CN1029127C - Binder for carpet backing and preparation thereof - Google Patents
Binder for carpet backing and preparation thereof Download PDFInfo
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- CN1029127C CN1029127C CN 89108494 CN89108494A CN1029127C CN 1029127 C CN1029127 C CN 1029127C CN 89108494 CN89108494 CN 89108494 CN 89108494 A CN89108494 A CN 89108494A CN 1029127 C CN1029127 C CN 1029127C
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Abstract
The present invention provides carpet backing adhesive. A sulfur system of concentrated natural latex is vulcanized to be prevulcanized latex at the constant temperature of 60 DEG C to 65 DEG C, wherein the latex chloroform value of the prevulcanized latex is three in medium and four in primary; stabilizing accessory ingredients are added, and the stabilized prevulcanized latex is used as base glue of the adhesive. Measured by the weight of dry basis, the adhesive comprises the components of 100.0 parts of base glue, 50.0 to 300.0 parts of filling agent, 2.0 to 5.0 parts of coloring agent and 3.5 to 8.5 parts of thickening agent. The method for making the adhesive is composed of four steps of the latex vulcanization, the preparation of the base glue, the preparation of paste of the filling agents and the preparation of the backing adhesive.
Description
The present invention relates to a kind of binder for carpet backing, particularly a kind of binder for carpet backing and manufacture method thereof that adopts natural rubber latex to make.
Woven, acupuncture reaches the backing that carries based carpet and needs adhesive coating, with anchoring villus, stable dimensions, and makes carpet have good paving property, wearing quality and moistureproofness.Therefore, the quality of adhesive quality directly affects the quality and the usability of carpet.Adopt natural rubber latex to make binder for carpet backing, generally be to use the cooperation natural rubber latex, latex does not carry out prevulcanized, but adhesive applicating is vulcanized after the drying to the carpet backing, thereby carpet manufacturing needs special high temperature vulcanized equipment.The binder for carpet backing that present domestic carpet manufacturing is used all is each carpet factory outsourcing pre-vulcanized natural latex, and oneself selects Synergist S-421 95, and weighting agent is processed into tackiness agent.Because prevulcanized latex is not to make the binder for carpet backing special adhesive, its quality and performance variation are big, the adhesive formulation difference selected of each factory in addition, thereby the quality of tackiness agent, performance difference are very big, cause and be both the carpet of producing same description, its quality, performance differ greatly, often because the inferior carpet that causes of adhesive quality is defective.Secondly, the adhesive system instability easily precipitates, layering, flocculation and agglomeration phenomena, so the backing tackiness agent that uses in the carpet actual production all is matching while using.Moreover the tackiness agent that uses needs behind the backing gluing to carry out drying under the temperature about 120 ℃ at present, and energy consumption is big.
It is stable the purpose of this invention is to provide a kind of tackiness agent, storage time is long, in storage, transportation and use, do not precipitate, layering, flocculation, coalescent and rotten, vulcanization curve is smooth, binder for carpet backing that the coating glue film physical and mechanical properties is good and manufacture method thereof.
It is 60-75%(weight that binder for carpet backing adopts total solids level) concentrated natural latex carry out the prevulcanized latex that prevulcanized makes and count 100.0 with butt weight, adding the stablizer casein is 0.5-1.5, potassium oleate is 0.1-0.5, diffusant methylene sodium dinaphthalenesulfonate 0.5-2.0, peregal-0 is 0.2-0.5, tertiary sodium phosphate, trisodium phosphate, sodium polyphosphate, in four sodium-metaphosphates one or more are 0.2-0.5, ammoniacal liquor is 0.2-0.4, permeate agent dibutyl sodium disulfonate 0.05-0.15, accelerant zinc dibutyl dithiocaarbamate or dimethyl, diethyl, the sizing material that in the zinc salt of the dithiocarbamic acid of dibenzyl one or more are made for 0.2-0.5 is a base-material glue.Binder for carpet backing goes out base-material glue, weighting agent, tinting material, thickening material and makes, in butt weight: base-material glue is 100.0, weighting agent is 50.0-300.0, it is 2.0-5.0 that tinting material adopts titanium dioxide, the thickening material carboxymethyl cellulose is 1.5-5.0, the thickening material ammonium polyacrylate is 1.0-2.0, the thickening material gelatin is 0.5-1.5, and the thickening material sodiun alginate is 1.0-3.0.
