CN102863146A - Physical toughened glass, solar cell panel and manufacture methods of physical toughened glass and solar cell panel - Google Patents
Physical toughened glass, solar cell panel and manufacture methods of physical toughened glass and solar cell panel Download PDFInfo
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- CN102863146A CN102863146A CN2011101985261A CN201110198526A CN102863146A CN 102863146 A CN102863146 A CN 102863146A CN 2011101985261 A CN2011101985261 A CN 2011101985261A CN 201110198526 A CN201110198526 A CN 201110198526A CN 102863146 A CN102863146 A CN 102863146A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
The invention discloses a piece of physical toughened glass, the thickness of the physical toughened glass is about 0.8-2.8mm, the compression strength of the physical toughened glass is about 120-300 MPa, the bending strength of the physical toughened glass is about 120-300 MPa, and the tensile strength of the physical toughened glass is about 90-180 MPa. The invention further discloses a solar cell panel comprising the physical toughened glass and manufacture methods of the physical toughened glass and the solar cell panel.
Description
Technical field
The relevant a kind of physical toughened glass of the application's case, especially a kind of thin thickness, and have the physical toughened glass of good mechanical properties, thermostability and transmittance, it can be used in opticglass, vehicle glass, building glass, ambetti and the aeronautical glasses, particularly solar panel.
Background technology
Toughened glass is called again chilled glass, has preferably mechanical properties and thermostability than general glass.Whether the tensile strength (tensile strength) of general common annealing glass is about 40MPa, and toughened glass is about 120 to 200MPa, depending on thickness, the Edge Finish of glass, hole or grooving and different.Toughened glass is exactly the tensile strength that has increased glass.If glass is processed through tempering in advance, then can allow 150 to 200 ℃ temperature head, also increased security simultaneously, therefore be widely used in each field.
Toughened glass is sheet glass, and such as the secondary processing product of float glass or annealed glass, it is to utilize physics or chemical process, forms a compressive stress layer at glass surface, forms a tension stress layer at inside glass simultaneously.When glass was subject to External Force Acting, this compressive stress layer can with the payment of part tension stress, be avoided the cracked of glass.Even the local generation of glass is damaged, then stress relief can occur, so that the countless fritters that glass breaking becomes not have sharp corners, be difficult for hurting sb.'s feelings.
Toughened glass can be divided into physical toughened glass and chemically toughened glass because of the processing mode difference.
Physical toughened glass is called again quenching toughened glass, it is that general sheet glass is cut into required size, carry out edging or boring, then be placed on the roller table, push the softening temperature (about 600 to 650 ℃) that is heated in the annealing furnace near glass, eliminate internal stress by the deformation of glass self, then glass sliding is gone out annealing furnace, with the bull nozzle cold high pressure air is blowed to the two sides of glass again, make it rapidly and be cooled to equably room temperature.After the cooling, can cause stress at glass surface, and inside glass forms tension stress, thereby reach the purpose that improves strength of glass.Because this kind tempering mode does not change the chemical constitution of glass, therefore be called physical toughened glass.
High about 3 to 5 times of the general glass of the strength ratio of physical toughened glass, and processing procedure is simple, expense is cheap, and long service life can reach the time about 20 years usually, is the present toughened glass of normal use on the market.But because the mode that heats by the roller table limits, the thickness of physical toughened glass needs more than 3 millimeters, just can not cause the distortion of glass.Yet as the glass that uses is too thick, with increasing the own wt of product, not only increases hauled weight, as using at top of building or roof surface, weight is born in increasing, causes the restriction in the use.In addition, the thicker transmittance of thickness of glass is then poorer.
Chemically toughened glass is the intensity that improves glass by the chemical constitution that changes glass surface, generally is that the methods such as application surface dealkalize or alkalimetal ion exchange process are carried out tempering.The chemical tempering mode has changed the contained composition of glass surface, so that glass produces very large carrying capacity, its effect and physical toughened category of glass are seemingly.
Strong about 9 to 15 times of the general glass of the strength ratio of chemically toughened glass, and without the upward restriction of thickness of processing.Yet chemically toughened glass is easy to because environmental factors damages, and follow-uply films difficultly, produce easily stripping phenomenon, so work-ing life is shorter, and usually only less than 10 years, and expense is higher, causes the restriction in the use.
In view of this, the present invention's research and development achievement of namely doing for foregoing problems.This case contriver finds to come toughened glass with the Aerodynamic Heating mode, can make thinner physical toughened glass, and does not affect or very can promote mechanical properties, thermostability and the transmittance of toughened glass, to meet the industry demand.
