CN102115044A - Device for preparing sulfur dioxide by directly burning raw sulfur - Google Patents

Device for preparing sulfur dioxide by directly burning raw sulfur Download PDF

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Publication number
CN102115044A
CN102115044A CN 201110025569 CN201110025569A CN102115044A CN 102115044 A CN102115044 A CN 102115044A CN 201110025569 CN201110025569 CN 201110025569 CN 201110025569 A CN201110025569 A CN 201110025569A CN 102115044 A CN102115044 A CN 102115044A
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China
Prior art keywords
sulphur
living
sulfur
burning
gas
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CN 201110025569
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CN102115044B (en
Inventor
袁长胜
张超群
芮世文
莫爱盘
程晓辉
崔平
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JIANGSU ZHONGXIAN GROUP CO Ltd
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JIANGSU ZHONGXIAN GROUP CO Ltd
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Publication of CN102115044B publication Critical patent/CN102115044B/en
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Abstract

The invention discloses a device for preparing sulfur dioxide by directly burning raw sulfur. The device for preparing the sulfur dioxide by directly burning the raw sulfur comprises a raw sulfur continuous burning furnace; a sulfur noodle extrusion molding machine is arranged on the top of the raw sulfur continuous burning furnace; the sulfur noodle extrusion molding machine is connected with a propulsion feeder; and a raw sulfur funnel is arranged on the propulsion feeder. By the device for preparing the sulfur dioxide by directly burning the raw sulfur, the technical problem that the raw sulfur is difficult to burn and cannot be burned totally is solved effectively; the amorphous, flowable and difficult burning characteristics of the raw sulfur are changed into moldable, static and incendive characteristics, so that the raw sulfur can be burned and is easy to burn, and SO2 can be prepared directly; meanwhile, the high-performance retention high-temperature gas heat is recycled, so a feasible method for treatment and economic utilization of the raw sulfur is found. The device is a reliable way for relieving the burden of the environment as the raw sulfur is continuously increased; and the device has better economic prospect and good social benefit.

