CN102848632A - Thermoplastic polyurethane (TPU)-modified asphalt waterproof coiled material - Google Patents

Thermoplastic polyurethane (TPU)-modified asphalt waterproof coiled material Download PDF

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Publication number
CN102848632A
CN102848632A CN2012102858198A CN201210285819A CN102848632A CN 102848632 A CN102848632 A CN 102848632A CN 2012102858198 A CN2012102858198 A CN 2012102858198A CN 201210285819 A CN201210285819 A CN 201210285819A CN 102848632 A CN102848632 A CN 102848632A
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CN
China
Prior art keywords
coiled material
asphalt
waterproof coiled
thermoplastic polyurethane
modified asphalt
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Pending
Application number
CN2012102858198A
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Chinese (zh)
Inventor
张金根
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUJIANG WSD WATERPROOF BUILDING MATERIAL CO Ltd
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WUJIANG WSD WATERPROOF BUILDING MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by WUJIANG WSD WATERPROOF BUILDING MATERIAL CO Ltd filed Critical WUJIANG WSD WATERPROOF BUILDING MATERIAL CO Ltd
Priority to CN2012102858198A priority Critical patent/CN102848632A/en
Publication of CN102848632A publication Critical patent/CN102848632A/en
Pending legal-status Critical Current

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Abstract

The invention provides a thermoplastic polyurethane (TPU)-modified asphalt waterproof coiled material. The TPU-modified asphalt waterproof coiled material comprises a blank base, an asphalt layer coated on the blank base and an isolation material. The asphalt layer comprises: by mass, 8 to 12% of 10# petroleum asphalt, 30 to 50% of 90# petroleum asphalt, 6 to 10% of 46# machine oil, 25 to 35% of mountain flour and 6 to 14% of TPU. Compared with a thermoplastic styrene-butadiene rubber (SBS)-modified asphalt coiled material, the TPU-modified asphalt waterproof coiled material has higher heat resistance, low-temperature flexibility, tensile strength and fluidity of molten asphalt.

