CN102888180A - Antimicrobial ultraviolet-curing paint and preparation method thereof - Google Patents
Antimicrobial ultraviolet-curing paint and preparation method thereof Download PDFInfo
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- CN102888180A CN102888180A CN2012103793078A CN201210379307A CN102888180A CN 102888180 A CN102888180 A CN 102888180A CN 2012103793078 A CN2012103793078 A CN 2012103793078A CN 201210379307 A CN201210379307 A CN 201210379307A CN 102888180 A CN102888180 A CN 102888180A
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Abstract
The invention discloses an antimicrobial ultraviolet-curing paint and a preparation method thereof. The paint is prepared by mixing polyurethane acrylate, active acrylate monomer, initiator, leveling agent, special antimicrobial agent and diluter. The preparation method comprises the steps of proportioning, dispersing and conditioning. According to the antimicrobial ultraviolet-curing paint, the high-activity high-reaction-speed polyurethane acrylate is used as the main component and carrier, the special antimicrobial agent and ultraviolet initiator are used as curing agents, the leveling agent is used as an auxiliary material, and the active acrylate monomer and diluter are used as viscosity modifiers, so that the ultraviolet-curing paint has antibacterial action.
Description
Technical field
The present invention relates to paint field, particularly a kind of ultraviolet light polymerization UV coating and preparation method thereof.
Background technology
Along with the progress of science and technology and the raising of people's living standard, in daily life, people use the electronic product as mobile phone so more and more.In recent years, there is related data to point out that daily electronic product contacts with the people for a long time, has bacterium and on electronic product, constantly grow breeding, by the final human body that infects of people's frequent contact, jeopardize HUMAN HEALTH.Therefore, has the coating technology operation of antibacterial and giving birth to.Common antibiotic paint great majority are to add sterilant on original basis on the market, and its disadvantage is toxic, dangerous, easy stripping, poor durability.1), the solvent-borne type photo-cured coating the common antibiotic paint that is used for electronic product has following two kinds:, its shortcoming is behind film-forming, and antibacterial ability is destroyed, without any fungi-proofing, antibacterial ability.2) although, aqueous product also has certain antibacterial bacteriostatic ability, after film forming, the antibacterial bacteriostatic ability can reduce rapidly or lose antibacterial ability fully, antibacterial ability is very limited.
In order to improve people's safety in utilization.In the urgent need to a kind of coating with antibacterial sterilization effect.
Summary of the invention
The purpose of this invention is to provide a kind of antibacterial ultraviolet-curable coating and preparation method thereof, this coating and preparation method can carry out antibacterial sterilization for a long time, effectively, and people are had provide protection.
Another object of the present invention is to provide a kind of antibacterial ultraviolet-curable coating and preparation method thereof,, this coating and preparation method are harmless, and curing speed is fast, and has efficient, environmental protection, the advantage such as energy-conservation.
For achieving the above object, the objective of the invention is to realize by following technique means.
A kind of antibacterial ultraviolet-curable coating, it is to be mixed by following component: in weight ratio, polyfunctionality urethane acrylate 30-70 part, initiator 3-5 part, flow agent 1-2 part, active acrylate's monomer 10-30 part, and antiseptic-germicide 5-10 part, thinner 30-50 part.
As preferably, described polyfunctionality urethane acrylate is the arbitrary combination of any two or three in four functionality urethane acrylates, three-functionality-degree urethane acrylate, the two functionality urethane acrylates, according to any resize ratio of hardness requirement, do not affect final anti-microbial property.
As preferably, described initiator is 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-methyl phenyl-propane-1-ketone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, 2,2'-two Chloro-O-Phenyls-4,4', 5,5'-tetraphenyl-1, any one in the 2'-diimidazole or any two, or any three kinds arbitrary combination.
As preferably, described flow agent is that propylene is polymer-modified, the combination of any one or two kinds in the acrylate containing silicone.
As preferably, described active acrylate's monomer front three propane triacrylate (TMPTA), 1, any one in 6-hexanediyl ester, the vinylformic acid laurate or any two combination.
As preferably, described antiseptic-germicide is that inorganic nano material and organic additive are composited.Wherein, inorganic nano material is one or both combinations in nano titanium oxide, the nano phase ag_2 o; Auxiliary agent is titanate coupling agent.Inorganic nano material can mix according to arbitrary proportion with auxiliary agent.
