CN102887667A - Inorganic fibre fireproof insulation board - Google Patents

Inorganic fibre fireproof insulation board Download PDF

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Publication number
CN102887667A
CN102887667A CN2012103960371A CN201210396037A CN102887667A CN 102887667 A CN102887667 A CN 102887667A CN 2012103960371 A CN2012103960371 A CN 2012103960371A CN 201210396037 A CN201210396037 A CN 201210396037A CN 102887667 A CN102887667 A CN 102887667A
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China
Prior art keywords
inorganic fibre
water
heated board
board according
fireproof heated
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CN2012103960371A
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CN102887667B (en
Inventor
姜伟基
魏君
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Chongqing dragon high tech Material Co., Ltd.
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CHONGQING LONGZHE LOW-CARBON ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD
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Priority to CN201210396037.1A priority Critical patent/CN102887667B/en
Publication of CN102887667A publication Critical patent/CN102887667A/en
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Publication of CN102887667B publication Critical patent/CN102887667B/en
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Abstract

The invention discloses an inorganic fibre fireproof insulation board which is prepared by the following steps: preparing a wet blank by using water and the following raw materials according to weight part ratio: an inorganic fibre, an organic binding agent and a moisture repellent with weight part ratio of 100: 2-10: 0.1-1; and then uniformly coating an interface treatment agent on the wet blank, wherein the interface treatment agent is formed by modulating water with the following materials: a cement, a styrene-acrylic emulsion, an alkali-swelling thickening agent and a water repellent in the weight part ratio of 30-60: 40-70: 0.05-0.15: 2-5, and finally drying the wet blank to obtain the finished product. The inorganic fibre fireproof insulation board is has the characteristics of low thermal conductivity, non-rigid material, good toughness, low water absorbing rate, low thermal capacity, excellent thermal stability and hot shock resistance, high compression strength, high tensile strength, long service life, excellent toughness, wind erosion resisting capability, excellent machining property and excellent sound-absorbing and noise-reducing properties.

