CN102872722B - Column-type hollow fiber membrane assembly - Google Patents

Column-type hollow fiber membrane assembly Download PDF

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Publication number
CN102872722B
CN102872722B CN201210254283.3A CN201210254283A CN102872722B CN 102872722 B CN102872722 B CN 102872722B CN 201210254283 A CN201210254283 A CN 201210254283A CN 102872722 B CN102872722 B CN 102872722B
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hollow fiber
water inlet
inlet end
bellows
fiber membrane
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CN102872722A (en
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林亚凯
徐大明
赵杰
王大新
田野
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Beijing Scino Membrance Technology Co ltd
Hebei Scinor Membrane Technology Co ltd
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BEIJING SCINO MEMBRANCE TECHNOLOGY Co Ltd
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Abstract

The invention relates to a column-type hollow fiber membrane assembly which comprises a membrane shell and a hollow fiber membrane unit fixed in the membrane shell. A water inlet and an air inlet are arranged on the membrane shell at the lower part of the hollow fiber membrane unit; a water production port and a concentrated solution drain port are arranged on the membrane shell at the upper part of the hollow fiber membrane unit; a concentrated solution drain pipe is arranged in the membrane shell at the upper part of the hollow fiber membrane unit; the hollow fiber membrane unit comprises a plurality of hollow fiber membrane components, a water inlet end center pipe and a water production end center pipe; each hollow fiber membrane component consists of a water inlet end membrane box, a water inlet end resin cast fixed layer, a water production end membrane box, a water production end resin cast fixed layer and a plurality of hollow fiber membrane yarns fixed between the two resin cast fixed layers; a gap is reserved between each two adjacent water inlet end membrane boxes to form a gas-liquid diversion passage; a plurality of gas-liquid diversion holes are also arranged inside each water inlet end membrane box; and each hollow fiber membrane component is connected with the water inlet end center pipe and the water production end center pipe by the water inlet end membrane boxes and the water production end membrane boxes.

Description

A kind of column type hollow fiber membrane modular
Technical field
The present invention relates to a kind of sewage-treatment plant, more specifically relate to a kind of column type hollow fiber membrane modular.
Background technology
Fast development along with China's economy, the consumption of water resource is multiplied, caused on the one hand the in short supply of water resource, also increased the generation of sewage simultaneously, strengthened the pressure of society and environment sustainable development, the parties concerned drop into a large amount of funds and sewage are processed to and made its resource recycling for this reason.Membrane separation technique and device have been widely used in the sewage treatment areas such as biology, chemical industry, medicine, food, municipal administration in recent years.For the ease of suitability for industrialized production and installation, improve the operating efficiency of film, in unit volume, realize maximum membrane area, conventionally film is assembled in an elementary cell equipment with certain form, under certain driving force, complete the separation of each component in mixed liquor, this class device is called membrane module.Hollow fiber film assembly because its loading density is high, cost is relatively low, the life-span is widely applied compared with long and film good pressure-resistant performance.
Current existing column type hollow fiber membrane modular 10(as shown in Figure 1), on putamina 11, be provided with water inlet 12, produce the mouth of a river 13, air inlet 14 and concentrate floss hole 15, in putamina 11, be fixed with water inlet end resin-cast fixed bed 32 and produce water end (W.E.) resin-cast fixed bed 34, in water inlet end resin-cast fixed bed 32, be provided with a plurality of gas-liquid pod apertures 23a, produce in water end (W.E.) resin-cast fixed bed 34 and be connected with again concentrate delivery pipe 16, between water inlet end resin-cast fixed bed 32 and product water end (W.E.) resin-cast fixed bed 34, be fixed with many hollow fiber film threads 35.
Mainly there is following problems in existing hollow fiber column type membrane module:
The first, existing column type hollow fiber membrane modular is with resin, hollow fiber film thread and putamina cast to be fixed together, and causes operation inconvenience when making large-scale hollow fiber film assembly, reduces production efficiency.