Description

A kind of thermoplastic polyurethane modified asphalt waterproof coiled material
Technical field
The present invention relates to the building waterproof coil field, particularly, is a kind of modified asphalt waterproof coiled material that comprises tire base and bituminous water-proof coating.
Background technology
Waterproof roll mainly is to locate for construction wall, roofing and tunnel, highway, refuse landfill etc., play a kind of flexible building material product that is curled into web-like of resisting extraneous rainwater, ground water seepage, being connected as ne-leakage between engineering foundation and the building, is the barrier of whole engineering waterproofing.
Present waterproof roll is mainly asphalt water-proof coiled material, comprise the tire base that is made of materials such as polyester felt, Chopped Strand Mat or fiberglass reinforcing polyester felts, dip-coating in the bitumen layer of tire primary surface, and the spacer material layer of upper and lower surface consists of.Wherein for the variation of the component of bitumen layer, can affect to a great extent the performance of waterproof roll, such as heat resistance, low temperature flexibility, impermeability, tensile property etc.For present modified asphalt waterproof coiled material, primary raw material adopts the SBS(thermoplastic styrene butadiene rubber of more amount in the bitumen layer except pitch) as solvent, its content is about about 10%, this kind coiled material is aspect heat resistance, and 100 ℃ of left and right sides tire bases do not fire, pitch is without trickling, low phenomenon; The low temperature flexibility aspect keeps low temperature flexibility about-25 ℃; Tensile strength is at 350N/50mm-900N/50mm; This kind performance parameter is at some comparatively under the rugged environment, still be difficult to resist, as under the impact of the north than cold air, temperature may be lower than subzero 30 ℃, coiled material is easily embrittlement just, and at Equipment for Heating Processing places such as close boilers, local ambient temperature may be higher than 100 ℃, then may cause the burning of tire base; In addition, in the dipping process process, SBS type modified pitch is under the melting dip-coating state about 190 ℃, and is mobile relatively poor, is unfavorable for that evenly entirely dip-coating is in the tire primary surface at the bitumen layer material; Therefore, present SBS type modified asphalt waterproof coiled material still haves much room for improvement.
Summary of the invention
For the problems referred to above, the object of the present invention is to provide a kind of thermoplastic polyurethane modified asphalt waterproof coiled material, this kind waterproof roll can further improve its heat resistance, low temperature flexibility, tensile strength than SBS type modified bituminous pitch coiled material, and improves the flowability under the pitch molten condition.
The technical solution adopted for the present invention to solve the technical problems is: this thermoplastic polyurethane modified asphalt waterproof coiled material comprises tire base, the bitumen layer of dip-coating on the tire base, and isolated material;
Described bitumen layer comprises 10# asphalt, 90# asphalt, 46# machinery oil, stone flour; Also comprise hot thermoplastic polyurethane (IPU); The content of each component is as follows by mass percentage:
10# asphalt: 8%-12%;
90# asphalt: 30%-50%;
46# machinery oil: 6%-10%;
IPU:?6%-14%;
Stone flour: 25%-35%.
As preferably, the mass percent content of described IPU is 8%-10%, and under this content, the combination property of coiled material is best.
As preferably, described tire base is made of polyester felt, Chopped Strand Mat or fiberglass reinforcing polyester felt.
As preferably, described isolated material is made of in polyethylene film, fine sand and the mineral pellet one or more.
Beneficial effect of the present invention is: this thermoplastic polyurethane modified asphalt waterproof coiled material has further improved its heat resistance, low temperature flexibility, tensile strength by after the component of bitumen layer is improved, and has improved the flowability under the pitch molten condition.
Description of drawings
Fig. 1 is the constitutional diagram of the embodiment one of this thermoplastic polyurethane modified asphalt waterproof coiled material;
Fig. 2 is the all-round property testing parameter list of Fig. 1 embodiment;
Fig. 3 is the combination property basic parameter table of SBS type modified asphalt waterproof coiled material.
Among the figure 1,10# asphalt; 2,90# asphalt; 3,46# machinery oil; 4, thermoplastic polyurethane (IPU); 5, stone flour.
The specific embodiment
The present invention is further described below in conjunction with drawings and Examples:
Embodiment one:
This thermoplastic polyurethane modified asphalt waterproof coiled material comprises tire base, the bitumen layer of dip-coating on the tire base that is made of polyester felt, Chopped Strand Mat or fiberglass reinforcing polyester felt, and isolated material;
The formation of described bitumen layer comprises 10# asphalt 1,90# asphalt 2,46# machinery oil 3, stone flour 5 shown in Fig. 1 embodiment; Also comprise hot thermoplastic polyurethane (IPU) 4; The content of each component is as follows by mass percentage:
10# asphalt: 10%;
90# asphalt: 40%;
46# machinery oil: 10%;
IPU:?10%;
Stone flour: 30%.
Described isolated material is made of in polyethylene film, fine sand and the mineral pellet one or more, decides on concrete field of employment.
Above-mentioned thermoplastic polyurethane modified asphalt waterproof coiled material according to the test method of GB18242-2008, is tested test specimen, and its Specifeca tion speeification that reaches as shown in Figure 2.Contrast SBS type modified asphalt waterproof coiled material shown in Figure 3, as seen, this thermoplastic polyurethane modified asphalt waterproof coiled material all is improved at aspects such as heat resistance, low temperature flexibility, tensile strength; And in process of production, under 195 ℃ of molten conditions, in the asphalt dip coating process, the flowability of asphalt grout significantly improves, and has more uniform dip-coating effect.
In another embodiment, the mass percent of IPU is got 8%, and carried out many groups of tests, combination property mean parameter and Fig. 2 of coiled material are suitable as a result, and when the mass percent of IPU was got beyond the 8%-10%, performance subsided a little, but still is better than SBS type modified asphalt waterproof coiled material.
The above only is preferred embodiment of the present invention, and is in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, is equal to replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (4)

1. a thermoplastic polyurethane modified asphalt waterproof coiled material comprises tire base, the bitumen layer of dip-coating on the tire base, and isolated material;
Described bitumen layer comprises 10# asphalt, 90# asphalt, 46# machinery oil, stone flour, it is characterized in that: described bitumen layer also comprises hot thermoplastic polyurethane (IPU); The content of each component is as follows by mass percentage:
10# asphalt: 8%-12%;
90# asphalt: 30%-50%;
46# machinery oil: 6%-10%;
IPU:?6%-14%;
Stone flour: 25%-35%.
2. thermoplastic polyurethane modified asphalt waterproof coiled material according to claim 1, it is characterized in that: the mass percent content of described IPU is 8%-10%.
3. thermoplastic polyurethane modified asphalt waterproof coiled material according to claim 1 and 2, it is characterized in that: described tire base is made of polyester felt, Chopped Strand Mat or fiberglass reinforcing polyester felt.
4. thermoplastic polyurethane modified asphalt waterproof coiled material according to claim 1 and 2 is characterized in that: described isolated material is made of in polyethylene film, fine sand and the mineral pellet one or more.
CN2012102858198A 2012-08-13 2012-08-13 Thermoplastic polyurethane (TPU)-modified asphalt waterproof coiled material Pending CN102848632A (en)

