CN102888179A - Oil-resisting and alkali-resisting metal anti-rust paint and preparation method thereof - Google Patents
Oil-resisting and alkali-resisting metal anti-rust paint and preparation method thereof Download PDFInfo
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- CN102888179A CN102888179A CN2012103407699A CN201210340769A CN102888179A CN 102888179 A CN102888179 A CN 102888179A CN 2012103407699 A CN2012103407699 A CN 2012103407699A CN 201210340769 A CN201210340769 A CN 201210340769A CN 102888179 A CN102888179 A CN 102888179A
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- 239000003973 paint Substances 0.000 title claims abstract description 48
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 title abstract description 3
- 239000002184 metal Substances 0.000 title abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims description 25
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- 239000004113 Sepiolite Substances 0.000 claims description 14
- 229910052624 sepiolite Inorganic materials 0.000 claims description 14
- 235000019355 sepiolite Nutrition 0.000 claims description 14
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000004576 sand Substances 0.000 claims description 12
- 238000004537 pulping Methods 0.000 claims description 11
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Diphosphoinositol tetrakisphosphate Chemical compound OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- -1 cyclopentenyl ethoxyl methyl Chemical group 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 5
- QUKFNRQNPQSTPD-UHFFFAOYSA-N 2-methylpropanoic acid;pentane-1,3-diol Chemical compound CC(C)C(O)=O.CCC(O)CCO QUKFNRQNPQSTPD-UHFFFAOYSA-N 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 239000012188 paraffin wax Substances 0.000 claims description 5
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 5
- 229920005749 polyurethane resin Polymers 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 abstract description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 238000006748 scratching Methods 0.000 abstract 1
- 230000002393 scratching effect Effects 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000005477 standard model Effects 0.000 description 1
Abstract
The invention discloses oil-resisting and alkali-resisting metal anti-rust paint and a preparation method thereof. The anti-rust paint is prepared from slurrying raw materials and paint mixing raw materials; a paint film formed by the anti-rust paint has high hardness, scratching resistance, strong adhesion, salt fog resistance, saline resistance, acid-base resistance, water resistance, and oil resistance; the paint can be used on the surface of an old paint film repeatedly; the damage to the paint film can be avoided; and super strong toughness of the paint film can be achieved. The service life of the paint film can reach 8 to 10 years generally.
Description
Technical field
The present invention relates to a kind of metallic anti-rust paint, specifically the alkaline-resisting metallic anti-rust paint of a kind of oil resistant.
Background technology
Various mechanical means appearances all need apply the layer of metal lacquer, and one side increases attractive in appearance, on the other hand dustproof rust resistance and corrosion resistance; Rust-inhibiting paint of the prior art produces poisonous, harmful in a large number volatile gases because containing a large amount of volatile organic solvents, polluted air and infringement human health.The aqueous rustproof lacquer is subject to people's concern and welcome because pollution is little.But aqueous rustproof lacquer ubiquity weather resistance is not good, easily comes off, inadaptable complicated, severe environment.
Summary of the invention
The invention provides alkaline-resisting metallic anti-rust paint of a kind of oil resistant and preparation method thereof, have good mechanical stability, snappiness and surface hardness, good weatherability.