The second, because the structural design of gas-liquid pod apertures in water inlet end resin-cast fixed bed is unreasonable, cause this fixed bed bulk strength to decline, unit volume amount of resin declines and has also reduced the adhesive strength between hollow fiber film thread simultaneously.
The 3rd, because being subject to the restriction of resin fixed bed intensity, gas-liquid pod apertures quantity makes the close thin inequality of hollow fiber film thread distribution, reduce hollow fiber film thread contamination resistance, affect the cleaning performance of column type hollow fiber membrane modular, reduction of service life.
The 4th, existing column type hollow fiber membrane modular is with resin, the cast of hollow fiber film thread and putamina to be fixed together, and in servicely when local hollow fiber film thread damage, can only scrap whole membrane module, causes the wasting of resources, the cost of increasing input.
Summary of the invention
The object of the present invention is to provide a kind of column type hollow fiber membrane modular with high antifouling property, long life, low alternative costs.
The present invention is achieved by the following technical solutions:
A kind of column type hollow fiber membrane modular, comprise putamina and be fixed on the hollow fiber film unit in putamina, on the putamina of hollow fiber film unit bottom, be provided with water inlet and air inlet, on the putamina on hollow fiber film unit top, be provided with and produce the mouth of a river and concentrate floss hole; In the putamina on hollow fiber film unit top, be provided with concentrate delivery pipe, it is characterized in that: described hollow fiber film unit comprises a plurality of hollow fibre membrane components, water inlet end central tube and produces water end (W.E.) central tube; Each hollow fibre membrane component by water inlet end bellows, water inlet end resin-cast fixed bed, many hollow fiber film threads producing water end (W.E.) bellows, produce water end (W.E.) resin-cast fixed bed and be fixed on water inlet end resin-cast fixed bed and produce between water end (W.E.) resin-cast fixed bed form, between two adjacent water inlet end bellows, leave gap and form gas-liquid flow-guiding channel, each water inlet end bellows inside is also provided with a plurality of gas-liquid pod apertures; Each hollow fibre membrane component is connected with product water end (W.E.) central tube with water inlet end central tube with product water end (W.E.) bellows by water inlet end bellows respectively.
Hollow fiber film unit of the present invention is fixed in putamina by top board, sealing gasket, lower platen, location jump ring and a plurality of trip bolt.
Described hollow fiber film unit is comprised of 2~12 hollow fibre membrane components, is circumference equidistantly arrangement or the arrangement of circumference non-equidistance.Described water inlet end bellows and the cross sectional shape that produces water end (W.E.) bellows are fan-shaped, circle or polygon
Described water inlet end resin-cast fixed bed and product water end (W.E.) resin-cast fixed bed adopt epoxy resin, polyurethane or silicon rubber body.The material of described water inlet end bellows and product water end (W.E.) bellows adopts UPVC material, ABS material or stainless steel material.
Described putamina external diameter is preferably 90mm to 450mm; The quantity of the described inner gas-liquid pod apertures of water inlet end bellows is 1 to 6, and each gas-liquid pod apertures area of section is 5mm 2to 2000mm 2.
The present invention compared with prior art, has the following advantages and high-lighting effect:
The first, column type hollow fiber membrane modular of the present invention by a plurality of hollow fibre membrane components by water inlet end central tube, produce water end (W.E.) central tube, top board, sealing gasket, lower platen and trip bolt and be fixed in putamina and form, in servicely when damaging appears in local hollow fiber film thread, only need replace the hollow fibre membrane component at this hollow fiber film thread place, without scrapping whole column support type hollow fiber film assembly, greatly reduce the wasting of resources, reduced input cost.
