CN102775890A - Automatic marking and color developing function coating and preparation method thereof - Google Patents
Automatic marking and color developing function coating and preparation method thereof Download PDFInfo
- Publication number
- CN102775890A CN102775890A CN2012102703267A CN201210270326A CN102775890A CN 102775890 A CN102775890 A CN 102775890A CN 2012102703267 A CN2012102703267 A CN 2012102703267A CN 201210270326 A CN201210270326 A CN 201210270326A CN 102775890 A CN102775890 A CN 102775890A
- Authority
- CN
- China
- Prior art keywords
- function coating
- coloring function
- automatically
- coating
- functional resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses an automatic marking and color developing function coating which comprises the following components in percentage by weight: 40-70 percent of marking function resin, 10-40 percent of cyclohexanone, 10-20 percent of photosensitizer additive, 5-10 percent of 8'-substituted indole spirooxazine and 5 percent of 1173 photo initiator. The coating is mainly used for the marking and the color developing of ship steel plates and coiled materials. The marking automation and the production efficiency can be greatly improved.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of coloring function coating of ruling automatically that is used for.
Background technology
In shipbuilding, basic operation is the processing of section bar, i.e. the line of section bar and cutting.It is the operation that relies on the intrinsic technical ability of workman for a long time, and labour intensity is big, and production efficiency is low, and the low precision of line and cutting is uncontrollable.Along with the development of industrial robot and industrial automation technology, with enlarge the production automation with improve homework precision be the automatic lineation cutting system of section bar robot of target for reducing labor intensity, enhance productivity and brought hope.
The problem that in coiled material industry, equally also has line, the artificial line of tradition consumes a large amount of muscle power and manpower, and its speed is difficult to satisfy actual needs, needs to adopt the method for line automatically, solves such problem.
The shipbuilding sections robot rules automatically and diced system has successfully solved the operational difficulty of ship industry section bar manual cut and line first, and possesses the distortion of compensation section bar and high precision line and cutting function.From the input of section bar machining information, the metrophia compensation of section bar distortion is rule automatically and is cut to robot trajectory's off-line programing, robot, is all accomplished by computer-aided control, is one to overlap complete CAM system.
Automatically line occupies first place in ship industry section bar robotization processing technology, has strong actual application value.One of basic operation of hull construction is the tangent line and the cutting of section bar; Promptly cut out the starting material of long size the member of different shape; And on each member, mark information such as hole, literal and fabrication line, assemble and weld according to component information in order to subsequent handling.But present line is to adopt directly on metal, to carry out, and part has been damaged the intensity of metal; Reduce the work-ing life of material, in ruling automatically, a kind of optical apparatus occurred, utilized the change of light intensity and wavelength; Can on some materials, form pattern, but in hertzian wave, have only the UV-light energy than higher, though electron beam is bigger than uv energy; But the energy that it is too high with the performance of infringement material, therefore adopts the UV-light line more feasible; The automatic scoring system of UV-light is arranged singly, be difficult to form pattern, therefore need to cooperate this automatic UV-light line instrument at base material; Under the effect of UV-light, on section bar, form the colour developing pattern, so that distinguish with other part.
The nineteen eighty-three Almanden of IBM Corporation has delivered the paper about the chemically amplified photo resist agent in the research centre, has caused photosensitive polymer field, whole world colleague's very big concern.Henceforth, the chemical amplification technology is widely used in improving the sensitivity of resist system.So-called chemical amplification effect adds light inlet exactly and produces acid source in photosensitive composition, quantum yield takes place when illumination be not more than 1 photochemical reaction, produces a kind of chemical amplification agent (for example protonic acid and Lewis acid); This chemical amplification agent still can continue to take place chemical reaction after illumination stops, improving its quantum effect; Therefore be widely used; Light is produced technic acid combine, will be automatic line, new technology is provided with developing technology.
Summary of the invention
Thinking of the present invention is: on the coating that has formed, adopt UV-irradiation, in the place of UV-light process; Will be because of photochemical effect; Produce metachromasia, and do not shine, with keeping original color; So that line part and the part difference of not having line, thereby realize line automatically.
Therefore technical problem to be solved by this invention provides a kind of coloring function coating of ruling automatically that is used for.
The technical problem that the present invention also will solve provides the preparation method of above-mentioned coating.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is following:
A kind of coloring function coating of ruling automatically that is used for, it comprises following components in weight percentage:
Line functional resin 40 ~ 70%;
Pimelinketone 10 ~ 40%;
Photosensitizer additive 10 ~ 20%;
8 '-substituted indole Luo oxazine 5 ~ 10%;
1173 light triggers 5%.
