CN102934639A - Dithiocyano-methane/organophosphorus pesticide composition - Google Patents
Dithiocyano-methane/organophosphorus pesticide composition Download PDFInfo
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- CN102934639A CN102934639A CN2012104847022A CN201210484702A CN102934639A CN 102934639 A CN102934639 A CN 102934639A CN 2012104847022 A CN2012104847022 A CN 2012104847022A CN 201210484702 A CN201210484702 A CN 201210484702A CN 102934639 A CN102934639 A CN 102934639A
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- 229950001664 phoxim Drugs 0.000 claims abstract description 10
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 claims abstract description 10
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- DUFVKSUJRWYZQP-UHFFFAOYSA-N fosthiazate Chemical compound CCC(C)SP(=O)(OCC)N1CCSC1=O DUFVKSUJRWYZQP-UHFFFAOYSA-N 0.000 claims description 10
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a dithiocyano-methane/organophosphorus pesticide composition. The organophosphorus pesticide is one of thiazolyl phosphine, chlorazol phosphorus, chlorpyrifos, phoxim and profenofos. The mass ratio of the dithiocyano-methane to organophosphorus pesticide is (0.1-40):1, and the sum of the dithiocyano-methane and organophosphorus pesticide accounts for 1-60 wt% of the composition. The application method of the composition in preventing and treating pests and diseases is characterized in that the composition is applied on crops, or in soil, or in a seed dressing mode.
Description
Technical field
The invention belongs to the plant protection field, particularly relate to composition and the purposes aspect control nematode, insect thereof of dithiocyano-methane and organic phosphor desinsection composition.
Background technology
Plant nematode is one of plant infectious cause of disease, extensively colonizes on root, stem, leaf, flower, bud and the seed of various plants.In the world, the generation of plant nematode is on the rise with the variation of harm along with cropping system.At present the harmful nematode of plant there is kind more than 3000, China finds kind more than 40 at present, common such as root-knot nematode, cyst roundworm, pine wood nematode, sweet potato stem nematode etc., it all is important agriculture pathogenic nematode, wherein the harm of root-knot nematode and cyst roundworm is the heaviest, and the crop of main harm has cucumber, peanut, paddy rice, soybean, wheat, tobacco, potato, oranges and tangerines, corn etc.Nematode is generally caused crop failure 10%-40%, can cause 80% the underproduction when serious, even total crop failure.Except nematode, vegetable destructive soil-inhabiting insects also brings larger economic loss to the vegetable grower.The kind of soil insect comprises cutworm, grub, mole cricket, wireworm, root maggot etc., often causes and hinders root, dead seedling etc., causes the underproduction, endangers more serious in spring, two seasons of autumn.
Dithiocyano-methane (MBT) is a kind of efficient algae sterilization chemicals that kills, MBT has efficient killing effect for the main bacteria that exists in the cycle water, fungi and algae (all kinds of fungi), and duration of efficacy is long, the pH value of adaptation and wider range.The consumption that uses 3-4PPM up to more than 99%, also can reach high sterilizing rate to other all kinds of bacterium to the sterilizing rate of heterotroph, nitrite bacteria, sulfosalt reducing bacteria, Escherichia coli, iron wire bacterium, anaerobic bacteria, denitrifying bacterium and sulphur bacteria.Dithiocyano-methane is than the better effects if of its homicide/degerming medicine in removing all kinds of fungies.Its stoste is stable, can degrade rapidly again when using puzzled the decomposition, can not cause secondary pollution, highly-effective low-residue to environment.Bakanae disease of rice and Aplelenchiodes bessegi of rice, stripe disease of barley, net blotch, covered smut had higher preventive effect.To kind passing a nematode, bacterium and caused other disease of fungi good preventive effect is also arranged simultaneously, under recommended dose, to rice Wheat Seeds safety, and to improving Germination Percentage of Rice and percentage establishment of seedling certain effect is arranged.
In the existing nematicide agent, phonamiphos, fenamiphos, carbofuran, Isofenphos methyl, cadusafos, oxamyl are high malicious nematocides, nemagon is typical reproduction poisonous substance, because of the increasingly concern of people to environment and health of human body, is necessary to develop relatively efficient, safe medicament.Find by research, the composition of dithiocyano-methane fosthiazate, isazofos, chlopyrifos, phoxim, Profenofos has obvious synergistic effect to nematode and insect, so finished the present invention.
Summary of the invention
The purpose of this invention is to provide composition and the purposes aspect control nematode and insect thereof with synergistic effect.
Concrete, the invention provides a kind of composition that contains dithiocyano-methane and organic phosphor desinsection composition, wherein organic phosphor desinsection composition is a kind of in fosthiazate, isazofos, chlopyrifos, phoxim, the Profenofos.
In the above-mentioned composition, the mass ratio of dithiocyano-methane and organic insecticidal constituent is 0.1-40:1, and preferred, mass ratio is 0.5-10:1.
In the above-mentioned composition, the percentage that the quality summation of dithiocyano-methane and organic phosphor desinsection composition accounts for the composition gross mass is 1-60%, preferably, to account for the percentage of composition quality summation be 2-20% to the quality summation of dithiocyano-methane and organic phosphates insecticidal constituent.