The second, the preparation method of column type hollow fiber membrane modular of the present invention is by many hollow fiber film threads, water inlet end bellows and produces water end (W.E.) bellows and fixedly form hollow fibre membrane component by resin-cast, again by a plurality of hollow fibre membrane components by water inlet end central tube with produce water end (W.E.) central tube and assemble into hollow fiber film unit, then this hollow fiber film unit is fixed on and in putamina, is formed column type hollow fiber membrane modular by top board, sealing gasket, lower platen and trip bolt.Whole production process more than 70% be all assembling, simple to operation, greatly enhance productivity.
Three, the gas-liquid pod apertures of column type hollow fiber membrane modular of the present invention is comprised of two parts, a part is water inlet end bellows a plurality of gas-liquid pod apertures that inside is provided with when injection mo(u)lding, and another part is between the water inlet end bellows of adjacent two hollow fibre membrane components of when assembling, to leave gap to form gas-liquid flow-guiding channel; It is close evenly thin that this design of gas-liquid pod apertures can allow bellows internal membrane silk distribute, and improves and the contamination resistance and the cleaning performance that strengthen hollow fiber film thread the whole service life of prolongation column type hollow fiber membrane modular; Because there being bellows sidewall as support, this column type hollow fiber membrane modular water inlet termination bulk strength to be strengthened, between hollow fiber film thread, adhesive strength also can be strengthened greatly simultaneously.
Accompanying drawing explanation
Fig. 1 is the structural principle schematic diagram of the column type hollow fiber membrane modular of prior art.
Fig. 2 a, Fig. 2 b and Fig. 2 c are column type hollow fiber membrane modular structural principle schematic diagram of the present invention, and wherein Fig. 2 b is the A-A cutaway view of Fig. 2 a, and Fig. 2 c is the B-B cutaway view of Fig. 2 a.
The structural principle schematic diagram that Fig. 3 a, Fig. 3 b and Fig. 3 c are hollow fiber film unit of the present invention, wherein Fig. 3 b be the A of Fig. 3 a to view, Fig. 3 c is that the B of Fig. 3 a is to view.
Fig. 4 is the stereogram of hollow fibre membrane component of the present invention.
In figure: 10-column type hollow fiber membrane modular, 11-putamina; 12-water inlet; 13-produces the mouth of a river; 14-air inlet; 15-concentrate floss hole; 16-concentrate delivery pipe; 17-lower platen; 18-locates jump ring; 19-trip bolt; 20-hollow fiber film unit; 21-produces water end (W.E.) central tube; 22-water inlet end central tube; 23a-gas-liquid pod apertures; 23b-gas-liquid flow-guiding channel; 24-top board; 25-sealing gasket; 26-produces water end (W.E.) head; The 27-termination that intakes; 30-hollow fibre membrane component; 31-water inlet end bellows; 32-water inlet end resin-cast fixed bed; 33-produces water end (W.E.) bellows; 34-produces water end (W.E.) resin-cast fixed bed; 35-hollow fiber film thread.
The specific embodiment
In order to understand better the present invention, below in conjunction with accompanying drawing, the invention will be further described, to understand up hill and dale technical scheme of the present invention.
Fig. 2 a, Fig. 2 b and Fig. 2 c are the structural principle schematic diagram of column type hollow fiber membrane modular 10 of the present invention.As shown in Fig. 2 a, Fig. 2 b and Fig. 2 c, column type hollow fiber membrane modular 10 comprises putamina 11 and is fixed on the hollow fiber film unit 20 in putamina 11, on the putamina 11 of hollow fiber film unit 20 bottoms, be provided with water inlet 12 and air inlet 14, on the putamina 11 on hollow fiber film unit 20 tops, be provided with and produce the mouth of a river 13 and concentrate floss hole 15; In the putamina 11 on hollow fiber film unit 20 tops, be provided with concentrate delivery pipe 16; Described hollow fiber film unit 20 comprises a plurality of hollow fibre membrane components 30, water inlet end central tube 22 and produces water end (W.E.) central tube 21.