As preferably, described thinner is the combination of any one or two kinds in Virahol, the ethyl acetate.
The preparation method of antibacterial ultraviolet-curable coating of the present invention, it is as follows that the method comprising the steps of:
(1), batching
But in the stirred vessel of a constant volume, add polyfunctionality urethane acrylate, 5-15 part active acrylate monomer, adopt stirring rake middling speed (300rpm-500rpm) to be stirred to evenly; Obtain ingredients mixture.
Require: the polyfunctionality urethane acrylate will dissolve fully.
(2), disperse
Dissolve initiator, flow agent fully with thinner 15-30 part, filter with 600 orders, then add in the ingredients mixture that obtains of step (1), obtain mixing solutions.
Require initiator, flow agent will must not dissolve fully that particle etc. is arranged.
(3), modified
Accurate weighing antiseptic-germicide, the active acrylate's monomer and the dilution of thinner 15-20 part that then add 5-15 part stir, and obtain mixture; Mixture is slowly added in the mixing solutions of step (2) with low speed 200-300rpm, stir, be the antibacterial ultraviolet photo-cured coating.
In the described batching step, the churning time of middling speed (300rpm-500rpm) is 15-30 minute; In the described modified step, the time that the 200-300rpm rotating speed stirs is 5-10 minute, stirs with assurance.
In the described modified step, when stirring simultaneously up and down upgrading stirring rake falls, guarantee system even up and down, the rear check product viscosity that stirs, property indices after solidifying namely obtains the antibacterial ultraviolet photo-cured coating.
Antibacterial ultraviolet-curable coating antibacterial ultraviolet photo-cured coating of the present invention, take the high speed of response urethane acrylate of high reactivity as main component and carrier, take special antiseptic-germicide and ultraviolet initiator as solidifying agent, take flow agent as auxiliary material, the solvent of environmental protection is thinner, active acrylate's monomer and thinner are viscosity modifier, thereby make the present invention have anti-microbial effect when forming ultraviolet-curing paint.Specifically, the present invention has the following advantages.
1, this coating belongs to the UV-light photocuring system, and is harmless, energy-conservation, is Green Product.
2, this product do not contain heavy metal, without chlorine, without benzene, can detect by SGS and the ROSH of European Union.
3, do not affect other physics and chemistry performance of photocuring paint film.
4, can satisfy the production technique industrial requirement, realize high efficiency production.
Embodiment
The invention will be further described below in conjunction with example, but should understand these examples is not to limit the scope of the invention, in the situation that without prejudice to the spirit and scope of the present invention, art technology people can make changes and improvements so that it is fit to different service conditions, different conditions and embodiment to the present invention.
The antibacterial ultraviolet photo-cured coating that the present invention realizes, as main component and carrier take the high speed of response urethane acrylate of high reactivity, take special antiseptic-germicide and ultraviolet initiator as solidifying agent, take flow agent as auxiliary material, environmentally friendly solvent is thinner, and active acrylate's monomer and solvent are viscosity modifier.In weight ratio, polyfunctionality urethane acrylate 30-70 part, initiator 3-5 part, flow agent 1-2 part, active acrylate's monomer 10-30 part, antiseptic-germicide 5-10 part, thinner 30-50 part.Its production technique comprises batching, dispersion, modified three phases.
Wherein, the polyfunctionality urethane acrylate is any two kinds combination in four functionality urethane acrylates, three-functionality-degree urethane acrylate, the two functionality urethane acrylates or three kinds arbitrary combination.For having high rigidity, the product of the physical property such as endurance, sticking power, levelling property, gloss, the viscosity 50 of polyfunctionality urethane acrylate, 000mps/30 ℃, chromatic number is less than 1.
Wherein, initiator is selected from-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-methyl phenyl-propane-1-ketone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, 2,2'-two Chloro-O-Phenyls-4,4', 5,5'-tetraphenyl-1, any one in the 2'-diimidazole or any two, or even any three kinds combination, or this arbitrary combination of four kinds.
Wherein, flow agent be selected from that propylene is polymer-modified, the arbitrary combination of any one or two kinds in the acrylate containing silicone.
Wherein, active acrylate's monomer is selected from active acrylate's monomer front three propane triacrylate (TMPTA), 1, any one in 6-hexanediyl ester, the vinylformic acid laurate or the combination of any two.
