CN102826501B - Quartz fiber surface microstructure and preparation method thereof - Google Patents
Quartz fiber surface microstructure and preparation method thereof Download PDFInfo
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- CN102826501B CN102826501B CN201210341404.8A CN201210341404A CN102826501B CN 102826501 B CN102826501 B CN 102826501B CN 201210341404 A CN201210341404 A CN 201210341404A CN 102826501 B CN102826501 B CN 102826501B
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- fiber surface
- surface microstructure
- quartz
- preparation
- quartz fiber
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- 239000000835 fiber Substances 0.000 title claims abstract description 48
- 239000010453 quartz Substances 0.000 title claims abstract description 42
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 29
- 239000003960 organic solvent Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims description 10
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 claims description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 6
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 4
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 3
- KFUSEUYYWQURPO-UHFFFAOYSA-N 1,2-dichloroethene Chemical group ClC=CCl KFUSEUYYWQURPO-UHFFFAOYSA-N 0.000 claims description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 3
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 3
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 2
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 2
- 229960002415 trichloroethylene Drugs 0.000 claims description 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 description 22
- 230000007797 corrosion Effects 0.000 description 22
- 239000000463 material Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000002164 ion-beam lithography Methods 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
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- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a quartz fiber surface microstructure and a preparation method thereof; the quartz fiber surface microstructure comprises quartz fibers with the diameters being 1mum to 1000mum and a circular groove array which is around the fibers; the spacing of the circular grooves is adjustable from 1mum to 1000mum; and the depths of the circular grooves are adjustable from 100nm to 100mum. The preparation method comprises the following steps that (1) organic solvent a which has the proportion not higher than that of water and is insoluble with the water is added into a plastic beaker, then an appropriate amount of HF acid solution is added, finally organic solvent b which has the proportion lower than that of the water and is insoluble with the water is carefully added, and three layers of corrosive liquid are formed; (2) the quartz fibers are vertically arranged in the corrosive liquid, a set depth is corroded, a set distance is pulled and then the set depth is corroded continuously; and (3) the step (2) is repeated for a plurality of times, and the quartz fiber surface microstructure can be obtained. According to the quartz fiber surface microstructure and the preparation method, the structure is novel, the preparation is simple, and the microstructure can be applied in micro-nano optics, biology, sensing, information and other fields.
Description
Technical field
The present invention relates to a kind of quartz fiber surface microstructure and preparation method thereof, belong to material microstructure and preparing technical field thereof.
Background technology
Quartz fiber surface prepares micro-structural, can realize the modulation that light transmits in the fibre, as the micro-structural of other type of Template preparation, thus can have important application in fields such as micronano optical, biology, sensing, information.The main method preparing micro-structural at present on quartz fibre (as optical fiber) surface is micro-processing technology, such as, prepare nano-micro structure by technology such as focused-ion-beam lithographies on the surface of quartz fibre.Micro-processing technology is not high due to preparation efficiency and working (finishing) area, is in a disadvantageous position in extensive efficient preparation.
Summary of the invention
The object of this invention is to provide a kind of quartz fiber surface microstructure, make this fine structure material can obtain extensive use in fields such as micronano optical, biology, sensing, information.Another object of the present invention is to provide the preparation method of this fine structure material.
Quartz fiber surface microstructure of the present invention, the quartz fibre by diameter 1 μm-1000 μm and the annular groove array around fiber form, and the spacing of annular groove is that 1 μm of-1000um is adjustable, and the degree of depth of annular groove is that 100nm-100um is adjustable.
The preparation method of quartz fiber surface microstructure of the present invention, comprises the following steps:
(1) in plastic beaker, add proportion be greater than water and the organic solvent a do not dissolved each other with water, then add appropriate HF acid solution, the last careful proportion that adds is less than water and the organic solvent b do not dissolved each other with water, forms the corrosive liquid of three layers of liquid; Wherein, organic solvent a is chloroform, carbon tetrachloride, dichloroethanes, carrene, sym-dichloroethylene, acetylene tetrachloride, trichloro-ethylene or carbon disulfide etc.; Organic solvent b is dimethylbenzene, chlorobenzene, isobutyl acetate, styrene, toluene, n-hexane, nonane or decane etc.;
(2) quartz fibre is vertically placed in above-mentioned corrosive liquid, and after fiber erodes to set depth, lift continues corrosion set depth to setpoint distance;
(3) repeatedly repeat step (2), can quartz fiber surface microstructure be obtained.