Technical scheme of the present invention is:
The alkaline-resisting metallic anti-rust paint of a kind of oil resistant is characterized in that being made by the feed composition of following ingredients weight parts:
Pulping raw material:
Aluminium powder 3-8,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 5-10, anti-sedimentation agent 3300S 1-2, flow agent BYK-300 1-2, paraffin wax emulsions 5-10, magnesium hydroxide 10-15, dispersing agent MF 1-2, LBCB-1 thixotroping lubricant 1-2, sodium base bentonite 1-2, aluminium triphosphate 1-2, modified Nano sepiolite powder 5-10, modified soluble nano silicone colloidal sol 5-10;
The paint raw material:
Waterborne polyurethane resin 20-25, water-based fluorocarbon resin 10-15, myo-Inositol hexaphosphate 20-25, propylene glycol 50-60, double cyclopentenyl ethoxyl methyl acrylate 5-10, heavy alkylbenzene sulfonate 3-5, carboxymethyl cellulose 10-15,2-amino-2-methyl-1-propanol 1-2;
The modified Nano sepiolite powder prepares by the following method:
(1), sepiolite powder adds (0.8～1.2) g/L potassium permanganate solution and soaked 2-3 hour, pulls out, is washed to neutrality, the sodium radio-phosphate,P-32 solution of putting into again 2-5% soaked, at 60-80 ℃ of lower stirring reaction 3-4 hour;
(2), in soak solution, add 3-4% sodium laurylsulfate, 1-2% Di(dioctylpyrophosphato) ethylene titanate, 2-3% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20-25% ferrophosphorus powder that is equivalent to sepiolite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) oven dry is pulverized, and makes ultrafine powder;
Modified soluble nano silicone colloidal sol prepares by the following method:
The water-soluble nano grade silica sol adds 4-5% nano-carbon powder, 3-5% ferric oxide, is mixed and heated to 50-60 ℃, cooling after 30-40 minute.
The alkaline-resisting metallic anti-rust paint of described oil resistant is characterized in that being made by the feed composition of following ingredients weight parts:
Pulping raw material:
Aluminium powder 5,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 8, anti-sedimentation agent 3300S 2, flow agent BYK-300 2, paraffin wax emulsions 8, magnesium hydroxide 12, dispersing agent MF 2, LBCB-1 thixotroping lubricant 2, sodium base bentonite 1, aluminium triphosphate 2, modified Nano sepiolite powder 6, modified soluble nano silicone colloidal sol 6;
The paint raw material:
Waterborne polyurethane resin 25, water-based fluorocarbon resin 12, myo-Inositol hexaphosphate 25, propylene glycol 55, double cyclopentenyl ethoxyl methyl acrylate 5, heavy alkylbenzene sulfonate 4, carboxymethyl cellulose 12,2-amino-2-methyl-1-propanol 2.
The preparation method of the alkaline-resisting metallic anti-rust paint of described oil resistant is characterized in that may further comprise the steps:
(1), slurrying: pour pulping raw material into batching kettle and mix, then mixed pulping raw material is transported in the high-speed dispersing kettle and stirs, disperse 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after the dispersion is transported to carries out the wet type sand milling in the sand mill, disperse, obtain slurry, the slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add the paint raw material in the slurry that makes, then be transported in the high-speed dispersing kettle and stir, disperse, being transported to of component carried out wet type sand milling, dispersion after disperseing in the sand mill, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) paint vehicle that makes is transported to vibrating filter and filters and screen, fineness≤40um, the product after then will filtering is packed, warehouse-in.
The paint film that rust-inhibiting paint of the present invention forms has hardness height, damage resistant, strong adhesion, and salt spray resistance, salt water resistance, acid and alkali-resistance, water-fast, oil resistant are reusable at old coating surface, can not cause the paint film damage, superpower paint film flexibility etc.The general paint film life-span can reach 8-10.
Embodiment
The alkaline-resisting metallic anti-rust paint of oil resistant, made by the feed composition of following ingredients weight parts (kilogram):
Pulping raw material:
Aluminium powder 5,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 8, anti-sedimentation agent 3300S 2, flow agent BYK-300 2, paraffin wax emulsions 8, magnesium hydroxide 12, dispersing agent MF 2, LBCB-1 thixotroping lubricant 2, sodium base bentonite 1, aluminium triphosphate 2, modified Nano sepiolite powder 6, modified soluble nano silicone colloidal sol 6;
The paint raw material:
Waterborne polyurethane resin 25, water-based fluorocarbon resin 12, myo-Inositol hexaphosphate 25, propylene glycol 55, double cyclopentenyl ethoxyl methyl acrylate 5, heavy alkylbenzene sulfonate 4, carboxymethyl cellulose 12,2-amino-2-methyl-1-propanol 2.