The above-mentioned coloring function coating of ruling automatically that is used for preferably includes following components in weight percentage:
Line functional resin 50 ~ 70%;
Pimelinketone 10 ~ 25%;
Photosensitizer additive 10 ~ 20%;
8 '-substituted indole Luo oxazine 5 ~ 10%;
1173 light triggers 5%.
Wherein, described line functional resin structure is as follows:
Wherein, the n value is 30 ~ 100, and the molecular weight of line functional resin is 10000 ~ 30000.
Above-mentioned line functional resin is pacified following method and prepared: with 1,4 cyclohexanedicarboxylic acid and NSC 6366 is monomer, and polycondensation obtains polymkeric substance, promptly gets with the vinylformic acid end-blocking again.
Wherein, described photosensitizer additive is a N-tolysulfonyl oxygen phthalic imidine, and its molecular structure is following:
Wherein, described 8 '-substituted indole Luo oxazine, its molecular structure is following:
The preparation method of the above-mentioned coloring function coating that is used for ruling automatically, the solid ingredient mixing in will filling a prescription earlier adds the liquid ingredient mixing then, is ground to particle diameter and reaches 5 ~ 10 μ m, promptly gets.
Beneficial effect: automatic line coloring function coating of the present invention compared with prior art has following advantage:
1, curing speed is fast;
2, line is convenient, has reduced labour intensity;
3, can adopt UV-light to combine directly line with computingmachine, reduce the equipment input cost;
4, exposure is 60mJ/m
2
Embodiment
According to following embodiment, can understand the present invention better.Yet, those skilled in the art will readily understand that the described content of embodiment only is used to explain the present invention, and the present invention that should also can not limit in claims to be described in detail.
Following examples, used line functional resin structure is as follows:
Wherein, the n value is 30 ~ 100, and the molecular weight of line functional resin is 10000 ~ 30000.
Above-mentioned line functional resin is pacified following method and prepared: with 1,4 cyclohexanedicarboxylic acid and NSC 6366 is monomer, and polycondensation obtains polymkeric substance, promptly gets with the vinylformic acid end-blocking again.Wherein, the esterification polymerization process is under 100 ℃, to carry out, and initiator is a Lucidol; The quality of initiator is 4% of a monomer total mass, and polymerization time is 10 hours, can obtain petchem; Under 80 ℃, in obtaining polyester, add Hydroxyethyl acrylate then; The ratio that adds is according to mol ratio 2.05: carry out, add the vinylformic acid insulation after 5 hours, discharging.
The used photosensitizer additive of following examples is a N-tolysulfonyl oxygen phthalic imidine, and it is by benzene methanesulfonic acid and the inferior acid amides of O-phthalic are synthesized the product that obtains.Its molecular structure is following:
Following examples used 8 '-substituted indole Luo oxazine, available from Tylenol chemical industry ltd in Shanghai.Its molecular structure is following:
Embodiment 1:
A kind of coloring function coating of ruling automatically that is used for, it comprises following components in weight percentage:
Line functional resin 55%;
Pimelinketone 20%;
Photosensitizer additive 10%;
8 '-substituted indole Luo oxazine 10%;
1173 light triggers 5%.
The preparation method: the solid ingredient mixing in will filling a prescription earlier, add the liquid ingredient mixing then, be ground to particle diameter and reach 5 ~ 10 μ m, promptly get.
The roller coating construction is solidified under UV-light, and the base material translational speed of coiled material is 1 meter per second, gets final product film forming, processes 25-40 μ m coating.Reach 1 grade through detecting sticking power, the experiment of accelerated deterioration outside is 3000 hours, does not occur unusual.Shock-resistant qualified.
Embodiment 2:
A kind of coloring function coating of ruling automatically that is used for, it comprises following components in weight percentage:
Line functional resin 50%;
Pimelinketone 15%;
Photosensitizer additive 20%;
8 '-substituted indole Luo oxazine 10%;
1173 light triggers 5%.
The preparation method: the solid ingredient mixing in will filling a prescription earlier, add the liquid ingredient mixing then, be ground to particle diameter and reach 5 ~ 10 μ m, promptly get.
The roller coating construction is solidified under UV-light, and the base material translational speed of coiled material is 1 meter per second, gets final product film forming, processes 25-40 μ m coating.Reach 1 grade through detecting sticking power, the experiment of accelerated deterioration outside is 3000 hours, does not occur unusual.Shock-resistant qualified.
Embodiment 3:
A kind of coloring function coating of ruling automatically that is used for, it comprises following components in weight percentage:
Line functional resin 60%;
Pimelinketone 15%;
Photosensitizer additive 10%;
8 '-substituted indole Luo oxazine 10%;
1173 light triggers 5%.
