CN102816409B - Friction material for clutch - Google Patents

Friction material for clutch Download PDF

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Publication number
CN102816409B
CN102816409B CN201210305795.8A CN201210305795A CN102816409B CN 102816409 B CN102816409 B CN 102816409B CN 201210305795 A CN201210305795 A CN 201210305795A CN 102816409 B CN102816409 B CN 102816409B
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parts
order
powder
friction materials
powders
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CN102816409A (en
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戴初发
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Ningbo Sunlight Motor Parts Co Ltd
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Ningbo Sunlight Motor Parts Co Ltd
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Abstract

The invention discloses a friction material for a clutch, which comprises the following components in parts by weight: 35-37 parts of phenolic resin, 2-4 parts of polyvinyl alcohol butyral, 10-12 parts of sepiolite fiber, 6-8 parts of natural cellulose fiber, 4-6 parts of 120-320-mesh alumina powder, 5-7 parts of -200-mesh zinc oxide powder, 1-2 parts of -200-mesh boron nitride powder, 2-4 parts of diatomite, 5-7 parts of -320-mesh chromite powder, 6-8 parts of -150-mesh calcium silicate ceramic powder, 8-10 parts of -320-mesh barium sulfate, 3-5 parts of talc, 2-4 parts of colloidal molybdenum disulfide and 8-10 parts of -120-mesh flake graphite.

