CN102887684B - Unfired attapulgite fly ash haydite thermal-insulation brick - Google Patents

Unfired attapulgite fly ash haydite thermal-insulation brick Download PDF

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Publication number
CN102887684B
CN102887684B CN201210416383.1A CN201210416383A CN102887684B CN 102887684 B CN102887684 B CN 102887684B CN 201210416383 A CN201210416383 A CN 201210416383A CN 102887684 B CN102887684 B CN 102887684B
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China
Prior art keywords
attapulgite
insulating brick
fly ash
mine tailing
unburned
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CN201210416383.1A
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CN102887684A (en
Inventor
许庆华
李学东
李文娟
周浩
许盛英
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Nantong state Shun Building Materials Technology Development Co., Ltd.
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XUYI COUNTY DONGQIANG NEW BUILDING MATERIALS FACTORY
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses an unfired attapulgite fly ash haydite thermal-insulation brick. The technical scheme is as follows: the unfired attapulgite fly ash haydite thermal-insulation brick is prepared from attapulgite clay tailing powder, spherical attapulgite fly ash haydite, volcaniclastic rock mixture, bentonite tailing powder, kieselguhr tailing powder and cement. The unfired attapulgite fly ash haydite thermal-insulation brick is prepared by the following steps: stirring the materials, pressing into semi-finished products in different shapes, curing according to a routine caring method of cement products for 28 days, and packaging to obtain the unfired attapulgite fly ash haydite thermal-insulation brick finished product. The unfired attapulgite fly ash haydite thermal-insulation brick has the characteristics of high strength, thermal insulation, energy saving, sound insulation, heat insulation, fire resistance and flame retardancy. The materials use abundant various wastes, thereby being beneficial to enhancing the resource utilization rate and changing wastes into valuable substances, reducing the occupied soil, protecting and purifying the environment and saving the energy sources. The unfired attapulgite fly ash haydite thermal-insulation brick is suitable for walling construction of various buildings.