The fixed form of hollow fiber film unit 20 in putamina 11, can adopt gluing being connected in putamina 11, or be connected and fixed by applicable connected mode arbitrarily well-known to those skilled in the art, preferably adopt the following mode that is fixedly connected with: by top board 24, sealing gasket 25, lower platen 17, location jump ring 18 and a plurality of trip bolt 19, be fixed in putamina 11, intake termination 27 is connected with lower platen 17 by a plurality of location jump ring 18, and lower platen 17 is fixed in putamina 11 by a plurality of trip bolts 19; Produce water end (W.E.) head 26 and be connected with top board 24 with sealing gasket 25 successively by a plurality of trip bolts 19, top board 24 is fixed in putamina 11 by a plurality of trip bolts 19.The diameter of section of putamina 11 is generally 90mm-450mm, can select such as PVC material or glass-reinforced plastic material etc.
Fig. 3 a, Fig. 3 b and Fig. 3 c are the structural principle schematic diagram of hollow fiber film unit 20 of the present invention.As shown in Fig. 3 a, Fig. 3 b and Fig. 3 c, hollow fiber film unit 20 is by water inlet end bellows 31 and product water end (W.E.) bellows 33, to be connected to a fixed and to form with water inlet end central tube 22 and product water end (W.E.) central tube 21 respectively by 2 to 12 hollow fibre membrane components 30, and water inlet end bellows 31 and produce water end (W.E.) bellows 33 circumference is equidistant or circumference is non-is equidistantly arranged in water inlet end central tube 22 and produces water end (W.E.) central tube 21 around respectively, leaves gap and forms gas-liquid flow-guiding channel 23b between two adjacent water inlet end bellows 31.
Water inlet end bellows 31 and product water end (W.E.) bellows 33 and water inlet end central tube 22 and the connected mode of producing water end (W.E.) central tube 21, can adopt trip bolt to connect, or be connected and fixed by applicable connected mode arbitrarily well-known to those skilled in the art, preferably adopt following connected mode: water inlet end bellows 31 and product water end (W.E.) bellows 33 adopt buckle modes and water inlet end central tube 22 and produce water end (W.E.) central tube 21 and be connected and fixed, be that snap fit and the draw-in groove on water inlet end central tube 22 on the water inlet end bellows 31 of a plurality of hollow fibre membrane components 30 clamps locked formation water inlet termination 27 mutually, snap fit on the product water end (W.E.) bellows 33 of a plurality of hollow fibre membrane components 30 clamps locked formation product water end (W.E.) head 26 mutually with the draw-in groove producing on water end (W.E.) central tube 21.
Fig. 4 is the stereogram of hollow fibre membrane component 30 of the present invention.As shown in Figure 4, hollow fibre membrane component 30 by water inlet end bellows 31, water inlet end resin-cast fixed bed 32, the many hollow fiber film threads 35 that produce water end (W.E.) bellows 33, produce water end (W.E.) resin-cast fixed bed 34 and be fixed on water inlet end resin-cast fixed bed 32 and produce between water end (W.E.) resin-cast fixed bed 34 form, each water inlet end bellows 31 inside is also provided with a plurality of gas-liquid pod apertures 23a.The water inlet end bellows 31 of hollow fibre membrane component 30 and to produce water end (W.E.) bellows 33 cross sectional shapes be fan-shaped, circle or polygon, its material is UPVC material, ABS material or stainless steel material; The material of water inlet end resin-cast fixed bed 32 and product water end (W.E.) resin-cast fixed bed 34 adopts epoxy resin, polyurethane or silicon rubber body.
From the above, a plurality of gas-liquid pod apertures 23a that water inlet end bellows 31 inside are provided with can allow water inlet end bellows 31 inner hollow tunica fibrosa silks 35 distribute close evenly thin, greatly improve contamination resistance and the cleaning performance of hollow fiber film thread, extended the whole service life of this column type hollow fiber membrane modular 10; Gas-liquid flow-guiding channel 23b is because there being the sidewall on two adjacent water inlet end bellows 31 as support, water inlet termination 27 bulk strengths of this column type hollow fiber membrane modular 10 to be strengthened, and between hollow fiber film thread 35, adhesive strength has also obtained reinforcement.In use, because each hollow fibre membrane component 30 is separate, even if there is damaging the hollow fibre membrane component 30 that only needs to replace these hollow fiber film thread 35 places in local hollow fiber film thread 35, without scrapping whole column support type hollow fiber film assembly 10, greatly reduce the wasting of resources, reduced input cost.
