CN102924764A - Military shoe outsole rubber material and processing method of military shoe outsole sizing material - Google Patents

Military shoe outsole rubber material and processing method of military shoe outsole sizing material Download PDF

Info

Publication number
CN102924764A
CN102924764A CN2012104771165A CN201210477116A CN102924764A CN 102924764 A CN102924764 A CN 102924764A CN 2012104771165 A CN2012104771165 A CN 2012104771165A CN 201210477116 A CN201210477116 A CN 201210477116A CN 102924764 A CN102924764 A CN 102924764A
Authority
CN
China
Prior art keywords
parts
rubber
sizing
processing
carbon black
Prior art date
Application number
CN2012104771165A
Other languages
Chinese (zh)
Inventor
沈水林
蒋艳峰
李炎君
王景良
Original Assignee
际华三五一七橡胶制品有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 际华三五一七橡胶制品有限公司 filed Critical 际华三五一七橡胶制品有限公司
Priority to CN2012104771165A priority Critical patent/CN102924764A/en
Publication of CN102924764A publication Critical patent/CN102924764A/en

Links

Abstract

The invention relates to military shoe outsole rubber material and a processing method of the military shoe outsole rubber material. The rubber material is prepared from the following raw materials by weight: 40-90 parts of standard rubber, 10-60 parts of cis-butadiene rubber; intermediate material:2-6 parts of active zinc oxide, 1-3 parts of stearic acid, 0.1-0.5 parts of anti-aging agent H, 0.8-1.5 parts of anti-aging agent CD, 0.1-0.5 parts of magnesium oxide, and 5-20 parts of solid coumarone; reinforcing filler:40-80 parts of carbon black and 5-20 parts of pot clay, 10-30 parts of engine oil as softening plasticizer; and vulcanizing agent:1-3.5 parts of sulfur, 0.1-1parts of accelerator DM and 0.8-1.6 parts of accelerator CZ. The processing method of the rubber material is as follows: plasticizing standard rubber to obtain raw rubber; plasticizing masterbatch rubber; putting the raw rubber and masterbatch rubber into an internal mixer, and blending for 30''; putting into intermediate material, reinforcing filler and softening plasticizer, and blending until reaching stable load; putting into vulcanizing agent, and blending for 30''; discharging to a calendering machine for sheeting; cooling; inspecting; and inputting qualified rubber material of mixing outsole rubber to subsequent process for use. The processing method has the advantages of safety and reliability, and reducing energy sources and labor cost, thereby improving production efficiency.

Description

The large bottom sizing of a kind of liberation footwear and processing method thereof

Technical field

The present invention relates to the sole sizing material, refer in particular to the large bottom sizing of liberation footwear and the processing method thereof at the large ends of rubber overshoes such as a kind of suitable making liberation footwear.

Background technology

Banbury mixer is the requisite rubber preparing device of general large-scale rubber item company, but because the Banbury mixer glue furnacing temperature is high, rubber unvulcanizate easily produces the scorching phenomenon during vulcanizing agent under Banbury mixer, vulcanizing agent adds when all being flat-bed machine pulling-on piece after Banbury mixer is discharged glue, there are like this three problems: 1. because Banbury mixer peace acc power is large, it is even also to need thin-pass to draw behind the lower vulcanizing agent, and the time of refining glue is long, and the energy consumption of waste is large.2. because flat-bed machine belongs to open rubber preparing device, cause easily dust from flying during the vulcanizing agent of adding granular, to staff's health and production environment generation injury.3. belong to pure hand labour because flat-bed machine adds vulcanizing agent, intensity of workers is large.

Summary of the invention

The objective of the invention is provides a kind of energy-conservation, the large bottom sizing of liberation footwear of environment-friendly high-efficiency for the shortcoming that exists in the background technology and problem improvement and bring new ideas in addition.

Another object of the present invention provides the processing method of this large bottom sizing.