Description

A kind of clutch coupling friction materials
Technical field
The present invention relates to field of compound material, particularly a kind of clutch coupling friction materials.
Background technology
Clutch coupling friction materials is that medium-to-high grade automobile is as the critical material of transferring power in the arrangement of clutch of car, minibus and other motor vehicle and the use of various heavy-duty machinery.
Clutch coupling is different by Properties of Friction Materials, but conventionally all binding agent, fortifying fibre, abrasive material, lubricant, the large class material of filler five, consists of.In the 20-70 age in 20th century, containing the composite friction material of asbestos, be almost to rule all the land, adopt containing the composite friction material of asbestos and there is good performance and price as the brake friction material of various Motor vehicles.From 1972, international tumour medical association's confirmation asbestos and vaporization at high temperature thing belonged to carcinogens, start in the world the tide that one bans use of asbestos friction material, in the Friction Materials of nearly more than 30 years, the overwhelming majority concentrates on without asbestos composite friction material aspect.In replacing the fiber of asbestos, except steel fiber, more common having at present: the assorted fibre that glass fibre, carbon fiber, aramid fiber and these fibers mix mutually.
With steel fiber or metal powder (cast iron powder, reduced iron powder), replace fibrous magnesium silicate, application number: 89100843.8, semimetal friction material; Application number: 92106617.1, semi-metallic asbestos-free sedan brake disk and production method thereof.In use find that semimetal friction material exists following shortcoming: steel fiber gets rusty easily, after corrosion or occur adhesion antithesis or damage antithesis, make friction plate strength decreased, wearing and tearing aggravation, stable friction factor variation; Although semimetal friction material has been eliminated the high frequency noise that asbestos friction material easily produces, and easily produces the low frequency noise under low speed.
The feature of glass fibre is that hardness is high, better heat stability, good, cheap with resin affinity.Glass fibre developing history is longer, is in early stage asbestos-free friction material, to use more fiber.Application number: 02112952.5 asbest-free friction material reinforced base material and manufacturing process thereof, introduced the main composite friction material containing glass fibre.In use glass fibre friction materials all shows higher wear rate, glass fibre much higher hard and plasticity extreme difference is also one of reason causing high wear rate.Also can produce scratch and wearing and tearing by mating plate, under heavily loaded high temperature, frictional coefficient fluctuation is larger, less stable simultaneously.
Aramid fiber claims again Kevlar fiber, is the organic regenerated fiber of a kind of aromatic poly amide, is the product of du pont company's exploitation.Application number: 200610200693.4, a kind of fiber mixture reinforced friction material and preparation method thereof, has introduced the main composite friction material containing aramid fiber.It is characterized in that having under quite high intensity and toughness, medium modulus, very little density, wear-resisting, heat-resisting, high temperature dimensional stabilizing good, the fragility that does not have carbon fiber and glass fibre to present.But the content of in use finding Kevlar in friction materials can produce larger impact to its tribological property.When the content of Kevlar surpasses 10%, frictional coefficient reduces by 50%, and wear rate reduces an order of magnitude, but Kevlar content continues increase, and frictional coefficient remains unchanged substantially, and wear rate increases and continues to decline with Kevlar content.This shows, Kevlar adds the wear resistance that has greatly improved friction materials, but its frictional coefficient also declines thereupon.Although the friction materials that aramid fiber strengthens has extremely significantly wear resistance advantage, and has also arrived gratifying result in service testing, the reduction of the frictional coefficient causing is thus that Automotive Friction Material is undesirable.
The outstanding advantages of carbon fiber organic-type friction material is its high temperature friction good stability, wear-resisting.Application number: 200410075132.7, containing the friction materials of partially carbonized carbon fiber.But due to higher price promoting the use of of it.
In sum, the development of modern friction materials must be when considering to reduce friction materials production and adding the environmental pollution in man-hour, also must consider and pollution in use of friction materials and the contamination to environment of the friction materials scrapped, and the various factors such as the cost of friction materials and performance.Along with the development of technology, existing friction materials more and more can not meet the service requirements of clutch disc.
Summary of the invention
For the deficiencies in the prior art, one of object of the present invention is to provide a kind of clutch coupling friction materials.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of clutch coupling friction materials, this friction materials is comprised of following component in weight part: resol 35-37 part, polyvinyl alcohol butyral 2-4 part, sepiolite fibre 10-12 part, native cellulose fibre 6-8 part, 120-320 order aluminum oxide powder 4-6 part,-200 order oxide powder and zinc 5-7 parts,-200 order boron nitride powder 1-2 parts, diatomite 2-4 part ,-320 order chromite powder 5-7 parts,-150 order Calucium Silicate powder ceramics powder 6-8 parts,-320 order barium sulfate 8-10 parts, talcum powder 3-5 part, colloid molybdenumdisulphide 2-4 part ,-120 order flake graphite 8-10 parts.