Weighting agent adopts in butt weight, Calcium hydrogen carbonate is 50.0-100.0, Magnesium Silicate q-agent is 100.0-200.0, silicon-dioxide is 50.0-100.0, potassium oleate is 0.5-1.5, tertiary sodium phosphate, trisodium phosphate, sodium polyphosphate, one or more in four sodium-metaphosphates are the mashed prod that 0.2-0.5 dibutyl sodium disulfonate 0.2-0.5 and an amount of soft water are made.
Prevulcanized latex is that to adopt total fixed body content be 60-75%(weight) concentrated natural latex adds vulcanizing ingredient and vulcanizes prevulcanized latex to latex chloroform value to sulfurizing point 70-80%.
The kind and the ratio of the Synergist S-421 95 that the latex prevulcanized adds are: in butt weight, total solids level is a 60-75%(weight) concentrated natural latex be 100.0, sulphur is 0.5-3.0, promotor styroyl zinc dithiocarbamate or dimethyl, diethyl, dibutyl, the sodium of the dithiocarbamic acid of dibenzyl, ammonium, in the zinc salt one or more are 1.0-2.0, promotor thiuram compound tetramethylthiuram tetrasulfide, tetramethylthiuram monosulfide, tetrabutylthiuram disulfide, tetraethylthiuram disulfide, in the tetra-sulfurized pair pentamethyl-thiuram one or more are 0.2-0.5, zinc oxide is 0.8-3.0, the methylene sodium dinaphthalenesulfonate is 0.5-2.0, potassium zincate is 0.2-0.5, casein is 0.2-0.5, potassium hydroxide is 0.2-0.5, peregal-OS-15 is 0.2-0.5, peregal-O-20 is 0.3-0.6, anti-aging agent 2.6-di-tert-butyl-4-methylphenol or 2-methyl-4, the 6-dinonyl phenol, 2, the 5-ditert-butylhydro quinone, 2,2 '-in methylene double-basis (4-methyl)-6-t-butyl phenol one or more are 1.0-2.0, the hydroquinone dibenzyl ether is 0.5-1.5, and 2-thiol group benzimidazolyl zinc salt is 0.2-0.5.
The manufacture method of binder for carpet backing is made up of preparation, the preparation of weighting agent paste, four steps of backing tackiness agent preparation of latex prevulcanized, base-material glue.
The latex prevulcanized:
With total solids level is 60-75%(weight) the raw material concentrated natural latex be diluted to the latex of the total solids level of requirement with soft water, potassium hydroxide is made into 20%(weight) aqueous solution of concentration, casein is made into 10%(weight) the aqueous solution, methylene sodium dinaphthalenesulfonate (diffusion agent N F) is made into 30%(weight) the aqueous solution, peregal-OS-15, peregal-0-20 is made into 20%(weight) the aqueous solution, sulphur is made 100 hours dispersions of 50% ball mill grinding, dithiocarbamate(s), thiuram type accelerator, zinc oxide, anti-aging agent makes 50% respectively, 72 hours dispersions of ball mill grinding.Under temperature 30-35 ℃ and the condition that stir to exist (in actually operating temperature be controlled at be not less than 30 ℃ get final product), add in the latex successively in proper order and mix according to potassium zincate, casein, potassium hydroxide, diffusant, peregal.And then add the sulphur dispersion successively, promotor dispersion, anti-aging agent dispersion, mix the back add zinc oxide dosage 50% and mix.Reaction mixture material heat temperature raising 1-3 hour makes temperature of charge rise to 60-65 ℃.The material heat temperature raising adopts the heating in water bath mode, the constant temperature sulfuration is 60-90 minute under temperature 60-65 ℃ condition, latex chloroform value stops sulfuration when reaching sulfurizing point 70-80%, material cools, and adds other 50% zinc oxide and mix after temperature is reduced to normal temperature.Filter out impurities behind the hot routinely one-tenth of sizing material and be the prevulcanized latex that preparation base-material glue is used.