Sizing material of the present invention is made by the raw material of following weight part:

Standard rubber 40-90 part, cis-butadiene cement 10-60 part, sulphur 1-3.5 part, altax 0.1-1 part, accelerant CZ 0.8-1.6 part, active zinc flower 2-6 part, magnesium oxide 0.1-0.5 part, stearic acid 1-3 part, machine oil 10-30 part, carbon black 40-80 part, potter's clay 5-20 part, antioxidant H 0.1-0.5 part, anti-aging agent CD0.8-1.5 part and solid coumarone 5-20 part, wherein active zinc flower, stearic acid, antioxidant H, anti-aging agent CD, magnesium oxide and solid coumarone are middle material; Carbon black and potter's clay are packing strengthening agent, and machine oil is softening softening agent, and sulphur, altax and accelerant CZ are vulcanizing agent;

The manufacture craft of the large bottom sizing of described liberation footwear is as follows:

First with standard rubber mill plasticate the rubber of plasticating, and cis-butadiene cement 10-60 part, machine oil 10-20 part, carbon black 30-50 part refined into the master batch kind in Banbury mixer, the rubber that then will plasticate and cis-butadiene cement kind drop in the Banbury mixer, moulding 30 "; Material in dropping into again, packing strengthening agent, softening softening agent, moulding to powder is eaten up steady load; " rear binder removal to flat-bed machine is beaten sheet to drop into vulcanizing agent, moulding 30 again; After parking finally by cooling, passed examination namely gets mixing large bottom sizing and can provide to lower operation and use.

Machine oil of the present invention is 46# machine oil.Described carbon black is the N330 high wear-resistant carbon black.

The mixing large bottom sizing life cycle that the present invention makes is in 72 hours.

Advantage of the present invention and beneficial effect:

The present invention is applied to natural gum (standard rubber 2#) and synthetical glue (cis-butadiene cement) cooperation forms in liberation footwear big-sole formula and the technique, what use in its prescription is the accelerator combination of moderate accelerator and aftereffect, require behind the lower vulcanizing agent binder removal in 30 seconds in the technique, guaranteed that rubber unvulcanizate can not produce the scorching phenomenon.Cancel vulcanizing agent operation under the flat-bed machine, shortened the refining glue time, when raising labour productivity, reduced energy consumption.The present invention is vulcanizing agent under Banbury mixer, has stopped the injury of dust from flying to staff and environment, not only health but also environmental protection; Simultaneously do not need the staff in the flat-bed machine thin-pass, reduced staff's labour intensity.

The present invention is safe and reliable, through using, without bad consequence; And reduced the energy and cost of labor, improved production efficiency.Production technique of the present invention is simple, has simplified technique, has shortened technical process, and the glue stuff compounding uniformity that makes, and quality is good.

Embodiment

Embodiment 1:

First with the 90Kg standard rubber mill plasticate the rubber of plasticating, and cis-butadiene cement 10Kg, machine oil 10Kg, carbon black 30Kg refined into the master batch kind in Banbury mixer, the rubber that then will plasticate and cis-butadiene cement kind drop in the Banbury mixer, moulding 30 "; Drop into again active zinc flower 2Kg, stearic acid 1Kg, antioxidant H 0.1Kg, anti-aging agent CD0.8Kg, magnesium oxide 0.1Kg, solid coumarone 5Kg, N330 high wear-resistant carbon black 40Kg, potter's clay 5Kg, 46# machine oil 10Kg, moulding is stable to lotus, in the input behind the material to the lower sulphur pressing time is controlled according to actual load value and rubber quality by plant operators, eat up with powder that afterload is stable to be as the criterion; " rear binder removal to flat-bed machine is beaten sheet to drop into sulphur 1Kg, altax 0.1Kg and accelerant CZ 0.8Kg, moulding 30 again; After parking finally by cooling, the rubber unvulcanizate of passed examination can be provided to lower operation and use, and the glue stuff compounding life cycle is no more than 72 hours.

