800℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为2mm。 The intermediate billet is finished rolling, the finishing rolling process is 7 passes, the starting temperature of the finishing rolling is 1000°C, the temperature of the second rolling is 970°C, the temperature of the third rolling is 940°C, the temperature of the fourth rolling is 900°C, and the temperature of the fifth rolling is 860 ℃, the sixth rolling temperature is 820 ℃, the final rolling temperature is 800 ℃, the reduction of each pass of finishing rolling is controlled at 15~40%, and the strip thickness after finishing rolling is 2mm.

精轧后以60℃/s的速度水冷至400℃,通过卷取机卷取,获得成分按重量百分比为C 0.12%,Si 0.30%,Mn 1.80 %,Nb 0.04%,V 0.02%,Ti 0.18%,Ni 0.60%,Mo 0.40%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,力学性能测试结果为:屈服强度1120MPa,抗拉强度1190 MPa,断后伸长率12%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 400°C at a speed of 60°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.12%, Si 0.30%, Mn 1.80%, Nb 0.04%, V 0.02%, Ti 0.18 %, Ni 0.60%, Mo 0.40%, P<0.012%, S<0.01%, the balance is the finished hot-rolled steel strip of iron Fe, the mechanical property test results are: yield strength 1120MPa, tensile strength 1190MPa, elongation after fracture The elongation rate is 12%, and the cold bending test (B=35, d=2a) is qualified.

实施例8 Example 8

铸坯的制备方法及成分同实施例4,铸坯厚度为240mm。 The preparation method and composition of the slab are the same as in Example 4, and the thickness of the slab is 240mm.

粗轧过程同实施例4,获得厚度为48mm的中间坯。 The rough rolling process was the same as in Example 4, and an intermediate billet with a thickness of 48 mm was obtained.

将中间坯进行精轧,精轧过程为5道次,精轧开轧温度为1020℃,二轧温度为970℃,三轧温度为940℃,四轧温度为910℃,终轧温度为880℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为5mm。 Finish rolling of the intermediate billet, the finishing rolling process is 5 passes, the finishing rolling temperature is 1020°C, the second rolling temperature is 970°C, the third rolling temperature is 940°C, the fourth rolling temperature is 910°C, and the final rolling temperature is 880°C ℃, the reduction in each pass of finish rolling is controlled at 15~40%, and the strip thickness after finish rolling is 5mm.

精轧后以30℃/s的速度水冷至300℃,通过卷取机卷取,获得成分按重量百分比为C 0.12%,Si 0.30%,Mn 1.80 %,Nb 0.04%,V 0.02%,Ti 0.18%,Ni 0.60%,Mo 0.40%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,力学性能测试结果为:屈服强度1130MPa,抗拉强度1190 MPa,断后伸长率11.5%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 300°C at a speed of 30°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.12%, Si 0.30%, Mn 1.80%, Nb 0.04%, V 0.02%, Ti 0.18 %, Ni 0.60%, Mo 0.40%, P<0.012%, S<0.01%, the balance is the finished hot-rolled steel strip of iron Fe, the mechanical property test results are: yield strength 1130MPa, tensile strength 1190MPa, elongation after fracture The elongation rate is 11.5%, and the cold bending test (B=35, d=2a) is qualified.

实施例9 Example 9

铸坯的制备方法及成分同实施例4,铸坯厚度为240mm。 The preparation method and composition of the slab are the same as in Example 4, and the thickness of the slab is 240mm.

粗轧过程同实施例4,获得厚度为38mm的中间坯。 The rough rolling process was the same as in Example 4, and an intermediate billet with a thickness of 38 mm was obtained.

将中间坯进行精轧,精轧过程为6道次,精轧开轧温度为980℃,二轧温度为950℃,三轧温度为910℃,四轧温度为880℃,五轧温度为860℃,终轧温度为840℃,精轧每道次压下量控制在15~40%,精轧后带钢厚度为2mm。 Finish rolling of the intermediate billet, the finishing rolling process is 6 passes, the starting temperature of the finishing rolling is 980°C, the temperature of the second rolling is 950°C, the temperature of the third rolling is 910°C, the temperature of the fourth rolling is 880°C, and the temperature of the fifth rolling is 860°C ℃, the finish rolling temperature is 840 ℃, the reduction of each pass of finish rolling is controlled at 15~40%, and the strip thickness after finish rolling is 2mm.