Compared with prior art, its remarkable advantage is in the present invention: (1) can obtain novel quartz fiber surface microstructure.(2) with low cost, without the need to large-scale instrument, simple and reliable process.
Accompanying drawing explanation
Fig. 1 is schematic diagram prepared by quartz fiber surface microstructure of the present invention.
Fig. 2 is quartz fiber surface microstructure schematic diagram.
Detailed description of the invention
Embodiment 1: add organic solvent chloroform in plastic beaker, then adds appropriate HF acid solution, finally carefully adds organic solvent dimethylbenzene, forms the corrosive liquid of three layers of liquid.The quartz fibre of diameter 1000um is vertically placed in above-mentioned corrosive liquid, after lifting 1000um after the corrosion 100um degree of depth, continues corrosion 50um.Repeatedly repeat above-mentioned corrosion process, can obtain that annular array spacing is about 1000um, the degree of depth is the quartz fiber surface microstructure that 100um and 50um replaces.
Embodiment 2: add organic solvent carbon tetrachloride in plastic beaker, then adds appropriate HF acid solution, finally carefully adds organic solvent toluene, forms the corrosive liquid of three layers of liquid.The quartz fibre of diameter 1um is vertically placed in above-mentioned corrosive liquid, after lifting 1um after the corrosion 100nm degree of depth, continues corrosion 100nm.Repeatedly repeat above-mentioned corrosion process, can obtain that annular array spacing is about 1um, the degree of depth is the quartz fiber surface microstructure of 100nm.
Embodiment 3: add organic solvent dichloroethanes in plastic beaker, then adds appropriate HF acid solution, and the organic solvent acetic acid isobutyl ester of last careful interpolation, forms the corrosive liquid of three layers of liquid.The quartz fibre of diameter 10um is vertically placed in above-mentioned corrosive liquid, after lifting 10um after the corrosion 1um degree of depth, continues corrosion 2um.Repeatedly repeat above-mentioned corrosion process, can obtain that annular array spacing is about 10um, the degree of depth is the quartz fiber surface microstructure that 1um and 2um replaces.
Embodiment 4: add organic solvent sym-dichloroethylene in plastic beaker, then adds appropriate HF acid solution, and last careful interpolation organic solvent-benzene ethene, forms the corrosive liquid of three layers of liquid.The quartz fibre of diameter 125um is vertically placed in above-mentioned corrosive liquid, after lifting 50um after the corrosion 5um degree of depth, continues corrosion 5um.Repeatedly repeat above-mentioned corrosion process, can obtain that annular array spacing is about 50um, the degree of depth is the quartz fiber surface microstructure of 5um.
Embodiment 5: add organic solvent acetylene tetrachloride in plastic beaker, then adds appropriate HF acid solution, finally carefully adds organic solvent-normal hexane, forms the corrosive liquid of three layers of liquid.The quartz fibre of diameter 500um is vertically placed in above-mentioned corrosive liquid, after lifting 60um after the corrosion 30um degree of depth, continues corrosion 20um.Repeatedly repeat above-mentioned corrosion process, can obtain that annular array spacing is about 60um, the degree of depth is the quartz fiber surface microstructure that 30um and 20um replaces.
Embodiment 6: add organic solvent trichlorethylene in plastic beaker, then adds appropriate HF acid solution, and last careful interpolation organic solvent nonane, forms the corrosive liquid of three layers of liquid.The quartz fibre of diameter 300um is vertically placed in above-mentioned corrosive liquid, after lifting 100um after the corrosion 30um degree of depth, continues corrosion 10um.Repeatedly repeat above-mentioned corrosion process, can obtain that annular array spacing is about 100um, the degree of depth is the quartz fiber surface microstructure that 30um and 10um replaces.
Embodiment 7: add organic solvent carbon disulfide in plastic beaker, then adds appropriate HF acid solution, and last careful interpolation organic solvent decane, forms the corrosive liquid of three layers of liquid.The quartz fibre of diameter 100um is vertically placed in above-mentioned corrosive liquid, after lifting 20um after the corrosion 5um degree of depth, continues corrosion 2um.Repeatedly repeat above-mentioned corrosion process, can obtain that annular array spacing is about 20um, the degree of depth is the quartz fiber surface microstructure that 5um and 2um replaces.
