CN102899011B - Low-permeability reservoir water-lock releasing agent and preparation method thereof - Google Patents
Low-permeability reservoir water-lock releasing agent and preparation method thereof Download PDFInfo
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- CN102899011B CN102899011B CN201210460678.9A CN201210460678A CN102899011B CN 102899011 B CN102899011 B CN 102899011B CN 201210460678 A CN201210460678 A CN 201210460678A CN 102899011 B CN102899011 B CN 102899011B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000003921 oil Substances 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 34
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 10
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 10
- 239000011734 sodium Substances 0.000 claims abstract description 10
- WHKRHWSQMCFENF-UHFFFAOYSA-N [Si].OCCO Chemical compound [Si].OCCO WHKRHWSQMCFENF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 3
- -1 dodecyl Sodium Dicarboxylic Acids Chemical class 0.000 claims description 34
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 10
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- LCUMNKGLHJRIMH-UHFFFAOYSA-N 2-trimethylsilyloxyethanol Chemical class C[Si](C)(C)OCCO LCUMNKGLHJRIMH-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 4
- NNMXSGZHEJNVLB-UHFFFAOYSA-N C(C)[Si](CC)CC.C(CO)O Chemical compound C(C)[Si](CC)CC.C(CO)O NNMXSGZHEJNVLB-UHFFFAOYSA-N 0.000 claims description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- BRPNNYXZQLLLSN-UHFFFAOYSA-N sodium;dodecane Chemical compound [Na+].CCCCCCCCCCC[CH2-] BRPNNYXZQLLLSN-UHFFFAOYSA-N 0.000 claims description 2
- QXTIBZLKQPJVII-UHFFFAOYSA-N triethylsilicon Chemical compound CC[Si](CC)CC QXTIBZLKQPJVII-UHFFFAOYSA-N 0.000 claims description 2
- 239000012530 fluid Substances 0.000 abstract description 17
- 230000006378 damage Effects 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 6
- 230000035699 permeability Effects 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 4
- 239000013043 chemical agent Substances 0.000 abstract description 2
- 239000003209 petroleum derivative Substances 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000005086 pumping Methods 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 description 12
- 238000010992 reflux Methods 0.000 description 8
- 239000002826 coolant Substances 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000491 multivariate analysis Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001373 regressive effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- FCBUKWWQSZQDDI-UHFFFAOYSA-N rhamnolipid Chemical compound CCCCCCCC(CC(O)=O)OC(=O)CC(CCCCCCC)OC1OC(C)C(O)C(O)C1OC1C(O)C(O)C(O)C(C)O1 FCBUKWWQSZQDDI-UHFFFAOYSA-N 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
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Abstract
The invention discloses an oil field chemical agent used in petroleum gas oil-pumping operation construction, and particularly relates to a low-permeability reservoir water-lock releasing agent used in working fluid and a preparation method thereof. The low-permeability reservoir water-lock releasing agent consists of the following components in percentage by weight: 1 to 15 percent of glycol ether, 15 to 45 percent of didodecyl dicarboxylic sodium, 15 to 30 percent of ethylene glycol silicon ether and 30 to 60 percent of water. The preparation method comprises the following steps of: adding 30 to 60 percent of water into an enamel reaction kettle, starting a stirrer, and heating to raise the temperature to be between 30 and 40 DEG C; adding 1 to 15 percent of glycol ether and 15 to 45 percent of didodecyl dicarboxylic sodium into the reaction kettle, controlling the temperature and stirring for 1 hour; and adding 15 to 30 percent of ethylene glycol silicon ether into the reaction kettle, controlling the temperature to be between 40 and 80 DEG C, and reacting for 1 to 2 hours to obtain the water-lock releasing agent. The water-lock releasing agent is strong in surface activity and low in use level, can well maintain the permeability of a low-permeability reservoir and release water-lock damages, and is used in the working fluid such as fracturing fluid, perforating fluid, well control fluid and the like.
Description
Invention field
The present invention relates to the Oilfield Chemicals using in a kind of oil and gas oil producing operation construction, particularly a kind of low-permeability oil deposit Xie Shui lock agent and preparation method thereof, is mainly used in the working fluids such as fracturing liquid, perforating fluid and well control fluid.
Background technology
Low-permeability oil deposit generally has the features such as capillary pressure is high, water sensitivity is strong and pore throat is tiny, poor permeability, serious heterogeneity.In oil production process, working fluid is easy to occur water capillary imbibition, causes a large amount of working fluids to enter oil reservoir.The poor permeability of low-permeability oil deposit, the working fluid that causes invading oil reservoir returns row's difficulty, even can not the row of returning, form water blocking damage.Study and show both at home and abroad, water blocking damage is main, the most serious type of injury of low-permeability oil deposit, and damaging factor is generally 70%~90%, once come to harm, it is more difficult that oil reservoir perviousness is recovered, and long-term effect single well productivity, oil reservoir production efficiency increase cost of development.
