CN102911804A - Preparation method for efficient low-foaming detergent - Google Patents
Preparation method for efficient low-foaming detergent Download PDFInfo
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- CN102911804A CN102911804A CN2012104124930A CN201210412493A CN102911804A CN 102911804 A CN102911804 A CN 102911804A CN 2012104124930 A CN2012104124930 A CN 2012104124930A CN 201210412493 A CN201210412493 A CN 201210412493A CN 102911804 A CN102911804 A CN 102911804A
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Abstract
The invention discloses a preparation method for an efficient low-foaming detergent. The preparation method comprises steps as follows: synthesizing to obtain hydroxymethyl crylic acid, maleic anhydride and acrylamide copolymer; compounding the copolymer with the efficient low-foaming detergent so as to obtain an optimal detergent product containing 20% of solid. The efficient low-foaming detergent prepared by the preparation method disclosed by the invention has the advantages of being less in foam, fast in foam removing, high in cleaning performance, and strong in flooding resistance; and the efficient low-foaming detergent can be widely used as soaping for wool textiles, cotton textiles, fiber products, silk products and chemical fiber products and the like.
Description
Technical field:
The present invention relates to a kind of High Efficiency and Low Foam Detergent, particularly a kind of preparation method of new and effective low bubble detergent.
Background technology:
Detergent is the important after treatment aids of printing and dyeing mill.At present, used detergent is of a great variety on the market, but foam is more mostly, the generation of foam not only can cause the waste of raw material, and the pollution of water resources is run off, and spot that also may be a large amount of is detained, is piled up at cloth, cause the increase of energy consumption, make troubles to production operation.Especially on the production line that on-line velocity is high, the impact of foam is more serious.The foam that adopts low bubble nonionogenic tenside or defoamer to reduce and eliminate in the production process is the method for commonly using, yet the nonionogenic tenside price is generally higher, has limited its use range; Use the defoamer froth breaking, generally need to just can obtain preferably defoaming effect under higher defoamer massfraction, production cost increases, and also may produce the silicon spot, affects washing effect.This research is by great many of experiments, compositely prepares a kind of efficient, low bubble detergent.
Summary of the invention:
Goal of the invention: for the defective that prior art exists, it is few to the invention provides a kind of foam, and bubble burst is fast, the preparation method of washing excellent property, the strong detergent of removal loose colour ability.
Technical scheme: for achieving the above object, the present invention by the following technical solutions:
A kind of preparation of High Efficiency and Low Foam Detergent:
1) methylol vinylformic acid, the preparation of maleic anhydride and acrylamide copolymer: a, in being furnished with the 1000ml four-hole boiling flask of thermometer, reflux condensing tube, two dropping funnels, the maleic anhydride and the water that add metering, be warming up to 50 ~ 80 ℃, stirring and dissolving, the sodium hydroxide solution of adding 25% is regulated PH to 5.5 ~ 7.0, gets a liquid; B, take by weighing methylol vinylformic acid and the Sodium Persulfate of metering, be dissolved in suitable quantity of water, and regulate PH to 3.5 ~ 4.5 with 25% sodium hydroxide solution, get b liquid; C, take by weighing the acrylamide of metering, drip simultaneously in the people a liquid with b liquid, 80 ~ 110 ℃ of control temperature, time for adding 3 ~ 6 hours drips and finishes, and reacts under the reflux state 10 ~ 16 hours, is cooled to 50 ℃, obtains yellow sticky polymers product.
