CN102852300A - Glass fiber base material polyvinyl chloride (PVC) painting wall plastic and production method thereof - Google Patents

Glass fiber base material polyvinyl chloride (PVC) painting wall plastic and production method thereof Download PDF

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Publication number
CN102852300A
CN102852300A CN2011101832355A CN201110183235A CN102852300A CN 102852300 A CN102852300 A CN 102852300A CN 2011101832355 A CN2011101832355 A CN 2011101832355A CN 201110183235 A CN201110183235 A CN 201110183235A CN 102852300 A CN102852300 A CN 102852300A
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pvc
layer
coated
air brushing
fiberglass substrate
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CN2011101832355A
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Chinese (zh)
Inventor
李德荣
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SHANGHAI GRAND DRAGON CANOPY NEW MATERIALS CO Ltd
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SHANGHAI GRAND DRAGON CANOPY NEW MATERIALS CO Ltd
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Priority to CN2011101832355A priority Critical patent/CN102852300A/en
Publication of CN102852300A publication Critical patent/CN102852300A/en
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Abstract

The invention relates to a glass fiber base material polyvinyl chloride (PVC) painting wall plastic and a production method thereof. The wall plastic consists of a surface painting layer, a PVC surface processing layer, a base material scraping layer and a bottom back composite layer, wherein the surface painting layer, the PVC surface processing layer, the base material scraping layer and the bottom back composite layer are arranged from top to bottom, the surface painting layer is painted on the upper surface of the PVC surface processing layer, and the PVC surface processing layer, the base material scraping layer and the bottom back composite layer are subjected to hot press molding sequentially from top to bottom to form a layered composite structure. Compared with the prior art, the wall plastic is high in size stability, good in stain resistance, environment-friendly, flame retardant, anti-corrosion, mildew proof and capable of being widely applied to public places such as hospitals, exhibition halls and hotels. Patterns can be painted by a photo machine in accordance with requirements of clients.