Preferably, this friction materials is comprised of following component in weight part: resol 35.5-36.5 part, polyvinyl alcohol butyral 2.5-3.5 part, sepiolite fibre 10.5-11.5 part, native cellulose fibre 6.5-7.5 part, 120-320 order aluminum oxide powder 4.5-5.5 part,-200 order oxide powder and zinc 5.5-6.5 parts,-200 order boron nitride powder 1.3-1.7 parts, diatomite 2.5-3.5 part,-320 order chromite powder 5.5-6.5 parts,-150 order Calucium Silicate powder ceramics powder 6.5-7.5 parts,-320 order barium sulfate 8.5-9.5 parts, talcum powder 3.5-4.5 part, colloid molybdenumdisulphide 2.5-3.5 part,-120 order flake graphite 8.5-9.5 parts.
Most preferably, this friction materials is comprised of following component in weight part: 36 parts, resol, 3 parts of polyvinyl alcohol butyrals, 11 parts of sepiolite fibres, 7 parts of native cellulose fibres, 5 parts of 120-320 order aluminum oxide powders,-200 6 parts of order oxide powder and zincs,-200 1.5 parts of order boron nitride powders, 3 parts, diatomite ,-320 6 parts of order chromite powders,-150 7 parts of order Calucium Silicate powder ceramics powders,-320 9 parts, order barium sulfate, 4 parts of talcum powder, 3 parts of colloid molybdenumdisulphide, 9 parts of-120 order flake graphites.
The present invention has following beneficial effect:
1) optimized choice of the present invention the material of friction component and lubricant component, adopt the combination of sepiolite fibre and native cellulose fibre as fiber reinforcement constituent element.
2) add aluminum oxide powder, oxide powder and zinc, boron nitride powder, diatomite, chromite powder, Calucium Silicate powder ceramics powder, barium sulfate, the multiple ceramic composition of talcum powder simultaneously, utilize hardness, porosity, the refractoriness of above-mentioned various potteries, the difference of particle shape, mutually combine, mutually make up, jointly improve the performance of friction materials.
3) particularly optimize the blending powder of above-mentioned each ceramic powder, made it in friction materials, have skeleton to form component, had filling components.The cooperation of above-mentioned granularity makes ceramic composition in clutch coupling working process can play a supporting role to reduce abrasive action, can also play and reduce bonding to dual face, can also guarantee not scratch mating plate.
4) and on the basis of great many of experiments, reasonably selected the ratio of each component, make each component can play coordinative role effect at clutch coupling on period, reasonably allocate frictional coefficient, it is stablized suitable, reduced again wearing and tearing, and stable working, noiselessness.
5) static friction coefficient of friction materials of the present invention is large, weares and teares little, and transferring power efficiency is high.
Embodiment
Embodiment mono-
A kind of clutch coupling friction materials, this friction materials is comprised of following component in weight part: 4 parts of 35 parts of polyvinyl alcohol butyrals of resol, 8 parts of 10 parts of native cellulose fibres of sepiolite fibre, 4 parts of 120-320 order aluminum oxide powders,-200 7 parts of order oxide powder and zincs,-200 1 part of order boron nitride powder, 4 parts, diatomite ,-320 5 parts of order chromite powders,-150 8 parts of order Calucium Silicate powder ceramics powders,-320 8 parts, order barium sulfate, 5 parts of talcum powder, 2 parts of colloid molybdenumdisulphide, 10 parts of-120 order flake graphites.
Embodiment bis-
A clutch coupling friction materials, this friction materials is comprised of following component in weight part: 37 parts, resol, 2 parts of polyvinyl alcohol butyrals, 12 parts of sepiolite fibres, 6 parts of native cellulose fibres, 6 parts of 120-320 order aluminum oxide powders,-200 5 parts of order oxide powder and zincs,-200 2 parts of order boron nitride powders, 2 parts, diatomite ,-320 7 parts of order chromite powders,-150 6 parts of order Calucium Silicate powder ceramics powders,-320 10 parts, order barium sulfate, 3 parts of talcum powder, 4 parts of colloid molybdenumdisulphide, 8 parts of-120 order flake graphites.
Embodiment tri-
A kind of clutch coupling friction materials, this friction materials is comprised of following component in weight part: 35.5 parts, resol, 3.5 parts of polyvinyl alcohol butyrals, 10.5 parts of sepiolite fibres, 7.5 parts of native cellulose fibres, 4.5 parts of 120-320 order aluminum oxide powders,-200 6.5 parts of order oxide powder and zincs,-200 1.3 parts of order boron nitride powders, 3.5 parts, diatomite ,-320 5.5 parts of order chromite powders,-150 7.5 parts of order Calucium Silicate powder ceramics powders,-320 8.5 parts, order barium sulfate, 4.5 parts of talcum powder, 2.5 parts of colloid molybdenumdisulphide, 9.5 parts of-120 order flake graphites.
Embodiment tetra-
A kind of clutch coupling friction materials, this friction materials is comprised of following component in weight part: 36.5 parts, resol, 2.5 parts of polyvinyl alcohol butyrals, 11.5 parts of sepiolite fibres, 6.5 parts of native cellulose fibres, 5.5 parts of 120-320 order aluminum oxide powders,-200 5.5 parts of order oxide powder and zincs,-200 1.7 parts of order boron nitride powders, 2.5 parts, diatomite ,-320 6.5 parts of order chromite powders,-150 6.5 parts of order Calucium Silicate powder ceramics powders,-320 9.5 parts, order barium sulfate, 3.5 parts of talcum powder, 3.5 parts of colloid molybdenumdisulphide, 8.5 parts of-120 order flake graphites.
Embodiment five
A clutch coupling friction materials, this friction materials is comprised of following component in weight part: 36 parts, resol, 3 parts of polyvinyl alcohol butyrals, 11 parts of sepiolite fibres, 7 parts of native cellulose fibres, 5 parts of 120-320 order aluminum oxide powders,-200 6 parts of order oxide powder and zincs,-200 1.5 parts of order boron nitride powders, 3 parts, diatomite ,-320 6 parts of order chromite powders,-150 7 parts of order Calucium Silicate powder ceramics powders,-320 9 parts, order barium sulfate, 4 parts of talcum powder, 3 parts of colloid molybdenumdisulphide, 9 parts of-120 order flake graphites.
Applicant's statement, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, do not mean that the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to the selection of the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, concrete mode etc., within all dropping on protection scope of the present invention and open scope.