The earliest, the main natural gas pool aspect of concentrating of water blocking damage research that people carry out, in recent years along with development of low-permeability oil reservoir, people have strengthened the research to oil reservoir water blocking damage mechanism, extent of injury prediction aspect.As D.B.Bennion etc. thinks, liquid phase is assembled and is detained in hydrocarbon-bearing pool is the principal element of water blocking damage, and rate of permeation is lower, affects more serious; Li Shubai is studied the Forecasting Methodology of liquid phase trap infringement with multivariate analysis in regressive, has set up the functional relation between liquid phase trap harmful penetrance recovery value and reservoir permeability and porosity.
Along with the progressively intensification of people to water blocking damage understanding, to strengthen understanding the development except water blocking damage chemical agent, portioned product has carried out rig-site utilization, and effect is comparatively remarkable.The disclosed patent WO of U.S. CONOCOPHILLIPS CO, 2004096940[P] be a kind of water lock agent for releasing of hydrocarbon-containifirst tensio-active agent; The disclosed patent MX of U.S. UNIV TEXAS, 2009010142[P] relate to a kind of oil well Xie Shui lock agent and process the method for hydrocarbonaceous petroclastic rock.The people such as Xue Yuzhi develop sulfonated petro-leum, rhamnolipid and sodium carbonate compound system [< < Drilling and completion fluids > > 2009, Vol.26 No.6], can effectively improve the perviousness of Pinghu Oil and Gas Field low permeability reservoir; Ma Hongxing develops PWA water blocking damage treating agent [< < oil-gas geology and recovery ratio > > 2005 for chengdao oilfield low pressure well, Vol.26 No.4], well prevent and remove water block effect.
Rig-site utilization shows, the Xie Shui lock agent of single type is difficult to take into account the factors such as geology, reservoir condition and construction technology of low-permeability oil deposit, removes water blocking damage effect undesirable, is of limited application.Therefore, the Xie Shui lock agent that research and development are formed by two or more surfactant compound becomes trend, to improve the immunity from interference of Xie Shui lock agent, expands its range of application.
Summary of the invention
The present invention is difficult to take into account the factors such as geology, reservoir condition and construction technology of low-permeability oil deposit in order to solve the Xie Shui lock agent of single type, remove water blocking damage effect undesirable, the technical problem such as be of limited application, it is strong that the present invention one is to provide a kind of surfactivity, make working fluid return row easily, can efficient solution remove water blocking damage, maintain the infiltrative low-permeability oil deposit Xie Shui lock agent of oil reservoir; Two are to provide the preparation method of a kind of low-permeability oil deposit Xie Shui lock agent.
Solve the problems of the technologies described above by the following technical solutions: the agent of a kind of low-permeability oil deposit Xie Shui lock, it is characterized in that: described low-permeability oil deposit Xie Shui lock agent comprises glycol ether, two dodecyl Sodium Dicarboxylic Acid, ethylene glycol silicon ether and water with raw material, by mass percentage, glycol ether 1~15%, two dodecyl Sodium Dicarboxylic Acids 15~45%, ethylene glycol silicon ether 5~30%, water 30~60%, described glycol ether is a kind of of ethylene glycol monobutyl ether, diethylene glycol ether, Polyethylene glycol dimethyl ether; Described two dodecyl Sodium Dicarboxylic Acids are N, N'-bis-(dodecyl) quadrol base dipropionic acid, N, N'-bis-(dodecyl) quadrol base sodium diacelate, N, N'-bis-(dodecyl) butanediamine base dipropionic acid, N, N'-bis-(dodecyl) butanediamine base sodium diacelate a kind of; Described ethylene glycol silicon ether is a kind of of ethylene glycol trimethylsilyl ethers, ethylene glycol triethyl silicon ether, polyoxyethylene glycol trimethylsilyl ethers, polyoxyethylene glycol triethyl silicon ether.
A preparation method for low-permeability oil deposit Xie Shui lock agent, the device that described method is used comprises reactor stirrer, it is characterized in that, its preparation method comprises the steps: mass percent meter, in enamel reaction still, add 30~60% water, start stirrer, water is heated to 30~40 ℃; Then in reactor, add 1~15% glycol ether, 15~45% pairs of dodecyl Sodium Dicarboxylic Acids, temperature control stirring 1h; And then add 15~30% ethylene glycol silicon ethers, and controlling temperature at 40~80 ℃, reaction 1~2h obtains Xie Shui lock agent finished product.
