CN102828273B - Polyester insecticidal fabric production process - Google Patents
Polyester insecticidal fabric production process Download PDFInfo
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- CN102828273B CN102828273B CN201210260037.9A CN201210260037A CN102828273B CN 102828273 B CN102828273 B CN 102828273B CN 201210260037 A CN201210260037 A CN 201210260037A CN 102828273 B CN102828273 B CN 102828273B
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- terylene
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- 239000004744 fabric Substances 0.000 title claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 229920000728 polyester Polymers 0.000 title abstract description 16
- 230000000749 insecticidal effect Effects 0.000 title abstract 4
- 238000009987 spinning Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 6
- 230000008569 process Effects 0.000 claims abstract description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 72
- 229920004933 Terylene® Polymers 0.000 claims description 63
- 235000010603 pastilles Nutrition 0.000 claims description 45
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- 238000005516 engineering process Methods 0.000 claims description 14
- 239000000575 pesticide Substances 0.000 claims description 13
- 238000009941 weaving Methods 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 10
- -1 polyethylene terephthalate Polymers 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 229940024113 allethrin Drugs 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 6
- 239000005946 Cypermethrin Substances 0.000 claims description 5
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 5
- 229960005424 cypermethrin Drugs 0.000 claims description 5
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 4
- 239000005877 Alpha-Cypermethrin Substances 0.000 claims description 4
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 4
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 claims description 3
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- GQNBIMLHUAWKHJ-UHFFFAOYSA-N [4-(methoxymethyl)phenyl]methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound C1=CC(COC)=CC=C1COC(=O)C1C(C)(C)C1C=C(C)C GQNBIMLHUAWKHJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 238000007791 dehumidification Methods 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000009940 knitting Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims description 3
- 229960000490 permethrin Drugs 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 238000009965 tatting Methods 0.000 claims description 3
- 244000189548 Chrysanthemum x morifolium Species 0.000 claims 1
- 241000255925 Diptera Species 0.000 abstract description 28
- 239000008187 granular material Substances 0.000 abstract 2
- 239000002917 insecticide Substances 0.000 abstract 1
- 230000006870 function Effects 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- 241000238631 Hexapoda Species 0.000 description 6
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- 229920001903 high density polyethylene Polymers 0.000 description 5
- 239000004700 high-density polyethylene Substances 0.000 description 5
- 229920001684 low density polyethylene Polymers 0.000 description 5
- 239000004702 low-density polyethylene Substances 0.000 description 5
- 229920004934 Dacron® Polymers 0.000 description 4
- 238000003197 gene knockdown Methods 0.000 description 4
- 241000723353 Chrysanthemum Species 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005108 dry cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 206010014599 encephalitis Diseases 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 241000256173 Aedes albopictus Species 0.000 description 1
- 208000001490 Dengue Diseases 0.000 description 1
- 206010012310 Dengue fever Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000019771 cognition Effects 0.000 description 1
- 208000025729 dengue disease Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000005541 medical transmission Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000000384 rearing effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Abstract
The invention discloses a polyester insecticidal fabric production process. The process comprises the following steps: generating medicated polyester wet chip granules and utilizing the medicated polyester wet chip granules to generate medicated polyester dry chips, wherein an insecticide accounts for 1-16wt% of the total raw materials; and utilizing the medicated polyester dry chips to generate medicated polyester yarns and spinning the medicated polyester yarns to generate the polyester insecticidal fabric. The produced polyester insecticidal fabric has a long-acting mosquito expelling function.
Description
Technical field
The present invention relates to a kind of mosquito repellent textile material production technology, specifically, relate to a kind of terylene desinsection fabric production technology.
Background technology
Conventional textiles now, as clothes, mosquito net, coverlet etc. do not possess mosquito and insect expelling function, people's daily routines tend to be subject to having a strong impact on of mosquito.Because mosquito net does not have function of driving mosquitoes, mosquito can fly into and bite human body in bed evening, and people can not be fallen asleep; Because clothes does not have function of driving mosquitoes, people's cognition is not stopped to bite by mosquito, has a strong impact on people's work and life.
In addition, mosquito also can spread disease, and different types of mosquito can be propagated different diseases.Recently, the disease transmissions such as China's some areas encephalitis B (being called for short " encephalitis "), dengue fever, the routes of infection of these diseases are mainly to pass through mosquito.Mosquito is very common a kind of harmful insects of summer and autumn, and it is the harm of human body, and it is bitten after ill animal or human's body, pathogen can be transmitted to Healthy People.
