CN102863609A - Organic silicon curing agent for epoxy floor paint and preparation method and application thereof - Google Patents
Organic silicon curing agent for epoxy floor paint and preparation method and application thereof Download PDFInfo
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- CN102863609A CN102863609A CN2012103278594A CN201210327859A CN102863609A CN 102863609 A CN102863609 A CN 102863609A CN 2012103278594 A CN2012103278594 A CN 2012103278594A CN 201210327859 A CN201210327859 A CN 201210327859A CN 102863609 A CN102863609 A CN 102863609A
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Abstract
The invention discloses an organic silicon curing agent for the epoxy floor paint and a preparation method and application thereof. The structure of the organic silicon curing agent for the epoxy floor paint is shown as the formula I. The preparation method comprises the following steps: mixing 100 parts by weight of polydimethylsiloxane, 10-80 parts by weight of an aminosilane coupling agent and 0-20 parts by weight of water and reacting at 50-150 DEG C under the action of a catalyst to obtain the organic silicon curing agent for the epoxy floor paint. The curing agent has both amino curing groups and long-chain polysiloxane, thus the curing agent has double effects of the curing agent and the organic silicon modifier and correspondingly achieves excellent stain resistance, wear resistance, hardness and other performances.
Description
Technical field
The invention belongs to the epoxy flooring coating field, particularly a kind of epoxy flooring coating organosilicon solidifying agent and preparation method thereof and application.
Background technology
Epoxypaint because have that higher hardness, wear resistance are high, the characteristics such as strong adhesion and excellent chemical resistance, therefore at industry ground slab coating, the fields such as building coating are widely used.Exist in application process that weathering resistance is poor, matter is crisp, the problems such as impact resistance and the dirty poor performance of oil resistant, therefore, mainly be to overcome the problems such as epoxy flooring coating easily scratches, resistant, shock resistance be not poor to the modification of epoxy flooring coating.
The solidifying agent that is applied at present epoxy flooring coating mainly is polyamine, polyetheramine, the polyamino acid amides, traditional solidifying agent such as end amido polymeric amide, the hardness of the epoxy flooring coating that these solidifying agent solidify, wear resistance, shock resistance etc. are difficult to satisfy simultaneously the service requirements to epoxy flooring coating.
Summary of the invention
The shortcoming that primary and foremost purpose of the present invention is to overcome prior art provides a kind of epoxy flooring coating organosilicon solidifying agent with not enough.This organosilicon solidifying agent can use separately, also can jointly use with other epoxy flooring coating solidifying agent, with the dual function of solidifying agent and silicone additives.
Another object of the present invention is to provide the preparation method of described epoxy flooring coating with the organosilicon solidifying agent.
A further object of the present invention is to provide the application of described epoxy flooring coating with the organosilicon solidifying agent.
Purpose of the present invention is achieved through the following technical solutions: a kind of epoxy flooring coating organosilicon solidifying agent, and structural formula is suc as formula shown in the I:
Wherein, n is 50～2000 integer; N1 is 1～7 integer; R is-NH
2Or MNH-, M is phenyl, benzyl, aromatic base or alkyl etc.; R
1For H or carbon chain lengths are the alkyl of C1～C5;
The described epoxy flooring coating preparation method of organosilicon solidifying agent, comprise following steps: 100 mass parts polydimethylsiloxanes, 10～80 mass parts amino silicane coupling agents and 0～20 mass parts water are mixed, under the effect of catalyzer, in 50～150 ℃ of reactions, obtain epoxy flooring coating organosilicon solidifying agent;
The time of described reaction is preferably 3～10 hours;
It is 50～2000 that described polydimethylsiloxane is preferably polymerization degree n, and more preferably polymerization degree n is 500～1000 polydimethylsiloxane;
The structural formula of described amino silicane coupling agent is suc as formula shown in the II:
Wherein, n1 is 1～7 integer; R is-NH
2Or MNH-, M is phenyl, benzyl, aromatic base or alkyl etc.; R
1For H or carbon chain lengths are the alkyl of C1～C5;