Embodiment 2:

First with the 40Kg standard rubber mill plasticate the rubber of plasticating, and cis-butadiene cement 60Kg, machine oil 10Kg, carbon black 30Kg refined into the master batch kind in Banbury mixer, the rubber that then will plasticate and cis-butadiene cement kind drop in the Banbury mixer, moulding 30 "; Drop into again active zinc flower 6Kg, stearic acid 3Kg, antioxidant H 0.5Kg, anti-aging agent CD1.5Kg, magnesium oxide 0.5Kg, solid coumarone 20Kg, N330 high wear-resistant carbon black 80Kg, potter's clay 20Kg, 46# machine oil 30Kg, moulding is stable to lotus, in the input behind the material to the lower sulphur pressing time is controlled according to actual load value and rubber quality by plant operators, eat up with powder that afterload is stable to be as the criterion; " rear binder removal to flat-bed machine is beaten sheet to drop into sulphur 3.5Kg, altax 1Kg and accelerant CZ 1.6Kg, moulding 30 again; After parking finally by cooling, the rubber unvulcanizate of passed examination can be provided to lower operation and use, and the glue stuff compounding life cycle is no more than 72 hours.

Embodiment 3:

First with the 65Kg standard rubber mill plasticate the rubber of plasticating, and cis-butadiene cement 35Kg, machine oil 10Kg, carbon black 30Kg refined into the master batch kind in Banbury mixer, the rubber that then will plasticate and cis-butadiene cement kind drop in the Banbury mixer, moulding 30 "; Drop into again active zinc flower 4Kg, stearic acid 2Kg, antioxidant H 0.3Kg, anti-aging agent CD1Kg, magnesium oxide 0.3Kg, solid coumarone 12Kg, N330 high wear-resistant carbon black 60Kg, potter's clay 12Kg, 46# machine oil 20Kg, moulding is stable to lotus, in the input behind the material to the lower sulphur pressing time is controlled according to actual load value and rubber quality by plant operators, eat up with powder that afterload is stable to be as the criterion; " rear binder removal to flat-bed machine is beaten sheet to drop into sulphur 2Kg, altax 0.5Kg and accelerant CZ 1.2Kg, moulding 30 again; After parking finally by cooling, the rubber unvulcanizate of passed examination can be provided to lower operation and use, and the glue stuff compounding life cycle is no more than 72 hours.

Embodiment 4:

First with the 55Kg standard rubber mill plasticate the rubber of plasticating, and cis-butadiene cement 45Kg, machine oil 10Kg, carbon black 30Kg refined into the master batch kind in Banbury mixer, the rubber that then will plasticate and cis-butadiene cement kind drop in the Banbury mixer, moulding 30 "; Drop into again active zinc flower 3Kg, stearic acid 2Kg, antioxidant H 0.2Kg, anti-aging agent CD1.2Kg, magnesium oxide 0.4Kg, solid coumarone 16Kg, N330 high wear-resistant carbon black 50Kg, potter's clay 13Kg, 46# machine oil 20Kg, moulding is stable to lotus, in the input behind the material to the lower sulphur pressing time is controlled according to actual load value and rubber quality by plant operators, eat up with powder that afterload is stable to be as the criterion; " rear binder removal to flat-bed machine is beaten sheet to drop into sulphur 3Kg, altax 0.6Kg and accelerant CZ 1Kg, moulding 30 again; After parking finally by cooling, the rubber unvulcanizate of passed examination can be provided to lower operation and use, and the glue stuff compounding life cycle is no more than 72 hours.