Polyethylene (PE) is divided into high density polyethylene (HDPE) (HDPE) and low density polyethylene (LDPE) (LDPE).High density polyethylene (HDPE) has good washing performance, dry-cleaning slightly inferior properties, and it must could obtain good bonding effect under higher temperature and larger pressure, according to its these characteristics, is widely used for doing men's shirt adhesive lining.Water-fastness and the dry cleaning resistance of low density polyethylene (LDPE) can be all poor, but it is can be at a lower temperature bonding and have good bonding strength, therefore be widely used in temporary bonding lining cloth.
Terylene (Terylene) is an important kind in synthetic fiber, is the trade name of China's polyester fiber.It is fiber-forming polymer---the polyethylene terephthalate (PET) making through esterification or ester exchange and polycondensation reaction taking p-phthalic acid (PTA) or dimethyl terephthalate (DMT) (DMT) and ethylene glycol (EG) as raw material, the fiber of making through spinning and post processing.
Lack now a kind of can insect protected and the effective weaving face fabric of desinsection, thereby realize active insect and mosquitoe expelling longer.
Summary of the invention
Technical problem solved by the invention is to provide a kind of terylene desinsection fabric production technology, and the terylene desinsection fabric of production has long-acting insect expelling function.
Technical scheme is as follows:
A kind of terylene desinsection fabric production technology, comprising:
Generate the wet section of pastille terylene particle, utilize the wet section of pastille terylene particle to generate the dry section of pastille terylene, it is 1-16% that pesticide weight accounts for raw material gross mass percentage;
Utilize the dry section of pastille terylene to generate pastille terylene thread, the weaving of pastille terylene thread is generated to terylene desinsection fabric.
Further: described pesticide is chosen alphamethrin, cyfloxylate, Permethrin, cypermethrin, decis, ether chrysanthemum ester, Cyhalothrin, chlorine ether-ether, allethrin, rich d-allethrin or methothrin, 1～30g/kg that adding proportion is gross mass.
Further, the step that generates the wet section of pastille terylene particle comprises: utilize selected pesticide, phthalic acid and ethylene glycol to generate pastille Polyethyleneglycol Terephthalate, utilize pastille Polyethyleneglycol Terephthalate to generate the polyethylene terephthalate of pastille, after Cast Strip, cooling, dry, pelletizing, generate that pastille terylene is wet cuts into slices; Described phthalic acid accounts for gross mass ratio 42%-49.5%, and described ethylene glycol accounts for gross mass ratio 42%-49.5%.
Further, the step that generates the dry section of pastille terylene comprises: in wet chip bunker, the wet section of described pastille terylene particle is carried, generated the dry section of terylene after pre-crystallized, dry through screening, deironing, pulse, and dry described terylene section is sent into dry chip bunker; The hot-air of 120～170 DEG C of left and right of described pre-crystallized employing is to section heating, described dry rear process comprises: drop to-20 DEG C of following dry airs through the dew point of dehumidification processing and be heated to 160 DEG C of left and right, be transported to from drying tower bottom drying tower and make to cut into slices dehydration rapidly with reverse contact of section, dry air is taken moisture out of and is generated the dry section of pastille terylene from drying tower top.
Further, the step that generates pastille terylene thread comprises: described terylene is sent into screw extruder after doing and cut into slices after filtration, mixing, in described screw extruder, the dry section of described terylene is after melting, melt is admitted to spinning head, described melt forms melt thread from spinning head out, after lateral blowing is cooling, forms and solidifies strand, generates pastille terylene thread after warping; The heating-up temperature scope of described screw extruder is 270 DEG C to 300 DEG C.
Further, weaving adopt interweave, tatting, knitting or plain weave mode.
Beneficial effect of the present invention comprises:
1, utilize the fabric that the present invention produces to there is the feature soft, resistance to tension is strong and durable, and fabric have long-acting insect expelling function.Because weaving face fabric of the present invention adopted dosing processing before braiding, this textiles is soft, in practical application, and the pulling force more than anti-250KPA of ability, washable more than 20 times, the mosquito death rate still reaches 100%, and useful life is more than 5 years; Wash after 20 times, the rate of knockdown of mosquito and the death rate also can reach more than 85%.
2, weaving face fabric of the present invention is of many uses, can be used as conventional weaving face fabric and uses.
3, the present invention is different from general mosquito proof means, uses more convenient, clean environmental protection, simultaneously to human body also without injury, use safety.
4, utilize the present invention effectively to knock down and mosquito killer, and product is to user and washing person's safety, can be widely used in people's life.
Detailed description of the invention
In the present invention, mosquito-proof, function of driving mosquitoes is by joining pesticide in yarn and realize.Pesticide can be chosen: one or several combinations in alphamethrin, cyfloxylate, cypermethrin, decis, ether chrysanthemum ester, Cyhalothrin, chlorine ether-ether, allethrin, rich d-allethrin, methothrin etc., adding proportion is 1～30g/kg.