Summary of the invention
Therefore, in first aspect, the invention provides a kind of physical toughened glass, it has thinner thickness and good mechanical properties, thermostability and transmittance.Physical toughened glass of the present invention can be used for multiple fields, in opticglass, vehicle glass, building glass, ambetti and aeronautical glasses, particularly solar panel.
In second aspect, the invention provides a kind of manufacture method of physical toughened glass, it comprises processes glass through Aerodynamic Heating.
In the third aspect, the invention provides a kind of solar panel, it comprises above-mentioned thinner physical toughened glass.Solar panel of the present invention has good mechanical properties, thermostability and transmittance, can effectively promote the efficient of battery layers, and overall weight significantly alleviates, and not only can reduce cost, and range of application is wider.
In fourth aspect, the invention provides a kind of manufacture method of above-mentioned solar panel.
Embodiment
In herein, unless be particularly limited, odd number shape " " reaches " described " and also comprises its attached plural shape.Any and all embodiment and exemplary term (such as " for example ") purpose are only in order more to highlight the present invention herein, be not to be construed as limiting for scope of the present invention, the term in this case specification sheets should not be regarded as hinting that any not assembly of request can consist of the necessary assembly of implementing when of the present invention.
Physical toughened glass of the present invention has the thinner thickness of more commercially available physical toughened glass.Physical toughened glass of the present invention has about 0.8 millimeter to about 2.8 millimeters, better about 1.5 millimeters to about 2.5 millimeters, and better about 2.0 millimeters thickness, decides on the demand of the product of application.
In addition, physical toughened glass of the present invention has good mechanical properties, it comprises that about 120MPa is to about 300MPa, better about 150MPa is to the ultimate compression strength (compressive Strength) of about 250MPa, about 120MPa is to about 300MPa, better about 150MPa is to the bending strength (bending strength) of about 250MPa, and about 90MPa about 180MPa extremely, and better about 100MPa is the tensile strength (tensile strength) of about 150MPa extremely.
In addition, physical toughened glass of the present invention has splendid transmittance, and transmittance is relevant with the thickness of glass.In an implementation aspect of the present invention, have thickness and be about 2.0 millimeters physical toughened glass substrate and have about 92% to about 93% transmittance.
Implement in the aspect of the present invention one, the manufacture method of physical toughened glass may further comprise the steps:
Provide and have about 0.8 millimeter sheet glass to about 2.8 millimeters thickness;
Sheet glass is processed through Aerodynamic Heating; With
The cooling flat sheet glass.
In the present invention, the sheet glass that is fit to is the known person of persond having ordinary knowledge in the technical field of the present invention, and can be made by any prior art method, and it is such as but not limited to float glass or annealed glass.
In the present invention, term " Aerodynamic Heating " refers to that high-temperature gas that object and air or other gas produce when doing the high speed relative movement is to the heat transfer process of object.In of the present invention one better enforcement aspect, it is at an Aerodynamic Heating annealing furnace that Aerodynamic Heating is processed, and carries out in the dull and stereotyped annealing furnace (LiSEC ' s flatbed tempering furnace) such as Lee Saike company (LiSEC) production.
Implement in the aspect of the present invention one, the Heating temperature that Aerodynamic Heating is processed is about 600 ℃ to about 750 ℃, is preferably about 630 ℃ to about 700 ℃.
Being used in the present invention the method for cooling flat sheet glass is the known person of persond having ordinary knowledge in the technical field of the present invention, is preferably with air and uses nozzle to cool off rapidly.
Implement in the aspect of the present invention one, the manufacture method of physical toughened glass can optionally comprise other step, as before Aerodynamic Heating is processed, sheet glass is cut into desired size, edging or boring; Before Aerodynamic Heating is processed, on sheet glass, form a coating, it is such as but not limited to anti-reflecting layer, transparent conductive film, transparent metal oxide film, compound film or metallic film; With after cooled glass, on sheet glass, form a coating, it is such as but not limited to anti-reflecting layer, transparent conductive film, transparent metal oxide film, compound film or metallic film.
In of the present invention one better enforcement aspect, can after forming coating, glass be processed through the process furnace heating and cooling, with the sticking power between increase coating and glass, wherein the temperature of process furnace is preferably about 250 ℃ to about 400 ℃ such as but not limited to about 100 ℃ to about 600 ℃.