Adopt technique scheme, compared with prior art, low-permeability oil deposit Xie Shui lock provided by the invention agent mainly contains three kinds of active ingredients: two dodecyl Sodium Dicarboxylic Acids, ethylene glycol silicon ether, glycol ether.Two dodecyl Sodium Dicarboxylic Acids are a kind of Gemini surface active agent (Gemini Surfactants), have high surfactivity, and water-soluble better.Ethylene glycol silicon ether is a kind of organic silicon ether type tensio-active agent, has good synergistic effect with two dodecyl Sodium Dicarboxylic Acids.Glycol ether is Xie Shui lock agent active ingredient, can improve again the water-soluble of two dodecyl Sodium Dicarboxylic Acids, reduces the cloud point of Xie Shui lock agent.A kind of low-permeability oil deposit Xie Shui lock agent surfactivity the present invention relates to is strong, makes working fluid return row easily, can efficient solution remove water blocking damage, maintains the perviousness of oil reservoir.Its significant effect is: preparation method's science of the present invention, the product surface obtaining is active by force, consumption is few, strong adaptability, applied range.Can be used for the many kinds of measures operation in natural petroleum gas field process, in the working fluids such as fracturing liquid, perforating fluid, well control fluid.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described.
embodiment 1
The present embodiment discloses a kind of low-permeability oil deposit Xie Shui lock agent and preparation method thereof, this low-permeability oil deposit Xie Shui locks agent by mass: by 50 g butyl glycol ethers, and 90g N, N'-bis-(dodecyl) quadrol base dipropionic acid, 70g ethylene glycol triethyl silicon ether, 160g distilled water forms.Concrete preparation method is:
In the four-hole 500ml flask with reflux condensing tube, thermometer, dropping funnel, add 160g distilled water, put into stirring magneton, flask is put on the magnetic stirrer with electric mantle, open magnetic stirrer, open heater switch, temperature is controlled at 30~40 ℃, opens the water coolant of reflux condensing tube; Add 50 g butyl glycol ethers, then add 90g N, N'-bis-(dodecyl) quadrol base dipropionic acid, reaction 1h.Add 70g ethylene glycol triethyl silicon ether, control temperature at 70~80 ℃, reaction 1~2h, obtains a kind of low-permeability oil deposit and locks agent with Xie Shui.
embodiment 2
The present embodiment discloses a kind of low-permeability oil deposit Xie Shui lock agent and preparation method thereof, the agent of this low-permeability oil deposit Xie Shui lock is by adding 50 g methoxypolyethylene glycols by mass, 115g N, N'-bis-(dodecyl) quadrol base sodium diacelate, 56g ethylene glycol trimethylsilyl ethers, 140g distilled water forms.Concrete preparation method is:
In the four-hole 500ml flask with reflux condensing tube, thermometer, dropping funnel, add 140g distilled water, put into stirring magneton, flask is put on the magnetic stirrer with electric mantle, open magnetic stirrer, open heater switch, temperature is controlled at 30~40 ℃, opens the water coolant of reflux condensing tube; Add 50 g methoxypolyethylene glycols, then add 115g N, N'-bis-(dodecyl) quadrol base sodium diacelate, reaction 1h.Add 56g ethylene glycol trimethylsilyl ethers, control temperature at 65~75 ℃, reaction 1~2h, obtains a kind of low-permeability oil deposit and locks agent with Xie Shui.
embodiment 3
The present embodiment discloses a kind of low-permeability oil deposit Xie Shui lock agent and preparation method thereof, the agent of this low-permeability oil deposit Xie Shui lock is by 35 g diethylene glycol ethers by mass, 80g N, N'-bis-(dodecyl) butanediamine base dipropionic acid, 75g polyoxyethylene glycol trimethylsilyl ethers, 150g distilled water forms.Concrete preparation method is:
In the four-hole 500ml flask with reflux condensing tube, thermometer, dropping funnel, add 150g distilled water, put into stirring magneton, flask is put on the magnetic stirrer with electric mantle, open magnetic stirrer, open heater switch, temperature is controlled at 30~40 ℃, opens the water coolant of reflux condensing tube; Add 35 g diethylene glycol ethers, then add 80g NN ˊ – Shi bis-Wan Ji – quadrol base dipropionic acid, reaction 1h.Add 75g polyoxyethylene glycol trimethylsilyl ethers, control temperature at 65~75 ℃, reaction 1~2h, obtains a kind of low-permeability oil deposit and locks agent with Xie Shui.