In the present embodiment, select 7 kinds, respectively: alphamethrin, cyfloxylate, Permethrin, decis, Cyhalothrin, ether chrysanthemum ester and cypermethrin.Pesticide also can be chosen decis 1.8g/kg or cypermethrin 5.5g/kg.
Below terylene desinsection fabric production technology is elaborated.
Be below the production technology of terylene thread, pesticide is that the stage just adds at the beginning for polyester formulation in production technology.
Step 1: generate the wet section of pastille terylene particle;
Utilize selected various pesticides (it is 1-16% that weight accounts for raw material gross mass percentage), phthalic acid (accounting for gross mass ratio 42%-49.5%) and ethylene glycol (accounting for gross mass ratio 42%-49.5%) to generate pastille Polyethyleneglycol Terephthalate, utilize pastille Polyethyleneglycol Terephthalate to generate the polyethylene terephthalate of pastille, after Cast Strip, cooling, dry, pelletizing, generate the wet section of pastille terylene, pastille terylene wet granular is sent into wet chip bunker.
Step 2: generate the dry section of pastille terylene;
In wet chip bunker, the wet section of pastille terylene particle through screening, deironing, pulse carry, pre-crystallized (adopting the hot-air of 120～170 DEG C of left and right to section heating), (process comprises: the dry air (dew point drops to below-20 DEG C) of process dehumidification processing is heated to 160 DEG C of left and right after dry, be transported to from drying tower bottom drying tower and make to cut into slices dehydration rapidly with reverse contact of section, dry air is taken moisture out of from drying tower top) generate the dry section of pastille terylene, dry pastille terylene section is sent into dry chip bunker.
Step 3: generate pastille terylene thread;
The dry section of pastille terylene after filtration, after mixing, send into screw extruder, in screw extruder, (be generally divided into 6 thermals treatment zone heating independent heating-up temperature of controlling separately, for terylene from the temperature of six thermals treatment zone, first thermal treatment zone to the generally 270 DEG C to 295 DEG C left and right, its temperature adjustment is more flexible, but the temperature of last two zones is controlled at 290 ± 5 DEG C within the scope of this conventionally, because the temperature of melt when the temperature of last two zones directly has influence on by casing), the dry section of pastille terylene is after melting, melt is admitted to spinning head, melt forms melt thread from spinning head out, after lateral blowing is cooling, form and solidify strand, after warping, generate pastille terylene thread.Warping is that the warp thread of certain radical length is in accordance with regulations wound on warp beam or beam of a loom and forms terylene thread.
Step 4: generate terylene desinsection fabric.
Pastille terylene thread adopt interweave, tatting, knitting, plain weave or other weaving manners become to have and drive or kill mosquito effect screen cloth or fabric.Screen cloth or fabric can be for the production of mosquito net or clothes.
The washable test of weaving face fabric:
1, get the dacron polyester screen cloth sample with function of driving mosquitoes of 25cm*25cm for subsequent use;
2, according to World Health Organization's washing test standard, in large beaker, add 0.5L water and 1g soap, keep pH value 10～11,30 DEG C of water temperatures, all dissolve to soap;
3, the dacron polyester screen cloth sample with function of driving mosquitoes of 25cm*25cm size is put into the beaker containing above washing agent, and beaker is placed on shaking table, the weaving face fabric sample 10min washing with the speed of 155 times/min; Afterwards, sample is shifted out, in water purification, clean twice, clean the weaving face fabric sample 10min washing with the speed of 155 times/min equally on shaking table;
4, after washing, under 30 DEG C of room temperatures, dry, under dark condition, be saved to washing next time, 1-3d between each washing needs.
Above process is carried out at least 20 times repeatedly.
Mosquito proof test:
Sensitive strain aedes albopictus (female) 2～5 age in days adults of laboratory rearing.
Test result: the pesticide wash resistant number of times having in the dacron polyester screen cloth of function of driving mosquitoes is 30 ~ 35 times, and the mosquito death rate reaches more than 100%, even after washing 20 times, the death rate and rate of knockdown also can reach more than 85%.
The explanation of this result of the test, the feature such as that the dacron polyester screen cloth with function of driving mosquitoes of the present invention has is washable, durable, mosquito rate of knockdown is high, the pesticide drug action time is long.
