Background technology
Mineral Resources in China 80% is intergrowth mineral, and a large amount of valuable resources retain among mine tailing, and tailings impoundment need to take a large amount of soils.A lot of Tailings Dams exceed the time limit or excess load is used, and even violation operation, make Tailings Dam have great potential safety hazard, and people's property and the life security of surrounding area caused to serious threat.
Attapulgite clay, except containing attapulgite, often contains the mineral such as montmorillonite, kaolinite, hydromica, sepiolite, quartz, opal and carbonate.
With the volcanoclastic rock that also has of attapulgite clay ore deposit symbiosis, volcanoclastic rock is mostly on the upper strata in attapulgite clay ore deposit, the volcanoclastic rock ore bed on upper strata, some attapulgite clays mining area
'sthickness is up to tens of rice, attapulgite clay is in recovery process, the volcanoclastic rock on upper strata, attapulgite clay mining area is abandoned as waste, investigate factually, the volcanoclastic rock that 1 ton of attapulgite clay of every exploitation produces has more than 30 tons, by the output of producing 150000 tons per year, calculates, the volcanoclastic rock produced is up to 4,500,000 tons, all can be utilized for many years, whole mining area is the volcanoclastic rock mixture of again piling up everywhere, causes the serious wasting of resources and financial loss.
Refractory concrete is a kind ofly can bear high temperature, and at high temperature keeps the special concrete of needed Physical and mechanical properties, formulated by a certain percentage by suitable gelling material, refractory aggregate, fire resistant ceramsites, adulterant and water.
Coal gangue is thrown aside, takies tract, and sulfide in coal gangue is overflowed or leached can atmosphere pollution, farmland and water body, and waste dump also can the spontaneous combustion presence of fire, or, in the avalanche in rainy season, silts river up and cause disaster.
Summary of the invention
The objective of the invention is to overcome weak point in prior art, a kind of unburned attapulgite fire-retarding ceramsite insulating brick is provided.
The batching of unburned attapulgite fire-retarding ceramsite insulating brick is comprised of attapulgite clay mine tailing, spherical attapulgite refractory ceramsite, volcanoclastic rock mixture, wilkinite mine tailing, expanded vermiculite and aluminate cement.The production method of unburned attapulgite fire-retarding ceramsite insulating brick: the batching of unburned attapulgite fire-retarding ceramsite insulating brick process is stirred, be pressed into difform unburned attapulgite fire-retarding ceramsite insulating brick work in-process, maintenance is carried out in conventional maintenance process according to cement products, is packaged as the finished product of unburned attapulgite fire-retarding ceramsite insulating brick after 28 days.
Attapulgite clay be a kind of layer of chain-like structure containing Shuifu County's zeopan clay mineral, attapulgite clay soil property exquisiteness, water-absorbent is strong, tool viscosity and plasticity-when wet, be conducive to the bonding between raw material, and can improve intensity and the porosity of unburned attapulgite fire-retarding ceramsite insulating brick.
Attapulgite clay can mix in recovery process a certain amount of rubble and earth, can't be sieved, and as a kind of mine tailing, abandons, and causes a large amount of wastings of resources, and the present invention selects the attapulgite clay mine tailing after pulverizing, particle fineness≤0.149 millimeter.
Spherical attapulgite refractory ceramsite is spheroidal, surface irregularity and hard, there is a large amount of trickle pores inside, be a kind of lightweight, ultimate compression strength is high, thermal conductivity is low, refractoriness is high, stable chemical performance, the fire resistant ceramsites that corrosion-resistant and heat preservation and soundproof is effective, the present invention selects the particle diameter of spherical attapulgite refractory ceramsite≤20.0 millimeters.
Volcanoclastic rock is the rock of the transitional type between magma lava and sedimentogeneous rock, wherein the composition more than 50% is comprised of the material of pyroclastic flow ejection, and these tephras are mainly the lava of premature coagulation on volcano, the rock formation that passage is burst on every side when volcanic eruption.The volcanoclastic rock mixture comprises landwaste, brilliant bits, glassiness bits, slurry bits, volcanic block, volcanic gravel and volcanic ash, volcanoclastic rock can increase the intensity of unburned attapulgite fire-retarding ceramsite insulating brick, the present invention selects the volcanoclastic rock mixture after pulverizing, particle fineness≤5.0 millimeter.
Wilkinite has plasticity-and agglutinating value(of coal), and the wilkinite mine tailing that the present invention selects is distributed in the lower floor in attapulgite clay ore deposit mostly, is difficult to carry out independent exploitation, quality is also poor, major part is abandoned in the mine tailing district, and the present invention selects the wilkinite mine tailing after pulverizing, particle fineness≤0.25 millimeter.
The fabric and raw-vermiculite sheet is after high-temperature roasting, its volume energy expands rapidly several times to tens times, vermiculite after volumetric expansion just is expanded vermiculite, it is laminate structure, interlayer contains crystal water, and thermal conductivity is little, is good heat-insulating heat-preserving material, the present invention selects the expanded vermiculite after pulverizing, particle fineness≤1.0 millimeter.
The cement selection aluminate cement.
The present invention is achieved by following technical proposals:
1, the batching of unburned attapulgite fire-retarding ceramsite insulating brick is comprised of following component by weight percentage: attapulgite clay mine tailing 2~20%, spherical attapulgite refractory ceramsite 5~30%, volcanoclastic rock mixture 5~25%, wilkinite mine tailing 2~15%, expanded vermiculite 2~10%, aluminate cement 5~15% and water 10~40%;
The production method of described unburned attapulgite fire-retarding ceramsite insulating brick: the batching of unburned attapulgite fire-retarding ceramsite insulating brick is added in the two shaft pugmill mixer moved and stirs, after stirring, be transported in fully-automatic building block forming machine, be pressed into difform unburned attapulgite fire-retarding ceramsite insulating brick work in-process, maintenance is carried out in conventional maintenance process according to cement products, is packaged as the finished product of unburned attapulgite fire-retarding ceramsite insulating brick after 28 days;
Describedly be pressed into difform unburned attapulgite fire-retarding ceramsite insulating brick work in-process, refer to according to the design needs, be pressed into the unburned attapulgite fire-retarding ceramsite insulating brick work in-process of square, rectangle, trilateral, ellipse, trapezoidal, quincunx, rhombus;
Described spherical attapulgite refractory ceramsite is comprised of the sticky attapulgite clay powder of height, attapulgite clay mine tailing, GBFS, iron tailings powder, colliery powder, bauxite gangue powder and diatomite mine tailing; The production method of spherical attapulgite refractory ceramsite: be spherical attapulgite refractory ceramsite through mixing, granulation, roasting, cooling and screening by the batching of spherical attapulgite refractory ceramsite.
Spherical attapulgite refractory ceramsite is the patent of invention that the inventor applied on November 10th, 2011, China Patent Publication No.: 102515784A, open day: on 06 27th, 2012.
Unburned attapulgite fire-retarding ceramsite insulating brick has that intensity is good, thermal conductivity is low, refractoriness is high and the characteristics of good effect of heat insulation.
In the batching of unburned attapulgite fire-retarding ceramsite insulating brick, the various wastes of a large amount of employing, not only be conducive to improve resource utilization, turns waste into wealth, and can also reduce land occupation, and protection and environment purification are saved the energy, reduce production costs, and increase economic efficiency.
Unburned attapulgite fire-retarding ceramsite insulating brick is applicable to various fire-resistant engineering constructions
.