Description

The inorganic fibre fireproof heated board
Technical field
The invention belongs to a kind of inorganic heat insulating fiber PLASTIC LAMINATED, belong to the energy-saving building materials field.
Background technology
Building energy conservation is an important component part of save energy.Carrying out building energy conservation is a fundamental state policy of country's reply climate change, realization national economy sustainable development.Since Eleventh Five-Year Plan, reduce discharging at national energy-saving under the energetically promotion of policy, China's Building Energy-saving Work has obtained fast development.Up to the present, more than 17 hundred million square metres of energy saving buildings have been totaled.The exterior wall of these newly-built energy saving buildings and existing building reducing energy consumption mainly adopts External Thermal Insulation Technology for External, particularly the northern area of China almost all adopts the thin heat-insulation systems of plastering such as pasting styrofoam (EPS/XPS), spraying polyurethane, account for more than 95% of engineering application quantity, these technology are that the Building Energy-saving Work of China has been made outstanding contributions.
But owing to styrofoam (EPS/XPS), spraying polyurethane all belong to inflammable material, in ground external wall insulation project frequent occurrence fire disaster accidents such as Shanghai, Shenyang, cause the leader's of State Council great attention, therefore can become the fresh target that the insider studies by the fp warming plate.
Asbestos are a kind of good thermostable heat-isolating materials, has low price, the characteristics such as short texture, light specific gravity, once be widely used in making various insulations, heat insulation and high temperature material, but asbestos are comparatively serious to the harm of the pollution of environment and human body, particularly the dust of dry state is very harmful to HUMAN HEALTH, thereby its application is restricted.In the situation that the application of asbestos is restricted, exploitation becomes the demand of relevant industries without asbestos high-temperature-resistant thermal-insulation plate.
At present, many asbestos-free inorganic fiber thermal insulation PLASTIC LAMINATED have appearred on the market, mainly be by various fibers, electrodeless wedding agent, organic bond, a large amount of mineral fillers and additive form, for example application number is that 200610155138.4 Chinese patent discloses a kind of without asbestos thermostable heat-isolating plate, by high-temperature fibre, mineral filler and tackiness agent form, wherein the content of high-temperature fibre is 40%-80%, the content of mineral filler is 10%-50%, make sheet material in when making, adding to a large amount of mineral fillers without polar fibers, again granulation frothing mold moulding, spray mo(u)lding, foaming etc., this will certainly have influence on the thermal conductivity of filamentary material, cause thermal conductivity higher, and can cause refractory temperature low, also only can reach 900 ℃ such as the high temperature resistant of the sheet material in this piece patent application.But one skilled in the art will appreciate that if do not add mineral filler, sheet material just can be very soft, physical strength is not high.
Summary of the invention
In order to solve the problems of the technologies described above, the object of the present invention is to provide a kind of thermal conductivity that does not affect fiber, high temperature resistant and inorganic fibre fireproof heated board that physical strength is high.
The present invention seeks to realize like this: a kind of inorganic fibre fireproof heated board is characterized in that: following starting material and water by ratio of weight and number are made wet base: inorganic fibre: organic bond: hydrophober=100: 2-10: 0.1-1;
Then on wet base, coat uniformly interface treating agent, described interface treating agent is formed by following material and the water modulation of ratio of weight and number: cement: benzene emulsion: alkali holds swollen thickening material: hydrophober=30-60: 40-70: 0.05-0.15: 2-5, and final drying obtains finished product.
Adopt technique scheme, the wet base behind the inorganic fibre fireproof heat insulating sheet metal forming uses interface treating agent to carry out surface treatment.Use the slab of the inorganic fibre fireproof heated board that this proportioning produces because only containing a small amount of organic gel, do not contain other fillers, the thermal conductivity of inorganic fibre can not be affected, resistance to elevated temperatures is good (to can reach 1360 ℃ of high temperature therefore have, mass loss rate is less than 5%), good thermal shock, good heat insulating under the normal temperature (thermal conductivity only is 0.045W/mk) and wait lastingly premium properties, in addition, surperficial and inner slab all adds hydrophober, surperficial and inner hydrophobic nature uniformity and reach higher standard (the hydrophobic rate greater than 98%, 28 day water-intake rate less than 3kg/m 2), nonhygroscopic, not softening, last, interface treating agent has strengthened the interface pull strength greatly, has improved security and weather resistance, enables for field of thermal insulation such as building inside and outside wall and roofings.
As preferably: when making wet base, the add-on of described water and the ratio of weight and number of inorganic fibre are 90-100:100.
As preferably: the weight of the water that adds when the modulated interface treatment agent is 1/10th to 1/3rd of cement, benzene emulsion, the alkali gross weight of holding swollen thickening material and hydrophober.
In technique scheme, the thickness of the interface treating agent of evenly smearing on the described wet base is 4-5mm, and the interface treating agent that wherein 2-3mm is thick has been penetrated under the wet base surface.
As of the present invention preferred: described inorganic fibre is glass fibre, quartz glass fibre, boron fibre, ceramic fiber, slag wool, high silica fiber, sapphire whisker.
