CN102911424A - Environment-friendly material plastomer and production method and manufacturing process thereof - Google Patents
Environment-friendly material plastomer and production method and manufacturing process thereof Download PDFInfo
- Publication number
- CN102911424A CN102911424A CN2012104578632A CN201210457863A CN102911424A CN 102911424 A CN102911424 A CN 102911424A CN 2012104578632 A CN2012104578632 A CN 2012104578632A CN 201210457863 A CN201210457863 A CN 201210457863A CN 102911424 A CN102911424 A CN 102911424A
- Authority
- CN
- China
- Prior art keywords
- inorganic powder
- plastomer
- environment
- graft modification
- molten
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to the field of polymer materials and particularly relates to an environment-friendly material plastomer and a production method and a manufacturing process thereof. The environment-friendly material plastomer can be applicable to the production of plastic films, paper, non-woven fabric, building materials, pipes, plates and the like. The invention relates to an environment-friendly material plastomer, which consists of carbon chain type inorganic powder with content of 70%-80% and polymer resin with content of 30%-20%. The invention provides an environment-friendly material plastomer which is easier in degradation compared with conventional plastic products, can thoroughly avoid white pollution without toxicity or odor, pollution to air, water and soil after being used, discarded and burnt, or any damage to a human body, and simultaneously has the advantages of good toughness, high strength and low cost.
Description
Technical field
The present invention relates to a kind of polymeric material field, particularly a kind of environment-friendly materials plastomer and production method and manufacturing processed, this environment-friendly materials plastomer goes for producing plastics film, paper, non-woven fabrics, building materials, tubing, sheet material etc.
Background technology
China of today has become the world's second-biggest economy, and the Economic development of advancing by leaps and bounds has also caused the pollution of urbanization simultaneously, and wherein the pollution of plastics bag is outstanding especially.According to the statistic data of house and town and country construction section, the annual rubbish that produces more than one hundred million tons in the whole nation.Whole world rubbish average annual growth is 8.42% at present, and Chinese rubbish rate of increase more reaches more than 10%.Use the quantity of plastics bag to grow with each passing day, unite issue according to China Chain Operation Association and Department of Commerce: approximately 50,000,000,000 of the annual plastics bags that consumes in supermarket.Take in Beijing as example, annual discarded plastics bag is nearly 2,300,000,000 at present.Moreover, the national common people at least 10 hundred million plastics bags of will using up of buying vegetables every day, and the plastics bag consumption of other type also is that every day is more than 3,000,000,000.Cause severe contamination for environment, and difficulty and the cost of processing plastic garbage are huge, cause huge the expending of national society's resource.In view of this, China has formally included environmental protection policy in the financial budget of country in 12 planning, estimates that the gold money that drops into environmental protection policy reaches 3.1 trillion yuan.The requirement of low-carbon green certainly will will stimulate the flourish of environmental protection raw material industry. have the environment-friend substitution raw material of high performance number, low price, can effectively reduce the usage quantity of conventional plastic, real performance environmental protection effect. certainly will also will become main flow, lead market to drive the green waves of a new round.
In short, plastic degradation has three kinds of modes, that is exactly biological degradation, photodegradation and burning degraded. at present research biodegradable for what is called or the photodegradable plastics bag has many, for example, add in process of production a certain amount of additive (such as starch, treated starch or other Mierocrystalline cellulose, photosensitizers, biodegradation agent etc.), the phase makes the stability decreases of plastics bag and degrades.But test through reality, most of so-called degradable plasticss, in fact all need certain envrionment conditions, real degradation effect is very not practical, especially manufacturing cost extra-high-speed, have conceptual but the shortage practicality. advanced country in the world the most effective employed trash processing way is to be to burn at present, but the product that uses polyethylene (Polyethylene is called for short PE) to make, except can produce to harm great carcinogenic substance " two mouthfuls of evil English " when burning, its resistates also will cause the damage of incinerator.And there is the difficult shortcoming of degraded in this PE, and the plastics bag goods of producing easily cause white pollution.
Summary of the invention
In view of the above problems, the object of the present invention is to provide a kind of environment-friendly materials plastomer and production method and manufacturing processed.
For achieving the above object, the technical solution adopted in the present invention is: a kind of environment-friendly materials plastomer, it is characterized in that, and this plastomer is that 70%～80% carbochain type inorganic powder and content are that 30%～20% macromolecule resin forms by content.Thus, this environment-friendly materials plastomer is produced plastics, and is mainly take carbochain type inorganic powder as main body, cheaper with the plastics price that adopts before PE to produce fully.