The preparation method: the solid ingredient mixing in will filling a prescription earlier, add the liquid ingredient mixing then, be ground to particle diameter and reach 5 ~ 10 μ m, promptly get.
The roller coating construction is solidified under UV-light, and the base material translational speed of coiled material is 1 meter per second, gets final product film forming, processes 25-40 μ m coating.Reach 1 grade through detecting sticking power, the experiment of accelerated deterioration outside is 3300 hours, does not occur unusual.Shock-resistant qualified.
Embodiment 4:
A kind of coloring function coating of ruling automatically that is used for, it comprises following components in weight percentage:
Line functional resin 70%;
Pimelinketone 10%;
Photosensitizer additive 10%;
8 '-substituted indole Luo oxazine 5%;
1173 light triggers 5%.
The preparation method: the solid ingredient mixing in will filling a prescription earlier, add the liquid ingredient mixing then, be ground to particle diameter and reach 5 ~ 10 μ m, promptly get.
The roller coating construction is solidified under UV-light, and the base material translational speed of coiled material is 1 meter per second, gets final product film forming, processes 25-40 μ m coating.Reach 1 grade through detecting sticking power, the experiment of accelerated deterioration outside is 3300 hours, does not occur unusual.Shock-resistant qualified.
Embodiment 5:
A kind of coloring function coating of ruling automatically that is used for, it comprises following components in weight percentage:
Line functional resin 50%;
Pimelinketone 25%;
Photosensitizer additive 15%;
8 '-substituted indole Luo oxazine 5%;
1173 light triggers 5%.
The preparation method: the solid ingredient mixing in will filling a prescription earlier, add the liquid ingredient mixing then, be ground to particle diameter and reach 5 ~ 10 μ m, promptly get.
The roller coating construction is solidified under UV-light, and the base material translational speed of coiled material is 1 meter per second, gets final product film forming, processes 25-40 μ m coating.Reach 1 grade through detecting sticking power, the experiment of accelerated deterioration outside is 3400 hours, does not occur unusual.Shock-resistant qualified.
Embodiment 6:
A kind of coloring function coating of ruling automatically that is used for, it comprises following components in weight percentage:
Line functional resin 50%;
Pimelinketone 20%;
Photosensitizer additive 20%;
8 '-substituted indole Luo oxazine 5%;
1173 light triggers 5%.
The preparation method: the solid ingredient mixing in will filling a prescription earlier, add the liquid ingredient mixing then, be ground to particle diameter and reach 5 ~ 10 μ m, promptly get.
The roller coating construction is solidified under UV-light, and the base material translational speed of coiled material is 1 meter per second, gets final product film forming, processes 25-40 μ m coating.Reach 1 grade through detecting sticking power, the experiment of accelerated deterioration outside is 3400 hours, does not occur unusual, shock-resistant qualified.
Claims (6)
1. one kind is used for the coloring function coating of ruling automatically, it is characterized in that, it comprises following components in weight percentage:
Line functional resin 40 ~ 70%;
Pimelinketone 10 ~ 40%;
Photosensitizer additive 10 ~ 20%;
8 '-substituted indole Luo oxazine 5 ~ 10%;
1173 light triggers 5%.
2. the coloring function coating of ruling automatically that is used for according to claim 1 is characterized in that, described line functional resin structure is as follows:
Wherein, the n value is 30 ~ 100, and the molecular weight of line functional resin is 10000 ~ 30000.
3. the coloring function coating of ruling automatically that is used for according to claim 2; It is characterized in that described line functional resin is pacified following method and prepared: with 1,4 cyclohexanedicarboxylic acid and NSC 6366 is monomer; Polycondensation obtains polymkeric substance, promptly gets with the vinylformic acid end-blocking again.