Claims (3)
1. a preparation method for quartz fiber surface microstructure, is characterized in that the method comprises the following steps:
(1) in plastic beaker, add proportion be greater than water and the organic solvent a do not dissolved each other with water, then add appropriate HF acid solution, finally add proportion and be less than water and the organic solvent b do not dissolved each other with water, form the corrosive liquid of three layers of liquid;
(2) quartz fibre is vertically placed in above-mentioned corrosive liquid, and after fiber erodes to set depth, lift setpoint distance continues to erode to set depth;
(3) step (2) is repeatedly repeated, quartz fiber surface microstructure can be obtained, the quartz fibre of described quartz fiber surface microstructure by diameter 1 μm-1000 μm and the annular groove array around fiber form, the spacing of annular groove is that 1 μm of-1000um is adjustable, and the degree of depth of annular groove is that 100nm-100um is adjustable.
2. the preparation method of quartz fiber surface microstructure according to claim 1, it is characterized in that, the organic solvent a described in step (1) is chloroform, carbon tetrachloride, dichloroethanes, carrene, sym-dichloroethylene, acetylene tetrachloride, trichloro-ethylene, carbon disulfide or chlorobenzene.
3. the preparation method of quartz fiber surface microstructure according to claim 1 and 2, is characterized in that, the organic solvent b described in step (1) is dimethylbenzene, isobutyl acetate, styrene, toluene, n-hexane, nonane or decane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210341404.8A CN102826501B (en) | 2012-09-17 | 2012-09-17 | Quartz fiber surface microstructure and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210341404.8A CN102826501B (en) | 2012-09-17 | 2012-09-17 | Quartz fiber surface microstructure and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102826501A CN102826501A (en) | 2012-12-19 |
| CN102826501B true CN102826501B (en) | 2015-01-07 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2183561Y (en) * | 1994-02-25 | 1994-11-23 | 清华大学 | Optical-fiber mechanical quantity transducer |
| US6203660B1 (en) * | 1997-10-29 | 2001-03-20 | California Institute Of Technology | Device for chemically etching a fiber probe |
| CN1815077A (en) * | 2006-01-17 | 2006-08-09 | 陈光威 | Carbon fiber pipe |
| CN101030455A (en) * | 2006-03-03 | 2007-09-05 | 北京大学 | Field optical fibre probe and its production |
| CN201632114U (en) * | 2010-01-25 | 2010-11-17 | 杭州大立过滤设备有限公司 | Carbon fiber composite filter core |
| CN202267759U (en) * | 2011-09-20 | 2012-06-06 | 浙江大学 | Micro optical fiber Bragg grating |
-
2012
- 2012-09-17 CN CN201210341404.8A patent/CN102826501B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2183561Y (en) * | 1994-02-25 | 1994-11-23 | 清华大学 | Optical-fiber mechanical quantity transducer |
| US6203660B1 (en) * | 1997-10-29 | 2001-03-20 | California Institute Of Technology | Device for chemically etching a fiber probe |
| CN1815077A (en) * | 2006-01-17 | 2006-08-09 | 陈光威 | Carbon fiber pipe |
| CN101030455A (en) * | 2006-03-03 | 2007-09-05 | 北京大学 | Field optical fibre probe and its production |
| CN201632114U (en) * | 2010-01-25 | 2010-11-17 | 杭州大立过滤设备有限公司 | Carbon fiber composite filter core |
| CN202267759U (en) * | 2011-09-20 | 2012-06-06 | 浙江大学 | Micro optical fiber Bragg grating |
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| CN102826501A (en) | 2012-12-19 |
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Effective date of registration: 20171109 Address after: 401120 Chongqing Longxi street, California city garden, Yubei District, 3, 8-5 Patentee after: CHONGQING FANCHAO BRAND MANAGEMENT CO., LTD. Address before: The 401120 northern New District of Chongqing municipality Mount Huangshan Middle Road No. 66 A207 Patentee before: Chongqing AOPO Ruisen Technology Co. Ltd. |
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Effective date of registration: 20190605 Address after: 221600 Peixian Highway 21, Peixian Economic Development Zone, Xuzhou City, Jiangsu Province Patentee after: Jiangsu Jinrongtai New Material Technology Co., Ltd. Address before: 401120 Chongqing Yubei District Longxi Street 3 California City Garden 8-5 Patentee before: CHONGQING FANCHAO BRAND MANAGEMENT CO., LTD. |