A kind of sulphur mud, sulphur cream conversion system and conversion process
Technical field
The invention belongs to the technical field that desulfuration byproduct is processed, be specifically related to a kind of sulphur mud, sulphur cream conversion system and conversion process.
Background technology
Sulphur exists with three kinds of forms in coal, i.e. organosulfur, sulfurous iron ore sulphur (sulphur that the form such as pyrite and white pyrite sulphur exists) and sulfate sulfur.The heat release though sulphur can burn, it is the composition being very harmful to.After combustion of sulfur, generating sulfurous gas (SO2) and a small amount of sulphur trioxide (SO3), enter atmosphere energy contaminate environment, is the essential substance that forms acid rain, all harmful to human body and animals and plants and above ground structure.For reducing above harm, coke-oven plant, fertilizer plant etc. uses coal rich and influential family, with all fire coal being carried out to desulfurization before coal.
At present, domestic many coke-oven plants adopt take the sulfur removal technology that ammonia is alkali source, and the sulfur removing pregnant solution that this technique belongs to after wet desulphurization , desulfurization workshop section absorbing hydrogen sulphide produces sulphur foam in regenerative process, and this sulphur foam show bubble, is a kind of solidliquid mixture.A lot of coal chemical enterprises are all after taking the method for centrifuge dripping to dewater, the sulphur mud of the certain water content finally obtaining or sulphur cream.Solids in sulphur mud or sulphur cream is mainly sulfur granule, also contains a small amount of coloured oily organic impurity.Sulphur is a kind of important chemical raw material, but because contained sulfur purity in sulphur mud or sulphur cream is not high, is difficult to purify and processing.Therefore, the value of sulphur mud, sulphur cream is not high, is mainly used as solid waste disposal.General treatment process is to stack landfill or take-away, and these sulphur mud, sulphur cream are deposited in and will cause environmental pollution outward, are also a kind of wastings of resources simultaneously; Take out that economic benefit is low, and buyer refines sulfur waste sulphur by heating, consume coal amount high, cause the wasting of resources.
Also the technique that has pair sulphur mud, sulphur cream to recycle in prior art to utilize: (1) take the distil process that steam or flue gas are thermal source, and this technique is owing to having ignored coloured organic impurity in solid, and the sulfur purity of gained is not high, and utility value is not high; (2) adopt the sulphur in extraction process recovery and purification sulphur mud, sulphur cream, this processing step is complicated, and production cost is high, and the productive rate of gained sulphur is low; (3) sulfur melting kettle sulfur-melting technology, this technique is that sulphur mud, sulphur cream are added in sulfur melting kettle, and the sulphur in sulphur mud, sulphur cream is all molten into liquid, the energy consumption of this technique in molten sulphur process is excessive, greatly increases production cost.
The harmless treatment of sulphur mud, sulphur cream is the important component part of desulfurization recycle section.Seen from the above description, the byproducts such as the sulphur mud of producing after desulfurization from fire coal, sulphur cream, sulfur purity is low, of poor quality, sale is difficult, except boiling the sulphur of low-purity, does not also have at present other reasonable methods to be used.
Summary of the invention
The object of the invention is to for the defect of above-mentioned existence and a kind of sulphur mud, sulphur cream conversion system and conversion process are provided.This treatment process is simple, and production cost is low, can make full use of to greatest extent sulphur mud, sulphur cream.
Technical scheme of the present invention is: a kind of sulphur mud, sulphur cream conversion system, and the base support that comprises housing and be welded in lower housing portion, has furnace gas export at the end face of housing; Opening for feed is arranged at housing feed end top, and opening for feed place is provided with feeder; Slag outlet is arranged at housing slag output end bottom, and slag exit is provided with water seal arrangement; Housing bottom surface is inclined-plane, on this housing bottom surface, arranges and is fixed with fixed grate film step by step, is provided with air compartment below fixed grate film, and air compartment is provided with inlet valve; Between two adjacent fixed grate films of described fixed grate film, be provided with movable furnace grate plate, this movable furnace grate plate is fixed on adjustable shelf, described adjustable shelf be positioned at housing bottom surface under; Described adjustable shelf bottom is provided with several resting supports, and resting support bottom joins by pulley and the slide rail being fixed on base support; Described resting support connection for transmission device; Described enclosure interior is provided with waste heat recovery unit.