Above-mentioned composition can be processed and be mixed with microemulsion, suspending agent, wetting powder or water dispersible granules, and processing method is the formulation preparation method of this area routine.
The present invention also provides above-mentioned composition to be used for the purposes of control crop pest, wherein said crop is any crop that suffers the nematode infringement, described crop is cereal crops, vegetables, forest or other crops, and cereal crops are peanut, corn, paddy rice, soybean, Chinese sorghum or wheat; Vegetables are cucumber, tomato, celery, spinach, Chinese cabbage, beet or capsicum; Forest is willow, pine tree, cypress, cocoanut tree or bamboo grows, and other crops are banana, tobacco, potato or oranges and tangerines.
In the such use, described insect is the insect of any damage to crops, preferably, insect is root knot nematode, cereal crops root-knot nematode or forest root-knot nematode etc., concrete such as cucumber root-knot nematode, tomato root-knot eelworm, celery root-knot nematode, capsicum root-knot nematode, sweet potato stem nematode, banana root-knot nematode etc., and can prevent and treat vegetables or cereal crops soil insect such as the aphid in maggot, grub or vegetative period.
Advantage of the present invention, the composition of dithiocyano-methane of the present invention and organic phosphor desinsection composition such as fosthiazate, isazofos, chlopyrifos, phoxim, Profenofos is obvious to the active synergy of nematode, has played beyond thought effect; Composition to vegetative period aphid also show preferably effect.
Embodiment
The invention will be further described below in conjunction with embodiment, but the present invention never is limited to following embodiment.The following stated only is used for explaining the present invention, for not departing from modification, replacement or the improvement that the present invention is spiritual and principle is made, all belongs to the scope of protection of present invention.
Embodiment 1
The composition of dithiocyano-methane single dose, fosthiazate single dose, isazofos single dose, chlopyrifos single dose, phoxim single dose, Profenofos single dose and certain mass ratio is diluted to certain variable concentrations.The quantitative dilution that will contain the cucumber root-knot nematode drips on the slide, the microscopy counting; Microscopy is sneaked into the root-knot nematode dilution of quantitative pharmacy in the same way, and the microscopy counting is measured respectively each reagent agent lethal concentration of 50 LC
50, according to the co-toxicity coefficient (CTC value) of the abundant method calculation composition of Sun Yun, the CTC value greater than 120 for synergistic effect, concrete grammar is as follows.
Setting a kind of single dose (A) is the standard single dose, and specifying its toxicity index (TI) is 100, then:
The percentage of TI * single dose in mixture of the theoretical toxicity index (TTI) of mixture=each single dose of Σ
Result such as following table 1.
The different built agents of table 1 are to the synergistic effect of cucumber root-knot nematode
As can be seen from Table 1, when dithiocyano-methane is 0.2-10:1 with the proportioning of fosthiazate, isazofos, chlopyrifos, phoxim, Profenofos respectively, 4 proportionings of every kind of composition all greater than 120, illustrate that dithiocyano-methane is obvious to the synergistic effect of cucumber root-knot nematode with the composition of fosthiazate, isazofos, chlopyrifos, phoxim, Profenofos respectively in the composition to the co-toxicity coefficient of cucumber root-knot nematode.
Embodiment 2 compositions are to the preventive effect of crop nematode
Be mixed into compost with sterilization soil and sterilization river sand, sneak into and kill line composition or single dose, fully mix thoroughly, add clear water and make water content 40%, the basin alms bowl of packing into has the 30d tomato plant to be transplanted in the basin growth, 10d after transplanting, 500 of every basin access Meloidogyne incognita 2 instar larvaes place the greenhouse, the quantitative watering management.If 3 repetitions of every processing, and establish that not sneak into chemicals treatment be blank.After 20 days, when blank plant rhizosphere has a large amount of root knot, the every strain root knot of investigation records number, and carry out classification by Liu Weizhi (1995): 0 grade, without root knot; 1 grade, the 1-2 root knot; 2 grades, 3-10 root knot; 3 grades, 11-30 root knot; 4 grades, 31-100 root knot; 5 grades, 100 above root knots.The results are shown in Table 2.
Table 2 composition is to the effect of tomato root-knot eelworm
Table 2 shows, with respect to corresponding single dose and blank, dithiocyano-methane obviously reduces with the composition root knot number of fosthiazate, isazofos, chlopyrifos, phoxim, Profenofos respectively, the processing plant diseases of composition obviously alleviates, and illustrates that composition is obvious to the control efficiency of tomato root-knot eelworm.
The seed dressing of embodiment 3 compositions is to the effect of cotton diseases and insect pests
Dithiocyano-methane and the composition of fosthiazate, isazofos, chlopyrifos, phoxim, Profenofos are pressed 200:1 kind medicine than (mass ratio of seed and preparation) weighing medicament, after dripping the gauge water dilution, evenly mix cotton kind 30min, sow at living geodetic ridging, other establishes blank, a situation arises after planting to observe the aphid of cotton in seedling stage, the random regularly statistics of every processing cotton plants root knot mean, and carry out disease scale by embodiment 2.The results are shown in Table 3.