2) High Efficiency and Low Foam Detergent is composite: A, in the reactor of 1000ml, add successively fatty alcohol-polyoxyethylene ether-15, and water, be warming up to 30 ~ 60 ℃, stirred 0.5 ~ 1 hour, make its dissolving.Add successively in B, the solution that obtains to steps A, poly-(4 monohydroxy tetramethylenes 1, the 2-dicarboxylic acid) (CP2), methylol vinylformic acid, maleic anhydride and acrylamide copolymer, fatty alcohol-polyoxyethylene ether-9 sodium sulfate adds quantitative water again, stirred 0.5 ~ 2 hour at 50 ~ 80 ℃, make solid content and be 20% optimization detergent product.Raw materials used mass fraction is:
Fatty alcohol-polyoxyethylene ether-15:5 ~ 20 part
Poly-(4 monohydroxy tetramethylenes 1,2-dicarboxylic acid): 50 ~ 200 parts
Methylol vinylformic acid, maleic anhydride and acrylamide copolymer: 10 ~ 30 parts
Fatty alcohol-polyoxyethylene ether-9 sodium sulfate: 10 ~ 30 parts
Water: an amount of
In the preparation of described High Efficiency and Low Foam Detergent, fatty alcohol-polyoxyethylene ether-15: poly-(4 monohydroxy tetramethylenes 1, the 2-dicarboxylic acid): methylol vinylformic acid, maleic anhydride and acrylamide copolymer: the mass ratio of fatty alcohol-polyoxyethylene ether-9 sodium sulfate is 1:10 ~ 40:1 ~ 10:1 ~ 10.
According to above technical scheme, can realize following beneficial effect: compared with prior art, the present invention has the following advantages: High Efficiency and Low Foam Detergent that the present invention obtains: it is few to have a foam, bubble burst is fast, the washing excellent property, remove the advantages such as the loose colour ability is strong, and can be widely used in wool spinning, cotton, fiber crops, silk, the fabrics such as chemical fibre are used as soaping agent.
Embodiment:
Below in conjunction with embodiment the present invention is done further detailed description, but the scope of protection of present invention is not limited to the scope that embodiment represents.
Embodiment 1:
1) hydroxyl acrylic, the preparation of maleic anhydride and acrylamide copolymer: a, in being furnished with the 1000ml four-hole boiling flask of thermometer, reflux condensing tube, two dropping funnels, add Malaysia dicarboxylic anhydride (1.0mol) and water (500ml), be warming up to 50 ~ 80 ℃, stirring and dissolving, the sodium hydroxide solution of adding 25% is regulated PH to 5.5 ~ 7.0, gets a liquid; B, take by weighing hydroxyl acrylic (2.6mol), Sodium Persulfate (0.1mol) is dissolved in the 100ml water, and regulates PH to 3.5 ~ 4.5 with 25% sodium hydroxide solution, gets b liquid; C, take by weighing acrylamide (0.6mol); D, with b and c two the dropping in a liquid simultaneously, 80 ~ 110 ℃ of control dropping temperatures, time for adding 3 ~ 6 hours drips and finishes, and reacts under the reflux state 10 ~ 16 hours, reacts complete, is cooled to 50 ℃, obtains yellow sticky polymers product.
2) High Efficiency and Low Foam Detergent is composite: A, in the reactor of 1000ml, add successively 16g fatty alcohol-polyoxyethylene ether-15, and 500ml water, be warming up to 30 ~ 60 ℃, stirred 0.5 ~ 1 hour, make its dissolving.Add successively 152g CP2, methylol vinylformic acid in B, the solution that obtains to steps A, 18g maleic anhydride and acrylamide copolymer, 14g fatty alcohol-polyoxyethylene ether-9 sodium sulfate, again 300ml water, stirred 0.5 ~ 2 hour at 50 ~ 80 ℃, make solid content and be 20% optimization detergent product.