Embodiment 5:

First with the 80Kg standard rubber mill plasticate the rubber of plasticating, and cis-butadiene cement 20Kg, machine oil 10Kg, carbon black 30Kg refined into the master batch kind in Banbury mixer, the rubber that then will plasticate and cis-butadiene cement kind drop in the Banbury mixer, moulding 30 "; Drop into again active zinc flower 3.5Kg, stearic acid 1.8Kg, antioxidant H 0.4Kg, anti-aging agent CD1Kg, magnesium oxide 0.35Kg, solid coumarone 14Kg, N330 high wear-resistant carbon black 55Kg, potter's clay 17Kg, 46# machine oil 19Kg, moulding is stable to lotus, in the input behind the material to the lower sulphur pressing time is controlled according to actual load value and rubber quality by plant operators, eat up with powder that afterload is stable to be as the criterion; " rear binder removal to flat-bed machine is beaten sheet to drop into sulphur 2Kg, altax 0.8Kg and accelerant CZ 1.2Kg, moulding 30 again; After parking finally by cooling, the rubber unvulcanizate of passed examination can be provided to lower operation and use, and the glue stuff compounding life cycle is no more than 72 hours.

Embodiment of the present invention only is the description that preferred implementation of the present invention is carried out; be not that design of the present invention and scope are limited; under the prerequisite that does not break away from design philosophy of the present invention; engineering technical personnel make technical scheme of the present invention in this area various modification and improvement; all should fall into protection scope of the present invention; the technology contents that the present invention asks for protection all is documented in claims.

Claims (6)

1. liberation footwear large bottom sizing is characterized in that it is made by the raw material of following weight part:
Standard rubber 40-90 part, cis-butadiene cement 10-60 part, sulphur 1-3.5 part, altax 0.1-1 part, accelerant CZ 0.8-1.6 part, active zinc flower 2-6 part, magnesium oxide 0.1-0.5 part, stearic acid 1-3 part, machine oil 10-30 part, carbon black 40-80 part, potter's clay 5-20 part, antioxidant H 0.1-0.5 part, anti-aging agent CD0.8-1.5 part and solid coumarone 5-20 part; Wherein active zinc flower, stearic acid, antioxidant H, anti-aging agent CD, magnesium oxide and solid coumarone are middle material, and carbon black and potter's clay are packing strengthening agent, and machine oil is softening softening agent, and sulphur, altax and accelerant CZ are vulcanizing agent;
The manufacture craft of the large bottom sizing of described liberation footwear is as follows:
First with standard rubber mill plasticate the rubber of plasticating, and cis-butadiene cement etc. refined into the master batch kind in Banbury mixer, the rubber that then will plasticate and master batch kind drop in the Banbury mixer, moulding 30 "; Material in dropping into again, packing strengthening agent, softening softening agent, moulding to powder is eaten up steady load; " rear binder removal to flat-bed machine is beaten sheet to drop into vulcanizing agent, moulding 30 again; After parking finally by cooling, passed examination namely gets mixing large bottom sizing and can provide to lower operation and use.
2. the large bottom sizing of a kind of liberation footwear according to claim 1 and processing method thereof is characterized in that described sizing material made by the raw material of following weight part:
12 parts of 65 parts of standard rubbers, 35 parts of cis-butadiene cements, 2 parts in sulphur, 0.5 part of altax, 1.2 parts of accelerant CZs, 4 parts of active zinc flowers, 0.3 part in magnesium oxide, 2 parts of stearic acid, 20 parts in machine oil, 60 parts of carbon blacks, 12 parts in potter's clay, 0.3 part of antioxidant H, anti-aging agent CD1 part and solid coumarones.
3. the large bottom sizing of a kind of liberation footwear according to claim 1 and processing method thereof is characterized in that described master batch kind made by the raw material of lower routine weight part: cis-butadiene cement 10-60 part, machine oil 10-20 part and carbon black 30-50 part.
4. the large bottom sizing of a kind of liberation footwear according to claim 1 and processing method thereof is characterized in that described machine oil is 46# machine oil.
5. the large bottom sizing of a kind of liberation footwear according to claim 1 and processing method thereof is characterized in that described carbon black is the N330 high wear-resistant carbon black.
6. the large bottom sizing of a kind of liberation footwear according to claim 1 and processing method thereof, the mixing large bottom sizing life cycle that it is characterized in that making is in 72 hours.
CN2012104771165A 2012-11-22 2012-11-22 Military shoe outsole rubber material and processing method of military shoe outsole sizing material CN102924764A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012104771165A CN102924764A (en) 2012-11-22 2012-11-22 Military shoe outsole rubber material and processing method of military shoe outsole sizing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012104771165A CN102924764A (en) 2012-11-22 2012-11-22 Military shoe outsole rubber material and processing method of military shoe outsole sizing material