In some embodiments, carbochain type inorganic powder comprises inorganic powder and the compound carboxylic esters of aluminium titanium; With the compound carboxylic esters grafting of aluminium titanium and full close the surface that is adsorbed in inorganic powder and form the irreversible covalent chemical bond of peeling off.Owing to, discarded all pollution-free to air, water, soil through burning after using if it is nonpoisonous and tasteless that the environment-friendly materials plastomer is produced plastics, reach human body without any injury, more easily degraded can thoroughly solve white pollution.
A kind of production method of environment-friendly materials plastomer, specific as follows:
(1) grafting of thermodynamics and chemistry;
The principle that application interface is learned under specified temp, through the compound carboxylic esters graft modification of aluminium titanium, plays bonding action with inorganic powder, and full closing is adsorbed in inorganic powder surface;
(2) the molten molten blend of physics;
Carbochain type inorganic powder again with a small amount of macromolecule resin, the molten molten homogeneous system that is blended under the high temperature about temperature 165 degree Celsius forms plastomer after the cooling;
(3) granulation formation.
A kind of manufacturing processed of environment-friendly materials plastomer, concrete steps are as follows:
Hyperthermia drying: inorganic powder is transported in the kiln carry out heat to 190 first
0C～200
0C; Until with the inorganic powder complete drying;
Disperse: again the inorganic powder after the oven dry is carried out mechanical dispersion, reach the size of primary particle diameter;
Graft modification: then add the compound carboxylic esters of aluminium titanium and carry out graft modification;
Molten molten blend granulation: carbochain type inorganic powder again with a small amount of macromolecule resin, the molten molten homogeneous system that is blended under the high temperature about temperature 165 degree Celsius forms plastomer, again granulation after the cooling;
Above-mentioned be separated into that mechanical type disperses and graft modification all is to finish in four tunnel convection current graft modification devices.
In some embodiments, the graft modification agent is the compound carboxylic esters of aluminium titanium.
Embodiment
A kind of environment-friendly materials plastomer, this plastomer are that 70%～80% carbochain type inorganic powder and content are that 30%～20% macromolecule resin forms by content.This environment-friendly materials plastomer is produced plastics, and is mainly take carbochain type inorganic powder as main body, cheaper with the plastics price that adopts before PE to produce fully.
Carbochain type inorganic powder comprises inorganic powder and the compound carboxylic esters of aluminium titanium; With the compound carboxylic esters grafting of aluminium titanium and full close the surface that is adsorbed in inorganic powder and form the irreversible covalent chemical bond of peeling off
During production, only needing to add 30%～20% macromolecule resin mixes with plastomer, just can produce the bag film of with low cost and real environmental protection, have that resistance to salt water is good, non-conductive, toughness carefully, intensity is high, heat-resisting, water consumption is low, and can not produce oil stain black smoke and two mouthfuls of evil English after burning, and its final residual material is reduced to inorganic powder, just can reclaim easily.
A kind of production method of environment-friendly materials plastomer, specific as follows:
(1) grafting of thermodynamics and chemistry;
The principle that application interface is learned under specified temp, through the compound carboxylic esters graft modification of aluminium titanium, plays bonding action with inorganic powder, and full closing is adsorbed in inorganic powder surface;
(2) the molten molten blend of physics;
Carbochain type inorganic powder again with a small amount of macromolecule resin, the molten molten homogeneous system that is blended under the high temperature about temperature 165 degree Celsius forms plastomer after the cooling;
(3) granulation formation.
Thermodynamics is the character of material system when balance and set up the equilibrium relationship of energy in the research thermal phenomenon, and state system and the extraneous subject that interacts (comprising transmission ofenergy and conversion) when changing.Engineering thermodynamics is the branch that thermodynamics develops at first, and it mainly studies mutually rule and the application thereof of conversion between heat energy and mechanical energy and other energy, is one of mechanical important foundation subject.Thermodynamics is an aspect of calorifics theory.Thermodynamics mainly is the thermal properties of studying material from the viewpoint of Conversion of energy, and it has disclosed the macroscopic law that energy is deferred to when a kind of formal transformation is another kind of form.Thermodynamics is to sum up the macroscopic appearance of material and the calorifics theory that obtains, does not relate to the microtexture of material and the interaction of microcosmic particle.Therefore it is a kind of macroscopic theory of phenomenological, has reliability and the ubiquity of height.Thermodynamics three laws are thermodynamic (al) basic theories.