Description

A kind of fiberglass substrate PVC air brushing wall is moulded and manufacture method
Technical field
The present invention relates to a kind of wallpaper product and manufacture method thereof, especially relate to a kind of fiberglass substrate PVC air brushing wall and mould and manufacture method.
Background technology
Wall covering material product in the market mostly is wallpaper, wall paper, decorative panel, and it is functional, all there is defective in various degree in usability.Be mainly manifested in that moisture-proof is poor, resistance to soiling is poor, poor dimensional stability, poor fire, application life are short etc.The present invention relates to an improvement fiberglass substrate PVC wall moulds, PVC is coated with the method for scraping, PVC rolling process, three kinds of techniques of PVC composite algorithm organically combines, this method is higher than other process products made thereby dimensional stabilitys, the advantages such as resistance to soiling is stronger, environmental protection flame retardant, anticorrosive mildewproof.Pattern is according to the air brushing on wide format printer of client's hobby, and applicability is wider.
Summary of the invention
Purpose of the present invention be exactly provide in order to overcome the defective that above-mentioned prior art exists that a kind of dimensional stability is higher, resistance to soiling is stronger, the fiberglass substrate PVC air brushing wall of environmental protection flame retardant, anticorrosive mildewproof moulds and manufacture method.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of fiberglass substrate PVC air brushing wall is moulded, it is characterized in that, this wall is moulded to be coated with by surperficial air brushing layer, PVC list processing layer, base material and is scraped layer and back of the body composite bed in the end forms from top to bottom, described surperficial air brushing layer is sprayed on the upper surface of PVC list processing layer, and PVC list processing layer, base material are coated with scrapes layer and end back of the body composite bed hot-forming formation layered composite structure successively from top to bottom.
Described surperficial air brushing layer is the blotting dope layer through ultraviolet curing, and thickness is 0.1~0.5mm.
Described PVC list processing layer is the PVC rete, and thickness is 0.1~0.5mm.
Described base material is coated with scrapes layer for being coated with the glass layer of PVC thickener.
Back of the body composite bed is the hot pressing mixed layer of polyvinyl chloride resin and calcium carbonate at the described end, and thickness is 1~4cm.
The manufacture method that a kind of fiberglass substrate PVC air brushing wall is moulded is characterized in that, the method may further comprise the steps:
(1) the manufacturing fiberglass substrate is coated with and scrapes layer
A, get the raw materials ready according to following component and weight portion content:
PVC paste resin (PVC) 100, diisononyl phthalate (DINP) 65~75, calcium carbonate 100, stabilizing agent 3, thinner 15~20, titanium dioxide 3, fire retardant 7;
B, above-mentioned raw materials is dropped into the high speed dispersor high speed by prescription stir 10~15min, continuous and change approximately 10min of stirring at low speed over to, vacuumizing and exhausting while stirring, the mixed PVC thickener that obtains, squeeze in the high-order storage vat by air pump, glass fiber is advanced being coated with kerf, the PVC thickener is evenly coated on the fiberglass substrate by ball valve control flow being coated with cutter position, the glass fiber that coats the PVC thickener enters the heating of gel roller, become gel state, cooling enters 12M baking oven further plasticizing and cooling again, obtains fiberglass substrate and is coated with and scrapes layer;
(2) make end back of the body composite bed
A, get the raw materials ready according to following component and weight portion content:
Corvic (PVC) 100, calcium carbonate 150, stabilizing agent 3, diisononyl phthalate (DINP) 35~40, titanium dioxide 10, fire retardant 7;
