CN102774081A - Manufacture technology for high-frequency material - Google Patents
Manufacture technology for high-frequency material Download PDFInfo
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- CN102774081A CN102774081A CN2011101201080A CN201110120108A CN102774081A CN 102774081 A CN102774081 A CN 102774081A CN 2011101201080 A CN2011101201080 A CN 2011101201080A CN 201110120108 A CN201110120108 A CN 201110120108A CN 102774081 A CN102774081 A CN 102774081A
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Abstract
The invention relates to a technology for reducing machinery processing problems of printed circuit boards by using a high-frequency material as a basic material. The high-frequency material at least comprises a copper foil, a teflon (polytetrafluoroethylene) resin, glass fiber, and the like, wherein the glass fiber is treated for reducing mechanical strength and is beneficial for processing when machining in subsequent manufacture processes. Materials produced by the method are not changed in material performance and not changed greatly in production cost. However, production yield and production capacity for the subsequently printing circuit boards are improved. The technology can play important role in the development of electronic industry.
Description
Technical field
Printed wiring board is maximum in an ordinary electronic product components and parts, and it is the carrier that is carrying various electronic devices and components and making the connection of mutual maintenance certain way between them, thereby realizes the design function of use of electronic product; The IC encapsulating carrier plate; Then be important electron components and parts in the ic component; It is the carrier of wafer, make between the wafer and wafer and other electronic devices and components between keep being connected of certain way each other, thereby realize the design function of use of ic component.The main raw material of electronic devices and components such as printed wiring board and IC encapsulating carrier plate---copper-clad plate and partly change cured sheets; Mainly constitute by materials such as Copper Foil, resin, glass fabrics; If resin mainly is made up of materials such as Teflons; Then formed a kind of special material, it has characteristics such as high frequency, high temperature resistant, high reliability.
Background technology
The conventional glass fiber all is from the glass furnace of high temperature melting, to pull out filament, and many filaments are twisted with the fingers into one, again one one fiber is made into the cloth shape, can become the glass fabric that we are commonly called as.Glass fabric is through after a series of processing; Carry out the resin impregnation; After containing the glass fibre process low-temperature bake that is soaked with resin; Become the flaky substance of semi-cured state, promptly prepreg (English abbreviates as: PP), cover with Copper Foil and impose HTHP again by the prepreg two sides; Just can become the main raw material of printed wiring board: copper-clad plate, printed wiring board or IC encapsulating carrier plate are made through a series of processed after high-temperature high-pressure lumps together by the copper-clad plate of having made figure and prepreg again.And at present used Teflon high frequency material is because Teflon material itself is softer; The Teflon material of processed position deforms when machining (comprise cut, cut, cut, mill, processing method such as brill, plane); Cause glass fibre to be broken by effective shearing; Add the active force acting in conjunction of pullling but received shearing,, to have caused working position after the machining generation that the fracture of glass fibre is uneven, hang silk, problem such as coarse to occur so glass fibre is pulled; These problems have caused yield not good, have also influenced the machining accuracy of Teflon materials, printed on wiring board simultaneously.The present invention relates to a kind of Teflon manufacturing method of plate thereof that how to improve Teflon material mechanical processing characteristics, thus can be so that the manufacturing technology level of Teflon high frequency material plate be gone on a new step.
Summary of the invention
The technical problem that the present invention solves is: a kind of technology that how to reduce with the high frequency material printed wiring board machining problem that is base material is provided; It adopts the method for a series of reduction glass fibre mechanical strengths and the adhesion between raising and resin and the glass fibre, to obtain the favorable mechanical processing characteristics.The material that adopts such method to produce; Material property can not change, and production cost does not change significantly yet, but produces the raising of the yield and the ability of making for follow-up printed wiring board; Play facilitation greatly, can play very big effect for the development of electronics industry.