Description

A kind of be used for directly burning give birth to the device that sulphur prepares sulfurous gas
Technical field
The present invention relates to a kind of burning process device of living sulphur of wet desulphurization generation, be specifically related to a kind of device that living sulphur prepares sulfurous gas that is used for directly burning.
Background technology
Sulphur typically refers to ripe sulphur or crystallization sulphur or elemental sulfur, is one of main raw material of sulfurous gas or gas washing in SA production.Under the normal temperature, sulphur is solid, and property is crisp, and is frangible, good dispersity, easy firing.Give birth to sulphur, be commonly referred to sulphur cream, the amorphous shape, sulphur content is low, contains the amount of moisture height, and easy mobility is amorphous, difficult to burn.Therefore, the factory of production sulfurous gas such as vitriol works does not adopt living sulphur to make raw material.Catalytic wet oxidation method sulfur removal technology is adopted in the coal gas desulfurization decyanation of domestic coke-oven plant mostly, and the sulphur bubble processing approach of generation has two kinds, and the one, make melting sulphur, another kind is to produce to give birth to sulphur.Because of the process steam energy consumption height of system melting sulphur, the cost height, sulphur is second-rate, and market value is not high yet.So sulphur is selected to produce by most of coke-oven plants.Because of the marketable value of giving birth to sulphur is extremely low, be difficult for again selling, and take landfill, air storage, means such as discarded are handled, and this just causes secondary pollution to environment.
At present, it is quite big to give birth to sulphur output, and the annual sulphur that removes and reclaim from coke-oven gas has 53.6 ten thousand tons, and wherein 60% is unprocessed living sulphur, be converted to living sulfur content about 64.32 ten thousand tons/year to 700,000 tons/year.Seeking feasible method for these disposal and economic utilizations of giving birth to sulphur, is to solve to give birth to the unique channel that sulphur increases the pressure that causes to environment continually.
Summary of the invention
Goal of the invention: at the deficiencies in the prior art, the purpose of this invention is to provide a kind of device that living sulphur prepares sulfurous gas that is used for directly burning, in order to overcome the technical problem of the nonflammable and incomplete combustion of living sulphur, with give birth to sulphur amorphous, can flow, nonflammable proterties, change into moulding, mobile, incendive proterties, realize giving birth to flammable, the inflammable purpose of sulphur.
Technical scheme: in order to realize the foregoing invention purpose, the technical solution used in the present invention is:
A kind of be used for directly burning give birth to the device that sulphur prepares sulfurous gas, comprise living sulphur continuous incinerator, be provided with sulphur noodles single-lead-screw extruding briquetting machine at living sulphur continuous incinerator top, described sulphur noodles single-lead-screw extruding briquetting machine links to each other with advancing feeding machine, advances feeding machine to be provided with living sulphur hopper.
Be provided with the vacuum filter that is used to filter the fully living sulphur of sulphur infusion at described living sulphur hopper side.
At described living sulphur continuous incinerator is vertical incinerator, and the top neck is the preheating and drying section, and the middle part bosh is an incineration section, and the bottom is that gas is discharged section; Be provided with the burning bed in incineration section, discharge section at gas and be provided with gas discharge outlet, be provided with ash discharging hole in the bottom; Vertical incinerator is provided with fuel air pipe and air blast pipe.
Described burning bed is provided with 2 layers; Described air blast pipe is provided with 2 places, and the tuyere of described 2 place's air blast pipes is separately positioned in the last lower hearth that burns bed.
Described sulphur noodles single-lead-screw extruding briquetting machine comprises tubular shell, is provided with pattern at the hypomere of housing, is provided with reciprocating piston on pattern top, and piston is provided with push rod; On the tubular shell on pattern top, be provided with and the living sulphur import that advances feeding machine to communicate; Described tubular shell lower end is given birth to the sulphur inlet with the neck of giving birth to the sulphur continuous incinerator and is communicated.
The hypomere outer wall of described tubular shell is provided with the water cooling chuck.
