CN102786744B - Automobile environment-friendly brake hose and preparation method thereof - Google Patents
Automobile environment-friendly brake hose and preparation method thereof Download PDFInfo
- Publication number
- CN102786744B CN102786744B CN201210301775.3A CN201210301775A CN102786744B CN 102786744 B CN102786744 B CN 102786744B CN 201210301775 A CN201210301775 A CN 201210301775A CN 102786744 B CN102786744 B CN 102786744B
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- Prior art keywords
- parts
- brake hose
- oil
- automobile environment
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- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 229920001971 elastomer Polymers 0.000 claims abstract description 38
- 239000003921 oil Substances 0.000 claims abstract description 19
- 235000019198 oils Nutrition 0.000 claims abstract description 19
- 241000196324 Embryophyta Species 0.000 claims abstract description 15
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 13
- 239000003549 soybean oil Substances 0.000 claims abstract description 13
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005864 Sulphur Substances 0.000 claims abstract description 8
- 239000006229 carbon black Substances 0.000 claims abstract description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000008117 stearic acid Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000004593 Epoxy Substances 0.000 claims description 10
- 229920001897 terpolymer Polymers 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- YXJYBPXSEKMEEJ-UHFFFAOYSA-N phosphoric acid;sulfuric acid Chemical group OP(O)(O)=O.OS(O)(=O)=O YXJYBPXSEKMEEJ-UHFFFAOYSA-N 0.000 claims description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000009967 tasteless effect Effects 0.000 abstract description 2
- 239000011787 zinc oxide Substances 0.000 abstract description 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 229920002943 EPDM rubber Polymers 0.000 abstract 1
- 239000010692 aromatic oil Substances 0.000 abstract 1
- 238000013475 authorization Methods 0.000 abstract 1
- 238000011156 evaluation Methods 0.000 abstract 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 abstract 1
- 239000004902 Softening Agent Substances 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 231100000357 carcinogen Toxicity 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- STSDHUBQQWBRBH-UHFFFAOYSA-N n-cyclohexyl-1,3-benzothiazole-2-sulfonamide Chemical compound N=1C2=CC=CC=C2SC=1S(=O)(=O)NC1CCCCC1 STSDHUBQQWBRBH-UHFFFAOYSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Valves And Accessory Devices For Braking Systems (AREA)
Abstract
Disclosed are an automobile environment-friendly brake hose and a preparation method thereof. Raw material components of the automobile environment-friendly brake hose include, by weight, 100 parts of ethylene-propylene-diene monomers, 90-120 parts of carbon black, 15-30 parts of 828-type plant based rubber filling oil, 5-10 parts of epoxidized soybean oil, 1-3 parts of nano zinc oxide, 1-3 parts of stearic acid, 2-5 parts of accelerators and 3-5 parts of sulphur. Compared with the prior art, the automobile environment-friendly brake hose has the advantages that both the 828-type plant based rubber filling oil and the epoxidized soybean oil are nonpoisonous and tasteless plasticizers which are safe and environment-friendly, contain no polycyclic aromatic hydrocarbons limited by the REACH (registration, evaluation, authorization and restriction of chemicals) and have no harmful volatile substances during preparation and use as compared with conventional plasticizers such as naphthenic oil and aromatic oil; both the 828-type plant based rubber filling oil and the epoxidized soybean oil come from plants and accordingly have remarkable cost advantages; vulcanizing time is short, production period is short, and energy consumption is low; and compared with an existing brake hose, the automobile environment-friendly brake hose has high hardness and tensile strength and good properties of heat resistance and aging resistance.
Description
Technical field
The present invention relates to auto parts machinery, more specifically, relate to a kind of automobile environment-protection brake rubber pipe and preparation method thereof.
Background technology
Along with the raising of people's living standard, automobile has become one of vehicles of people.The breaking system of automobile is at car deceleration or requisite system while stopping, and breaking system comprises stopper and brake rubber pipe.Brake rubber pipe is the vitals that automobile is improved quality and required very strictly, is related to vehicle and personnel safety.Brake rubber pipe, except resistance to braking fluid, also must have good ageing-resistant performance and moisture vapor transmission properties etc.Aromatic hydrocarbon oil large usage quantity in existing rubber oil product, and aromatic hydrocarbon is universally acknowledged carcinogens, contains condensed-nuclei aromatics (PAHs) composition.The brake rubber pipe of producing with the high aromatic rubber oil of tradition, in use carcinogens can evaporate.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of automobile environment-protection brake rubber pipe and preparation method thereof is provided.