B, above-mentioned raw materials dropped into by prescription utilize ten thousand horsepowers of machines to shear and plasticizing 7min after the high speed dispersor high speed stirs, recycling is rolled turbine and is further plastified, the control plasticization temperature is 155 ℃, the controlled filter temperature is 165 ℃ of filtrations impurity wherein, and through four-roll calender calendering formation and embossing, the temperature of No. 1 roller of four-roll calender is 178 ℃, the temperature of No. two rollers is 178 ℃, the temperature of No. three rollers is 175 ℃, and the temperature of No. four rollers is 173 ℃, gets after the cooling cutting edge and carries on the back on earth composite bed;
(3) hot pressing is compound
PVC film take thickness as 0.1~0.5mm is as PVC list processing layer, PVC list processing layer, base material be coated with scrape layer and back of the body composite bed in the end places on the MULTILAYER COMPOSITE machine, through preheating, flattening, applying, refrigerating work procedure, obtain fiberglass substrate PVC air brushing wall and mould semiproduct;
(4) surfacing
Be coated with at PVC list processing layer and tie up one deck blotting coating, and solidify through ultraviolet equipment, again cool off rolling, namely obtain fiberglass substrate PVC air brushing wall and mould.
Described stabilizing agent is zinc stearate, calcium stearate or barium stearate.
Described thinner is that PVC sticks with paste thinner TXIB.
Described fire retardant is TCEP, TCPP, TDCPP, IPPP, MCA, eight bromo ether or triphenyl phosphate.
Compared with prior art, dimensional stability of the present invention is higher, resistance to soiling is stronger, environmental protection flame retardant, anticorrosive mildewproof, pattern be according to the air brushing on wide format printer of client's hobby, the public place in extensive use hospital, exhibition hall, hotel etc.
Description of drawings
Fig. 1 is structural representation of the present invention;
Fig. 2 is process chart of the present invention.
1 scrapes layer, 4 and is that the end carries on the back composite bed for base material is coated with for PVC list processing layer, 3 for surperficial air brushing layer, 2 among the figure.
The specific embodiment
The present invention is described in detail below in conjunction with the drawings and specific embodiments.
Embodiment 1
A kind of fiberglass substrate PVC air brushing wall is moulded, its structure as shown in Figure 1, this wall is moulded to be coated with by surperficial air brushing layer 1, PVC list processing layer 2, base material and is scraped layer 3 and back of the body composite bed 4 in the end forms from top to bottom, surface air brushing layer 1 is sprayed on the upper surface of PVC list processing layer 2, this surface air brushing layer 1 is the blotting dope layer through ultraviolet curing, thickness is 0.1mm, and PVC list processing layer 2, base material are coated with scrapes layer 3 and end back of the body composite bed 4 hot-forming formation layered composite structure successively from top to bottom.PVC list processing layer 2 is the PVC rete, and thickness is 0.1mm, and base material is coated with scrapes layer 3 for being coated with the glass layer of PVC thickener, and end back of the body composite bed 4 is the polyvinyl chloride resin layer, and thickness is 2cm.
The preparation method that fiberglass substrate PVC air brushing wall is moulded may further comprise the steps:
(1) raw material is pressed prescription PVC paste resin (PVC) 100kg, diisononyl phthalate (DINP) 70kg, calcium carbonate 100kg, stabilizing agent 3kg, thinner 18kg, titanium dioxide 3kg, antimony oxide 7kg dropped into high speed dispersor high speed stir about 13 minutes, continuous and changed stirring at low speed over to approximately 10 minutes, vacuumizing and exhausting while stirring, mixed PVC thickener is squeezed in the high-order storage vat by air pump.Glass fiber is advanced being coated with kerf, and the PVC thickener is evenly coated on the fiberglass substrate by ball valve control flow being coated with cutter position, and the glass fiber that coats the PVC thickener enters the heating of gel roller, becomes gel state, and cooling enters the 12M baking oven again and further plastifies.Cooling is batched stand-by.