The seed dressing of table 3 composition is to the effect of cotton in seedling stage aphid and root-knot nematode
The composition seed dressing of dithiocyano-methane and several organic phosphors sees Table 3 to the effect of cotton diseases and insect pests, can find, the root-knot nematode number of compositions-treated is apparently higher than corresponding single dose and space management, outstanding is, the compositions-treated plant of the composition of dithiocyano-methane and fosthiazate, dithiocyano-methane and isazofos is without aphid generation in seedling stage, and plant shows that without root knot compositions-treated is better than single dose to the successful of the cotton root-knot nematode of nematode behind the 90d.
Claims (10)
1. composition that contains dithiocyano-methane and organic phosphor desinsection composition, wherein organic phosphor desinsection composition is a kind of in fosthiazate, isazofos, chlopyrifos, phoxim, the Profenofos.
2. composition according to claim 1, wherein the mass ratio of dithiocyano-methane and organic insecticidal constituent is 0.1-40:1.
3. composition according to claim 2, wherein the mass ratio of dithiocyano-methane and organic insecticidal constituent is 0.5-10:1.
4. each described composition according to claim 1-3, wherein to account for the percentage of composition gross mass be 1-60% to the quality summation of dithiocyano-methane and organic phosphor desinsection composition.
5. composition according to claim 4, wherein to account for the percentage of composition quality summation be 2-20% to the quality summation of dithiocyano-methane and organic phosphates insecticidal constituent.
6. each described composition according to claim 1-5, processed microemulsion, suspending agent, wetting powder or the water dispersible granules of being mixed with of described composition.
7. each described composition is used for the purposes of control crop pest according to claim 1-6, and wherein said crop is any crop that suffers the nematode infringement, and wherein said insect is the insect of any damage to crops.
8. purposes according to claim 7, wherein said crop is cereal crops, vegetables, forest or other crops, cereal crops are peanut, corn, paddy rice, soybean, Chinese sorghum or wheat; Vegetables are cucumber, tomato, celery, spinach, Chinese cabbage, beet or capsicum; Forest is willow, pine tree, cypress, cocoanut tree or bamboo grows, and other crops are banana, tobacco, potato or oranges and tangerines.
9. purposes according to claim 7, wherein insect is root knot nematode, cereal crops root-knot nematode or forest root-knot nematode etc.
10. purposes according to claim 9, wherein insect is cucumber root-knot nematode, tomato root-knot eelworm, celery root-knot nematode, capsicum root-knot nematode, sweet potato stem nematode or banana root-knot nematode.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104026149A (en) * | 2013-07-26 | 2014-09-10 | 海南正业中农高科股份有限公司 | Agricultural compound containing sulphur and organophosphorus pest killing constituent |
| CN106305759A (en) * | 2016-08-22 | 2017-01-11 | 田文华 | Pesticide composition containing fluorine thiamethoxam sulfone and dithiocyano methane |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB791291A (en) * | 1954-04-15 | 1958-02-26 | Bayer Ag | Agents for combating nematodes |
| CN1210674A (en) * | 1998-07-28 | 1999-03-17 | 南京农业大学 | Method for preventing and controlling plant diseases in agriculture |
| CN1561723A (en) * | 2004-03-18 | 2005-01-12 | 南京农业大学 | Novel soil sterilizing preparation and its use |
| CN101669517A (en) * | 2009-10-13 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Nematicide composition |
| CN102246795A (en) * | 2011-06-20 | 2011-11-23 | 甘肃农业大学 | Seed coating agent for preventing and treating cyst nematodes in wheat crops and application thereof |
-
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB791291A (en) * | 1954-04-15 | 1958-02-26 | Bayer Ag | Agents for combating nematodes |
| CN1210674A (en) * | 1998-07-28 | 1999-03-17 | 南京农业大学 | Method for preventing and controlling plant diseases in agriculture |
| CN1561723A (en) * | 2004-03-18 | 2005-01-12 | 南京农业大学 | Novel soil sterilizing preparation and its use |
| CN101669517A (en) * | 2009-10-13 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Nematicide composition |
| CN102246795A (en) * | 2011-06-20 | 2011-11-23 | 甘肃农业大学 | Seed coating agent for preventing and treating cyst nematodes in wheat crops and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 胡京昂等: "不同药剂防治番茄根结线虫的药效试验", 《长江蔬菜》, no. 19, 8 October 2010 (2010-10-08) * |
| 茵凯等: "9种杀线剂对香蕉根结线虫病的防效评价", 《植物保护》, vol. 37, no. 5, 8 October 2011 (2011-10-08) * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104026149A (en) * | 2013-07-26 | 2014-09-10 | 海南正业中农高科股份有限公司 | Agricultural compound containing sulphur and organophosphorus pest killing constituent |
| CN106305759A (en) * | 2016-08-22 | 2017-01-11 | 田文华 | Pesticide composition containing fluorine thiamethoxam sulfone and dithiocyano methane |
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| CN102934639B (en) | 2014-02-26 |
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