According to an aspect of the present invention, a kind of automobile environment-protection brake rubber pipe, each feed composition content proportioning is by weight: terpolymer EP rubber 100, carbon black 90～120,828 plant base rubber filling oils 15～30, epoxy soybean oil 5～10, nano zine oxide 1～3, stearic acid 1～3, promotor 2～5, sulphur 3～5.
According to another aspect of the present invention, a kind of preparation method of automobile environment-protection brake rubber pipe, each feed composition content proportioning is by weight: terpolymer EP rubber 100, carbon black 90～120,828 plant base rubber filling oils 15～30, epoxy soybean oil 5～10, nano zine oxide 1～3, stearic acid 1～3, promotor 2～5, sulphur 3～5;
After above-mentioned raw materials is mixing, extrusion moulding, vulcanize, curing temperature is 150～170 ℃, and curing time is 15～30min.
Described promotor can be sulfate-phosphate derivative or CZ.
Than prior art, the present invention at least has the following advantages:
1) 828 plant base rubber filling oils and epoxy soybean oil are nonpoisonous and tasteless softening agent, compare with aromatic hydrocarbons wet goods with conventional softening agent naphthenic oil, safety and environmental protection, not containing the PAHs material of REACH regulation limitations, the objectionable impurities of can not volatilizing in preparation process and use procedure.
2) 828 plant base rubber filling oils and epoxy soybean oil all derive from plant, belong to renewable resources, than take the conventional softening agent of oil as raw material refining, have significant cost advantage.
3) curing time is short, with short production cycle, and energy consumption is low;
4) compare with existing brake rubber pipe material, there is larger hardness and tensile strength and heat-resisting, oxygen aging performance preferably.
Embodiment
Below in conjunction with specific embodiment, describe content of the present invention in detail.
Embodiment 1
Respectively by the terpolymer EP rubber of 100 weight parts, the carbon black of 90 weight parts, 828 plant base rubber filling oils of 15 weight parts, the epoxy soybean oil of 10 weight parts, the nano zine oxide of 1 weight part, the stearic acid of 2 weight parts, CZ(N-cyclohexyl-2-benzothiazole sulfonamide of 2 weight parts), after the sulphur premix of 3 weight parts, add mixer mixing, after extrusion moulding, at 170 ℃, vulcanize 15min, obtain goods.
Embodiment 2
Respectively by the terpolymer EP rubber of 100 weight parts, the carbon black of 110 weight parts, 828 plant base rubber filling oils of 30 weight parts, the epoxy soybean oil of 5 weight parts, the nano zine oxide of 3 weight parts, the stearic acid of 3 weight parts, the CZ of 5 weight parts, after the sulphur premix of 5 weight parts, add mixer mixing, after extrusion moulding, at 150 ℃, vulcanize 30min, obtain goods.
Embodiment 3
Respectively by the terpolymer EP rubber of 100 weight parts, the carbon black of 120 weight parts, 828 plant base rubber filling oils of 25 weight parts, the epoxy soybean oil of 8 weight parts, the zinc oxide of 2 weight parts, the stearic acid of 1 weight part, the sulfate-phosphate derivative of 4 weight parts, after the sulphur premix of 4 weight parts, add mixer mixing, after extrusion moulding, at 160 ℃, vulcanize 20min, obtain goods.
828 plant base rubber filling oils used in embodiments of the invention can be for example purchased from Shanghai Cheng Sheng Industrial Co., Ltd., nano zine oxide can be for example purchased from Shijiazhuang City Chang'an Xin Nada nano material factory, epoxy soybean oil can be for example purchased from Yueling City Ju Xin auxiliary agent Chemical Co., Ltd., and other raw materials are the routine selection of preparing rubber item.