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CN2012102858198A CN102848632A (en) 2012-08-13 2012-08-13 Thermoplastic polyurethane (TPU)-modified asphalt waterproof coiled material

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Application Number Priority Date Filing Date Title
CN2012102858198A CN102848632A (en) 2012-08-13 2012-08-13 Thermoplastic polyurethane (TPU)-modified asphalt waterproof coiled material

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CN102848632A true CN102848632A (en) 2013-01-02

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104118163A (en) * 2013-04-23 2014-10-29 江苏凯伦建材股份有限公司 Novel aluminum-plastic waterproof roll
CN106183217A (en) * 2016-07-05 2016-12-07 潍坊市宇虹防水材料(集团)有限公司 Elastomer modified asphalt waterproof roll and preparation method thereof
CN109735124A (en) * 2019-01-09 2019-05-10 临沂市临河防水材料有限公司 A kind of production technology of heat molten type waterproof roll
CN110872433A (en) * 2019-12-04 2020-03-10 泰安乐邦环保科技有限公司 Waterproof coiled material prepared from coating waste residues and preparation method thereof
WO2021109035A1 (en) * 2019-12-04 2021-06-10 惠州东方雨虹建筑材料有限责任公司 Flame retardant modified asphalt waterproofing coiled material coating, flame retardant self-adhesive asphalt waterproofing coiled material and preparation method therefor

Citations (5)

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Publication number Priority date Publication date Assignee Title
US5763036A (en) * 1995-07-10 1998-06-09 Interface, Inc. Polyurethane-modified bitumen sheet material and method for protective moisture barrier
WO2010110661A2 (en) * 2009-03-24 2010-09-30 De Veenvoort B.V. Covering material for water- or weather-proofing
US20100297902A1 (en) * 2009-05-22 2010-11-25 The Garland Company, Inc. Use of thermoplastic polyurethanes in rubber modified bitumen roofing membranes
CN102031833A (en) * 2010-12-10 2011-04-27 上海台安工程实业有限公司 High-performance synthetic rubber asphalt waterproof coiled material
EP2364841A1 (en) * 2010-03-12 2011-09-14 Silcart S.r.l. Thermal insulation panel, particularly for the thermal insulation of buildings

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763036A (en) * 1995-07-10 1998-06-09 Interface, Inc. Polyurethane-modified bitumen sheet material and method for protective moisture barrier
WO2010110661A2 (en) * 2009-03-24 2010-09-30 De Veenvoort B.V. Covering material for water- or weather-proofing
US20100297902A1 (en) * 2009-05-22 2010-11-25 The Garland Company, Inc. Use of thermoplastic polyurethanes in rubber modified bitumen roofing membranes
EP2364841A1 (en) * 2010-03-12 2011-09-14 Silcart S.r.l. Thermal insulation panel, particularly for the thermal insulation of buildings
CN102031833A (en) * 2010-12-10 2011-04-27 上海台安工程实业有限公司 High-performance synthetic rubber asphalt waterproof coiled material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王东升等: "《建筑工程材料供应与管理》", 31 July 2010, 中国矿业大学出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104118163A (en) * 2013-04-23 2014-10-29 江苏凯伦建材股份有限公司 Novel aluminum-plastic waterproof roll
CN106183217A (en) * 2016-07-05 2016-12-07 潍坊市宇虹防水材料(集团)有限公司 Elastomer modified asphalt waterproof roll and preparation method thereof
CN109735124A (en) * 2019-01-09 2019-05-10 临沂市临河防水材料有限公司 A kind of production technology of heat molten type waterproof roll
CN110872433A (en) * 2019-12-04 2020-03-10 泰安乐邦环保科技有限公司 Waterproof coiled material prepared from coating waste residues and preparation method thereof
WO2021109035A1 (en) * 2019-12-04 2021-06-10 惠州东方雨虹建筑材料有限责任公司 Flame retardant modified asphalt waterproofing coiled material coating, flame retardant self-adhesive asphalt waterproofing coiled material and preparation method therefor

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Application publication date: 20130102