The preparation of base-material glue is to add Synergist S-421 95 to carry out stabilization treatment in prevulcanized latex.Make the sizing material system stable, add and have good preservation stability after weighting agent is made binder for carpet backing, do not precipitate, layering, flocculation, coalescent and denaturalization phenomenon, to guarantee the quality and the performance of tackiness agent.
The preparation process of base-material glue is to take by weighing various materials in reinforced ratio, casein is made into 10%(weight) the aqueous solution, potassium oleate is made into 20%(weight) aqueous solution, diffusion agent N F is made into 30%(weight) aqueous solution, peregal-0 is made into 20%(weight) aqueous solution, phosphoric acid salt is made into 5%(weight) aqueous solution, the dibutyl sodium disulfonate is made into 20%(weight) aqueous solution, promotor dibutyl dithiocaarbamate salt is made 72 hours dispersions of 50% ball mill grinding.Under normal temperature and the condition that stir to exist, add in the latex successively according to the order of stablizer, permeate agent, promotor and to mix.
The preparation of weighting agent is to determine the soft water consumption as requested, then under the condition of normal temperature and stirring existence, with phosphoric acid salt, potassium oleate, dibutyl sodium disulfonate, silicon-dioxide, Magnesium Silicate q-agent, Calcium hydrogen carbonate add to mix in the soft water made the even paste that requires concentration in 40-60 minute successively.
The preparation process of backing tackiness agent is: tinting material titanium dioxide is made 24 hours dispersions of 25% ball mill grinding, the thickening material carboxymethyl cellulose is made into 3%(weight) aqueous solution, polyacrylic acid ammonia is made into 20%(weight) aqueous solution, under normal temperature and the condition that stir to exist according to weighting agent, titanium dioxide, thickening material order adds successively and mixed in the base-material glue 50-70 minute, and the sizing material of making homogeneous system is binder for carpet backing.
Binder for carpet backing provided by the invention uses the prevulcanized latex manufacturing of its sulfuration point of control, guaranteed the physical and mechanical properties of backing coating glue film, prevulcanized latex carries out stabilization treatment, add behind the weighting agent sealing that is chelated of the heavy metal ion in the tackiness agent, layering, precipitation, flocculation, coalescent and denaturalization phenomenon do not take place in sizing material, quality, performance are uniform and stable, and the storage time is long, store, vulcanization curve is smooth in the use.Adhesive applicating back line with rubber film gets final product dryness finalization under 65-70 ℃ of temperature, saved sulfuration process and equipment.Energy consumption is low, can reduce the carpet manufacturing cost.Have also in addition that glued membrane is ageing-resistant, acid-and base-resisting and chloridized, pliable and tough, good hand touch, shaping size is stable, free from extraneous odour, advantage such as seepage force, bonding force are strong.
Embodiment:
Adopt binder for carpet backing prescription provided by the invention and process for manufacturing adhesive to make binder for carpet backing.
One, natural rubber latex
Adopting total solids level is the 60-75% concentrated natural latex
Two, binder for carpet backing
Finished carpet backing tackiness agent is that total solids level is a 50%(weight) above white homogeneous system sizing material.
Three, binder for carpet backing performance and effect measured result
(1), tackiness agent stability in storage experimental result:
1, experimental technique
The bottled indoor storage that seals under the natural condition
2, experimental result
Deposited the sizing material no change three months.
(2), backing gluing experimental result
1, backing gluing sample production method
Hardened coating, Amount of spread are 130-150 gram/time, linked network cloth behind the gluing, the typing in 3 hours of 40-50 ℃ of drying.Carry out flat blanket, chlorination rinsing 20 minutes (treatment agent is a clorox, the normal temperature rinsing) after the film clips.Use the sodium hydroxide neutralizing treatment then 3 minutes, used the sulphuric acid soln rinsing again 5-10 minute.Alkali cleaning, pickling are all carried out at normal temperatures.Wash to neutrality after the centrifuge dehydration under 70-80 ℃ of temperature dry 12 hours at last with water.Carry out second again and imitate gluing, linked network cloth is up to the standards to be to detect through flat flower and uses sample behind the gluing.