Technical scheme of the present invention is: the manufacturing technology that a kind of high frequency material is provided; It is characterized in that; The minimum materials such as Copper Foil, Teflon (being polytetrafluoroethylene (PTFE)) resin, glass fibre that comprise of this material, Copper Foil is made up of at interior material crisscross glass fibre and the minimum polyflon that comprises between the Copper Foil of two sides as the constituent material on these two surfaces of material; Crisscross glass fibre is provided with for the bulk strength of reinforcing material; And used glass fibre is through reducing the processing of mechanical strength, is more conducive to processing when making the machining of glass fibre in subsequent manufacturing processes.
Further technical scheme of the present invention is: the method that reduces the glass fibre mechanical strength in a kind of manufacturing technology of high frequency material is provided, it is characterized in that, adopt the method for long-time high-temperature baking to reduce the mechanical strength of glass fibre.
Further technical scheme of the present invention is: the method that reduces the glass fibre mechanical strength in a kind of manufacturing technology of high frequency material is provided, it is characterized in that the diameter of described glass fibre is controlled between 0.5um～5um, to reduce the mechanical strength of glass fibre.
Further technical scheme of the present invention is: the method that reduces the glass fibre mechanical strength in a kind of manufacturing technology of high frequency material is provided; It is characterized in that; The diameter of described glass fibre is controlled between 0.5um～5um; And adopt the method for long-time high-temperature baking, to reduce the mechanical strength of glass fibre.
Further technical scheme of the present invention is: the method that reduces the glass fibre mechanical strength in a kind of manufacturing technology of high frequency material is provided; It is characterized in that; The diameter of described glass fibre is controlled between 0.5um～5um; And again fiberglass surfacing is stung the erosion alligatoring after adopting long-time high-temperature baking, to reduce the mechanical strength of glass fibre.
Further technical scheme of the present invention is: the method that reduces the glass fibre mechanical strength in a kind of manufacturing technology of high frequency material is provided; It is characterized in that; The diameter of described glass fibre is controlled between 0.5um～5um; And fiberglass surfacing is stung the erosion alligatoring, to reduce the mechanical strength of glass fibre.
Further technical scheme of the present invention is: a kind of baking method that reduces the glass fibre mechanical strength is provided; It is characterized in that; The method of long-time high-temperature baking is the minimum following processing that comprises: under 400 ℃～650 ℃ temperature conditions, toasted 90～120 hours.
Further technical scheme of the present invention is: a kind of baking method that reduces the glass fibre mechanical strength is provided; It is characterized in that; The method of long-time high-temperature baking is the minimum following processing that comprises: under 200 ℃～400 ℃ temperature conditions, toasted 200～400 hours.
Further technical scheme of the present invention is: provide a kind of alligatoring that reduces the glass fibre mechanical strength to sting the method for erosion fiberglass surfacing, it is characterized in that, sting the erosion minimum composition that contains fluorine of chemicals that glass fibre adopted.
Further technical scheme of the present invention is: provide a kind of alligatoring that reduces the glass fibre mechanical strength to sting the method for erosion fiberglass surfacing; It is characterized in that; Employing has acid chemicals fiberglass surfacing is stung erosion, thereby makes original more smooth fiberglass surfacing become coarse.
The effect that the present invention obtains is: improve through the production process of raw material is controlled with character; Thereby finally changed the physical characteristic of high frequency material; Make it be more conducive to the carrying out of the machining in the subsequent production process; Make the raw material of electronic product obtain the more development of high-tech, satisfy the demand of the electronics industry of world's high speed development.
Description of drawings
Fig. 1 is the three-dimensional tangent plane sketch map of high frequency material.
Glass fibre and the surperficial segment sketch map thereof of Fig. 2 for not passing through alligatoring.
Glass fibre and the surperficial segment sketch map thereof of Fig. 3 for passing through alligatoring.
The specific embodiment
Below in conjunction with the practical implementation example, technical scheme of the present invention is further specified.