The present invention comes toughened glass with the Aerodynamic Heating mode, and glass does not directly contact with annealing furnace, can not cause the distortion of glass, the glass that applicable tempering is thinner.In addition, the physical toughened glass that the present invention makes by above method, have good mechanical properties, thermostability and transmittance, can be used for multiple fields, such as opticglass, vehicle glass, building glass, ambetti and aeronautical glasses, the particularly glass substrate of solar panel, double glazing, heat-protecting glass or sound control glass, the best is in the solar panel.
Based on this, the present invention provides a kind of solar panel in addition, and it comprises:
With described herein physical toughened glass as glass substrate;
The photovoltaic cell layer; With
Backboard.
In solar panel of the present invention, the photovoltaic cell layer is the known person of persond having ordinary knowledge in the technical field of the present invention.Implement in the aspect of the present invention one, the photovoltaic cell layer is to be selected from the group that is comprised of wafer type photovoltaic cell layer and film-type photovoltaic cell layer, its such as but not limited to, silicon single crystal photovoltaic cell layer, polysilicon photovoltaic cells Ceng, Arsenic potassium photovoltaic cell layer, amorphous silicon photovoltaic battery layers, cadmium telluride photovoltaic cell layer, copper indium diselenide photovoltaic cell layer, copper-indium-gallium-selenium photovoltaic battery layers or dye-sensitized photovoltaic battery layers.And each cell piece in the battery layers between be to be pooled to lead end by the wire series and parallel.
In solar panel of the present invention, backboard is the known person of persond having ordinary knowledge in the technical field of the present invention, and it is such as but not limited to glass substrate, plastic plate, stainless steel plate, aluminium sheet or matrix material.
Solar panel of the present invention optionally comprises other assembly in addition, and it is such as but not limited to anti-reflecting layer, insulating or absorber plate.
The present invention uses has about 0.8 millimeter extremely about 2.8 millimeters physical toughened glass as glass substrate, compare with the glass substrate of 3.0 millimeters of known normal operations or 4.0 millimeters, volume, weight all under with about 30% to about 80%, be preferably about 40%, thereby overall weight and the volume of solar panel have been reduced, also corresponding packing and the transportation cost of having reduced reduced the load-bearing of power plant bracket, roof and other buildings.Solar panel can be in the constant situation of other technique, working condition, make the total cost of solar panel production, transportation and installation that by a relatively large margin reduction be arranged, and created condition for the solar panel Pool Purchase Price near the thermoelectricity electricity price, economic benefit is huge.
The present invention also provides a kind of method of making solar panel, and it may further comprise the steps:
Provide herein described physical toughened glass as glass substrate;
On glass substrate, form the photovoltaic cell layer; With
Backboard is arranged on the photovoltaic cell layer.
Implement in the aspect of the present invention one, the photovoltaic cell layer is the centre that is sealed in glass substrate and backboard by sticking agent, wherein employed sticking agent is the known person of persond having ordinary knowledge in the technical field of the present invention, its such as but not limited to, polyvinyl butyral resin (PVB) composite bed or ethylene-vinyl acetate copolymer (EVA) composite bed.
Solar panel of the present invention be use thinner and physical toughened glass with good mechanical properties, thermostability and transmittance as glass substrate, therefore can effectively promote the efficient of battery layers, produce more electric energy, have higher intensity, and can bear larger blast and larger day and night difference variation.In addition, overall weight significantly alleviates, and not only can reduce cost, and range of application is wider.
The details of one or more embodiment of the present invention will be set forth in following description.According to these descriptions and claims, can easily understand further feature of the present invention, purpose and advantage.
Embodiment 1
Prepare physical toughened glass of the present invention
A sheet of annealed glass is cut into 2 millimeters of 2 meters of required length, 1 meter of width and thickness, then carry out edging, with in the boring of the position of subsequent installation terminal box or cut out desired shape, then it is pushed in the dull and stereotyped pneumatic annealing furnace of Lee Saike company (LiSEC) production, with about 600 ℃ air heating, then glass is shifted out dull and stereotyped pneumatic annealing furnace, with the bull nozzle cold high pressure air is blowed to the two sides of glass again, make it rapidly and be cooled to equably room temperature.
Given foregoing, the present invention processes with the tempering that the Aerodynamic Heating mode is carried out glass, extremely is fit to the thin glass of tempering.In addition, the present invention processes resulting physical toughened glass by Aerodynamic Heating and has good mechanical properties, thermostability and transmittance, be fit to be applied to multiple fields, particularly in the solar panel, can effectively promote the efficient of battery layers in the solar panel, produce more electric energy, can bear larger blast and larger day and night difference variation, reduce overall weight, and reduce cost, make its range of application more extensive.