2, heat ageing test result
(1) the test measured result of 100 ℃ of temperature
(2) 70 ℃ * 168 hours test-results of temperature
Tackiness agent of the present invention and existing binder for carpet backing all have yellowing phenomenon, but all not hardening, are clamminess and embrittlement.
3, bonding strength test result
(3) tackiness agent
Flash test result
Use GB261-83 close flash point instrument to measure
Tackiness agent time and phenomenon
24 hours 48 hours 72 hours 96 hours
The existing whole embrittlement dry lintings of flavescence hardening local embrittlement
Flavescence of the present invention with 24 hours with hardening in 24 hours but still flexible
Stripping strength
The tackiness agent remarks
Newton/meter
Sample 1 0.9-1.7
Existing
Sample 2 1.1-1.5
Sample 1 2.6-3.7
The present invention
Sample 2 2.6-4.2
The tackiness agent test-results
Have now by room temperature and heat up every lighting a fire twice once to 87 ℃ of not flash burns of lighting a fire all that foam.
The present invention is heated up every lighting a fire twice once until 88 ℃ of not flash burns of lighting a fire all that foam by room temperature.
Annotate: except that indicating, method for testing and detecting all adopts existing normally used standard method.
Claims (3)
1, a kind of carpet backing jelly is characterized in that,
(1) prevulcanized latex
The total solid weight that with the total solids level is the 60-75% concentrated natural latex is 100.0,
Sulphur is 0.5-3.0
Promotor
Styroyl zinc dithiocarbamate or dimethyl, in the sodium of the dithiocarbamic acid of diethyl, dibutyl, dibenzyl, ammonium, the zinc salt one or more are 1.0-2.0, in promotor tetramethylthiuram tetrasulfide, tetramethylthiuram monosulfide, curing four fourth methyl thiurams, tetraethylthiuram disulfide, tetramethylthiuram tetrasulfide, the tetra-sulfurized pair pentamethyl-thiuram one or more are 0.2-0.5
Zinc oxide is 0.8-3.0,
The methylene sodium dinaphthalenesulfonate is 0.5-2.0,
Potassium zincate is 0.2-0.5,
Stablizer
Casein is 0.2-0.5,
Potassium hydroxide is 0.2-0.5,
Peregal-OS-15 is 0.2-0.5,
Peregal-O-20 is 0.3-0.6,
Anti-aging agent
2.6-di-tert-butyl-4-methylphenol or 2-methyl-4,6-dinonyl phenol, 2,5-ditert-butylhydro quinone, 2,2 '-in methylene double-basis (4-methyl)-6-t-butyl phenol one or more are 1.0-2.0, the hydroquinone dibenzyl ether is 0.5-1.5, and 2-thiol group benzimidazolyl zinc salt is 0.2-0.5;
(2) base-material glue
With the prevulcanized latex total solid weight is 100.0,
Stablizer
Casein is 0.5-1.5,
Potassium oleate is 0.1-0.5,
Diffusant
The methylene sodium dinaphthalenesulfonate is 0.5-2.0,
Peregal-O is 0.2-0.5,
Tertiary sodium phosphate, trisodium phosphate, sodium polyphosphate, one or more are 0.2-0.5 in four sodium-metaphosphates,
Ammoniacal liquor is 0.2-0.4,
Permeate agent
The dibutyl sodium disulfonate is 0.05-0.15,
Promotor
In the zinc salt of the dithiocarbamic acid of zinc dibutyl dithiocarbamate or dimethyl, diethyl, dibenzyl one or more: be 0.2-0.5,
(3) binder for carpet backing
With base-material glue total solid weight is 100.0,
Weighting agent is 50.0-300.0,
Tinting material titanium dioxide is 2.0-5.0,
The thickening material carboxymethyl cellulose is 1.5-5.0,
Ammonium polyacrylate is 1.0-2.0,
Obvious results is 0.5-1.5,
Sodiun alginate is 1.0-3.0.