精轧后以40℃/s的速度水冷至200℃,通过卷取机卷取,获得成分按重量百分比为C 0.12%,Si 0.30%,Mn 1.80 %,Nb 0.04%,V 0.02%,Ti 0.18%,Ni 0.60%,Mo 0.40%,P<0.012%,S<0.01%,余量为铁Fe的成品热轧带钢,力学性能测试结果为:屈服强度1150MPa,抗拉强度1200 MPa,断后伸长率12%,冷弯测试(B=35, d=2a)合格。 After finishing rolling, it is water-cooled to 200°C at a speed of 40°C/s, and coiled by a coiler to obtain components by weight percentage of C 0.12%, Si 0.30%, Mn 1.80%, Nb 0.04%, V 0.02%, Ti 0.18 %, Ni 0.60%, Mo 0.40%, P<0.012%, S<0.01%, the balance is the finished hot-rolled steel strip of iron Fe, the mechanical property test results are: yield strength 1150MPa, tensile strength 1200MPa, elongation after fracture The elongation rate is 12%, and the cold bending test (B=35, d=2a) is qualified.

Claims (2)

1. a yield strength 1100MPa level non-quenched and tempered state hot rolled strip for engineering machinery, it is characterized in that chemical composition is by weight percentage: C 0.06 ~ 0.12%, and Si 0.10 ~ 0.30%, Mn 1.60 ~ 2.00%, and Nb 0.00 ~ 0.04%, V0.00 ~ 0.04%, Ti0.15 ~ 0.20%, Ni0.4 ~ 0.80%, Mo0.20 ~ 0.60%, P<0.012%, S<0.01%, surplus is iron Fe, its yield strength >=1100MPa, tensile strength >=1180MPa, elongation after fracture >=11%.
2. the preparation method of non-quenched and tempered state hot rolled strip for a yield strength 1100MPa level engineering machinery is characterized in that carrying out according to following steps:
(1) by the set component smelting molten steel and cast strand, set component is C0.06 ~ 0.12% by weight percentage, and Si 0.10 ~ 0.30%, Mn 1.60 ~ 2.00%, Nb 0.00 ~ 0.04%, and V 0.00 ~ 0.04%, and Ti 0.15 ~ 0.20%, Ni 0.4 ~ 0.80%, Mo 0.20 ~ 0.60%, P<0.012%, S<0.01%, surplus is iron Fe, and slab thickness is 220 ~ 250mm;
(2) strand is heated to 1220 ~ 1250 ℃, carries out 5 ~ 7 passage roughing, the roughing start rolling temperature is 1120 ~ 1170 ℃, and finishing temperature is 980 ~ 1070 ℃, the intermediate blank that acquisition thickness is 38 ~ 58mm;
(3) intermediate blank is carried out to 5 ~ 7 passage finish rolling, the finish rolling start rolling temperature is 950 ~ 1020 ℃, and finishing temperature is 800 ~ 880 ℃, and the finish rolling draught per pass is controlled at 15 ~ 40%, and after finish rolling, belt steel thickness is 2 ~ 6mm;
(4) after finish rolling, with the speed of 15 ~ 60 ℃/s, will be with steel to be cooled to 200 ~ 400 ℃, and be batched, the coil of strip product after batching is directly used, its yield strength >=1100MPa, tensile strength >=1180MPa, elongation after fracture >=11%.
CN2012104914898A 2012-11-28 2012-11-28 Yield strength 1100MPa level engineering machinery non-quenched and tempered hot rolled strip and preparation method thereof Pending CN102943204A (en)

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CN105256234A (en) * 2015-10-29 2016-01-20 首钢总公司 Low-carbon microalloyed steel, preparing method and application of low-carbon microalloyed steel, ventilator blade and ventilator
CN105256238A (en) * 2015-10-27 2016-01-20 西安交通大学 Low-carbon martensite non-quenched-and-tempered steel for automobile parts and manufacturing method for low-carbon martensite non-quenched-and-tempered steel
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CN109023105A (en) * 2018-09-25 2018-12-18 首钢集团有限公司 A kind of vehicle structure hot-strip and manufacturing method
CN110358971A (en) * 2019-06-20 2019-10-22 天津大学 A kind of yield strength 1300MPa grades low-carbon super-high strength steel and preparation method thereof

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CN1840723A (en) * 2005-03-30 2006-10-04 宝山钢铁股份有限公司 Superhigh strength steel plate with yield strength more than 1100Mpa and method for producing same
CN101560629A (en) * 2009-05-27 2009-10-21 东北大学 Hot rolling strip steel having yield strength being higher than 800MPa and preparation method thereof
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CN105256238A (en) * 2015-10-27 2016-01-20 西安交通大学 Low-carbon martensite non-quenched-and-tempered steel for automobile parts and manufacturing method for low-carbon martensite non-quenched-and-tempered steel
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CN109023105A (en) * 2018-09-25 2018-12-18 首钢集团有限公司 A kind of vehicle structure hot-strip and manufacturing method
CN110358971A (en) * 2019-06-20 2019-10-22 天津大学 A kind of yield strength 1300MPa grades low-carbon super-high strength steel and preparation method thereof

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Application publication date: 20130227