When producing, hollow fiber film thread 35 is fixed on special stand, determine the length of hollow fiber film thread 35, excision redundance its one end of shutoff.Fixedly water inlet end bellows 31, hollow fiber film thread 35 is not loaded in this bellows one end of shutoff, mixture to the interior injection hard resin of water inlet end bellows 31 and curing agent, wait solidify to form after hard resin fixed bed again the mixture to the interior injection flexible resin of water inlet end bellows 31 and curing agent to it, standing to resin solidification formation flexible resin fixed bed, this flexible resin fixed bed and hard resin fixed bed form water inlet end resin-cast fixed bed 32 jointly.The fixing water end (W.E.) bellows 33 that produces, one end of hollow fiber film thread 35 shutoff is loaded in this bellows, to the mixture that produces water end (W.E.) bellows 33 interior injection hard resins and curing agent, wait solidify to form after hard resin fixed bed again to the mixture that produces water end (W.E.) bellows 33 interior injection flexible resins and curing agent to it, standing to solidifying to form flexible resin fixed bed, this flexible resin fixed bed and hard resin fixed bed form product water end (W.E.) resin-cast fixed bed 34, so far hollow fibre membrane component 30 casting completes jointly.The end face of the product water end (W.E.) bellows 33 of excision hollow fibre membrane component 30 and product water end (W.E.) resin-cast fixed bed 34 is until hollow fiber film thread 35 exposes internal void.Snap fit on the product water end (W.E.) bellows 33 of a plurality of hollow fibre membrane components 30 is inserted respectively to produce in water end (W.E.) central tube 21 draw-in groove around and clamp locked row one-tenth and produce water end (W.E.) head 26, sealing gasket 25 and top board 24 are installed successively on product water end (W.E.) head 26 and are fixed with trip bolt 19.Snap fit on the water inlet end bellows 31 of a plurality of hollow fibre membrane components 30 is inserted into respectively in water end (W.E.) central tube 22 draw-in groove around and clamps locked row one-tenth water inlet termination 27, so far hollow fiber film unit 20 has been assembled.Hollow fiber film unit 20 is packed in putamina 11 according to the order of the rear product water end (W.E.) of first water inlet end head 27 head 26, lower platen 17 fixing with location jump ring 18 is installed on water inlet termination 27.With trip bolt 19, respectively the water inlet termination of hollow fiber film unit 20 27 and product water end (W.E.) head 26 are fixed in putamina 11, so far hollow fiber column type membrane module 10 has been produced.Known to above-mentioned, whole production process more than 70% be all assembling process, simple to operation, can greatly enhance productivity.
Hollow fiber column type membrane module disclosed by the invention has higher contamination resistance and longer service life, and alternative costs are low, can under more severe condition of water quality, work, aquifer yield is stable and water quality is good, is applicable to the harness the river pretreatment of system of large reverse osmosis.