Description

Unburned attapulgite flyash haydite insulating brick
Technical field
The present invention relates to building material field, be specifically related to a kind of unburned attapulgite flyash haydite insulating brick.
Background technology
Mineral Resources in China 80% is intergrowth mineral, and a large amount of valuable resources retain among mine tailing, and tailings impoundment need to take a large amount of soils.A lot of Tailings Dams exceed the time limit or excess load is used, and even violation operation, makes Tailings Dam have great potential safety hazard, and people's property and the life security of surrounding area are caused to serious threat.
Attapulgite clay, except containing attapulgite, often contains the mineral such as montmorillonite, kaolinite, hydromica, sepiolite, quartz, opal and carbonate.
The volcanoclastic rock that also has with the symbiosis of attapulgite clay ore deposit, volcanoclastic rock is mostly on the upper strata in attapulgite clay ore deposit, the thickness of the volcanoclastic rock ore bed on upper strata, some attapulgite clays mining area is up to tens of rice, attapulgite clay is in recovery process, the volcanoclastic rock on upper strata, attapulgite clay mining area is abandoned as waste, according to field trip, the volcanoclastic rock that 1 ton of attapulgite clay of every exploitation produces has more than 30 tons, calculate by the output of producing 150000 tons per year, the volcanoclastic rock producing is up to 4,500,000 tons, all can be utilized for many years, whole mining area is the volcanoclastic rock mixture of again piling up everywhere, cause the serious wasting of resources and financial loss.
Flyash is to receive and catch the thin ash getting off in the flue gas from coal combustion, the main solid waste that flyash Ye Shi coal-burning power plant discharges, be one of industrial residue that the current discharge capacity of China is larger, along with the development of power industry, the flyash quantity discharged of coal-burning power plant increases year by year.A large amount of flyash does not add processing, will produce airborne dust, atmosphere pollution; Can cause river to silt up if enter water system, toxic chemical substance wherein also can work the mischief to human body and biology.
Haydite is a kind of artificial lightweight coarse aggregate, and case surface is coarse and hard, and inner porous is generally formed through pulverizing, granulation, sintering and screening by the material such as shale, clay rock.
Summary of the invention
The object of the invention is to overcome weak point in prior art, a kind of unburned attapulgite flyash haydite insulating brick is provided.
The batching of unburned attapulgite flyash haydite insulating brick is by attapulgite clay mine tailing, spherical attapulgite lytag, volcanoclastic rock mixture, wilkinite mine tailing, diatomite mine tailing and cement composition; The batching process of unburned attapulgite flyash haydite insulating brick is stirred, be pressed into difform unburned attapulgite flyash haydite insulating brick work in-process, maintenance is carried out in conventional maintenance process according to cement products, is packaged as the finished product of unburned attapulgite flyash haydite insulating brick after 28 days.
Attapulgite clay be a kind of layer of chain-like structure containing Shuifu County's zeopan clay mineral, attapulgite clay soil property exquisiteness, water-absorbent is strong, tool viscosity and plasticity-when wet, be conducive to the bonding between raw material, and can improve intensity and the porosity of unburned attapulgite flyash haydite insulating brick.
Attapulgite clay can mix in recovery process a certain amount of rubble and earth, cannot sieve, and abandons as a kind of mine tailing, causes a large amount of wastings of resources, and the present invention selects the attapulgite clay mine tailing after pulverizing, particle fineness≤0.149 millimeter.
Spherical attapulgite lytag is spheroidal, epidermis is coarse and hard, there is a large amount of trickle pores inside, that one is lightweight, intensity is high, thermal conductivity is low, refractoriness is high, chemical stability is good, weather resistance and the good building porcelain granule of heat preservation and soundproof performance, and the present invention selects particle diameter≤20.0 millimeter of spherical attapulgite lytag.
Volcanoclastic rock is the rock of the transitional type between magma lava and sedimentogeneous rock, the material that wherein more than 50% composition is sprayed by pyroclastic flow forms, and these tephras are mainly the lava of premature coagulation on volcano, the rock formation that passage is around burst in the time of volcanic eruption.Volcanoclastic rock mixture comprises landwaste, brilliant bits, glassiness bits, slurry bits, volcanic block, volcanic gravel and volcanic ash, volcanoclastic rock can increase the intensity of unburned attapulgite flyash haydite insulating brick, the present invention selects the volcanoclastic rock mixture after pulverizing, particle fineness≤5.0 millimeter.
Wilkinite has plasticity-and agglutinating value(of coal), and the wilkinite mine tailing that the present invention selects is distributed in the lower floor in attapulgite clay ore deposit mostly, is difficult to carry out independent exploitation, quality is also poor, major part is abandoned in mine tailing district, and the present invention selects the wilkinite mine tailing after pulverizing, particle fineness≤0.25 millimeter.
Diatomite exquisiteness, loose, light weight, porous, specific surface area is large, space is regular distribution, stable chemical nature, it is a kind of natural nano aperture amorphous silicon material, but diatomite is made a low multiple use, most products come from one-level soil, and two, three grades of soil are discarded in a large number, caused serious waste of resources, also polluted environment, diatomite can increase the porosity of unburned attapulgite flyash haydite insulating brick, the present invention selects the diatomite mine tailing after pulverizing, particle fineness≤0.25 millimeter.
Cement selection silicate cement.
The present invention is achieved by following technical proposals:
1, the batching of unburned attapulgite flyash haydite insulating brick is made up of following component by weight percentage: attapulgite clay mine tailing 5~20%, spherical attapulgite lytag 5~25%, volcanoclastic rock mixture 5~20%, wilkinite mine tailing 2~10%, diatomite mine tailing 2~10%, cement 5~15% and water 10~40%;
The production method of described unburned attapulgite flyash haydite insulating brick: the batching of unburned attapulgite flyash haydite insulating brick is added in the two shaft pugmill mixer having moved and stirred, after stirring, be transported in fully-automatic building block forming machine, be pressed into difform unburned attapulgite flyash haydite insulating brick work in-process, maintenance is carried out in conventional maintenance process according to cement products, is packaged as the finished product of unburned attapulgite flyash haydite insulating brick after 28 days;
Describedly be pressed into difform unburned attapulgite flyash haydite insulating brick work in-process, refer to according to design needs, be pressed into the unburned attapulgite flyash haydite insulating brick work in-process of square, rectangle, trilateral, ellipse, trapezoidal, quincunx or rhombus;
Described spherical attapulgite lytag is made up of the sticky attapulgite clay powder of height, attapulgite clay mine tailing, flyash, Kaolin Tailings powder, quartz sand mine tailing and wood dust; The production method of spherical attapulgite lytag: be spherical attapulgite lytag through mixing, granulation, roasting, cooling and screening by the batching of spherical attapulgite lytag.
Spherical attapulgite lytag is the patent of invention that the inventor applied on November 10th, 2011, China Patent Publication No.: 102515832A, open day: on 06 27th, 2012.
Unburned attapulgite flyash haydite insulating brick has that intensity is good, the feature of heat preservation energy-saving, sound-insulating and heat-insulating and fire protection flame retarding.
In the batching of unburned attapulgite flyash haydite insulating brick, the various wastes of a large amount of employing, are not only conducive to improve resource utilization, turn waste into wealth, and can also reduce land occupation, and protection and environment purification are saved the energy, reduce production costs, and increase economic efficiency.
Unburned attapulgite flyash haydite insulating brick is applicable to the wall construction of various buildings .
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, the batching of unburned attapulgite flyash haydite insulating brick is made up of following component by weight percentage: attapulgite clay mine tailing 12%, spherical attapulgite lytag 22%, volcanoclastic rock mixture 12%, wilkinite mine tailing 8%, diatomite mine tailing 6%, cement 10% and water 30%;
The production method of described unburned attapulgite flyash haydite insulating brick: the batching of unburned attapulgite flyash haydite insulating brick is added in the two shaft pugmill mixer having moved and stirred, after stirring, be transported in fully-automatic building block forming machine, be pressed into difform unburned attapulgite flyash haydite insulating brick work in-process, maintenance is carried out in conventional maintenance process according to cement products, is packaged as the finished product of unburned attapulgite flyash haydite insulating brick after 28 days;
Describedly be pressed into difform unburned attapulgite flyash haydite insulating brick work in-process, refer to according to design needs, be pressed into leg-of-mutton unburned attapulgite flyash haydite insulating brick work in-process.