Although described with reference to an illustrative embodiment the present invention, should be understood that any modification that the those skilled in the art can be easy to realize or change will belong in the scope of disclosure of this specification and the appended claims.
Claims (20)
1. physical toughened glass, its have about 0.8 millimeter to about 2.8 millimeters thickness, about 120MPa is to the ultimate compression strength of about 300MPa, about 120MPa is the bending strength of about 300MPa extremely, and about 90MPa tensile strength of about 180MPa extremely.
2. physical toughened glass according to claim 1, its have about 1.5 millimeters to about 2.5 millimeters thickness.
3. physical toughened glass according to claim 2, it has about 2.0 millimeters thickness.
4. physical toughened glass according to claim 1, it has about 150MPa to the ultimate compression strength of about 250MPa, and about 150MPa is the bending strength of about 250MPa extremely, and about 100MPa tensile strength of about 150MPa extremely.
5. physical toughened glass according to claim 1, wherein said physical toughened be the Aerodynamic Heating tempering.
6. physical toughened glass according to claim 1, it is for opticglass, vehicle glass, building glass, ambetti or aeronautical glasses.
7. physical toughened glass according to claim 6, it is glass substrate, double glazing, heat-protecting glass or sound control glass for solar panel.
8. the manufacture method of a physical toughened glass according to claim 1, it may further comprise the steps:
Provide and have about 0.8 millimeter sheet glass to about 2.8 millimeters thickness;
Described sheet glass is processed through Aerodynamic Heating; With
Cool off described sheet glass.
9. manufacture method according to claim 8, it is to carry out in the Aerodynamic Heating annealing furnace that wherein said Aerodynamic Heating is processed.
10. manufacture method according to claim 8, the temperature that wherein said Aerodynamic Heating is processed is about 600 ℃ to about 750 ℃.
11. manufacture method according to claim 10, the temperature that wherein said Aerodynamic Heating is processed is about 630 ℃ to about 700 ℃.
12. manufacture method according to claim 8, it further is included in before Aerodynamic Heating is processed, with described sheet glass cutting, edging or boring.
13. manufacture method according to claim 8, it further is included in before Aerodynamic Heating is processed, and forms coating on described sheet glass.
14. manufacture method according to claim 8, it forms coating after further being included in the described glass of cooling on described sheet glass.
15. manufacture method according to claim 14, it is processed described sheet glass after further being included in and forming described coating through heating and cooling.
16. a solar panel, it comprises:
With physical toughened glass according to claim 1 as glass substrate;
The photovoltaic cell layer; With
Backboard.
17. solar panel according to claim 16, wherein said photovoltaic cell layer are to be selected from the group that is comprised of wafer type photovoltaic cell layer and film-type photovoltaic cell layer.
18. solar panel according to claim 16, wherein said photovoltaic cell layer are to be selected from the group that is comprised of silicon single crystal photovoltaic cell layer, polysilicon photovoltaic cells Ceng, Arsenic potassium photovoltaic cell layer, amorphous silicon photovoltaic battery layers, cadmium telluride photovoltaic cell layer, copper indium diselenide photovoltaic cell layer, copper-indium-gallium-selenium photovoltaic battery layers and dye-sensitized photovoltaic battery layers.
19. solar panel according to claim 16, wherein said backboard are to be selected from the group that is comprised of glass substrate, plastic plate, stainless steel plate, aluminium sheet and matrix material.