Chemical bond (chemical bond) refer in the molecule or crystal in the general designation of strong interaction force between adjacent two or more atoms (or ion).Be divided into ionic linkage, covalent linkage, metallic bond.
Ionic linkage: be the adelphotaxy that is produced by the ion with the charges of different polarity.
Covalent linkage: be the sucking action that two or more atoms produce by share electron pair, typical covalent linkage is that two atoms are by means of attracting a pair of bonding electrons and forming.
Metallic bond: be the interaction that atoms metal is combined, can regard the covalent linkage of height delocalization as.
A kind of manufacturing processed of environment-friendly materials plastomer, concrete steps are as follows:
Hyperthermia drying: inorganic powder is transported in the kiln carry out heat to 190 first
0C～200
0C; Until with the inorganic powder complete drying;
Disperse: again the inorganic powder after the oven dry is carried out mechanical dispersion, reach the size of primary particle diameter;
Graft modification: then add the compound carboxylic esters of aluminium titanium and carry out graft modification;
Molten molten blend granulation: carbochain type inorganic powder again with a small amount of macromolecule resin, the molten molten homogeneous system that is blended under the high temperature about temperature 165 degree Celsius forms plastomer, again granulation after the cooling;
Above-mentioned be separated into that mechanical type disperses and graft modification all is to finish in four tunnel convection current graft modification devices.
Be exclusively used in the machine of producing the environment-friendly materials plastomer and comprise pack into the condensing drying unit of inorganic powder of inside, what be connected with condensed type drying machine is four tunnel convection current graft modification devices, what be connected with four tunnel convection current graft modification devices is high temperature gravity-type synthesizer, what be connected with high temperature gravity-type synthesizer is the flexibility device of plasticating, and what plasticate that device is connected with flexibility is but prilling granulator of low-temperature air-cooling.
The graft modification agent is the compound carboxylic esters of aluminium titanium
Above-described only is the preferred implementation of a kind of environment-friendly materials plastomer of the present invention and production method and manufacturing processed; should be understood that; for the person of ordinary skill of the art; under the prerequisite that does not break away from the invention design; can also make some distortion and improvement, these all belong to protection scope of the present invention.
Claims (5)
1. an environment-friendly materials plastomer is characterized in that, this plastomer is that 70%～80% carbochain type inorganic powder and content are that 30%～20% macromolecule resin forms by content.
2. a kind of environment-friendly materials plastomer according to claim 1 is characterized in that, described carbochain type inorganic powder comprises inorganic powder and the compound carboxylic esters of aluminium titanium; With the compound carboxylic esters grafting of aluminium titanium and full close the surface that is adsorbed in inorganic powder and form the irreversible covalent chemical bond of peeling off.
3. make the production method of the described a kind of environment-friendly materials plastomer of claim 2, specific as follows:
(1) grafting of thermodynamics and chemistry;
The principle that application interface is learned under specified temp, through the compound carboxylic esters graft modification of aluminium titanium, plays bonding action with inorganic powder, and full closing is adsorbed in inorganic powder surface;
(2) the molten molten blend of physics;
Carbochain type inorganic powder again with a small amount of macromolecule resin, the molten molten homogeneous system that is blended under the high temperature about temperature 165 degree Celsius forms plastomer after the cooling;
(3) granulation formation.
4. make the manufacturing processed of the described a kind of environment-friendly materials plastomer of claim 2, concrete steps are as follows:
Hyperthermia drying: inorganic powder is transported in the kiln carry out heat to 190 first
0C～200
0C; Until with the inorganic powder complete drying;
Disperse: again the inorganic powder after the oven dry is carried out mechanical dispersion, reach the size of primary particle diameter;
Graft modification: then add the compound carboxylic esters of aluminium titanium and carry out graft modification;
Molten molten blend granulation: carbochain type inorganic powder again with a small amount of macromolecule resin, the molten molten homogeneous system that is blended under the high temperature about temperature 165 degree Celsius forms plastomer, again granulation after the cooling;
Above-mentioned be separated into that mechanical type disperses and graft modification all is to finish in four tunnel convection current graft modification devices.