Described transmission mechanism comprises union lever and drive unit, and described resting support is connected with drive unit by union lever.
Described drive unit is motor or hydro-cylinder or cylinder or oil cylinder.
On described housing, there is lagging material.
Sulphur mud, a sulphur cream conversion process, comprise the following steps:
(1) first sulphur mud, sulphur cream are dried to its water content and are less than 8%;
(2) dried sulphur mud, sulphur cream are sent into the opening for feed of conversion system by feeder, sulphur mud, sulphur cream are distributed on fixed grate film and/or movable furnace grate plate;
(3) wood chip naked light ignites, and makes in housing to be progressively warming up to sulphur mud, sulphur cream is lighted; Air compartment is controlled the air input of air, and sulphur mud, sulphur cream are fully burnt, and sulphur mud, sulphur cream are converted into sulfur dioxide gas and slag; The sulfur dioxide gas producing enters by the furnace gas export of housing end face the sulfur dioxide recovery device being connected with housing, and sulfurous gas is reclaimed; Slag along housing bottom surface step by step the slag exit to housing move, slag enters by slag outlet the water seal arrangement that is positioned at slag exit, reclaims slag after water seal; The used heat that sulphur mud, the burning of sulphur cream produce is used for recycling via waste heat recovery unit.
Beneficial effect of the present invention is: conversion system of the present invention is that this device is designed to inclined-plane by housing bottom surface for the processing of sulphur mud, sulphur cream, is conducive to the discharge of slag.Separately be provided with fixed grate film and movable furnace grate plate, the fixed grate film that is positioned at housing is directly arranged and is fixed on housing bottom surface step by step, be combined as a whole with housing bottom surface, not only can make full use of the ramp effect of housing bottom surface, and simple in structure, without re-using complicated fixing part, cost-saving; Movable furnace grate plate is spaced between two adjacent fixed grate films, the movable furnace grate plate entering in housing through housing bottom surface can back and forth move between fixed grate film, both can help sulphur mud, sulphur cream in enclosure interior fully burning repeatedly, slag after fully burning can be pushed to fixed grate film again, make it along housing bottom surface, inclined-plane, drain into slag outlet, further enter water seal arrangement, sediment depositing dust.Meanwhile, in enclosure interior, be provided with waste heat recovery unit, the pick up the heat that sulphur mud, the burning of sulphur cream can be produced, save energy, environmental protection.
Seen from the above description, this conversion system reasonable in design, simple in structure, practical, easy and simple to handle, serviceability is high.Highly-efficient treatment environmental protection to sulphur mud, sulphur cream.
Sulphur mud of the present invention, sulphur cream conversion process are first sulphur mud, sulphur cream to be lighted in above-mentioned sulphur mud, sulphur cream conversion system, burning conversion is sulfurous gas and slag, again sulfurous gas being sent into retrieving arrangement reclaims, can be for the production of vulcanizates such as ammonium sulphites, slag reclaims and can be used to prepare cement, and the used heat that burning produces is also recycled by waste heat recovery unit.
Described sulphur mud, that sulphur cream conversion process has technique is new; the advantage that system is reliable; compared to existing technologies, can make full use of to greatest extent sulphur mud, sulphur cream, simultaneously; production cost is low; energy consumption is little, reclaims the vulcanizates such as ammonium sulphite that sulfur dioxide gas obtains, and has very high economic worth; so conversion process of the present invention both had great importance to protection of the environment, there is again good economic benefit.
Accompanying drawing explanation
Fig. 1 is the structural representation of sulphur mud in the specific embodiment of the invention, sulphur cream conversion system.
Wherein, 1 is housing, and 2 is base support, and 3 is furnace gas export, 4 is housing feed end, and 5 is feeder, and 6 is housing slag output end, and 7 is slag outlet, 8 is water seal arrangement, and 9 is housing bottom surface, and 10 is fixed grate film, 11 is air compartment, and 12 is adjustable shelf, and 13 is movable furnace grate plate, 14 is resting support, and 15 is pulley, and 16 is slide rail, 17 is waste heat recovery unit, and 18 is union lever, and 19 is drive unit.