20. a method of making solar panel, it may further comprise the steps:
Provide physical toughened glass according to claim 1 as glass substrate;
On described glass substrate, form the photovoltaic cell layer; With
Backboard is arranged on the described photovoltaic cell layer.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101985261A CN102863146A (en) | 2011-07-06 | 2011-07-06 | Physical toughened glass, solar cell panel and manufacture methods of physical toughened glass and solar cell panel |
| TW101124301A TWI497732B (en) | 2011-07-06 | 2012-07-05 | Physical tempered glass, solar cover plate, solar backsheet and solar panel |
| US13/541,995 US20130008500A1 (en) | 2011-07-06 | 2012-07-05 | Physical tempered glass, solar cover plate, solar backsheet and solar panel |
| EP12175155.6A EP2543644A3 (en) | 2011-07-06 | 2012-07-05 | Physical tempered glass, solar cover plate, solar backsheet and solar panel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101985261A CN102863146A (en) | 2011-07-06 | 2011-07-06 | Physical toughened glass, solar cell panel and manufacture methods of physical toughened glass and solar cell panel |
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| Publication Number | Publication Date |
|---|---|
| CN102863146A true CN102863146A (en) | 2013-01-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101985261A Pending CN102863146A (en) | 2011-07-06 | 2011-07-06 | Physical toughened glass, solar cell panel and manufacture methods of physical toughened glass and solar cell panel |
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| Country | Link |
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| CN (1) | CN102863146A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103887356A (en) * | 2014-04-14 | 2014-06-25 | 江苏宇兆能源科技有限公司 | Light solar photovoltaic power generation component and stacking method in production technology thereof |
| CN104465826A (en) * | 2013-09-18 | 2015-03-25 | 常州亚玛顿股份有限公司 | High-power high-reliability solar module |
| CN106098824A (en) * | 2016-07-13 | 2016-11-09 | 合肥中南光电有限公司 | The mounting structure of solar module |
| CN106795036A (en) * | 2014-07-31 | 2017-05-31 | 康宁股份有限公司 | The method and apparatus of hot safety glass and the hot tempering for glass |
| CN107799626A (en) * | 2016-08-30 | 2018-03-13 | 天津市瓦克新能源科技有限公司 | A kind of manufacture method of photovoltaic battery panel |
| US11485673B2 (en) | 2017-08-24 | 2022-11-01 | Corning Incorporated | Glasses with improved tempering capabilities |
| US11643355B2 (en) | 2016-01-12 | 2023-05-09 | Corning Incorporated | Thin thermally and chemically strengthened glass-based articles |
| US11697617B2 (en) | 2019-08-06 | 2023-07-11 | Corning Incorporated | Glass laminate with buried stress spikes to arrest cracks and methods of making the same |
| US11708296B2 (en) | 2017-11-30 | 2023-07-25 | Corning Incorporated | Non-iox glasses with high coefficient of thermal expansion and preferential fracture behavior for thermal tempering |
| US11795102B2 (en) | 2016-01-26 | 2023-10-24 | Corning Incorporated | Non-contact coated glass and related coating system and method |
| US11891324B2 (en) | 2014-07-31 | 2024-02-06 | Corning Incorporated | Thermally strengthened consumer electronic glass and related systems and methods |
| CN117855341A (en) * | 2024-03-07 | 2024-04-09 | 龙焱能源科技（杭州）有限公司 | Curved surface film photovoltaic module and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104465826A (en) * | 2013-09-18 | 2015-03-25 | 常州亚玛顿股份有限公司 | High-power high-reliability solar module |
| CN103887356A (en) * | 2014-04-14 | 2014-06-25 | 江苏宇兆能源科技有限公司 | Light solar photovoltaic power generation component and stacking method in production technology thereof |
| CN106795036A (en) * | 2014-07-31 | 2017-05-31 | 康宁股份有限公司 | The method and apparatus of hot safety glass and the hot tempering for glass |
| CN106795036B (en) * | 2014-07-31 | 2021-05-28 | 康宁股份有限公司 | Thermally tempered glass and method and apparatus for thermal tempering of glass |
| US11891324B2 (en) | 2014-07-31 | 2024-02-06 | Corning Incorporated | Thermally strengthened consumer electronic glass and related systems and methods |
| US11643355B2 (en) | 2016-01-12 | 2023-05-09 | Corning Incorporated | Thin thermally and chemically strengthened glass-based articles |
| US11795102B2 (en) | 2016-01-26 | 2023-10-24 | Corning Incorporated | Non-contact coated glass and related coating system and method |
| CN106098824A (en) * | 2016-07-13 | 2016-11-09 | 合肥中南光电有限公司 | The mounting structure of solar module |
| CN107799626A (en) * | 2016-08-30 | 2018-03-13 | 天津市瓦克新能源科技有限公司 | A kind of manufacture method of photovoltaic battery panel |
| US11485673B2 (en) | 2017-08-24 | 2022-11-01 | Corning Incorporated | Glasses with improved tempering capabilities |
| US11708296B2 (en) | 2017-11-30 | 2023-07-25 | Corning Incorporated | Non-iox glasses with high coefficient of thermal expansion and preferential fracture behavior for thermal tempering |
| US11697617B2 (en) | 2019-08-06 | 2023-07-11 | Corning Incorporated | Glass laminate with buried stress spikes to arrest cracks and methods of making the same |
| CN117855341A (en) * | 2024-03-07 | 2024-04-09 | 龙焱能源科技（杭州）有限公司 | Curved surface film photovoltaic module and preparation method thereof |
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Application publication date: 20130109 |