Described amino silicane coupling agent is γ aminopropyltriethoxy silane, 4-aminobutyl triethoxyl silane, anilinomethyl triethoxysilane, 3-TSL 8330, anilinomethyl trimethoxy silane, γ-aminopropyltrimethoxysilane, phenylamino Trimethoxy silane, N-(aminoethyl more preferably)-at least a in γ-aminopropyl methyldiethoxysilane or the aminoethyl aminoethyl aminopropyl trimethoxysilane;
Described catalyzer is organic tin compound or Louis's acids etc.;
Described organic tin compound is preferably two bay dibutyl acid tin;
Described Lewis acid is preferably aluminum chloride, tindichloride and zinc chloride etc.;
The consumption of described catalyzer is preferably 0.001～1% of reaction system quality, and more preferably 0.01～0.5%;
Described reaction is hydrolysis-condensation reaction;
Described epoxy flooring coating can use separately with the organosilicon solidifying agent, also can jointly use with other epoxy flooring coating solidifying agent;
Described other epoxy flooring coating solidifying agent is at least a in polyamine, urethane, polyetheramine, polyamino acid amides, end amido polymeric amide or the organic acid anhydride;
A kind of epoxy flooring coating comprises following component by mass parts:
100 parts of Resins, epoxy, described epoxy flooring coating are with 0～50 part of 5～90 parts in organosilicon solidifying agent, 0～20 part of epoxide diluent, 20～150 parts of fillers, 0～10 part of dispersion agent, 0～30 part in common solidifying agent, 0～1.5 part of promotor, 0.1～5 part of flow agent, 0.1～6 part of defoamer, 0.1～3 part of tinting material and organic solvent;
Described Resins, epoxy is liquid epoxies, is preferably a kind of in bisphenol A type epoxy resin, bisphenol f type epoxy resin, o-cresol formaldehyde epoxy resin, novolac epoxy or the bisphenol A-type novolac epoxy or at least two kinds;
Described epoxide diluent is the compound of glycidyl ester class, comprises a kind of in epoxy propane butyl ether, C12～C14 Fatty Alcohol(C12-C14 and C12-C18) glycidyl ether, propylene oxide phenyl ether or the propylene oxide benzylic ether or at least two kinds;
Described filler is a kind of in silicon-dioxide, polynite, kaolin, quartz sand, talcum powder or the calcium carbonate or at least two kinds;
Described dispersion agent is the unsaturated polycarboxylic acid polymers soln of lower molecular weight, is preferably at least a among BYK-P104, the BYK-P105 of German BYK company or the BYK163;
Described common solidifying agent is a kind of in amine curing agent, polyamine, polyamines base amide hardener, end amido polymeric amide, polyetheramine, urethane, isocyanic ester or the organic acid anhydride or at least two kinds;
Described promotor comprises imidazoles and imdazole derivatives, tertiary amine, quaternary amine, organic bases and Lewis acid etc.;
Described imdazole derivatives is preferably 2-ethyl-4-methylimidazole and glyoxal ethyline etc.;
Described organic bases is preferably Tetramethylammonium hydroxide etc.;
Described Lewis acid is preferably zinc chloride and aluminum chloride etc.;
Described flow agent is preferably fluorine carbon flow agent, more preferably EFKA3777
Described defoamer is the polysiloxane defoamer, more preferably the defoamer BYK066 of German Bi Ke (BYK);
Described tinting material is preferably a kind of in titanium dioxide, carbon black, phthalocyanine, chrome yellow, organic yellow, red iron oxide or the iron oxide black or at least two kinds;
Described organic solvent is a kind of in dimethylbenzene, phenylcarbinol, butanone, butanols, hexone or the N-BUTYL ACETATE or at least two kinds.
Principle: the present invention has prepared a kind of organosilicon solidifying agent by hydrolysis-condensation reaction, owing to containing the functional group that participates in epoxy resin cure in this organosilicon solidifying agent structure, the segment that contains simultaneously polydimethylsiloxane, in epoxy flooring coating, with the effect of solidifying agent and organosilicon modifier; And in solidifying the process of terrace paint, the polysiloxane of long-chain is fixed in the Resins, epoxy, increased the consistency between Resins, epoxy and the polysiloxane, be conducive to improve the shock resistance of epoxy flooring coating, toughness and resistance to soiling etc.
The present invention has following advantage and effect with respect to prior art:
(1) amino silicane coupling agent and polydimethylsiloxane carry out the synthetic a kind of terrace paint organosilicon solidifying agent of hydridization among the present invention, in the solidification process of epoxy flooring coating, the polysiloxane of long-chain are fixed in the cross linking of epoxy resin network.
(2) the prepared terrace paint of the present invention has the polysiloxane of long-chain, with the double effects of solidifying agent and organosilicon modifier simultaneously with in the organosilicon solidifying agent structure amino curing groups being arranged not only.