2, by the described binder for carpet backing of claim 1, the weighting agent that it is characterized in that said binder for carpet backing is Calcium hydrogen carbonate, Magnesium Silicate q-agent, silicon-dioxide, wherein Calcium hydrogen carbonate is 50.0-100.0, and Magnesium Silicate q-agent is 100.0-200.0, and silicon-dioxide is 50.0-100.0.
3, the manufacture method of the described binder for carpet backing of a kind of claim 1 is characterized in that:
(1) prevulcanized latex
The total solid weight that with the total solids level is the 60-75% concentrated natural latex is 100.0,
Sulphur is 0.5-3.0,
Promotor
In the sodium of the dithiocarbamic acid of styroyl zinc dithiocarbamate or dimethyl, diethyl, dibutyl, dibenzyl, ammonium, the zinc salt one or more are 1.0-2.0,
The blue nurse of four sulfuration tetramethyl-s, tetramethylthiuram monosulfide, one or more in tetrabutylthiuram disulfide, four tetraethylthiuram sulfides, the tetra-sulfurized pair pentamethyl-thiuram are 0.2-0.5,
Zinc oxide is 0.8-3.0,
The methylene sodium dinaphthalenesulfonate is 0.5-2.0,
Potassium zincate is 0.2-0.5,
Stablizer
Casein is 0.2-0.5,
Potassium hydroxide is 0.2-0.5,
Peregal-OS-15 is 0.2-0.5,
Peregal-O-20 is 0.3-0.6,
Anti-aging agent
2,6-tertiary butyl-4-methylphenol, 2-methyl-4, the 6-dinonyl phenol, 2, the 5-ditert-butylhydro quinone, 2,2 '-in methylene double-basis (4-methyl)-6-t-butyl phenol one or more are 1.0-2.0, the hydroquinone dibenzyl ether is 0.5-1.5,2-thiol group benzimidazolyl zinc salt is 0.2-0.5, with soft water the natural concentrating glue breast is diluted to requirement concentration after taking by weighing each material by ratio of components, potassium hydroxide is made into 20% the aqueous solution, casein is made into 10% the aqueous solution, the methylene sodium dinaphthalenesulfonate is made into 30% the aqueous solution, peregal-OS-15, peregal-O-20 is made into 20% aqueous solution, sulphur is made 00 hour dispersion of 50% ball mill grinding, dithiocarbamate(s), thiuram type accelerator, zinc oxide, anti-aging agent is made 72 hours dispersions of 50% ball mill grinding, temperature 30-35 ℃ and stir in the presence of according to potassium zincate, casein, potassium hydroxide, the methylene sodium dinaphthalenesulfonate, peregal order adds in the latex successively and mixes, add the sulphur dispersion then successively, the promotor dispersion, the anti-aging agent dispersion, the zinc oxide that mixes back adding consumption 50% mixes, heat up then the material temperature rise was vulcanized to 60-65 ℃ of constant temperature 60-90 minute, stop sulfuration during the 70-80% of latex vulcanizate to the chloroform value to sulfurizing point, material is cooled to and adds the zinc oxide of residue 50% behind the normal temperature and mix, mix after-filtration and remove impurity
(2) base-material glue
With prevulcanized latex total solid weight 100.0.
Stablizer
Casein is 0.5-1.5,
Potassium oleate is 0.1-0.5,
Diffusant
The methylene sodium dinaphthalenesulfonate is 0.5-2.0,
Peregal-O is 0.2-0.5,
Tertiary sodium phosphate, trisodium phosphate, sodium polyphosphate, one or more are 0.2-0.5 in four sodium-metaphosphates,
Ammoniacal liquor is 0.2-0.4,
Permeate agent
The dibutyl sodium disulfonate is 0.05-0.15,
Promotor
In the zinc salt of the dithiocarbamic acid of the zinc salt of dibutyl dithiocaarbamate or dimethyl, diethyl, dibenzyl one or more are 0.2-0.5,
Take by weighing behind the various materials by ratio of components and casein to be made into 10% the aqueous solution, potassium oleate is made into 20% aqueous solution, the methylene sodium dinaphthalenesulfonate is made into 30% the aqueous solution, peregal-O is made into 20% aqueous solution, and the promotor dithiocar-bamate makes 50%, 72 hours dispersions of ball mill grinding, at normal temperature and in the presence of stirring according to stablizer, permeate agent, promotor order add in the prevulcanized latex successively and mix
(3) preparation of weighting agent paste is by weight:
Weighting agent 200.00-300.0,
Potassium oleate is 0.5-1.5,
In tertiary sodium phosphate, trisodium phosphate, sodium polyphosphate, four sodium-metaphosphates one or more are 0.2-0.5,
The dibutyl sodium disulfonate is 0.2-0.5,
An amount of soft water.