Wherein, antiseptic-germicide is that inorganic nano material and organic additive are composited.Wherein, inorganic nano material is one or both combinations in nano titanium oxide, the nano phase ag_2 o; Auxiliary agent is titanate coupling agent.
Wherein, thinner is the arbitrary combination of any one or two kinds in Virahol, the ethyl acetate.
Embodiment one.
(1), batching.
In the opening scuffing of cylinder bore that stirs of a constant volume, add 30 parts of polyfunctionality urethane acrylates, 5 parts of active acrylate's monomers, middling speed 300rpm stir 15 minutes to evenly, obtain ingredients solution.
(2), disperse.
Add light inlet and draw 1 part of 3 parts of agent and flow agent, after 15 parts of dissolvings of thinner, filter in the ingredients solution that adds again step (1) with 600 orders and to stir 10 minutes, obtain mixing solutions, require initiator, flow agent will fully dissolve noresidue particle etc.
(3), modified.
Accurately 5 parts of weighing antiseptic-germicides (are made in advance, are usually adopted inorganic nano material and organic additive to be composited.Wherein, inorganic nano material is the arbitrary combination of any one or two kinds in nano titanium oxide, the nano phase ag_2 o; Auxiliary agent is titanate coupling agent, and inorganic nano material can mix according to arbitrary proportion with auxiliary agent.), and add 5 parts of active acrylate's monomers and 15 parts of thinners, mixing solutions is slowly added with the 200rpm rotating speed, at the uniform velocity stirred simultaneously oscilaltion stirring rake, guarantee system even up and down 5 minutes.At last, by property indices after check product viscosity, the curing, be the antibacterial ultraviolet photo-cured coating.
Embodiment two.
(1), batching.
In the opening scuffing of cylinder bore that stirs of a constant volume, add 50 parts of urethane acrylates, 8 parts of active acrylate's monomers, middling speed 400rpm stir 17 minutes to evenly, obtain ingredients solution.
(2), disperse.
Add light inlet and draw 1.5 parts of 4 parts of agent and flow agents, after 15 parts of dissolvings of thinner, filter in the ingredients solution that adds again step (1) with 600 orders and to stir 15 minutes, obtain mixing solutions, require initiator, flow agent will fully dissolve noresidue particle etc.
(3), modified.
Accurately 7.5 parts of weighing antiseptic-germicides (are made in advance, are usually adopted inorganic nano material and organic additive to be composited.Wherein, inorganic nano material is the arbitrary combination of any one or two kinds in nano titanium oxide, the nano phase ag_2 o; Auxiliary agent is titanate coupling agent, and inorganic nano material can mix according to arbitrary proportion with auxiliary agent.), and add 7 parts of active acrylate's monomers and 25 parts of solvent cuts, mixing solutions is slowly added with the 250rpm rotating speed, at the uniform velocity stirred simultaneously oscilaltion stirring rake, guarantee system even up and down 7 minutes.At last, by property indices after check product viscosity, the curing, be the antibacterial ultraviolet photo-cured coating.
Embodiment three.
(1), batching.
In the opening scuffing of cylinder bore that stirs of a constant volume, add 70 parts of urethane acrylates, 15 parts of active acrylate's monomers, middling speed 500rpm stir 20 minutes to evenly, obtain ingredients solution.
(2), disperse.
Light is drawn 2 parts of 5 parts of agent and flow agents, behind 30 parts of mixed dissolutions of thinner, filter in the ingredients solution that adds again step (1) with 600 orders and to stir 20 minutes, obtain mixing solutions, disperse to require: initiator, flow agent will fully dissolve the noresidue particle.
(3), modified.
Accurately 10 parts of weighing antiseptic-germicides (are made in advance, are usually adopted inorganic nano material and organic additive to be composited.Wherein, inorganic nano material is the arbitrary combination of any one or two kinds in nano titanium oxide, the nano phase ag_2 o; Auxiliary agent is titanate coupling agent, and inorganic nano material can mix according to arbitrary proportion with auxiliary agent.), and add 15 parts of functional acrylate reactive monomers and 20 parts of solvent cuts, mixing solutions is slowly added with the 300rpm rotating speed, at the uniform velocity stirred simultaneously oscilaltion stirring rake, guarantee system even up and down 10 minutes.At last, by property indices after check product viscosity, the curing, be the antibacterial ultraviolet photo-cured coating.