5. the manufacturing processed of a kind of environment-friendly materials plastomer according to claim 4 is characterized in that described graft modification agent is the compound carboxylic esters of aluminium titanium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104578632A CN102911424A (en) | 2012-11-15 | 2012-11-15 | Environment-friendly material plastomer and production method and manufacturing process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104578632A CN102911424A (en) | 2012-11-15 | 2012-11-15 | Environment-friendly material plastomer and production method and manufacturing process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102911424A true CN102911424A (en) | 2013-02-06 |
Family
ID=47610017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012104578632A Pending CN102911424A (en) | 2012-11-15 | 2012-11-15 | Environment-friendly material plastomer and production method and manufacturing process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102911424A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266763A (en) * | 2017-04-26 | 2017-10-20 | 蒋建义 | A kind of Novel environment-friendlymaterial material thermoplasticity eutectic |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102277005A (en) * | 2011-07-07 | 2011-12-14 | 宋旭 | Highly-filled fully-biodegradable packaging material |
| CN102295793A (en) * | 2011-07-07 | 2011-12-28 | 宋旭 | Highly extended oxidation-degradable high-molecular packaging material and preparation method thereof |
| CN102765233A (en) * | 2012-08-06 | 2012-11-07 | 昆明钢铁控股有限公司 | Environment-friendly stone plate and preparation method thereof |
-
2012
- 2012-11-15 CN CN2012104578632A patent/CN102911424A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102277005A (en) * | 2011-07-07 | 2011-12-14 | 宋旭 | Highly-filled fully-biodegradable packaging material |
| CN102295793A (en) * | 2011-07-07 | 2011-12-28 | 宋旭 | Highly extended oxidation-degradable high-molecular packaging material and preparation method thereof |
| CN102765233A (en) * | 2012-08-06 | 2012-11-07 | 昆明钢铁控股有限公司 | Environment-friendly stone plate and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 山西省化工研究所: "《塑料橡胶加工助剂 第二版》", 31 October 2002, article "《塑料橡胶加工助剂 第二版》", pages: 576-578 * |
| 王琛等: "《高分子材料改性技术》", 30 April 2007, article "《高分子材料改性技术》", pages: 418-423 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266763A (en) * | 2017-04-26 | 2017-10-20 | 蒋建义 | A kind of Novel environment-friendlymaterial material thermoplasticity eutectic |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103980051B (en) | A kind of ureaformaldehyde humic acid organic fertilizer | |
| CN109370607A (en) | The modified production soil conditioner of gasifier slag humic acid and its soil improvement reparation application | |
| CN103113763A (en) | Method for modifying clay by using organic silicon micro-emulsion | |
| Song et al. | Fabrication of mechanical robust keratin film by mesoscopic molecular network reconstruction and its performance for dye removal | |
| CN108580526A (en) | A kind of method for comprehensively treating rubbish | |
| CN104403174A (en) | Environment-friendly controllable degradable film filled with high calcium carbonate | |
| CN103449688A (en) | Sludge processing method | |
| CN106065090A (en) | Caprolactone starch degradable thin film that a kind of polyvinyl alcohol strengthens and preparation method thereof | |
| CN105950184A (en) | Ecological agriculture and forestry soil sterilization and restoring treatment agent | |
| CN102911424A (en) | Environment-friendly material plastomer and production method and manufacturing process thereof | |
| Ye et al. | Hydrochar as an environment-friendly additive to improve the performance of biodegradable plastics | |
| CN105885116A (en) | Polylactic acid-caprolactone-starch extrusion blown film and preparation method thereof | |
| CN103524780B (en) | Poly extracting method in polyethylene white garbage | |
| CN107266763A (en) | A kind of Novel environment-friendlymaterial material thermoplasticity eutectic | |
| CN106111659A (en) | Utilize the method that bacillus firmus reduces incineration of refuse flyash Leaching | |
| Maiti et al. | Structural changes of starch/polyvinyl alcohol biocomposite films reinforced with microcrystalline cellulose due to biodegradation in simulated aerobic compost environment | |
| CN104231416A (en) | Degradable environment-friendly bag and production method thereof | |
| CN106810032A (en) | A kind of municipal sludge drying processing method | |
| CN102303415B (en) | The manufacture method of anti-acarid polyethylene light conveyer belt | |
| CN104327402A (en) | Waste high impact polystyrene modified material and preparation method thereof | |
| KR101032625B1 (en) | Oxidation and biodegradable material composition with a main component of sio2 inorganic substance and method for preparing thereof | |
| CN102807761A (en) | Gel and manufacturing process thereof | |
| CN104593115A (en) | Method for preparing artificial coal from household garbage and household sludge | |
| CN107955385A (en) | A kind of novel environment friendly packaging material | |
| CN106317473A (en) | Temperature-resistant caprolactone-grafted starch degradable film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130206 |