(3) the prepared terrace paint of the present invention has good resistance to soiling with the epoxy flooring coating that the organosilicon solidifying agent solidifies, and is wear-resisting, the performances such as hardness.
Embodiment
The present invention is described in further detail below in conjunction with embodiment, but embodiments of the present invention are not limited to this.
Embodiment 1
(1) the epoxy flooring coating preparation of organosilicon solidifying agent: with 100g polydimethylsiloxane (n=50), the 10g γ aminopropyltriethoxy silane, water 1g and catalyzer two bay dibutyl acid tin 0.01g join in the reaction flask, the condensation reaction 7 hours that is hydrolyzed under 110 ℃ obtains epoxy flooring coating organosilicon solidifying agent.
(2) the epoxy flooring coating application of organosilicon solidifying agent: with bisphenol A type epoxy resin (oxirane value: 0.51mol/100g) 60g, bisphenol f type epoxy resin (oxirane value: 0.51mol/100g) 40g, epoxy flooring coating organosilicon solidifying agent 90g, epoxy propane butyl ether 20g, silicon-dioxide 80g, dispersant B YK-P1042g, glyoxal ethyline 1.5g, flow agent EFKA3777 1g, defoamer BYK066 2g, red iron oxide 3g, butanone 20g, obtain epoxy flooring coating after stirring, it is directly carried out testing its performance behind the curing of coating.The hardness of terrace paint adopts standard GB/T6739-1996(determination of pencil hardness method) to measure, wear resistance adopts standard GB/T 1768-2006 to measure, and impact resistance adopts the method for 6.4.9 among the standard GB/T22374-2008 to test.The hardness of test result terrace paint is 2H, and wear resistance is 0.020, and impact resistance is the II level, and the flawless nothing of coatingsurface comes off.
Embodiment 2
(1) the epoxy flooring coating preparation of organosilicon solidifying agent: with 100g polydimethylsiloxane (n=2000), 30g 4-aminobutyl triethoxyl silane, 10g water and catalyzer aluminum chloride 0.05g join in the reaction flask, 100 ℃ of lower reactions 8 hours, obtain epoxy flooring coating organosilicon solidifying agent.
(2) the epoxy flooring coating application of organosilicon solidifying agent: with bisphenol A-type novolac epoxy (oxirane value: 0.44mol/100g) 40g, phenol aldehyde type epoxy resin (oxirane value: 0.51mol/100g) 50g, Bisphenol F shape Resins, epoxy (oxirane value: 0.51mol/100g) 10g, 70 parts in organosilicon solidifying agent of epoxy flooring coating, polyetheramine (D230) 5g, dodecyl Fatty Alcohol(C12-C14 and C12-C18) glycidyl ether 10g, kaolin 50g, dispersant B YK-P104 1g, zinc chloride 0.3g, flow agent EFKA3777 0.5g, defoamer BYK066 0.3g, titanium dioxide 0.8g, dimethylbenzene 35g, obtain epoxy flooring coating after stirring, it is directly carried out testing its performance behind the curing of coating.The hardness of terrace paint adopts standard GB/T6739-1996(determination of pencil hardness method) to measure, wear resistance adopts standard GB/T 1768-2006 to measure, and impact resistance adopts the method for 6.4.9 among the standard GB/T22374-2008 to test.The hardness of test result terrace paint is 2H, and wear resistance is 0.022, and impact resistance is the II level, and the flawless nothing of coatingsurface comes off.
Embodiment 3
(1) the epoxy flooring coating preparation of organosilicon solidifying agent: with the polydimethylsiloxane (n=200) of 100g, the 80g anilinomethyl triethoxysilane, water 20g, catalyzer 0.04g tindichloride joins in the reaction flask, the condensation reaction 4 hours that is hydrolyzed under 150 ℃ obtains epoxy flooring coating organosilicon solidifying agent.