Of the present invention being used for directly burned the device that living sulphur prepares sulfurous gas, will give birth to sulphur and form tiny noodles shape with advancing feeding machine to push in incinerator.Tiny sulphur noodles rapid drying in the high temperature incineration burner hearth, and under oxidizing atmosphere all burnt.This device comprises five parts, that is: vacuum filter is given birth to the sulphur hopper, the propelling feeding machine, and sulphur noodles single-lead-screw extruding briquetting machine and living sulphur continuous incinerator wherein, advance feeding machine, and sulphur noodles single-lead-screw extruding briquetting machine and living sulphur continuous incinerator are core apparatus.The effect of vacuum filter is that living sulphur cream is made in the dehydration of sulphur bubble; The effect of giving birth to the sulphur hopper is to store, pass on living sulphur; Advancing the effect of feeding machine is that life sulphur is advanced shaper continuously.The effect of sulphur noodles single-lead-screw extruding briquetting machine is to be squeezed into tiny sulphur noodles with giving birth to sulphur.The effect of incinerator is with the living sulphur silk drying of noodles shape, burns into sulfurous gas.
Sending into the living sulphur of living sulphur hopper can be sent into after with sulphur bubble dehydration by vacuum filter, also can be sent into by the living sulphur that other devices are made.Give birth to sulphur and slip into the propelling feeding machine, be pushed into spiral and be pressed into sulphur noodles single-lead-screw extruding briquetting machine from hopper.The push rod of sulphur noodles single-lead-screw extruding briquetting machine back and forth drives piston, and the living sulphur that sucks is back and forth pushed to pattern, extrudes silk silk sulphur noodles, and the sulphur noodles fall in the incinerator and are built on the burning bed of lattice type with refractory brick, burn under the air effect that the air blast pipe is sent into.Be provided with two-layer burning bed and twice air blast pipe in the stove, tuyere connects with airduct, in order to guarantee that fire box temperature reaches more than 800 ℃ when the blow-on, also is provided with the fuel gas inlet pipe, and the interior temperature of help stove is brought up to and required temperature.After the sulphur silk burning to be generated, temperature can be kept in the stove, and later assisted gas can stop.Burn the sulfur dioxide gas that produces and flow to waste heat boiler recovery heat from the stove lower part outlet, sulfurous gas acid gas and sulfuric acid production system couple together, and furnace bottom is provided with an ash discharging hole, regularly the deashing deslagging.
Giving birth to the inlet amount of sulphur can adjust by the stroke of regulating push rod or piston.Advance feeding machine to make charging stable.Sulphur noodles single-lead-screw extruding briquetting machine makes living sulphur moulding, and tiny easy burning.Burner hearth is established and is burned bed and unburnt living sulphur silk is dropped on when scorching hot bed is gone up burn immediately to the greatest extent.Fire box temperature is relevant with living combustion of sulfur amount, can transfer to control input speed by furnace temperature and inlet amount string.
Beneficial effect: of the present invention be used for directly burning give birth to the device that sulphur prepares sulfurous gas, compare with incinerator of the prior art, the present invention efficiently solves the technical problem of the nonflammable and incomplete combustion of living sulphur, with give birth to sulphur amorphous, can flow, nonflammable proterties, change into moulding, mobile, incendive proterties, it is flammable and inflammable to realize giving birth to sulphur, directly prepares SO 2Reclaim simultaneously and efficiently continue to employ the high-temperature gas heat, the disposal of the sulphur of making a living and economic utilization have searched out feasible method, are to solve to give birth to the reliable approach that sulphur increases the pressure that causes to environment continually, have the better economic prospect, can produce good social benefit.
Description of drawings
Accompanying drawing is the structural representation that living sulphur prepares the device of sulfurous gas that is used for directly burning of the present invention.
Embodiment
The present invention will be further explained below in conjunction with accompanying drawing.
As shown in drawings, for of the present invention be used for directly burning give birth to the device that sulphur prepares sulfurous gas.This device will be given birth to sulphur and be pushed the tiny noodles shape of formation with feeding machine in incinerator.Tiny sulphur noodles rapid drying in the high temperature incineration burner hearth, and under the oxic gas sweet smell all burnt.This device comprises five parts, that is: vacuum filter 5, gives birth to sulphur hopper 3, propelling feeding machine 4, and sulphur noodles single-lead-screw extruding briquetting machine 2 and living sulphur continuous incinerator 1 wherein, advance feeding machine 4, and sulphur noodles single-lead-screw extruding briquetting machine 2 and living sulphur continuous incinerator 1 are core apparatus.The effect of vacuum filter 5 is that living sulphur cream is made in the dehydration of sulphur bubble; The effect of giving birth to sulphur hopper 3 is to store, pass on living sulphur; Advancing the effect of feeding machine 4 is that life sulphur is advanced shaper continuously.The effect of sulphur noodles single-lead-screw extruding briquetting machine 2 is to be squeezed into tiny sulphur noodles with giving birth to sulphur.The effect of giving birth to sulphur continuous incinerator 1 is with the living sulphur silk drying of noodles shape, burns into sulfurous gas.At living sulphur continuous incinerator 1 top sulphur noodles single-lead-screw extruding briquetting machine 2 is set, sulphur noodles single-lead-screw extruding briquetting machine 2 links to each other with advancing feeding machine 3, advances feeding machine 3 to be provided with living sulphur hopper 2, at living sulphur hopper 2 sides vacuum filter 1 is set.