To mix the even paste of system in phosphoric acid salt, potassium oleate, dibutyl sodium disulfonate, the weighting agent adding soft water successively at normal temperature and in the presence of stirring,
(4) backing tackiness agent preparation,
Count 100.0 with base-material glue total solid weight,
Weighting agent is 50.0-300.0, and tinting material titanium dioxide is 2.0-5.0, and the thickening material gelatin is 0.5-1.5, and sodiun alginate is 1.0-3.0, and polypropylene acid ammonium is 1.0-2.0, and carboxymethyl cellulose is 1.5-5.0,
After taking by weighing each material by ratio of components the weighting agent preparation method is made mashed prod,
Titanium dioxide is made 24 hours dispersions of 25% ball mill grinding,
Carboxymethyl cellulose is made into 3% aqueous solution, and ammonium polyacrylate is made into 20% aqueous solution, adds successively in the base-material glue according to weighting agent, titanium dioxide, thickening material order at normal temperature and under stirring to mix.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 89108494 CN1029127C (en) | 1989-11-14 | 1989-11-14 | Binder for carpet backing and preparation thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 89108494 CN1029127C (en) | 1989-11-14 | 1989-11-14 | Binder for carpet backing and preparation thereof |
Publications (2)
Publication Number | Publication Date |
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CN1051749A CN1051749A (en) | 1991-05-29 |
CN1029127C true CN1029127C (en) | 1995-06-28 |
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CN 89108494 Expired - Fee Related CN1029127C (en) | 1989-11-14 | 1989-11-14 | Binder for carpet backing and preparation thereof |
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CN1854229B (en) * | 2005-04-28 | 2011-02-09 | 深圳市比克电池有限公司 | Production of lithium ion battery cathode binder and cathode chip |
RU2406736C2 (en) * | 2005-06-09 | 2010-12-20 | БОЛЬЁ ГРУП, ЭлЭлСи Ди/Би/Эй БОЛЬЁ ОФ АМЕРИКА | Thermoplastic polymeric composition, preparation method and use thereof |
CN101967356B (en) * | 2010-09-21 | 2011-12-07 | 华南理工大学 | Preparation method of environment-friendly spraying glue |
CN102199414A (en) * | 2011-03-29 | 2011-09-28 | 际华三五一七橡胶制品有限公司 | Macromolecular adhesive |
CN104419347A (en) * | 2013-09-10 | 2015-03-18 | 贵州大自然科技有限公司 | Low-temperature vulcanizing adhesive for palm mattress and preparation method thereof |
US20200109318A1 (en) * | 2018-10-09 | 2020-04-09 | Sumitomo Rubber Industries, Ltd. | Adhesive for tennis ball |
CN113736392B (en) * | 2020-05-27 | 2023-05-09 | 深圳市准能新材料有限公司 | Odor-removing antistatic carpet back adhesive composition, back adhesive, preparation method of back adhesive and carpet |
CN113736371B (en) * | 2020-05-27 | 2023-04-07 | 深圳市准能新材料有限公司 | Environment-friendly water-based carpet back adhesive composition, back adhesive, preparation method of back adhesive and carpet |
CN113072897B (en) * | 2021-03-09 | 2022-08-05 | 宁波恩派新材料科技有限公司 | High-temperature vulcanized natural latex adhesive and preparation method thereof |
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1989
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