(2) back pressure is prolonged moulding at the end: according to prescription Corvic (PVC) 100kg, and calcium carbonate 150kg, stabilizing agent 3kg, diisononyl phthalate (DINP) 37kg, titanium dioxide 10kg, fire retardant 7kg mixes at high-speed mixer.7 minutes are fully sheared, plastified to ten thousand horsepowers of machines.Roll 155 ℃ of the further plasticization temperatures of turbine.Filter filters 165 ℃ of foreign matter impurity temperature.178 ℃ on No. 1 roller of four-roll calender calendering formation, 178 ℃ on No. two rollers, 175 ℃ on No. three rollers, 173 ℃ on No. four rollers.The knurling rolls embossing, cooling, cutting edge, rolling is stand-by.
(3) MULTILAYER COMPOSITE: the preheating on the MULTILAYER COMPOSITE machine of above-mentioned process product, flattening, applying, cooling, rolling.PVC table place layer: tie up one deck blotting coating but be coated with, and solidify through ultraviolet equipment, again cool off rolling.The product that obtains is fiberglass substrate PVC (air brushing) wall and moulds.
Embodiment 2
A kind of fiberglass substrate PVC air brushing wall is moulded, this wall is moulded to be coated with by surperficial air brushing layer, PVC list processing layer, base material and is scraped layer and back of the body composite bed in the end forms from top to bottom, this surface air brushing layer is the blotting dope layer through ultraviolet curing, thickness is 0.5mm, surface air brushing layer is sprayed on the upper surface of PVC list processing layer, and PVC list processing layer, base material are coated with scrapes layer and end back of the body composite bed hot-forming formation layered composite structure successively from top to bottom.PVC list processing layer is the PVC rete, and thickness is 0.5mm, and base material is coated with scrapes layer for being coated with the glass layer of PVC thickener, and end back of the body composite bed is the polyvinyl chloride resin layer, and thickness is 4cm.
The manufacture method that fiberglass substrate PVC air brushing wall is moulded may further comprise the steps, its technological process as shown in Figure 2:
(1) the manufacturing fiberglass substrate is coated with and scrapes layer
A, get the raw materials ready according to following component and content:
PVC paste resin (PVC) 100kg, diisononyl phthalate (DINP) 65kg, calcium carbonate 100kg, stabilizing agent 3kg, thinner 15kg, titanium dioxide 3kg, fire retardant 7kg, wherein, stabilizing agent is zinc stearate, and thinner is that PVC sticks with paste thinner TXIB, and fire retardant is TCEP;
B, above-mentioned raw materials is dropped into the high speed dispersor high speed by prescription stir 10min, continuous and change approximately 10min of stirring at low speed over to, vacuumizing and exhausting while stirring, the mixed PVC thickener that obtains, squeeze in the high-order storage vat by air pump, glass fiber is advanced being coated with kerf, the PVC thickener is evenly coated on the fiberglass substrate by ball valve control flow being coated with cutter position, the glass fiber that coats the PVC thickener enters the heating of gel roller, become gel state, cooling enters 12M baking oven further plasticizing and cooling again, obtains fiberglass substrate and is coated with and scrapes layer;
(2) make end back of the body composite bed
A, get the raw materials ready according to following component and weight portion content:
Corvic (PVC) 100kg, calcium carbonate 150kg, stabilizing agent 3kg, diisononyl phthalate (DINP) 35kg, titanium dioxide 10kg, fire retardant 7kg, wherein, stabilizing agent is calcium stearate, fire retardant is eight bromo ether;
B, above-mentioned raw materials dropped into by prescription utilize ten thousand horsepowers of machines to shear and plasticizing 7min after the high speed dispersor high speed stirs, recycling is rolled turbine and is further plastified, the control plasticization temperature is 155 ℃, the controlled filter temperature is 165 ℃ of filtrations impurity wherein, and through four-roll calender calendering formation and embossing, the temperature of No. 1 roller of four-roll calender is 178 ℃, the temperature of No. two rollers is 178 ℃, the temperature of No. three rollers is 175 ℃, and the temperature of No. four rollers is 173 ℃, gets after the cooling cutting edge and carries on the back on earth composite bed;
(3) hot pressing is compound