Publications (1)

Publication Number Publication Date
CN102924764A true CN102924764A (en) 2013-02-13

Family

ID=47639704

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012104771165A CN102924764A (en) 2012-11-22 2012-11-22 Military shoe outsole rubber material and processing method of military shoe outsole sizing material

Country Status (1)

Country Link
CN (1) CN102924764A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103275361A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Wear-resistant and anti-static sole rubber, as well as preparation method and application thereof
CN103275360A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Wear-resistant and anti-static flavorless sole rubber, as well as preparation method and application thereof
CN103524801A (en) * 2013-10-11 2014-01-22 昆山纯柏精密五金有限公司 Wear-resistant rubber sole and preparation method thereof
CN103554562A (en) * 2013-11-05 2014-02-05 际华三五三七制鞋有限责任公司 Frosted ruber sole rubber and preparation method thereof, and preparation method of product of frosted ruber sole rubber
CN104311928A (en) * 2014-10-30 2015-01-28 际华三五三七制鞋有限责任公司 Master mixing process of calendering type black rubber foxing rubber for liberation shoes
CN105131363A (en) * 2015-10-09 2015-12-09 际华三五三七制鞋有限责任公司 Inter-steam vulcanization rolling type purplish red external binding method rubber sole glue and preparation method and application thereof
CN105218891A (en) * 2015-11-14 2016-01-06 际华三五一五皮革皮鞋有限公司 At the bottom of a kind of novel and portable skid-proof rubber
CN105795572A (en) * 2016-04-20 2016-07-27 东莞市鑫艺来塑胶制品有限公司 Shoe and information sharing system based on shoe

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003157A (en) * 2006-12-25 2007-07-25 三角轮胎股份有限公司 Parallel auxiliaries type technique of one step for refining rubber
CN101020530A (en) * 2007-03-23 2007-08-22 无锡市宝通带业有限公司 Tearproof antiwear conveying belt
CN101768297A (en) * 2008-12-26 2010-07-07 际华三五一五皮革皮鞋有限公司 Production formula of flame retardant dual density glue and production technique
CN102276884A (en) * 2011-07-21 2011-12-14 际华三五三七制鞋有限责任公司 High-strength high-elongation wear-resistant environmentally-friendly rubber sole rubber and preparation method thereof
CN102304239A (en) * 2011-09-07 2012-01-04 际华三五三七制鞋有限责任公司 Black bi-vulcanized rubber outsole for mat high-modulus shoe and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003157A (en) * 2006-12-25 2007-07-25 三角轮胎股份有限公司 Parallel auxiliaries type technique of one step for refining rubber
CN101020530A (en) * 2007-03-23 2007-08-22 无锡市宝通带业有限公司 Tearproof antiwear conveying belt
CN101768297A (en) * 2008-12-26 2010-07-07 际华三五一五皮革皮鞋有限公司 Production formula of flame retardant dual density glue and production technique
CN102276884A (en) * 2011-07-21 2011-12-14 际华三五三七制鞋有限责任公司 High-strength high-elongation wear-resistant environmentally-friendly rubber sole rubber and preparation method thereof
CN102304239A (en) * 2011-09-07 2012-01-04 际华三五三七制鞋有限责任公司 Black bi-vulcanized rubber outsole for mat high-modulus shoe and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
梁星宇,周木英: "《橡胶工业手册 第三分册 配方与基本工艺》", 31 January 1996, article "密炼机", pages: 683-696 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103275361A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Wear-resistant and anti-static sole rubber, as well as preparation method and application thereof
CN103275360A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Wear-resistant and anti-static flavorless sole rubber, as well as preparation method and application thereof
CN103275361B (en) * 2013-06-18 2015-11-04 际华三五三七制鞋有限责任公司 Wear-resisting Antistatic sole rubber and preparation method thereof and application
CN103275360B (en) * 2013-06-18 2015-11-11 际华三五三七制鞋有限责任公司 Tasteless sole rubber of wear-resisting anti-electrostatic and preparation method thereof and application
CN103524801A (en) * 2013-10-11 2014-01-22 昆山纯柏精密五金有限公司 Wear-resistant rubber sole and preparation method thereof
CN103554562A (en) * 2013-11-05 2014-02-05 际华三五三七制鞋有限责任公司 Frosted ruber sole rubber and preparation method thereof, and preparation method of product of frosted ruber sole rubber
CN104311928A (en) * 2014-10-30 2015-01-28 际华三五三七制鞋有限责任公司 Master mixing process of calendering type black rubber foxing rubber for liberation shoes
CN105131363A (en) * 2015-10-09 2015-12-09 际华三五三七制鞋有限责任公司 Inter-steam vulcanization rolling type purplish red external binding method rubber sole glue and preparation method and application thereof
CN105218891A (en) * 2015-11-14 2016-01-06 际华三五一五皮革皮鞋有限公司 At the bottom of a kind of novel and portable skid-proof rubber
CN105795572A (en) * 2016-04-20 2016-07-27 东莞市鑫艺来塑胶制品有限公司 Shoe and information sharing system based on shoe