(2) the epoxy flooring coating application of organosilicon solidifying agent: with bisphenol A type epoxy resin (oxirane value: 0.54mol/100g) 30g, o-cresol epoxy resin (oxirane value: 0.51mol/100g) 60g, bisphenol A-type phenolic aldehyde epoxy tree (oxirane value: 0.51mol/100g) fat 10g, epoxy flooring coating organosilicon solidifying agent 10g, polyetheramine (ZY-1784) 30g, propylene oxide phenyl ether 15g, talcum powder 10g, polynite 10g, flow agent EFKA3777 0.1g, defoamer BYK066 0.1g, phthalocyanine 0.5g, phenylcarbinol 10g obtains epoxy flooring coating after stirring, and it is directly carried out testing its performance behind the curing of coating.The hardness of terrace paint adopts standard GB/T6739-1996(determination of pencil hardness method) to measure, wear resistance adopts standard GB/T 1768-2006 to measure, and impact resistance adopts the method for 6.4.9 among the standard GB/T22374-2008 to test.The hardness of test result terrace paint is 2H, and wear resistance is 0.019, and impact resistance is the II level, and the flawless nothing of coatingsurface comes off.
Embodiment 4
(1) the epoxy flooring coating preparation of organosilicon solidifying agent: with the polydimethylsiloxane (n=500) of 100g, 5g 3-TSL 8330,25g γ-anilinomethyl trimethoxy silane, catalyzer 0.02g zinc chloride joins in the reaction flask, the condensation reaction 9 hours that is hydrolyzed under 50 ℃ obtains the organosilicon solidifying agent.
(2) the epoxy flooring coating application of organosilicon solidifying agent: with bisphenol A type epoxy resin (oxirane value: 0.41mol/100g) 30g, bisphenol A-type novolac epoxy 70g(oxirane value: 0.54mol/100g), epoxy flooring coating organosilicon solidifying agent 30g, alicyclic ring amine curing agent (ZY3002) 5g, silica 1 00g, imidazoles 0.05g, flow agent EFKA3777 2g, defoamer BYK066 0.8g, titanium oxide 0.1g, N-BUTYL ACETATE 40g obtains epoxy flooring coating after stirring, and it is directly carried out testing its performance behind the curing of coating.The hardness of terrace paint adopts standard GB/T6739-1996(determination of pencil hardness method) to measure, wear resistance adopts standard GB/T 1768-2006 to measure, and impact resistance adopts the method for 6.4.9 among the standard GB/T22374-2008 to test.The hardness of test result terrace paint is H, and wear resistance is 0.023, and impact resistance is the II level, and the flawless nothing of coatingsurface comes off.
Embodiment 5
(1) the epoxy flooring coating preparation of organosilicon solidifying agent: with the polydimethylsiloxane (n=1000) of 100g, the 25g γ-aminopropyltrimethoxysilane, 25g phenylamino Trimethoxy silane, water 8g, catalyzer 0.03g two bay dibutyl acid tin joins in the reaction flask, the condensation reaction 7 hours that is hydrolyzed under 80 ℃ obtains the organosilicon solidifying agent.
(2) the epoxy flooring coating application of organosilicon solidifying agent: with bisphenol A type epoxy resin (oxirane value: 0.44mol/100g) 20g, bisphenol f type epoxy resin (oxirane value: 0.51mol/100g) 50g, novolac epoxy (oxirane value: 0.51mol/100g) 15g, bisphenol A-type novolac epoxy (oxirane value: 0.54mol/100g) 15g, epoxy flooring coating organosilicon solidifying agent 5g, end amido polymeric amide (ZY-140) 25g, epoxy propane butyl ether 20g, kaolin 150g, dispersant B YK-P105 8g, flow agent EFKA3777 5g, defoamer BYK066 6g, organic yellow 1g, hexone 50g, obtain epoxy flooring coating after stirring, it is directly carried out testing its performance behind the curing of coating.The hardness of terrace paint adopts standard GB/T6739-1996(determination of pencil hardness method) to measure, wear resistance adopts standard GB/T 1768-2006 to measure, and impact resistance adopts the method for 6.4.9 among the standard GB/T22374-2008 to test.The hardness of test result terrace paint is H, and wear resistance is 0.023, and impact resistance is the II level, and the flawless nothing of coatingsurface comes off.
Embodiment 6
(1) the epoxy flooring coating preparation of organosilicon solidifying agent: with the polydimethylsiloxane (n=800) of 100g, 50g γ-anilinomethyl trimethoxy silane, 5g N-(aminoethyl)-γ-aminopropyl methyldiethoxysilane, water 5g, catalyzer 0.05g two bay dibutyl acid tin joins in the reaction flask, the condensation reaction 8 hours that is hydrolyzed under 100 ℃ obtains the organosilicon solidifying agent.