Embodiment
As can be seen from Figure 1, a kind of sulphur mud, sulphur cream conversion system, the base support 2 that comprises housing 1 and be welded in housing 1 bottom, has furnace gas export 3 at the end face of housing 1; Opening for feed is arranged at housing feed end 4 tops, and opening for feed place is provided with feeder 5, and feeder 5 can be sent to pending sulphur mud, sulphur cream to housing 1.Slag outlet 7 is arranged at housing slag output end 6 bottoms, slag exports 7 places water seal arrangement 8 is installed, and this water seal arrangement 8 both can cut off the air access to plant that slag exports 7 places, can play again the effect of slag depositing dust, effectively prevent slag ash dust pollution atmosphere, be beneficial to environmental protection.Housing bottom surface 9 is inclined-plane, on this housing bottom surface 9, arranges and is fixed with fixed grate film 10 step by step, is provided with air compartment 11 below fixed grate film 10, and air compartment 11 is provided with inlet valve.By the inlet valve of air compartment 11, control and enter the air flow quantity in housing 1, to reach the object of controlling furnace gas export 3 sulfur dioxide gas body burdens.Between two adjacent fixed grate films 10 of described fixed grate film 10, be provided with movable furnace grate plate 13, this movable furnace grate plate 13 is fixed on adjustable shelf 12, described adjustable shelf 12 be positioned at housing bottom surface 9 under.Described adjustable shelf 12 bottoms are provided with several resting supports 14, and resting support 14 bottoms join by pulley 15 and the slide rail 16 being fixed on base support 2; Described resting support 14 connection for transmission devices; Described housing 1 inside is provided with waste heat recovery unit 17.
Described transmission mechanism comprises union lever 18 and drive unit 19, and described resting support 14 is connected with drive unit 19 by union lever 18.
Described drive unit 19 is motor or hydro-cylinder or cylinder or oil cylinder.
On described housing 1, there is lagging material.
Sulphur mud, sulphur cream conversion process, comprise the following steps:
(1) first sulphur mud, sulphur cream are dried to its water content and are less than 8%;
(2) dried sulphur mud, sulphur cream are sent into the opening for feed of conversion system by feeder 5, sulphur mud, sulphur cream are distributed on fixed grate film 10 and/or movable furnace grate plate 13;
(3) wood chip naked light ignites, and makes in housing 1 to be progressively warming up to sulphur mud, sulphur cream is lighted; Air compartment 11 is controlled the air input of air, and sulphur mud, sulphur cream are fully burnt, and sulphur mud, sulphur cream are converted into sulfur dioxide gas and slag; The sulfur dioxide gas producing enters by the furnace gas export 3 of housing end face the sulfur dioxide recovery device being connected with housing 1, and sulfurous gas is reclaimed, and sulfur dioxide recovery can be produced the vulcanizates such as ammonium sulphite.Slag exports 7 places to the slag of housing 1 step by step along housing bottom surface 9 and moves, and slag is entered and is positioned at the water seal arrangement 8 that slag exports 7 places by slag outlet 7, reclaims slag after water seal; The used heat that the burning of sulphur mud, sulphur cream produces via waste heat recovery unit 17 for recycling.
Pending sulphur mud, sulphur cream are sent to housing 1 by feeder 5, the air that sulphur mud, sulphur cream and air compartment 11 are sent into converges, light, make sulphur mud, sulphur cream in housing 1 internal combustion, the sulfur dioxide gas that burning produces is via furnace gas export 3 dischargers, enter the sulfur dioxide recovery device being connected with housing 1, sulfurous gas is recycled, can produce the vulcanizates such as ammonium sulphite.Along housing bottom surface 9, by housing feed end 4, to the direction of housing slag output end 6, be followed successively by the alternative arrangement of movable furnace grate plate 13 and fixed grate film 10.The thrust that drive unit 19 motors or hydro-cylinder or cylinder or oil cylinder provide or pulling force act on resting support 14 by union lever 18, the pulley 15 that resting support 14 bottoms connect can be slided along slide rail 16 by thrust or pulling force, the adjustable shelf 12 being connected with resting support 14 moves thereupon, thereby making to arrange step by step the movable furnace grate plate 13 being fixed on adjustable shelf 12 moves back and forth 10 of fixed grate films, the to-and-fro movement of movable furnace grate plate 13 not only contributes to sulphur mud, sulphur cream burns fully in the housing 1 of device, and the slag that movable furnace grate plate 13 can promote to produce after fully burning is step by step discharged to slag outlet 7, and enter the water seal arrangement 8 that slag exports 7 places.