The modified Nano sepiolite powder prepares by the following method:
(1), sepiolite powder adds the 0.8g/L potassium permanganate solution and soaked 2 hours, pulls out, is washed to neutrality, put into again 5% sodium radio-phosphate,P-32 solution and soak, 60-70 ℃ of lower stirring reaction 4 hours;
(2), in soak solution, add 3% sodium laurylsulfate, 2% Di(dioctylpyrophosphato) ethylene titanate, 2% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20% ferrophosphorus powder that is equivalent to sepiolite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) oven dry is pulverized, and makes ultrafine powder;
Modified soluble nano silicone colloidal sol prepares by the following method:
The water-soluble nano grade silica sol adds 5% nano-carbon powder, 3% ferric oxide, and mix and blend is heated to 50-60 ℃, cooling after 30-40 minute.
The preparation method of the alkaline-resisting metallic anti-rust paint of oil resistant may further comprise the steps:
(1), slurrying: pour pulping raw material into batching kettle and mix, then mixed pulping raw material is transported in the high-speed dispersing kettle and stirs, disperse 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after the dispersion is transported to carries out the wet type sand milling in the sand mill, disperse, obtain slurry, the slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add the paint raw material in the slurry that makes, then be transported in the high-speed dispersing kettle and stir, disperse, being transported to of component carried out wet type sand milling, dispersion after disperseing in the sand mill, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) paint vehicle that makes is transported to vibrating filter and filters and screen, fineness≤40um, the product after then will filtering is packed, warehouse-in.Metallic anti-rust paint performance index of the present invention:
1, paint film color and outward appearance: smooth smooth, color conformance with standard model and aberration scope
2, (23 ± 1 ℃ are coated with-4 viscometers to viscosity, S): 80-120
3, fineness≤50
4, time of drying (25 ℃): surface drying 25-30min, do solid work 48h
5, snappiness mm≤2
6, hardness 〉=2H
7, high temperature resistant (130 ℃) 〉=450h
8, shock-resistance 50
9, salt spray resistance (120h level) 〉=2
10, water tolerance (29 ± 1 ℃ of 240h): non-foaming, do not come off
11, oil resistant (90# gasoline, 56h): non-foaming, do not come off
12, alkali resistance (GB/T9755-2001): by 48 hours
13, artificial weathering ageing resistance (GB/T9755-2001): by 1000 hours.
Claims (3)
1. alkaline-resisting metallic anti-rust paint of oil resistant is characterized in that being made by the feed composition of following ingredients weight parts:
Pulping raw material:
Aluminium powder 3-8,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 5-10, anti-sedimentation agent 3300S 1-2, flow agent BYK-300 1-2, paraffin wax emulsions 5-10, magnesium hydroxide 10-15, dispersing agent MF 1-2, LBCB-1 thixotroping lubricant 1-2, sodium base bentonite 1-2, aluminium triphosphate 1-2, modified Nano sepiolite powder 5-10, modified soluble nano silicone colloidal sol 5-10;
The paint raw material:
Waterborne polyurethane resin 20-25, water-based fluorocarbon resin 10-15, myo-Inositol hexaphosphate 20-25, propylene glycol 50-60, double cyclopentenyl ethoxyl methyl acrylate 5-10, heavy alkylbenzene sulfonate 3-5, carboxymethyl cellulose 10-15,2-amino-2-methyl-1-propanol 1-2;
The modified Nano sepiolite powder prepares by the following method:
(1), sepiolite powder adds (0.8～1.2) g/L potassium permanganate solution and soaked 2-3 hour, pulls out, is washed to neutrality, the sodium radio-phosphate,P-32 solution of putting into again 2-5% soaked, at 60-80 ℃ of lower stirring reaction 3-4 hour;
(2), in soak solution, add 3-4% sodium laurylsulfate, 1-2% Di(dioctylpyrophosphato) ethylene titanate, 2-3% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20-25% ferrophosphorus powder that is equivalent to sepiolite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) oven dry is pulverized, and makes ultrafine powder;
Modified soluble nano silicone colloidal sol prepares by the following method:
The water-soluble nano grade silica sol adds 4-5% nano-carbon powder, 3-5% ferric oxide, is mixed and heated to 50-60 ℃, cooling after 30-40 minute.