Claims (3)

1. a clutch coupling friction materials, it is characterized in that, this friction materials is comprised of following component in weight part: resol 35-37 part, polyvinyl alcohol butyral 2-4 part, sepiolite fibre 10-12 part, native cellulose fibre 6-8 part, 120-320 order aluminum oxide powder 4-6 part ,-200 order oxide powder and zinc 5-7 parts ,-200 order boron nitride powder 1-2 parts, diatomite 2-4 part,-320 order chromite powder 5-7 parts ,-150 order Calucium Silicate powder ceramics powder 6-8 parts ,-320 order barium sulfate 8-10 parts, talcum powder 3-5 part, colloid molybdenumdisulphide 2-4 part ,-120 order flake graphite 8-10 parts.
2. clutch coupling friction materials as claimed in claim 1, it is characterized in that, this friction materials is comprised of following component in weight part: resol 35.5-36.5 part, polyvinyl alcohol butyral 2.5-3.5 part, sepiolite fibre 10.5-11.5 part, native cellulose fibre 6.5-7.5 part, 120-320 order aluminum oxide powder 4.5-5.5 part,-200 order oxide powder and zinc 5.5-6.5 parts,-200 order boron nitride powder 1.3-1.7 parts, diatomite 2.5-3.5 part,-320 order chromite powder 5.5-6.5 parts,-150 order Calucium Silicate powder ceramics powder 6.5-7.5 parts,-320 order barium sulfate 8.5-9.5 parts, talcum powder 3.5-4.5 part, colloid molybdenumdisulphide 2.5-3.5 part,-120 order flake graphite 8.5-9.5 parts.
3. clutch coupling friction materials as claimed in claim 1 or 2, it is characterized in that, this friction materials is comprised of following component in weight part: 36 parts, resol, 3 parts of polyvinyl alcohol butyrals, 11 parts of sepiolite fibres, 7 parts of native cellulose fibres, 5 parts of 120-320 order aluminum oxide powders ,-200 6 parts of order oxide powder and zincs ,-200 1.5 parts of order boron nitride powders, 3 parts, diatomite,-320 6 parts of order chromite powders ,-150 7 parts of order Calucium Silicate powder ceramics powders ,-320 9 parts, order barium sulfate, 4 parts of talcum powder, 3 parts of colloid molybdenumdisulphide, 9 parts of-120 order flake graphites.
CN201210305795.8A 2012-08-24 2012-08-24 Friction material for clutch Active CN102816409B (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9915331B2 (en) * 2016-01-15 2018-03-13 Schaeffler Technologies AG & Co. KG Wet friction materials including calcium silicate
CN105605132B (en) * 2016-03-08 2018-01-30 泉州市力将机件企业有限公司 Automobile brake sheet
CN112682446B (en) * 2020-12-21 2022-09-16 蚌埠市科达电器有限公司 Preparation method of high-wear-resistance sector clutch friction block

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101555921A (en) * 2009-01-25 2009-10-14 瑞阳汽车零部件(仙桃)有限公司 Ceramic brake pad with high performance for middle-to-high grade sedan
CN101813150A (en) * 2010-05-20 2010-08-25 湖南博云汽车制动材料有限公司 Ceramic fiber reinforced ceramic matrix automotive brake friction material and preparation method thereof
CN101831273A (en) * 2010-05-14 2010-09-15 唐山市丰南区国荣基管业有限公司 Ceramic-based friction material and method for preparing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101555921A (en) * 2009-01-25 2009-10-14 瑞阳汽车零部件(仙桃)有限公司 Ceramic brake pad with high performance for middle-to-high grade sedan
CN101831273A (en) * 2010-05-14 2010-09-15 唐山市丰南区国荣基管业有限公司 Ceramic-based friction material and method for preparing same
CN101813150A (en) * 2010-05-20 2010-08-25 湖南博云汽车制动材料有限公司 Ceramic fiber reinforced ceramic matrix automotive brake friction material and preparation method thereof

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Address after: Yinzhou District Lianfeng road 315175 Zhejiang city of Ningbo Province, No. 889

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Address after: 889 Lianfeng Middle Road, Gaoqiao Town, Haishu District, Ningbo City, Zhejiang Province

Patentee after: NINGBO SUNLIGHT MOTOR PARTS Co.,Ltd.

Address before: 315175 889 Luen Fung Road, Yinzhou District, Ningbo, Zhejiang

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Application publication date: 20121212

Assignee: NINGBO XINGKE AUTOMOBILE NEW MATERIAL TECHNOLOGY Co.,Ltd.

Assignor: NINGBO SUNLIGHT MOTOR PARTS Co.,Ltd.

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Denomination of invention: Friction material for clutch

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Record date: 20211018