As of the present invention preferred: described organic bond is one or more the mixture in pasted starch or the polyvinyl alcohol.
As of the present invention preferred: described hydrophober is silicone based water-resisting agent.
As of the present invention preferred: described hydrophober is one or more mixtures in the mixture, methyl silicate, hydrogen polysiloxanes of polysilane and siloxanes.
As of the present invention preferred: it is that AT-75 alkali holds swollen thickening material or T-900 alkali holds swollen thickening material that described alkali holds swollen thickening material.
Beneficial effect: the present invention has low heat conductivity, non-brittle material, good toughness, low water absorption, low heat capacity, good thermostability and heat-shock resistance, compressive strength is high, tensile strength is high, long service life, and tool excellent toughness, weather-proof ability, good machinability, good absorbing sound and lowering noise performance.
Embodiment
The present invention is described further below in conjunction with embodiment:
Embodiment 1: get glass fibre 100kg, pasted starch 3kg, polyvinyl alcohol 2kg, the mixture 0.2kg of polysilane and siloxanes, add in the 95kg water and stir, mixed pulp, then adopt vacuum forming to produce wet base, wet base surface uniform after the moulding smear the thick interface treating agent of 5mm, the interface treating agent that wherein 3mm is thick has been penetrated under the wet base surface at last, 2mm is positioned at the surface of wet base, and described interface treating agent is by 30 parts of cement (weight part), 40 parts of benzene emulsions (weight part), AT-75 alkali holds 0.05 part of swollen thickening material, and (AT-75 is acrylate, the cross-linked type macromolecule emulsion thickener that the methacrylic ester copolymerization forms), the mixture of hydrophober polysilane and siloxanes 2 parts (weight part) and water 7.2 parts (weight parts) modulation that stirs forms.To wet base at last after lower drying about 110 ℃, and postmenstruation, working cut was made finished product.
Embodiment 2: get ceramic fiber 100kg, pasted starch 2kg, hydrogen polysiloxanes 0.1kg, add in the 100kg water and stir, mixed pulp, then adopt vacuum forming to produce wet base, wet base surface uniform after the moulding smear the thick interface treating agent of 4mm, the interface treating agent that wherein 2mm is thick has been penetrated under the wet base surface at last, 2mm is positioned at the surface of wet base, and described interface treating agent is by 40 parts of cement (weight part), 40 parts of benzene emulsions (weight part), T-900 alkali holds swollen 0.1 part of thickening material (weight part), hydrophober hydrogen polysiloxanes 3 parts (weight part) and water 31 parts (weight parts) modulation that stirs forms.To wet base at last after lower drying about 110 ℃, and postmenstruation, working cut was made finished product.
Embodiment 3: get rock wool fibers 100kg, pasted starch 10kg, polysilane/siloxanes 0.85kg, methyl silicate 0.15kg, add in the 90kg water and stir, mixed pulp, then adopt vacuum forming to produce wet base, wet base surface uniform after the moulding smear interface treating agent, the thickness of interface treating agent is 5mm, the interface treating agent that approximately 3mm is thick at last has been penetrated under the wet base surface at last, 2mm is positioned at the surface of wet base, described interface treating agent is by 60 parts of cement, (weight part) AT-75 alkali holds swollen thickening material 0.15 part (weight part), and (AT-75 is acrylate, the cross-linked type macromolecule emulsion thickener that the methacrylic ester copolymerization forms), 3 parts in the mixture of hydrophober polysilane and siloxanes (weight part), 2 parts of methyl silicates (weight part), 70 parts of benzene emulsions and water 27 parts (weight parts) stir to modulate and form.Then after lower drying about 110 ℃, postmenstruation, working cut was made finished product.
Embodiment 4: get each 50kg of quartz glass fibre and ceramic fiber, polyvinyl alcohol 6kg, polysilane/siloxanes 0.6kg, add in the 100kg water and stir, mixed pulp, then adopt vacuum forming to produce wet base, wet base surface uniform after the moulding smear interface treating agent, the thickness of interface treating agent is 5mm, the interface treating agent that approximately 3mm is thick at last has been penetrated under the wet base surface at last, 2mm is positioned at the surface of wet base, and described interface treating agent is by 50 parts of cement (weight part), AT-75 alkali holds 0.10 part of swollen thickening material, and (AT-75 is acrylate, the cross-linked type macromolecule emulsion thickener that the methacrylic ester copolymerization forms), 2 parts in the mixture of hydrophober polysilane and siloxanes, 0.5 part of methyl silicate, 45 parts of benzene emulsions and 30 parts of modulation of water form.Then after lower drying about 110 ℃, postmenstruation, working cut was made finished product.
Embodiment 5: get boron fibre, each 33.3kg of quartz glass fibre and sapphire whisker, polyvinyl alcohol 8kg, the mixture 0.7kg of polysilane and siloxanes, add in the 100kg water and stir, mixed pulp, then adopt vacuum forming to produce wet base, wet base surface uniform after the moulding smear interface treating agent, the thickness of interface treating agent is 4.5mm, the interface treating agent that approximately 2.5mm is thick at last has been penetrated under the wet base surface at last, 2mm is positioned at the surface of wet base, and described interface treating agent is by 45 parts of cement, AT-75 alkali holds 0.08 part of swollen thickening material, and (AT-75 is acrylate, the cross-linked type macromolecule emulsion thickener that the methacrylic ester copolymerization forms), 2 parts in the mixture of hydrophober polysilane and siloxanes, 60 parts of benzene emulsions and 15 parts of modulation of water form.Then after lower drying about 110 ℃, postmenstruation, working cut was made finished product.
The present invention is not limited to specific embodiment, as long as any type of variation under invention aim of the present invention all falls into protection scope of the present invention.