Above-mentioned prescription is at 600-800mj/cm
23-5 solidifies second under the energy, and antibacterial ultraviolet photo-cured coating performance index are as follows.
Sticking power test (3M adhesive tape, the test of hundred lattice): 100%.
Hardness test: the H of Mitsubishi pencil, 1Kgf 1 HB surface is without obvious cut.
RCA is wear-resisting: RCA paper tape, 175G power＞600 time.
Cold cycling :-40 ℃ 2 hours ,+80 ℃ 2 hours be a circulation, 8 circulations.Adhere to outward appearance unchanged.
Anti-makeup: be coated with large precious SOD honey, put 48 hours at hot and humid case, adhere to outward appearance unchanged.
Water boiling resistance: 100 ℃ are boiled 2 hours, unchanged, adhere to 100%.
The artificial perspiration resistance: emerging standard in the reference, outward appearance is unchanged, adheres to＞4B.
In sum; antibacterial ultraviolet photo-cured coating curing speed of the present invention is fast, chemical resistance good, extensively the above only is preferred embodiment of the present invention to suitability; not in order to limit the present invention; all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. antibacterial ultraviolet-curable coating, it is to be mixed by following component: in weight ratio, polyfunctionality urethane acrylate 30-70 part, initiator 3-5 part, flow agent 1-2 part, active acrylate's monomer 10-30 part, and antiseptic-germicide 5-10 part, thinner 30-50 part.
2. antibacterial ultraviolet-curable coating according to claim 1 is characterized in that described polyfunctionality urethane acrylate is the arbitrary combination of any two or three in four functionality urethane acrylates, three-functionality-degree urethane acrylate, the two functionality urethane acrylates.
3. antibacterial ultraviolet-curable coating according to claim 1, it is characterized in that described initiator is 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-methyl phenyl-propane-1-ketone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, 2,2'-two Chloro-O-Phenyls-4,4', 5,5'-tetraphenyl-1, any one in the 2'-diimidazole or any two, or any three kinds arbitrary combination.
4. antibacterial ultraviolet-curable coating according to claim 1 is characterized in that flow agent is that propylene is polymer-modified, the combination of any one or two kinds in the acrylate containing silicone.
5. described antibacterial ultraviolet-curable coating according to claim 1 is characterized in that described active acrylate's monomer front three propane triacrylate, 1, any one in 6-hexanediyl ester, the vinylformic acid laurate or any two combination.
6. antibacterial ultraviolet-curable coating according to claim 1 is characterized in that, described antiseptic-germicide is inorganic nano material and organic additive is compound forms according to arbitrary proportion.
7. antibacterial ultraviolet-curable coating according to claim 1 is characterized in that thinner is the arbitrary combination of any one or two kinds in Virahol, the ethyl acetate.
8. the preparation method of an antibacterial ultraviolet-curable coating is characterized in that the method comprises the steps:
(1), batching
But in the stirred vessel of a constant volume, add polyfunctionality urethane acrylate, 5-15 part active acrylate monomer, adopt the stirring rake middling speed to be stirred to evenly; Obtain ingredients mixture;
(2), disperse
Dissolve initiator, flow agent fully with 15-30 part thinner, and filter with 600 orders, then add in the ingredients mixture that step (1) obtains, obtain mixing solutions;
(3), modified
Accurate weighing antiseptic-germicide, the active acrylate's monomer and the dilution of 15-20 part thinner that then add 5-15 part stir, and obtain mixture; Mixture is slowly added in the mixing solutions of step (2) with low speed 200-300rpm rotating speed, stir, be the antibacterial ultraviolet photo-cured coating.
9. the preparation method of a kind of antibacterial ultraviolet-curable coating according to claim 1 is characterized in that in the described batching step, and middling speed is 300rpm-500rpm, and churning time is 15-30 minute; In the described modified step, low speed is the 200-300rpm rotating speed, and the time of stirring is 5-10 minute, stirs with assurance.
10. the preparation method of a kind of antibacterial ultraviolet-curable coating according to claim 1 is characterized in that in the described modified step, when stirring simultaneously up and down upgrading stirring rake falls, guarantee system even up and down.
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