Claims (7)

1. a column type hollow fiber membrane modular (10), comprise putamina (11) and be fixed on the hollow fiber film unit (20) in putamina (11), on the putamina (11) of hollow fiber film unit (20) bottom, be provided with water inlet (12) and air inlet (14), on the putamina (11) on hollow fiber film unit (20) top, be provided with and produce the mouth of a river (13) and concentrate floss hole (15); In the putamina (11) on hollow fiber film unit (20) top, be provided with concentrate delivery pipe (16), it is characterized in that: described hollow fiber film unit (20) comprises a plurality of hollow fibre membrane components (30), water inlet end central tube (22) and produces water end (W.E.) central tube (21); Each hollow fibre membrane component (30) by water inlet end bellows (31), water inlet end resin-cast fixed bed (32), produce water end (W.E.) bellows (33), produce water end (W.E.) resin-cast fixed bed (34) and be fixed on water inlet end resin-cast fixed bed (32) and product water end (W.E.) resin-cast fixed bed (34) between many hollow fiber film threads (35) form, between adjacent two water inlet end bellows (31), leave gap and form gas-liquid flow-guiding channel (23b), each water inlet end bellows (31) inside is also provided with a plurality of gas-liquid pod apertures (23a); Each hollow fibre membrane component (30) is connected with product water end (W.E.) central tube (21) with water inlet end central tube (22) with product water end (W.E.) bellows (33) by water inlet end bellows (31) respectively; Described hollow fiber film unit (20) is fixed in putamina (11) by top board (24), sealing gasket (25), lower platen (17), location jump ring (18) and a plurality of trip bolt (19).
2. a kind of column type hollow fiber membrane modular as claimed in claim 1 (10), it is characterized in that: described hollow fiber film unit (20) is comprised of 2~12 hollow fibre membrane components (30), be circumference equidistantly arrangement or the arrangement of circumference non-equidistance.
3. a kind of column type hollow fiber membrane modular as claimed in claim 1 (10), is characterized in that: described water inlet end bellows (31) and the cross sectional shape that produces water end (W.E.) bellows (33) are fan-shaped, circle or polygon.
4. a kind of column type hollow fiber membrane modular as claimed in claim 1 (10), is characterized in that: described water inlet end resin-cast fixed bed (32) and product water end (W.E.) resin-cast fixed bed (34) adopt epoxy resin, polyurethane or silicon rubber body.
5. a kind of column type hollow fiber membrane modular as claimed in claim 1 (10), is characterized in that: the material of described water inlet end bellows (31) and product water end (W.E.) bellows (33) adopts UPVC material, ABS material or stainless steel material.
6. a kind of column type hollow fiber membrane modular as claimed in claim 1 (10), is characterized in that: described putamina (11) external diameter is 90mm to 450mm.
7. a kind of column type hollow fiber membrane modular as claimed in claim 1 (10), it is characterized in that: the quantity of the inner gas-liquid pod apertures of described water inlet end bellows (31) (23a) is 1 to 6, each gas-liquid pod apertures (23a) area of section is 5mm 2to 2000mm 2.
CN201210254283.3A 2012-07-20 2012-07-20 Column-type hollow fiber membrane assembly Active CN102872722B (en)

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CN104072642A (en) * 2013-03-29 2014-10-01 海南大学 Device for recycling skim rubber
KR101486886B1 (en) * 2013-12-16 2015-01-28 주식회사 휴비스 Cap for fixing hollow fiber membrane and fluid distribution
CN104128095B (en) * 2014-08-06 2016-08-24 北京赛诺膜技术有限公司 A kind of high resistant to pollution hollow fiber film assembly
CN106914137B (en) * 2015-12-24 2019-11-22 国投生物科技投资有限公司 A kind of film concentration systems and method
CN107285459B (en) * 2017-08-16 2024-05-03 陕西雷光环保科技有限公司 Membrane bioreactor
CN113368689B (en) * 2021-06-30 2022-05-17 北京赛诺膜技术有限公司 Immersion type hollow fiber membrane element, membrane module device, membrane module system and preparation method

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CN201189450Y (en) * 2008-03-26 2009-02-04 天津大学 Laminar hollow fiber membrane module
CN201997263U (en) * 2010-12-21 2011-10-05 旭化成化学株式会社 Impregnated membrane unit
CN202283454U (en) * 2011-10-14 2012-06-27 北京碧水源膜科技有限公司 Columnar beam-splitting pulsation type hollow-fiber membrane element
CN202778284U (en) * 2012-07-20 2013-03-13 北京赛诺膜技术有限公司 Column type hollow fiber membrane assembly

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