Claims (1)

1. a unburned attapulgite flyash haydite insulating brick, it is characterized in that, the batching of unburned attapulgite flyash haydite insulating brick is made up of following component by weight percentage: attapulgite clay mine tailing 5~20%, spherical attapulgite lytag 5~25%, volcanoclastic rock mixture 5~20%, wilkinite mine tailing 2~10%, diatomite mine tailing 2~10%, cement 5~15% and water 10~40%;
The production method of described unburned attapulgite flyash haydite insulating brick: the batching of unburned attapulgite flyash haydite insulating brick is added in the two shaft pugmill mixer having moved and stirred, after stirring, be transported in fully-automatic building block forming machine, be pressed into difform unburned attapulgite flyash haydite insulating brick work in-process, maintenance is carried out in conventional maintenance process according to cement products, is packaged as the finished product of unburned attapulgite flyash haydite insulating brick after 28 days;
Describedly be pressed into difform unburned attapulgite flyash haydite insulating brick work in-process, refer to according to design needs, be pressed into the unburned attapulgite flyash haydite insulating brick work in-process of square, rectangle, trilateral, ellipse, trapezoidal, quincunx or rhombus;
Described spherical attapulgite lytag is made up of the sticky attapulgite clay powder of height, attapulgite clay mine tailing, flyash, Kaolin Tailings powder, quartz sand mine tailing and wood dust; The production method of spherical attapulgite lytag: be spherical attapulgite lytag through mixing, granulation, roasting, cooling and screening by the batching of spherical attapulgite lytag;
Select the attapulgite clay mine tailing after pulverizing, particle fineness≤0.149 millimeter; Select particle diameter≤20.0 millimeter of spherical attapulgite lytag; Select the volcanoclastic rock mixture after pulverizing, particle fineness≤5.0 millimeter; Select the wilkinite mine tailing after pulverizing, particle fineness≤0.25 millimeter; Select the diatomite mine tailing after pulverizing, particle fineness≤0.25 millimeter.
CN201210416383.1A 2012-10-27 2012-10-27 Unfired attapulgite fly ash haydite thermal-insulation brick Active CN102887684B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105669238B (en) * 2016-01-15 2017-12-12 湖南中建恒泰建材科技有限公司 Environment protection architecture insulation material, warming plate, sight shield, environment-friendly insulating metope
CN106116671A (en) * 2016-06-27 2016-11-16 安徽梅兰园林景观工程有限公司 A kind of energy-saving brick for garden landscape and preparation method thereof
CN106277983B (en) * 2016-08-15 2018-11-02 贵州安顺家喻新型材料股份有限公司 A kind of baking-free insulating brick and preparation method thereof
CN113845338A (en) * 2021-10-25 2021-12-28 太原理工大学 Solid waste based high-strength unfired fly ash ceramsite and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN102515631A (en) * 2011-11-09 2012-06-27 许庆华 Baking-free gravel-shaped attapulgite fly ash ceramisites
CN102515633B (en) * 2011-11-10 2013-04-17 许庆华 Baking-free cylindrical attapulgite river bottom mud ceramisites
CN102515837B (en) * 2011-11-10 2013-04-17 许庆华 Spherical attapulgite bed silt ceramsites

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Owner name: NANTONG BANGSHUN BUILDING MATERIAL TECHNOLOGY DEVE

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Address after: 226300 Jiangsu city of Nantong province Tongzhou District Liu Qiao Zhen Jiang Yi Cun 11 groups

Patentee after: Nantong state Shun Building Materials Technology Development Co., Ltd.

Address before: 211700 Huaian city goussen Mo Jian village in Jiangsu province Xuyi County Township

Patentee before: Xuyi County Dongqiang New Building Materials Factory