embodiment 4
The present embodiment discloses a kind of low-permeability oil deposit Xie Shui lock agent and preparation method thereof, the agent of this low-permeability oil deposit Xie Shui lock is by 55 g ethylene glycol monobutyl ethers by mass, 95gN, N'-bis-(dodecyl) quadrol base sodium diacelate, 75g ethylene glycol trimethylsilyl ethers, 150g distilled water forms, and concrete preparation method is:
By mass: in the four-hole 500ml flask with reflux condensing tube, thermometer, dropping funnel, add 150g distilled water, put into stirring magneton, flask is put on the magnetic stirrer with electric mantle, open magnetic stirrer, open heater switch, temperature is controlled at 30~40 ℃, opens the water coolant of reflux condensing tube; Add 55 g ethylene glycol monobutyl ethers, then add 95gN, N'-bis-(dodecyl) quadrol base sodium diacelate, reaction 1~2h.Add 75g ethylene glycol trimethylsilyl ethers, control temperature at 65~75 ℃, reaction 1~2h, obtains a kind of low-permeability oil deposit and locks agent with Xie Shui.
Disclosed is above only specific embodiments of the invention; although the present invention discloses as above with preferred embodiment; but the present invention is not limited thereto; the changes that any person skilled in the art can think of; within not departing from design philosophy of the present invention and scope; the present invention is carried out to various changes and retouching, within all protection scope of the present invention should being dropped on.
Claims (2)
1. low-permeability oil deposit Xie Shui lock agent, it is characterized in that: described low-permeability oil deposit Xie Shui lock agent comprises glycol ether, two dodecyl Sodium Dicarboxylic Acid, ethylene glycol silicon ether and water with raw material, by mass percentage, glycol ether 1~15%, two dodecyl Sodium Dicarboxylic Acids 15~45%, ethylene glycol silicon ether 5~30%, water 30~60%, described glycol ether is a kind of of ethylene glycol monobutyl ether, diethylene glycol ether, Polyethylene glycol dimethyl ether; Described two dodecyl Sodium Dicarboxylic Acids are N, N'-bis-(dodecyl) quadrol base dipropionic acid, N, N'-bis-(dodecyl) quadrol base sodium diacelate, N, N'-bis-(dodecyl) butanediamine base dipropionic acid, N, N'-bis-(dodecyl) butanediamine base sodium diacelate a kind of; Described ethylene glycol silicon ether is a kind of of ethylene glycol trimethylsilyl ethers, ethylene glycol triethyl silicon ether, polyoxyethylene glycol trimethylsilyl ethers, polyoxyethylene glycol triethyl silicon ether.
2. the preparation method of low-permeability oil deposit Xie Shui as claimed in claim 1 lock agent, the device that described method is used comprises reactor stirrer, it is characterized in that, its preparation method comprises the steps: mass percent meter, in enamel reaction still, add 30~60% water, start stirrer, water is heated to 30~40 ℃; Then in reactor, add 1~15% glycol ether, 15~45% pairs of dodecyl Sodium Dicarboxylic Acids, temperature control stirring 1h; And then add 15~30% ethylene glycol silicon ethers, and controlling temperature at 40~80 ℃, reaction 1~2h obtains Xie Shui lock agent finished product.
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CN104449631B (en) * | 2014-11-25 | 2016-02-24 | 中国石油大学(华东) | Strong gas wettability nano silicon Xie Shui locks the method for agent, its preparation method and rock surface wettability reversal |
CN105214557A (en) * | 2015-10-28 | 2016-01-06 | 北京工商大学 | A kind of N-alkyl aminopropionic acid type Gemini surface active agent and method for making |
CN107986981B (en) * | 2017-11-23 | 2020-02-18 | 中国石油大学(华东) | Gemini gas-wet reversal agent compound and preparation method and application thereof |
CN108485616B (en) * | 2018-03-26 | 2020-09-08 | 中国石油天然气集团有限公司 | Environment-friendly organic silicon waterproof locking agent for drilling fluid and preparation method and application thereof |
CN109181669A (en) * | 2018-10-18 | 2019-01-11 | 陕西新奥石油工程有限公司 | A kind of mating medicament and technique releasing reservoir water lock, blocking |
CN111978933B (en) * | 2019-05-21 | 2022-09-09 | 中石化南京化工研究院有限公司 | Waterproof lock composition for oil field and application thereof |
CN110669486A (en) * | 2019-10-10 | 2020-01-10 | 北京大德广源石油技术服务有限公司 | Enhanced gas production material for comprehensive treatment of gas well and preparation method thereof |
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