Giving birth to sulphur continuous incinerator 1 is vertical incinerator, and the top neck is the preheating and drying section, and the middle part bosh is an incineration section, and the bottom is that gas is discharged section; Be provided with burning bed 11 in incineration section, discharge section at gas and be provided with gas discharge outlet 15, be provided with ash discharging hole 14 in the bottom; Vertical incinerator is provided with fuel air pipe 13 and air blast pipe 12.Burn bed 11 and be provided with 2 layers; Air blast pipe 12 is provided with 2 places, and the tuyere of 2 place's air blast pipes 12 is separately positioned in the last lower hearth that burns bed 11.
Sulphur noodles single-lead-screw extruding briquetting machine 2 comprises tubular shell, is provided with pattern 23 at the hypomere of tubular shell, is provided with reciprocating piston 22 on pattern 23 tops, and piston 22 is provided with push rod 21; On the tubular shell on pattern 23 tops, be provided with and the living sulphur import that advances feeding machine 4 to communicate; The tubular shell lower end is given birth to the sulphur inlet with the neck of giving birth to the sulphur continuous incinerator and is communicated.The hypomere outer wall of tubular shell is provided with water cooling chuck 24.
Of the present inventionly be used for directly burning giving birth to the device that sulphur prepares sulfurous gas, send into the livings sulphur 6 of living sulphur hopper 3 and can send into after with the dehydration of sulphur bubble, also can send into by the living sulphur of other device manufacturings by vacuum filter.Give birth to sulphur and slip into propelling feeding machine 4, be pushed into spiral and be pressed into sulphur noodles single-lead-screw extruding briquetting machine 2 from 6 living sulphur hoppers 3.The push rod 21 of sulphur noodles single-lead-screw extruding briquetting machine 2 back and forth drives piston 22, the living sulphur 6 that sucks is back and forth pushed to shaping mould 23, extrude silk silk sulphur noodles, the sulphur noodles fall in the incinerator and are built on the burning bed 11 of lattice type with refractory brick, burn under the air effect that air blast pipe 12 is sent into.Be provided with two-layer burning bed and twice air blast pipe in the incinerator, tuyere connects with airduct, in order to guarantee that fire box temperature reaches more than 800 ℃ when the blow-on, also is provided with fuel gas inlet pipe 13, and the interior temperature of help stove is brought up to and required temperature.After the sulphur silk burning to be generated, temperature can be kept in the stove, and later assisted gas can stop.Burn the sulfur dioxide gas 7 that produces and flow to waste heat boiler recovery heat from stove lower part outlet 15, sulfurous gas acid gas and sulfuric acid production system couple together.The incinerator bottom is provided with an ash discharging hole 14, regularly the deashing deslagging.
Giving birth to the inlet amount of sulphur 6 can adjust by the stroke of regulating push rod or piston.Advance feeding machine 4 to make charging stable.Sulphur noodles single-lead-screw extruding briquetting machine 2 makes living sulphur moulding, and tiny easy burning, and burner hearth is established and burned bed and unburnt living sulphur silk is dropped on when scorching hot bed is gone up burn immediately to the greatest extent.Fire box temperature is relevant with living combustion of sulfur amount, can transfer to control input speed by furnace temperature and inlet amount string.
Of the present invention be used for directly burning give birth to the device that sulphur prepares sulfurous gas, compare with incinerator of the prior art, the present invention efficiently solves the technical problem of the nonflammable and incomplete combustion of living sulphur, with give birth to sulphur amorphous, can flow, nonflammable proterties, change into moulding, mobile, incendive proterties, it is flammable and inflammable to realize giving birth to sulphur, directly prepares SO 2Reclaim simultaneously and efficiently continue to employ the high-temperature gas heat, the disposal of the sulphur of making a living and economic utilization have searched out feasible method, are to solve to give birth to the reliable approach that sulphur increases the pressure that causes to environment continually, have the better economic prospect, can produce good social benefit.

Claims (6)

1. one kind is used for directly burning the device that living sulphur prepares sulfurous gas, it is characterized in that: comprise living sulphur continuous incinerator, be provided with sulphur noodles single-lead-screw extruding briquetting machine at living sulphur continuous incinerator top, described sulphur noodles single-lead-screw extruding briquetting machine links to each other with advancing feeding machine, advances feeding machine to be provided with living sulphur hopper.
2. according to claim 1 being used for directly burned the device that living sulphur prepares sulfurous gas, it is characterized in that: be provided with the vacuum filter that is used to filter the fully living sulphur of sulphur infusion at described living sulphur hopper side.
3. according to claim 1 being used for directly burned the device that living sulphur prepares sulfurous gas, and it is characterized in that: at described living sulphur continuous incinerator is vertical incinerator, and the top neck is the preheating and drying section, and the middle part bosh is an incineration section, and the bottom is that gas is discharged section; Be provided with the burning bed in incineration section, discharge section at gas and be provided with gas discharge outlet, be provided with ash discharging hole in the bottom; Vertical incinerator is provided with fuel air pipe and air blast pipe.
4. according to claim 3 being used for directly burned the device that living sulphur prepares sulfurous gas, it is characterized in that: described burning bed is provided with 2 layers; Described air blast pipe is provided with 2 places, and the tuyere of described 2 place's air blast pipes is separately positioned in the last lower hearth that burns bed.
5. according to claim 1 be used for directly burning give birth to the device that sulphur prepares sulfurous gas, it is characterized in that: described single-lead-screw extruding briquetting machine comprises tubular shell, hypomere at housing is provided with pattern, is provided with reciprocating piston on pattern top, and piston is provided with push rod; On the tubular shell on pattern top, be provided with and the living sulphur import that advances feeding machine to communicate; Described tubular shell lower end is given birth to the sulphur inlet with the neck of giving birth to the sulphur continuous incinerator and is communicated.
6. according to claim 5 being used for directly burned the device that living sulphur prepares sulfurous gas, and it is characterized in that: the hypomere outer wall of described tubular shell is provided with the water cooling chuck.
CN 201110025569 2011-01-24 2011-01-24 Device for preparing sulfur dioxide by directly burning raw sulfur Expired - Fee Related CN102115044B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102815673A (en) * 2012-08-27 2012-12-12 徐昭平 Sulfur slurry or sulfur paste conversion device and conversion process
CN112225182A (en) * 2020-10-19 2021-01-15 宁波中科远东催化工程技术有限公司 System and method for preparing acid by utilizing industrial sulfur-containing waste

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1237474A (en) * 1998-06-02 1999-12-08 鞍山钢铁集团公司 Technological process for making gas desulfurization by adopting liquid-phase catalytic oxidation method and its equipment
CN2880797Y (en) * 2006-01-27 2007-03-21 林锋 Sulfur burning furnace
CN101597522A (en) * 2009-06-29 2009-12-09 朱春阳 A kind of desulfuration processing method of coke oven gas and isolated plant thereof
CN201990488U (en) * 2011-01-24 2011-09-28 江苏中显集团有限公司 Device for directly incinerating raw sulfur to prepare sulfur dioxide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1237474A (en) * 1998-06-02 1999-12-08 鞍山钢铁集团公司 Technological process for making gas desulfurization by adopting liquid-phase catalytic oxidation method and its equipment
CN2880797Y (en) * 2006-01-27 2007-03-21 林锋 Sulfur burning furnace
CN101597522A (en) * 2009-06-29 2009-12-09 朱春阳 A kind of desulfuration processing method of coke oven gas and isolated plant thereof
CN201990488U (en) * 2011-01-24 2011-09-28 江苏中显集团有限公司 Device for directly incinerating raw sulfur to prepare sulfur dioxide

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102815673A (en) * 2012-08-27 2012-12-12 徐昭平 Sulfur slurry or sulfur paste conversion device and conversion process
CN102815673B (en) * 2012-08-27 2014-02-26 徐昭平 Sulfur slurry or sulfur paste conversion device and conversion process
WO2014032384A1 (en) * 2012-08-27 2014-03-06 Xu Zhaoping Sulfur slurry or sulfur paste conversion device and conversion process
CN112225182A (en) * 2020-10-19 2021-01-15 宁波中科远东催化工程技术有限公司 System and method for preparing acid by utilizing industrial sulfur-containing waste

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