Similar Documents

Publication Publication Date Title
CN102993538B (en) A kind of modified plastics and manufacture method and purposes
CN103012899B (en) High impact strength wood-plastic composite material as well as preparation method and application thereof
CN104761761B (en) The nanofiber of a kind of high tenacity strengthens rubber-based 3D printing material and preparation method
CN101367977B (en) PVC fine foaming wood-plastic coiled material and method of preparing the same
CN101871219B (en) High-strength polyester composite well cover and preparation method thereof
Palmer et al. Sheet moulding compound (SMC) from carbon fibre recyclate
CN100503699C (en) Preparing method of composite material made of waste material
CN101525433B (en) Fiber-reinforced modified-reaction injection-molding nylon sheet and preparation method thereof
CN102690525A (en) Wood-plastic composite material using sweet sorghum slag as enhanced phase and preparation method for wood-plastic composite material
CN102501331B (en) Method for continuously preparing activated rubber powder
CN103540050B (en) A kind of PVC wood plastic ecological chamber internal hilar plate and production method
CN101759973B (en) Preparation method for thermoset resin/waste rubber powder/waste tire fiber composite material
CN102729311B (en) Production method of eucalyptus bark shaving boards
MY158279A (en) Rubber wet master batch, process for producing the same, rubber composition, and pneumatic tire
CN102504362B (en) Sizing material for rubber shoe sole and preparation method thereof
MY157398A (en) Uncured rubber composition,process for producing the same, and pneumatic tire
CN102852314B (en) Manufacturing method of rubber patterned coiled material floor
CN1931909A (en) Composite material of modified micro plant fiber powder and natural rubber and its prepn process and application
CN105061829B (en) A kind of preparation method of aluminium hydroxide flame-retardant glue
CN102174222B (en) Degradable plastic film and production method thereof
CN102875912B (en) High-performance polystyrene alloy prepared by polystyrene materials of waste and worn electrical appliances, as well as preparation method and application of high-performance polystyrene alloy
CN101508795B (en) Method for desulfurization regeneration of vulcanized rubber by employing double-screw extruder
CN103113640B (en) High-performance freezing-resistant and flame-retardant chloroprene rubber covering material
CN103756075A (en) Method for preparation of thermoplastic elastomer from waste rubber and waste plastics
CN101955599B (en) Formula for in situ preparing rolled high brightness shoe side rubber and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20130213