PVC film take thickness as 0.5mm is as PVC list processing layer, PVC list processing layer, base material is coated with scrapes layer and end back of the body composite bed places on the MULTILAYER COMPOSITE machine, through preheating, flattening, applying, refrigerating work procedure, obtains fiberglass substrate PVC air brushing wall and moulds semiproduct;
(4) surfacing
Be coated with at PVC list processing layer and tie up one deck blotting coating, and solidify through ultraviolet equipment, again cool off rolling, namely obtain fiberglass substrate PVC air brushing wall and mould.
Embodiment 3
A kind of fiberglass substrate PVC air brushing wall is moulded, this wall is moulded to be coated with by surperficial air brushing layer, PVC list processing layer, base material and is scraped layer and back of the body composite bed in the end forms from top to bottom, this surface air brushing layer is the blotting dope layer through ultraviolet curing, thickness is 0.5mm, surface air brushing layer is sprayed on the upper surface of PVC list processing layer, and PVC list processing layer, base material are coated with scrapes layer and end back of the body composite bed hot-forming formation layered composite structure successively from top to bottom.PVC list processing layer is the PVC rete, and thickness is 0.4mm, and base material is coated with scrapes layer for being coated with the glass layer of PVC thickener, and end back of the body composite bed is the polyvinyl chloride resin layer, and thickness is 1cm.
The manufacture method that fiberglass substrate PVC air brushing wall is moulded may further comprise the steps:
(1) the manufacturing fiberglass substrate is coated with and scrapes layer
A, get the raw materials ready according to following component and weight portion content:
PVC paste resin (PVC) 100kg, diisononyl phthalate (DINP) 75kg, calcium carbonate 100kg, stabilizing agent 3kg, thinner 20kg, titanium dioxide 3kg, fire retardant 7kg, wherein, stabilizing agent is zinc stearate, and thinner is that PVC sticks with paste thinner TXIB, and fire retardant is IPPP;
B, above-mentioned raw materials is dropped into the high speed dispersor high speed by prescription stir 15min, continuous and change approximately 10min of stirring at low speed over to, vacuumizing and exhausting while stirring, the mixed PVC thickener that obtains, squeeze in the high-order storage vat by air pump, glass fiber is advanced being coated with kerf, the PVC thickener is evenly coated on the fiberglass substrate by ball valve control flow being coated with cutter position, the glass fiber that coats the PVC thickener enters the heating of gel roller, become gel state, cooling enters 12M baking oven further plasticizing and cooling again, obtains fiberglass substrate and is coated with and scrapes layer;
(2) make end back of the body composite bed
A, get the raw materials ready according to following component and weight portion content:
Corvic (PVC) 100kg, calcium carbonate 150kg, stabilizing agent 3kg, diisononyl phthalate (DINP) 40kg, titanium dioxide 10kg, fire retardant 7kg, wherein, stabilizing agent is barium stearate, fire retardant is triphenyl phosphate;
B, above-mentioned raw materials dropped into by prescription utilize ten thousand horsepowers of machines to shear and plasticizing 7min after the high speed dispersor high speed stirs, recycling is rolled turbine and is further plastified, the control plasticization temperature is 155 ℃, the controlled filter temperature is 165 ℃ of filtrations impurity wherein, and through four-roll calender calendering formation and embossing, the temperature of No. 1 roller of four-roll calender is 178 ℃, the temperature of No. two rollers is 178 ℃, the temperature of No. three rollers is 175 ℃, and the temperature of No. four rollers is 173 ℃, gets after the cooling cutting edge and carries on the back on earth composite bed;
(3) hot pressing is compound
PVC film take thickness as 0.4mm is as PVC list processing layer, PVC list processing layer, base material is coated with scrapes layer and end back of the body composite bed places on the MULTILAYER COMPOSITE machine, through preheating, flattening, applying, refrigerating work procedure, obtains fiberglass substrate PVC air brushing wall and moulds semiproduct;
(4) surfacing
Be coated with at PVC list processing layer and tie up one deck blotting coating, and solidify through ultraviolet equipment, again cool off rolling, namely obtain fiberglass substrate PVC air brushing wall and mould.