Claims (9)

1. inorganic fibre fireproof heated board, it is characterized in that: following starting material and water by ratio of weight and number are made wet base: inorganic fibre: organic bond: hydrophober=100: 2-10: 0.1-1;
Then on wet base, coat uniformly interface treating agent, described interface treating agent is formed by following material and the water modulation of ratio of weight and number: cement: benzene emulsion: alkali holds swollen thickening material: hydrophober=30-60: 40-70: 0.05-0.15: 2-5, and final drying obtains finished product.
2. described inorganic fibre fireproof heated board according to claim 1, it is characterized in that: when making wet base, the add-on of described water and the ratio of weight and number of inorganic fibre are 90-100:100.
3. described inorganic fibre fireproof heated board according to claim 1 is characterized in that: the weight of the water that adds when the modulated interface treatment agent is 1/10th to 1/3rd of cement, benzene emulsion, the alkali gross weight of holding swollen thickening material and hydrophober.
4. described inorganic fibre fireproof heated board according to claim 1, it is characterized in that: the thickness of the interface treating agent of evenly smearing on the described wet base is 4-5mm, the interface treating agent that wherein 2-3mm is thick has been penetrated under the wet base surface.
5. described inorganic fibre fireproof heated board according to claim 1 and 2, it is characterized in that: described inorganic fibre is glass fibre, quartz glass fibre, boron fibre, ceramic fiber, slag wool, high silica fiber, sapphire whisker.
6. described inorganic fibre fireproof heated board according to claim 1 and 2 is characterized in that: described organic bond is one or more the mixture in pasted starch or the polyvinyl alcohol.
7. described inorganic fibre fireproof heated board according to claim 1 and 2, it is characterized in that: described hydrophober is silicone based water-resisting agent.
8. described inorganic fibre fireproof heated board according to claim 7 is characterized in that: described hydrophober is one or more mixtures in the mixture, methyl silicate, hydrogen polysiloxanes of polysilane and siloxanes.
9. described inorganic fibre fireproof heated board according to claim 1 and 2, it is characterized in that: it is that AT-75 alkali holds swollen thickening material or T-900 alkali holds swollen thickening material that described alkali holds swollen thickening material.
CN201210396037.1A 2012-08-20 2012-10-17 Inorganic fibre fireproof insulation board Expired - Fee Related CN102887667B (en)

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Application Number Priority Date Filing Date Title
CN201210396037.1A CN102887667B (en) 2012-08-20 2012-10-17 Inorganic fibre fireproof insulation board

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN2012102965908A CN102775097A (en) 2012-08-20 2012-08-20 Inorganic fiber fireproof heat-retaining board
CN201210296590.8 2012-08-20
CN201210396037.1A CN102887667B (en) 2012-08-20 2012-10-17 Inorganic fibre fireproof insulation board

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CN102887667B CN102887667B (en) 2014-03-19

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Publication number Priority date Publication date Assignee Title
CN105669141B (en) * 2016-03-07 2017-12-29 广州孚姆新材料科技股份有限公司 GRC products
CN105753409B (en) * 2016-03-07 2020-04-17 广州孚姆新材料科技股份有限公司 Preparation method of glass fiber reinforced material
CN106699101B (en) * 2017-01-22 2019-03-08 陕西科技大学 A kind of preparation method for the inorfil fireproof and heat-insulating material that foams
CN106930493B (en) * 2017-03-28 2022-07-15 北京艺高世纪科技股份有限公司 Fireproof heat-insulation decorative plate and manufacturing method thereof
CN107500603A (en) * 2017-08-31 2017-12-22 苏州仲勉装饰有限公司 A kind of preparation method of tunnel shock resistance insulation material
CN115010457A (en) * 2022-05-09 2022-09-06 唐山顺浩环保科技有限公司 Superfine ceramic fiber cotton thermal insulation pipe shell and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519294A (en) * 2009-04-15 2009-09-02 徐良骥 Method for preparing and using multifunctional inorganic fiber facing material
CN102336561A (en) * 2011-08-08 2012-02-01 刘建全 Outer wall insulation material for building by taking pearlite as aggregate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519294A (en) * 2009-04-15 2009-09-02 徐良骥 Method for preparing and using multifunctional inorganic fiber facing material
CN102336561A (en) * 2011-08-08 2012-02-01 刘建全 Outer wall insulation material for building by taking pearlite as aggregate

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CN102775097A (en) 2012-11-14

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Address after: 402247, Jiangjin District, Chongqing City Fu Industrial Park

Applicant after: LONGZHE INCORPORATED

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Free format text: CORRECT: APPLICANT; FROM: CHONGQING LONGZHE LOW-CARBON ENVIRONMENT PROTECTION SCIENCE + TECHNOLOGY CO., LTD. TO: CHONGQING LONGZHE HIGH-NEW MATERIAL CO., LTD.

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Effective date of registration: 20191204

Address after: 402246 building 3, No.16 Fu'an Road, Shuangfu street, Jiangjin District, Chongqing

Patentee after: Chongqing dragon high tech Material Co., Ltd.

Address before: 402247, Jiangjin District, Chongqing City Fu Industrial Park

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