Table 1 has provided the test result of the physicals of the automobile environment-protection brake rubber pipe of preparing according to method of the present invention.As known from Table 1, adopt the prepared automobile environment-protection brake rubber pipe of composition of raw materials of the present invention and vulcanization process, its hardness and tensile strength are larger, have good heatproof oxidation performance energy.Sebific duct of the present invention original performance after life-time service does not have too large variation, is conducive to guarantee braking effect.
The physicals of table 1 automobile environment-protection brake rubber pipe of the present invention
Claims (4)
1. an automobile environment-protection brake rubber pipe, it is characterized in that, each feed composition content proportioning is by weight: terpolymer EP rubber 100, carbon black 90～120,828 plant base rubber filling oils 15～30, epoxy soybean oil 5～10, nano zine oxide 1～3, stearic acid 1～3, promotor 2～5, sulphur 3～5.
2. the preparation method of an automobile environment-protection brake rubber pipe, each feed composition content proportioning is by weight: terpolymer EP rubber 100, carbon black 90～120,828 plant base rubber filling oils 15～30, epoxy soybean oil 5～10, nano zine oxide 1～3, stearic acid 1～3, promotor 2～5, sulphur 3～5;
After above-mentioned raw materials is mixing, extrusion moulding, vulcanize, wherein curing temperature is 150～170 ℃, and curing time is 15～30min.
3. preparation method according to claim 2, is characterized in that, described promotor is sulfate-phosphate derivative.
4. preparation method according to claim 2, is characterized in that, described promotor is CZ.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210301775.3A CN102786744B (en) | 2012-08-23 | 2012-08-23 | Automobile environment-friendly brake hose and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210301775.3A CN102786744B (en) | 2012-08-23 | 2012-08-23 | Automobile environment-friendly brake hose and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN102786744A CN102786744A (en) | 2012-11-21 |
| CN102786744B true CN102786744B (en) | 2014-07-16 |
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| CN201210301775.3A Expired - Fee Related CN102786744B (en) | 2012-08-23 | 2012-08-23 | Automobile environment-friendly brake hose and preparation method thereof |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103160033B (en) * | 2013-04-09 | 2015-04-15 | 北京瑞斯福高新科技股份有限公司 | Safety-warning sign adhesion tape for brake rubber hose of railway locomotive |
| CN103756157A (en) * | 2013-12-13 | 2014-04-30 | 芜湖佳诚电子科技有限公司 | Automobile environmental-friendly brake rubber pipe material |
| CN103724836A (en) * | 2013-12-13 | 2014-04-16 | 芜湖佳诚电子科技有限公司 | High-plasticization rubber power hose material |
| CN103819822B (en) * | 2014-02-26 | 2016-03-02 | 无锡二橡胶股份有限公司 | For the formula of ethylene propylene terpolymer with of environmental protection sebific duct |
| CN106633417A (en) * | 2015-08-02 | 2017-05-10 | 上海优宝橡塑制品有限公司 | Automobile product rubber formula and preparation method thereof |
| CN116218375B (en) * | 2022-12-20 | 2024-06-21 | 渭南科顺新型材料有限公司 | Polymer modified asphalt waterproof coiled material composition, waterproof coiled material, preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101676325A (en) * | 2008-09-19 | 2010-03-24 | 比亚迪股份有限公司 | Oil-resisting rubber compound, oil-resisting rubber and method of preparing oil-resisting rubber |
| CN101709120A (en) * | 2009-10-22 | 2010-05-19 | 北京万源瀚德汽车密封系统有限公司 | Rubber additive and ethylene propylene diene monomer containing same |
-
2012
- 2012-08-23 CN CN201210301775.3A patent/CN102786744B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101676325A (en) * | 2008-09-19 | 2010-03-24 | 比亚迪股份有限公司 | Oil-resisting rubber compound, oil-resisting rubber and method of preparing oil-resisting rubber |
| CN101709120A (en) * | 2009-10-22 | 2010-05-19 | 北京万源瀚德汽车密封系统有限公司 | Rubber additive and ethylene propylene diene monomer containing same |
Non-Patent Citations (2)
| Title |
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| "新型植物基环保增塑剂的应用";葛岚 等;《橡胶科技市场》;20111231(第1期);25-28 * |
| 葛岚 等."新型植物基环保增塑剂的应用".《橡胶科技市场》.2011,(第1期),25-28. |
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| CN102786744A (en) | 2012-11-21 |
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