(2) the epoxy flooring coating application of organosilicon solidifying agent: with bisphenol A-type novolac epoxy (oxirane value: 0.44mol/100g) 80g, novolac epoxy (oxirane value: 0.44mol/100g) 20g, epoxy flooring coating organosilicon solidifying agent 25g, organic acid anhydride 25g, propylene oxide benzylic ether 15g, calcium carbonate 50g, dispersant B YK163 1.5g, flow agent EFKA3777 1.5g, defoamer BYK0660.4g, chrome yellow 0.2g, butanols 30g, obtain epoxy flooring coating after stirring, it is directly carried out testing its performance behind the curing of coating.The hardness of terrace paint adopts standard GB/T6739-1996(determination of pencil hardness method) to measure, wear resistance adopts standard GB/T 1768-2006 to measure, and impact resistance adopts the method for 6.4.9 among the standard GB/T22374-2008 to test.The hardness of test result terrace paint is 2H, and wear resistance is 0.018, and impact resistance is the II level, and the flawless nothing of coatingsurface comes off.
Embodiment 7
(1) the epoxy flooring coating preparation of organosilicon solidifying agent: with the polydimethylsiloxane (n=1200) of 100g, 40g γ-anilinomethyl trimethoxy silane, 15g aminoethyl aminoethyl aminopropyl trimethoxysilane, water 5g, catalyzer two bay dibutyl acid tin 0.05g joins in the reaction flask, the condensation reaction 8 hours that is hydrolyzed under 100 ℃ obtains epoxy flooring coating with organosilicon solidifying agent (being numbered Si-CA).
(2) the epoxy flooring coating application of organosilicon solidifying agent: with the bisphenol epoxy of 0.51mol/100g, epoxy flooring coating organosilicon solidifying agent Si-CA and 4,4-diaminodiphenyl-methane (DDM), silicon-dioxide, epoxide diluent, dispersant B YK163, flow agent FKA3777, defoamer BYK066, red iron oxide, butanone is mixed with epoxy flooring coating according to the weight ratio shown in the table 1.The hardness of terrace paint adopts standard GB/T6739-1996(determination of pencil hardness method in the table 1) to measure, wear resistance adopts standard GB/T1768-2006 to measure, and impact resistance adopts the method for 6.4.9 among the standard GB/T22374-2008 to test.
As can be seen from Table 1, compare with the epoxy flooring coating that independent polyamino solidifying agent solidifies, use the prepared organosilicon solidifying agent of the present invention after, the wear resistance of terrace paint increases, impact resistance reaches the II level.Effectively raise impact resistance and the wear resistance of terrace paint.
The prescription of table 1 epoxy flooring coating
| Material | A/g | B/g | C/g |
| Bisphenol A epoxide resin | 100 | 100 | 100 |
| Si-CA | 0 | 40 | 25 |
| DDM | 21 | 0 | 15 |
| The epoxypropyl benzylic ether | 5 | 5 | 5 |
| Silicon-dioxide | 50 | 50 | 50 |
| Dispersant B YK163 | 2 | 2 | 2 |
| Tetramethylammonium hydroxide | 0.2 | 0.2 | 0.2 |
| Flow agent FKA3777 | 1 | 1 | 1 |
| Defoamer BYK066 | 0.5 | 0.5 | 0.5 |
| Red iron oxide | 3 | 3 | 3 |
| Butanone | 15 | 15 | 15 |
| Hardness | H | 2H | 2H |
| Wear resistance | 0.023 | 0.019 | 0.020 |
| Impact property | The I level | The II level | The II level |
Above-described embodiment is the better embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and the principle, substitutes, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. epoxy flooring coating organosilicon solidifying agent is characterized in that structural formula is suc as formula shown in the I:
Wherein, n is 50～2000 integer; N1 is 1～7 integer; R is-NH
2Or MNH-, M is phenyl, benzyl, aromatic base or alkyl; R
1For H or carbon chain lengths are the alkyl of C1～C5.
2. epoxy flooring coating claimed in claim 1 is with the preparation method of organosilicon solidifying agent, it is characterized in that comprising following steps: 100 mass parts polydimethylsiloxanes, 10～80 mass parts amino silicane coupling agents and 0～20 mass parts water are mixed, under the effect of catalyzer, in 50～150 ℃ of reactions, obtain epoxy flooring coating organosilicon solidifying agent;
The structural formula of described amino silicane coupling agent is suc as formula shown in the II:
Wherein, n1 is 1～7 integer; R is-NH
2Or MNH-, M is phenyl, benzyl, aromatic base or alkyl; R
1For H or carbon chain lengths are the alkyl of C1～C5.