2. the alkaline-resisting metallic anti-rust paint of oil resistant according to claim 1 is characterized in that being made by the feed composition of following ingredients weight parts:
Pulping raw material:
Aluminium powder 5,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 8, anti-sedimentation agent 3300S 2, flow agent BYK-300 2, paraffin wax emulsions 8, magnesium hydroxide 12, dispersing agent MF 2, LBCB-1 thixotroping lubricant 2, sodium base bentonite 1, aluminium triphosphate 2, modified Nano sepiolite powder 6, modified soluble nano silicone colloidal sol 6;
The paint raw material:
Waterborne polyurethane resin 25, water-based fluorocarbon resin 12, myo-Inositol hexaphosphate 25, propylene glycol 55, double cyclopentenyl ethoxyl methyl acrylate 5, heavy alkylbenzene sulfonate 4, carboxymethyl cellulose 12,2-amino-2-methyl-1-propanol 2.
3. the preparation method of the alkaline-resisting metallic anti-rust paint of oil resistant according to claim 1 is characterized in that may further comprise the steps:
(1), slurrying: pour pulping raw material into batching kettle and mix, then mixed pulping raw material is transported in the high-speed dispersing kettle and stirs, disperse 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after the dispersion is transported to carries out the wet type sand milling in the sand mill, disperse, obtain slurry, the slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add the paint raw material in the slurry that makes, then be transported in the high-speed dispersing kettle and stir, disperse, being transported to of component carried out wet type sand milling, dispersion after disperseing in the sand mill, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) paint vehicle that makes is transported to vibrating filter and filters and screen, fineness≤40um, the product after then will filtering is packed, warehouse-in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210340769.9A CN102888179B (en) | 2012-09-15 | 2012-09-15 | Alkaline-resisting metallic anti-rust paint of a kind of oil resistant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210340769.9A CN102888179B (en) | 2012-09-15 | 2012-09-15 | Alkaline-resisting metallic anti-rust paint of a kind of oil resistant and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102888179A true CN102888179A (en) | 2013-01-23 |
| CN102888179B CN102888179B (en) | 2016-01-20 |
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| CN103497597A (en) * | 2013-09-23 | 2014-01-08 | 无锡阳工机械制造有限公司 | Anticorrosive coating agent for surface of steel sheet |
| CN105969181A (en) * | 2016-05-19 | 2016-09-28 | 陆玉如 | Anticorrosive paint for water pump boxes |
| CN107151502A (en) * | 2017-07-12 | 2017-09-12 | 合肥思博特软件开发有限公司 | A kind of electric power computer room noise elimination antirust paint and preparation method thereof |
| CN107286774A (en) * | 2017-07-11 | 2017-10-24 | 合肥康之恒机械科技有限公司 | A kind of sanitation truck high brightness reflectorized paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103497597A (en) * | 2013-09-23 | 2014-01-08 | 无锡阳工机械制造有限公司 | Anticorrosive coating agent for surface of steel sheet |
| CN103497597B (en) * | 2013-09-23 | 2015-09-16 | 无锡阳工机械制造有限公司 | A kind of anticorrosion coating agent of surface of steel plate |
| CN105969181A (en) * | 2016-05-19 | 2016-09-28 | 陆玉如 | Anticorrosive paint for water pump boxes |
| CN107286774A (en) * | 2017-07-11 | 2017-10-24 | 合肥康之恒机械科技有限公司 | A kind of sanitation truck high brightness reflectorized paint and preparation method thereof |
| CN107151502A (en) * | 2017-07-12 | 2017-09-12 | 合肥思博特软件开发有限公司 | A kind of electric power computer room noise elimination antirust paint and preparation method thereof |
| CN107641361A (en) * | 2017-11-07 | 2018-01-30 | 邵莹 | Stud filter mozzle antirust paint |
| CN107760083A (en) * | 2017-11-07 | 2018-03-06 | 邵莹 | Stud filter shell emulsification antirust paint |
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| CN102888179B (en) | 2016-01-20 |
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