4. the coloring function coating of ruling automatically that is used for according to claim 1 is characterized in that, described photosensitizer additive is a N-tolysulfonyl oxygen phthalic imidine, and its molecular structure is following:
5. the coloring function coating of ruling automatically that is used for according to claim 1 is characterized in that, described 8 '-substituted indole Luo oxazine, its molecular structure is following:
6. the preparation method of the described coloring function coating that is used for ruling automatically of claim 1 is characterized in that the solid ingredient mixing in will filling a prescription earlier adds the liquid ingredient mixing then, is ground to particle diameter and reaches 5 ~ 10 μ m, promptly gets.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210270326.7A CN102775890B (en) | 2012-08-01 | 2012-08-01 | Automatic marking and color developing function coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210270326.7A CN102775890B (en) | 2012-08-01 | 2012-08-01 | Automatic marking and color developing function coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102775890A true CN102775890A (en) | 2012-11-14 |
| CN102775890B CN102775890B (en) | 2014-05-14 |
Family
ID=47121005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210270326.7A Expired - Fee Related CN102775890B (en) | 2012-08-01 | 2012-08-01 | Automatic marking and color developing function coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102775890B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5473068A (en) * | 1993-02-19 | 1995-12-05 | Yeda Research And Development Co. Ltd. At The Weizmann Institute Of Science | Photochromic spirooxazine monomers and polysiloxanes |
| CN101665655A (en) * | 2009-10-12 | 2010-03-10 | 西北永新化工股份有限公司 | High-performance wind-power generating facility coating prepared by taking organic fluorinated silicone modified elastic polyurethane-urea resin as substrate |
| CN102010653A (en) * | 2010-11-16 | 2011-04-13 | 北方涂料工业研究设计院 | Flame-resistant hydraulic oil resistant high solid polyurethane paint and preparation method thereof |
| CN102174286A (en) * | 2011-03-07 | 2011-09-07 | 中国海洋石油总公司 | Paint with low VOC (Volatile Organic Compound) for aircraft and preparation method thereof |
-
2012
- 2012-08-01 CN CN201210270326.7A patent/CN102775890B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5473068A (en) * | 1993-02-19 | 1995-12-05 | Yeda Research And Development Co. Ltd. At The Weizmann Institute Of Science | Photochromic spirooxazine monomers and polysiloxanes |
| CN101665655A (en) * | 2009-10-12 | 2010-03-10 | 西北永新化工股份有限公司 | High-performance wind-power generating facility coating prepared by taking organic fluorinated silicone modified elastic polyurethane-urea resin as substrate |
| CN102010653A (en) * | 2010-11-16 | 2011-04-13 | 北方涂料工业研究设计院 | Flame-resistant hydraulic oil resistant high solid polyurethane paint and preparation method thereof |
| CN102174286A (en) * | 2011-03-07 | 2011-09-07 | 中国海洋石油总公司 | Paint with low VOC (Volatile Organic Compound) for aircraft and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102775890B (en) | 2014-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101696332B (en) | Ultra-violet curing transfer ink | |
| CN102850899B (en) | A kind of photocuring alkali-resisting paint | |
| CN109517111B (en) | 3D printing method, 3D printing photocuring color-changing indicating resin and preparation method thereof | |
| CN104710548A (en) | 3D printing core material | |
| CN104559140B (en) | 3D printing-based photo-curing material and preparation method thereof | |
| CN110144140B (en) | Mixed photocuring ink-jet ink composition suitable for LED photocuring and mixer | |
| CN104151526A (en) | Novel photosensitive resin material applied to DLP3D printer | |
| CN104479460A (en) | LED-UV-cured ink-jet ink for flexible substrate printing | |
| CN106003767A (en) | Process for production of anisotropic optical film | |
| CN107513309B (en) | Three-dimensionally shaped photocuring transparent ink composition and its preparation method and application | |
| CN101747489A (en) | Special epoxy resin for UV-curable waterborne coatings and preparation method and application thereof | |
| CN107338007A (en) | The solid resistance to hot-press label of the special circular UV light of resin wheel | |
| CN104140734B (en) | AM-A ultra pottery repairs the preparation method of strongthener | |
| CN102775890B (en) | Automatic marking and color developing function coating and preparation method thereof | |
| CN106883653A (en) | A kind of ultraviolet moisture dual cure three-proofing coatings of LED and preparation method thereof | |
| CN104962152A (en) | Alumite chromatographic dye containing hyperbranched polymer and preparation method of alumite chromatographic dye | |
| CN109438631A (en) | A kind of high-precision and high heat distortion temperature stereolithography 3D printing photosensitive resin and preparation method thereof | |
| CN102033431B (en) | New polymer blue-ray engraving material | |
| CN104927482A (en) | Photo-curing offset printing ink | |
| CN110488570A (en) | A kind of photosensitive polymer combination and application thereof | |
| CN104311793A (en) | Photochromic ink prepolymer and preparation method thereof as well as photochromic ink | |
| CN103131003B (en) | Functionalized soybean oil compounds, and coating compositions comprising the same | |
| CN102241792A (en) | Hydrophilic high-molecular polymer photosensitive initiator and preparation method thereof | |
| CN104861769B (en) | Environment-friendly type UV light-curable inks and preparation method thereof | |
| Deng et al. | Amphiphilic Copolymers of Polyfluorene Methacrylates Exhibiting Tunable Emissions for Ink‐Jet Printing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140514 Termination date: 20200801 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |