CN102795769A - Formula of light lead glass tube - Google Patents

Formula of light lead glass tube Download PDF

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Publication number
CN102795769A
CN102795769A CN2011101405251A CN201110140525A CN102795769A CN 102795769 A CN102795769 A CN 102795769A CN 2011101405251 A CN2011101405251 A CN 2011101405251A CN 201110140525 A CN201110140525 A CN 201110140525A CN 102795769 A CN102795769 A CN 102795769A
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China
Prior art keywords
glass
formula
old
light lead
raw material
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Pending
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CN2011101405251A
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Chinese (zh)
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左彦毅
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Individual
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Individual
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Priority to CN2011101405251A priority Critical patent/CN102795769A/en
Publication of CN102795769A publication Critical patent/CN102795769A/en
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Abstract

The invention provides a formula of a light lead glass tube. 100 Kg of glass liquid raw materials comprise 215 Kg of SiO2, 63.94 Kg of Na2CO3, 15.77 Kg of KNO3, 6.78 Kg of K2CO3, 13.56 Kg of Na2B4O7, 21.19 Kg of CaCO3, 14.4 Kg of BaCO3, 23.39 Kg of lithium mica, 5.8 Kg of clarifying agent and 675 Kg of regenerated raw material crushed glass with the concentration of 62.5%; and the regenerated raw material crushed glass with the concentration of 62.5% is waste glass of old televisions for old-for-new service. The formula disclosed by the invention does not adopt the raw material lead silicate and the content of a heavy pollutant PbO in each 100 kilograms of the glass liquid is reduced compared with the previous formula and reaches 58%; and the luminance efficacy and the stretching performance of a product are improved, the product quality is ensured and the cost of each ton of the glass liquid is saved by more than 10%.

Description

The prescription of light lead glass pipe
Technical field: the present invention relates to a kind of prescription of light lead glass pipe, it is applicable to fields such as vacuum electronic, energy-saving electric light source, automotive industry.
Background technology: the conventional glass pipe by 100Kg glass metal formula for raw stock is: SiO 2, 215Kg; N a 2CO 3, 63.94 Kg; KN O 3, 15.77 Kg; K 2CO 3, 6.78 Kg; Pb 2SiO 4, 24.41 Kg; N a 2B 4O 7, 13.56 Kg; Ca CO 3, 21.19 Kg; Ba CO 3, 14.4 Kg; Lithionite 23.39 Kg; Finings 5.8 Kg; Glass cullet 675 Kg; By the resultant after the above proportioning fusing, content is by weight percentage: SiO 2, 67%; A l 2O 3, 1%; CaO, 3.5%; B 2O 3, 1%; Na 2O, 11%; K 2O, 5.5%; PbO, 11%.Wherein PbO is a heavy contaminant, and product cost is high, and physical strength toughness is low, light is well-illuminated low, can not satisfy the production development needs.
Summary of the invention: the object of the invention is exactly the prescription that a kind of light lead glass pipe will be provided, and it can overcome the existing existing above problem of Glass tubing.The objective of the invention is to realize like this, the prescription of light lead glass pipe is characterized in that: by 100Kg glass metal formula for raw stock be: SiO 2, 215Kg; N a 2CO 3, 63.94 Kg; KN O 3, 15.77 Kg; K 2CO 3, 6.78 Kg; N a 2B 4O 7, 13.56 Kg; Ca CO 3, 21.19 Kg; Ba CO 3, 14.4 Kg; Lithionite 23.39 Kg; Finings 5.8 Kg; 62.5% regenerative raw materials glass cullet, 675 Kg; Described 62.5% regenerative raw materials glass cullet are the old televisor discarded glass of old for new service; By the resultant after the above proportioning fusing, content is by weight percentage: SiO 2, 68%; A l 2O 3, 2%; CaO, 3.3%; B 2O 3, 1.3%; Na 2O, 11.8%; K 2O, 4%; Li 2O, 0.3%; CeO 2, 0.2%; BaO, 4.5%; PbO, 4.6%.The present invention does not adopt the raw material silicon lead plumbate, and per hundred kilograms of glass metals have reduced heavy contaminant PbO than original formulation, reach 58%, have increased B 2O 3, 0.3% is strong fusing assistant, makes in the molten glass process and has reduced fuel.Reduced expensive K 2O has increased the cheap strong physical strength flexible A l that has 2O 3, 1%; Improved the well-illuminated and extension property of light of product, guaranteed quality product, glass metal per ton is than practicing thrift cost originally more than 10%.
Embodiment;
The prescription of light lead glass pipe is characterized in that: by 100Kg glass metal formula for raw stock be: SiO 2, 215Kg; N a 2CO 3, 63.94 Kg; KN O 3, 15.77 Kg; K 2CO 3, 6.78 Kg; N a 2B 4O 7, 13.56 Kg; Ca CO 3, 21.19 Kg; Ba CO 3, 14.4 Kg; Lithionite 23.39 Kg; Finings 5.8 Kg; 62.5% regenerative raw materials glass cullet, 675 Kg; Described 62.5% regenerative raw materials glass cullet are the old televisor discarded glass of old for new service; By the resultant after the above proportioning fusing, content is by weight percentage: SiO 2, 68%; A l 2O 3, 2%; CaO, 3.3%; B 2O 3, 1.3%; Na 2O, 11.8%; K 2O, 4%; Li 2O, 0.3%; CeO 2, 0.2%; BaO, 4.5%; PbO, 4.6%.During practical implementation; Described 62.5% regenerative raw materials glass cullet are old televisor discarded glass that nobody shows any interest in, that environmental pollution is very serious, old for new service; Because contain 2% lead and other valuable metals and potassium, sodium ion in this glass, thus utilize old televisor glass bulb and televisor flat glass to replace lead and potassium, the sodium material of needs interpolation in the former batching, and do not adopt the raw material silicon lead plumbate; Per hundred kilograms of glass metals have reduced heavy contaminant PbO; Reach 58%, the industrial chemicals after weighing is according to a certain ratio packed into stirred 6 minutes uniformly in the stirrer, add the regenerative raw materials glass cullet that clean up after the pulverization process again; In stirrer, stirred 1 minute, and carried out melting when furnace temperature rises to 1550 industrial chemicals after sending stirring to when spending.

Claims (3)

1. the prescription of light lead glass pipe is characterized in that: by 100Kg glass metal formula for raw stock be: SiO 2, 215Kg; N a 2CO 3, 63.94 Kg; KN O 3, 15.77 Kg; K 2CO 3, 6.78 Kg; N a 2B 4O 7, 13.56 Kg; Ca CO 3, 21.19 Kg; Ba CO 3, 14.4 Kg; Lithionite 23.39 Kg; Finings 5.8 Kg; 62.5% regenerative raw materials glass cullet, 675 Kg.
2. the prescription of light lead glass pipe according to claim 1 is characterized in that: described 62.5% regenerative raw materials glass cullet are the old televisor discarded glass of old for new service.
3. the prescription of light lead glass pipe according to claim 1 is characterized in that: by the resultant after the above proportioning fusing, content is by weight percentage: SiO 2, 68%; A l 2O 3, 2%; CaO, 3.3%; B 2O 3, 1.3%; Na 2O, 11.8%; K 2O, 4%; Li 2O, 0.3%; CeO 2, 0.2%; BaO, 4.5%; PbO, 4.6%.
CN2011101405251A 2011-05-28 2011-05-28 Formula of light lead glass tube Pending CN102795769A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011101405251A CN102795769A (en) 2011-05-28 2011-05-28 Formula of light lead glass tube

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011101405251A CN102795769A (en) 2011-05-28 2011-05-28 Formula of light lead glass tube

Publications (1)

Publication Number Publication Date
CN102795769A true CN102795769A (en) 2012-11-28

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Family Applications (1)

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CN2011101405251A Pending CN102795769A (en) 2011-05-28 2011-05-28 Formula of light lead glass tube

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CN (1) CN102795769A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4419388A1 (en) * 1994-05-30 1995-12-07 Witega Angewandte Werkstoff Forschung Gemeinnuetzige Gmbh Adlershof Recycling waste glass from picture tubes of TV sets
US20040050106A1 (en) * 2002-08-29 2004-03-18 Murnane Rand A. Producing glass using outgassed frit
CN101643316A (en) * 2009-09-04 2010-02-10 云南家华新型墙体玻璃有限公司 Method for producing U-shaped glass by taking waste glass as raw material
CN101935163A (en) * 2010-08-03 2011-01-05 长兴康宁玻璃有限公司 Glass tube of novel high-efficiency energy-saving lamp

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4419388A1 (en) * 1994-05-30 1995-12-07 Witega Angewandte Werkstoff Forschung Gemeinnuetzige Gmbh Adlershof Recycling waste glass from picture tubes of TV sets
US20040050106A1 (en) * 2002-08-29 2004-03-18 Murnane Rand A. Producing glass using outgassed frit
CN101643316A (en) * 2009-09-04 2010-02-10 云南家华新型墙体玻璃有限公司 Method for producing U-shaped glass by taking waste glass as raw material
CN101935163A (en) * 2010-08-03 2011-01-05 长兴康宁玻璃有限公司 Glass tube of novel high-efficiency energy-saving lamp

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Application publication date: 20121128