3. epoxy flooring coating according to claim 2 is with the preparation method of organosilicon solidifying agent, and it is characterized in that: described polydimethylsiloxane is that polymerization degree n is 50～2000 polydimethylsiloxane.
4. epoxy flooring coating according to claim 2 is with the preparation method of organosilicon solidifying agent, and it is characterized in that: described amino silicane coupling agent is γ aminopropyltriethoxy silane, 4-aminobutyl triethoxyl silane, anilinomethyl triethoxysilane, 3-TSL 8330, anilinomethyl trimethoxy silane, γ-aminopropyltrimethoxysilane, phenylamino Trimethoxy silane, N-(aminoethyl)-at least a in γ-aminopropyl methyldiethoxysilane or the aminoethyl aminoethyl aminopropyl trimethoxysilane.
5. epoxy flooring coating according to claim 2 is with the preparation method of organosilicon solidifying agent, and it is characterized in that: the time of described reaction is 3～10 hours; The consumption of described catalyzer is 0.001～1% of reaction system quality; Described catalyzer is organic tin compound or Lewis acid.
6. epoxy flooring coating according to claim 5 is with the preparation method of organosilicon solidifying agent, and it is characterized in that: described organic tin compound is two bay dibutyl acid tin; Described Lewis acid is at least a in aluminum chloride, tindichloride or the zinc chloride.
7. epoxy flooring coating claimed in claim 1 is characterized in that with the application of organosilicon solidifying agent: described epoxy flooring coating is with the separately use or jointly use with other epoxy flooring coating solidifying agent of organosilicon solidifying agent;
Described other epoxy flooring coating solidifying agent is at least a in polyamine, urethane, polyetheramine, polyamino acid amides, end amido polymeric amide or the organic acid anhydride.
8. epoxy flooring coating is characterized in that comprising following component by mass parts: 100 parts of Resins, epoxy, epoxy flooring coating claimed in claim 1 are with 0～50 part of 5～90 parts in organosilicon solidifying agent, 0～20 part of epoxide diluent, 20～150 parts of fillers, 0～10 part of dispersion agent, 0～30 part in common solidifying agent, 0～1.5 part of promotor, 0.1～5 part of flow agent, 0.1～6 part of defoamer, 0.1～3 part of tinting material and organic solvent;
Described common solidifying agent is a kind of in amine curing agent, polyamine, polyamines base amide hardener, end amido polymeric amide, polyetheramine, urethane, isocyanic ester or the organic acid anhydride or at least two kinds.
9. epoxy flooring coating claimed in claim 8, it is characterized in that: described Resins, epoxy is liquid epoxies; Described epoxide diluent is the compound of glycidyl ester class; Described filler is a kind of in silicon-dioxide, polynite, kaolin, quartz sand, talcum powder or the calcium carbonate or at least two kinds; Described dispersion agent is the unsaturated polycarboxylic acid polymers soln of lower molecular weight; Described promotor is imidazoles and imdazole derivatives, tertiary amine, quaternary amine, organic bases or Lewis acid; Described flow agent is fluorine carbon flow agent; Described defoamer is the polysiloxane defoamer; Described tinting material is a kind of in titanium dioxide, carbon black, phthalocyanine, chrome yellow, organic yellow, red iron oxide or the iron oxide black or at least two kinds; Described organic solvent is a kind of in dimethylbenzene, phenylcarbinol, butanone, butanols, hexone or the N-BUTYL ACETATE or at least two kinds.
10. epoxy flooring coating according to claim 9 is characterized in that: described Resins, epoxy is a kind of in bisphenol A type epoxy resin, bisphenol f type epoxy resin, o-cresol formaldehyde epoxy resin, novolac epoxy or the bisphenol A-type novolac epoxy or at least two kinds;
Described epoxide diluent is a kind of in epoxy propane butyl ether, C12～C14 Fatty Alcohol(C12-C14 and C12-C18) glycidyl ether, propylene oxide phenyl ether or the propylene oxide benzylic ether or at least two kinds;
Described dispersion agent is at least a among BYK-P104, BYK-P105 or the BYK163;
Described imdazole derivatives is 2-ethyl-4-methylimidazole or glyoxal ethyline;
Described organic bases is Tetramethylammonium hydroxide; Described Lewis acid is zinc chloride or aluminum chloride;
Described flow agent is EFKA3777; Described defoamer is defoamer BYK066.
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