Claims (5)
1. a terylene desinsection fabric production technology, comprising:
Utilize selected pesticide, terephthalic acid (TPA) and ethylene glycol to generate pastille Polyethyleneglycol Terephthalate, utilize pastille Polyethyleneglycol Terephthalate to generate the polyethylene terephthalate of pastille, and after Cast Strip, cooling, dry, pelletizing, generate the wet section of pastille terylene particle, utilize the wet section of pastille terylene particle to generate the dry section of pastille terylene, it is 1-16% that pesticide weight accounts for raw material gross mass percentage;
Utilize the dry section of pastille terylene to generate pastille terylene thread, the weaving of pastille terylene thread is generated to terylene desinsection fabric;
The step of described generation pastille terylene thread comprises: described terylene is sent into screw extruder after doing and cut into slices after filtration, mixing, in described screw extruder, the dry section of described terylene is after melting, melt is admitted to spinning head, described melt forms melt thread from spinning head out, after lateral blowing is cooling, forms and solidify strand, after warping, generate pastille terylene thread; The heating-up temperature scope of described screw extruder is 270 DEG C to 300 DEG C.
2. terylene desinsection fabric production technology as claimed in claim 1, is characterized in that: described pesticide is chosen alphamethrin, cyfloxylate, Permethrin, cypermethrin, decis, ether chrysanthemum ester, Cyhalothrin, chlorine ether-ether, allethrin, rich d-allethrin or methothrin.
3. terylene desinsection fabric production technology as claimed in claim 1, is characterized in that, it is 42%-49.5% that described terephthalic acid (TPA) accounts for raw material gross mass percentage, and it is 42%-49.5% that described ethylene glycol accounts for raw material gross mass percentage.
4. terylene desinsection fabric production technology as claimed in claim 3, it is characterized in that, the step that generates the dry section of pastille terylene comprises: in wet chip bunker, the wet section of described pastille terylene particle is carried, is generated the dry section of terylene after pre-crystallized, dry through screening, deironing, pulse, and dry described terylene section is sent into dry chip bunker; The hot-air that described pre-crystallized employing is 120～170 DEG C is to section heating, described dry rear process comprises: drop to-20 DEG C of following dry airs through the dew point of dehumidification processing and be heated to 160 DEG C of left and right, be transported to from drying tower bottom drying tower and make to cut into slices dehydration rapidly with reverse contact of section, dry air is taken moisture out of and is generated the dry section of pastille terylene from drying tower top.
5. the terylene desinsection fabric production technology as described in claim 1 to 4 any one, is characterized in that, weaving adopts tatting or knitting type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210260037.9A CN102828273B (en) | 2012-07-25 | 2012-07-25 | Polyester insecticidal fabric production process |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210260037.9A CN102828273B (en) | 2012-07-25 | 2012-07-25 | Polyester insecticidal fabric production process |
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| CN102828273A CN102828273A (en) | 2012-12-19 |
| CN102828273B true CN102828273B (en) | 2014-12-10 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105177794A (en) * | 2015-07-14 | 2015-12-23 | 爱谱诗（苏州）服装有限公司 | Manufacturing process of anti-mosquito garment material |
| CN111270337A (en) * | 2020-04-13 | 2020-06-12 | 浙江正凯化纤有限公司 | Mosquito-repellent polyester fiber and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201785559U (en) * | 2010-08-10 | 2011-04-06 | 太仓市金辉化纤实业有限公司 | Insect-preventing mosquito-expellant fiber |
| CN102115951A (en) * | 2011-03-10 | 2011-07-06 | 江门市大自然纺织品有限公司 | Manufacturing method of long-acting mosquito-expelling textile |
| CN102149860A (en) * | 2008-10-21 | 2011-08-10 | 智能昆虫控制公司 | Textile product for killing insects |
| CN102220692A (en) * | 2011-04-26 | 2011-10-19 | 杨晓蓉 | Textile fabric with long-lasting insect-dispelling effect |
| CN102383258A (en) * | 2011-09-22 | 2012-03-21 | 杨晓蓉 | Long-lasting insect repellent fabric and method for producing same |
-
2012
- 2012-07-25 CN CN201210260037.9A patent/CN102828273B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102149860A (en) * | 2008-10-21 | 2011-08-10 | 智能昆虫控制公司 | Textile product for killing insects |
| CN201785559U (en) * | 2010-08-10 | 2011-04-06 | 太仓市金辉化纤实业有限公司 | Insect-preventing mosquito-expellant fiber |
| CN102115951A (en) * | 2011-03-10 | 2011-07-06 | 江门市大自然纺织品有限公司 | Manufacturing method of long-acting mosquito-expelling textile |
| CN102220692A (en) * | 2011-04-26 | 2011-10-19 | 杨晓蓉 | Textile fabric with long-lasting insect-dispelling effect |
| CN102383258A (en) * | 2011-09-22 | 2012-03-21 | 杨晓蓉 | Long-lasting insect repellent fabric and method for producing same |
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