Claims (2)
1. the preparation method of a High Efficiency and Low Foam Detergent is characterized in that: may further comprise the steps:
1) methylol vinylformic acid, the preparation of maleic anhydride and acrylamide copolymer: a, in being furnished with the 1000ml four-hole boiling flask of thermometer, reflux condensing tube, two dropping funnels, the maleic anhydride and the water that add metering, be warming up to 50 ~ 80 ℃, stirring and dissolving, the sodium hydroxide solution of adding 25% is regulated PH to 5.5 ~ 7.0, gets a liquid; B, take by weighing methylol vinylformic acid and the Sodium Persulfate of metering, be dissolved in suitable quantity of water, and regulate PH to 3.5 ~ 4.5 with 25% sodium hydroxide solution, get b liquid; C, take by weighing the acrylamide of metering, drip simultaneously in the people a liquid with b liquid, 80 ~ 110 ℃ of control temperature, time for adding 3 ~ 6 hours drips and finishes, and reacts under the reflux state 10 ~ 16 hours, is cooled to 50 ℃, obtains yellow sticky polymers product;
2) High Efficiency and Low Foam Detergent is composite: A, in the reactor of 1000ml, add successively fatty alcohol-polyoxyethylene ether-15, and water, be warming up to 30 ~ 60 ℃, stirred 0.5 ~ 1 hour, make its dissolving; Add successively in B, the solution that obtains to steps A, poly--4 monohydroxy tetramethylenes 1, the 2-dicarboxylic acid, methylol vinylformic acid, maleic anhydride and acrylamide copolymer, fatty alcohol-polyoxyethylene ether-9 sodium sulfate adds quantitative water again, stirs 0.5 ~ 2 hour at 50 ~ 80 ℃, make solid content and be 20% optimization detergent product, raw materials used mass fraction is:
Fatty alcohol-polyoxyethylene ether-15:5 ~ 20 part
Poly-(4 monohydroxy tetramethylenes 1,2-dicarboxylic acid): 50 ~ 200 parts
Methylol vinylformic acid, maleic anhydride and acrylamide copolymer: 10 ~ 30 parts
Fatty alcohol-polyoxyethylene ether-9 sodium sulfate: 10 ~ 30 parts
Water: an amount of.
2. the preparation method of described a kind of High Efficiency and Low Foam Detergent according to claim 1, it is characterized in that: in the preparation of described High Efficiency and Low Foam Detergent, fatty alcohol-polyoxyethylene ether-15: poly-(4 monohydroxy tetramethylenes 1, the 2-dicarboxylic acid): methylol vinylformic acid, maleic anhydride and acrylamide copolymer: the mass ratio of fatty alcohol-polyoxyethylene ether-9 sodium sulfate is 1:10 ~ 40:1 ~ 10:1 ~ 10.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210412493.0A CN102911804B (en) | 2012-10-25 | 2012-10-25 | Preparation method for efficient low-foaming detergent |
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| CN201210412493.0A CN102911804B (en) | 2012-10-25 | 2012-10-25 | Preparation method for efficient low-foaming detergent |
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| CN102911804A true CN102911804A (en) | 2013-02-06 |
| CN102911804B CN102911804B (en) | 2014-02-26 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103695194A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | High density washing powder for fabric and preparation method thereof |
| CN104560421A (en) * | 2015-01-28 | 2015-04-29 | 桑达化工（南通）有限公司 | Novel detergent |
| CN107118856A (en) * | 2016-02-24 | 2017-09-01 | 黄庆禄 | A kind of preparation of micro ecological active detergent and technique |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186862A (en) * | 2007-11-12 | 2008-05-28 | 大连广汇科技有限公司 | Foamless cleaning agent and preparation method thereof |
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2012
- 2012-10-25 CN CN201210412493.0A patent/CN102911804B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186862A (en) * | 2007-11-12 | 2008-05-28 | 大连广汇科技有限公司 | Foamless cleaning agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 黄茂福: "螯合剂及其在印染工业中的应用", 《印染》, no. 1, 31 December 2001 (2001-12-31) * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103695194A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | High density washing powder for fabric and preparation method thereof |
| CN103695194B (en) * | 2013-11-28 | 2015-07-08 | 万潇熠 | High density washing powder for fabric and preparation method thereof |
| CN104560421A (en) * | 2015-01-28 | 2015-04-29 | 桑达化工（南通）有限公司 | Novel detergent |
| CN107118856A (en) * | 2016-02-24 | 2017-09-01 | 黄庆禄 | A kind of preparation of micro ecological active detergent and technique |
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| CN102911804B (en) | 2014-02-26 |
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