Claims (9)

1. a fiberglass substrate PVC air brushing wall is moulded, it is characterized in that, this wall is moulded to be coated with by surperficial air brushing layer, PVC list processing layer, base material and is scraped layer and back of the body composite bed in the end forms from top to bottom, described surperficial air brushing layer is sprayed on the upper surface of PVC list processing layer, and PVC list processing layer, base material are coated with scrapes layer and end back of the body composite bed hot-forming formation layered composite structure successively from top to bottom.
2. a kind of fiberglass substrate PVC air brushing wall according to claim 1 is moulded, and it is characterized in that, described surperficial air brushing layer is the blotting dope layer through ultraviolet curing, and thickness is 0.1~0.5mm.
3. a kind of fiberglass substrate PVC air brushing wall according to claim 1 is moulded, and it is characterized in that, described PVC list processing layer is the PVC rete, and thickness is 0.1~0.5mm.
4. a kind of fiberglass substrate PVC air brushing wall according to claim 1 is moulded, and it is characterized in that, described base material is coated with scrapes layer for being coated with the glass layer of PVC thickener.
5. a kind of fiberglass substrate PVC air brushing wall according to claim 1 is moulded, and it is characterized in that, the back of the body composite bed of the described end is the hot pressing mixed layer of polyvinyl chloride resin and calcium carbonate, and thickness is 1~4cm.
6. the manufacture method that fiberglass substrate PVC air brushing wall as claimed in claim 1 is moulded is characterized in that, the method may further comprise the steps:
(1) the manufacturing fiberglass substrate is coated with and scrapes layer
A, get the raw materials ready according to following component and weight portion content:
PVC paste resin (PVC) 100, diisononyl phthalate (DINP) 65~75, calcium carbonate 100, stabilizing agent 3, thinner 15~20, titanium dioxide 3, fire retardant 7;
B, above-mentioned raw materials is dropped into the high speed dispersor high speed by prescription stir 10~15min, continuous and change approximately 10min of stirring at low speed over to, vacuumizing and exhausting while stirring, the mixed PVC thickener that obtains, squeeze in the high-order storage vat by air pump, glass fiber is advanced being coated with kerf, the PVC thickener is evenly coated on the fiberglass substrate by ball valve control flow being coated with cutter position, the glass fiber that coats the PVC thickener enters the heating of gel roller, become gel state, cooling enters 12M baking oven further plasticizing and cooling again, obtains fiberglass substrate and is coated with and scrapes layer;
(2) make end back of the body composite bed
A, get the raw materials ready according to following component and weight portion content:
Corvic (PVC) 100, calcium carbonate 150, stabilizing agent 3, diisononyl phthalate (DINP) 35~40, titanium dioxide 10, fire retardant 7;
B, above-mentioned raw materials dropped into by prescription utilize ten thousand horsepowers of machines to shear and plasticizing 7min after the high speed dispersor high speed stirs, recycling is rolled turbine and is further plastified, the control plasticization temperature is 155 ℃, the controlled filter temperature is 165 ℃ of filtrations impurity wherein, and through four-roll calender calendering formation and embossing, the temperature of No. 1 roller of four-roll calender is 178 ℃, the temperature of No. two rollers is 178 ℃, the temperature of No. three rollers is 175 ℃, and the temperature of No. four rollers is 173 ℃, gets after the cooling cutting edge and carries on the back on earth composite bed;
(3) hot pressing is compound
PVC film take thickness as 0.1~0.5mm is as PVC list processing layer, PVC list processing layer, base material be coated with scrape layer and back of the body composite bed in the end places on the MULTILAYER COMPOSITE machine, through preheating, flattening, applying, refrigerating work procedure, obtain fiberglass substrate PVC air brushing wall and mould semiproduct;
(4) surfacing
Be coated with at PVC list processing layer and tie up one deck blotting coating, and solidify through ultraviolet equipment, again cool off rolling, namely obtain fiberglass substrate PVC air brushing wall and mould.
7. a kind of fiberglass substrate PVC air brushing wall according to claim 6 manufacture method of moulding is characterized in that, described stabilizing agent is zinc stearate, calcium stearate or barium stearate.
8. a kind of fiberglass substrate PVC air brushing wall according to claim 6 manufacture method of moulding is characterized in that, described thinner is that PVC sticks with paste thinner TXIB.
9. a kind of fiberglass substrate PVC air brushing wall according to claim 6 manufacture method of moulding is characterized in that, described fire retardant is TCEP, TCPP, TDCPP, IPPP, MCA, eight bromo ether or triphenyl phosphate.
CN2011101832355A 2011-06-30 2011-06-30 Glass fiber base material polyvinyl chloride (PVC) painting wall plastic and production method thereof Pending CN102852300A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011101832355A CN102852300A (en) 2011-06-30 2011-06-30 Glass fiber base material polyvinyl chloride (PVC) painting wall plastic and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011101832355A CN102852300A (en) 2011-06-30 2011-06-30 Glass fiber base material polyvinyl chloride (PVC) painting wall plastic and production method thereof

Publications (1)

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CN102852300A true CN102852300A (en) 2013-01-02

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101070728A (en) * 2007-06-14 2007-11-14 北京威廉顺塑胶制品有限公司 Improved PVC elastic roll floor-board and production method
CN101666157A (en) * 2009-09-07 2010-03-10 江阴市江丽装饰材料有限公司 PVC enveloped floor coil

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101070728A (en) * 2007-06-14 2007-11-14 北京威廉顺塑胶制品有限公司 Improved PVC elastic roll floor-board and production method
CN101666157A (en) * 2009-09-07 2010-03-10 江阴市江丽装饰材料有限公司 PVC enveloped floor coil

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