For solving described problem; A kind of manufacturing technology of high frequency material is provided; Minimum Copper Foil (shown in 2 among Fig. 1), Teflon (being polytetrafluoroethylene (PTFE)) resin (shown in 3 among Fig. 1), the glass fibre materials such as (shown in 1 among Fig. 1) of comprising of this material, Copper Foil is made up of at interior material crisscross glass fibre and the minimum polyflon that comprises between the Copper Foil of two sides as the constituent material on these two surfaces of material; Crisscross glass fibre is provided with for the bulk strength of reinforcing material; And used glass fibre is through reducing the processing of mechanical strength, is more conducive to processing when making the machining of glass fibre in subsequent manufacturing processes.
Glass fibre: glass is a kind of mixture, and its definition is " inorganic matter is after the high temperature melting mixes, and cooling becomes a kind of hard objects of noncrystalline kenel again ".Is drawn into filaments (Filament) as a textile fiber material in the development of new uses for success in 1939 formally entered the era of glass fibers.Glass fibre can be divided into two kinds of situation: a kind of is continous way, is used to weave glass cloth (Cloth or Fabric); Another kind is discontinuous fixed length formula, and slabbing glued together is called glass seat (Mat).Many glass fiber compositions are a branch of, and glass fiber is pressed warp-wise and broadwise interlacing Cheng Buzhuan one by one again, can obtain glass fabric.
Glass fabric used in copper-clad plate (English abbreviation: CCL) with printed wiring board (English abbreviation: PCB) on the industry in the market; Grade is that E-Grade is the electron level material, and it is the cloth shape material that is woven and be made into through a series of processing by the electronic-grade glass yarn.Glass fabric kind commonly used has 7628,2116,1080 etc., and it be a code name, the digital meaning of no essence.Detail specifications and forming as follows:
Original glass fibre making process has: moisture regain, and------heald frame--is gone up weft yarn----boil off--grey cloth check--the silicon alkane processing-product inspection etc. of weaving cotton cloth to sizing to warping.Specify as follows:
Moisture regain: the extremely crisp and easy fracture of former glass, it is unusual when next operation, to be prone to produce filoplume, broken silk, broken yarn etc., handles so before coming into operation, will pass through moisture regain.The purpose is to allow a resurgence of moisture condenses into water film on the glass surface, glass fiber enhanced flexibility.
Warping: glass fabric be by warp thread (Warp) and weft yarn (Fill) be interwoven in length and breadth, because of the length of warp thread is very long, concerning the overall quality of cloth.So need the just cloth fabric width degree that weaves, with the raw yarn bought again in addition close interval arrange, just again with multireel raw yarn while parallel around wait weave cotton cloth on axle (Warp beam).Weft yarn then be directly on cop (Qvill or bobbin) going to weave cotton cloth gets final product.Because warp thread is through arrangement, and the yarn number is also many than weft yarn, so endurance strength is all good than weft yarn, thereby the stressed bigger direction of printed wiring board, should be advisable with warp-wise.
Sizing: sizing is the warp thread of arranging compiling again, and the processing (Sizing) that also will do a starching is called " slurry warp ".The purpose is to increase lubrication and reduce friction.These slurries also want destarch to handle after being made into cloth, to obtain clean glass surface.The Tension Control that this kind starching is handled is wanted SC, in case its fracture and influence the quality of cloth.The last warp thread of crossing slurry also will squeeze wheel (Nip Roll) through one and squeeze out redundant sizing agent, and then through after the oven dry of heat steam, can carry out the operation (Entering) of heald frame.
Heald frame: claim to combine yarn again.This action is every warp thread all to be penetrated the steel of taking the lead smash, and enables that (Loom) carries up and down in loom.Simultaneously, also need go up weft yarn, last weft yarn be original-pack living yarn again directly on cop; When weaving cotton cloth by " shuttle " or compressed-air actuated drive; Back and forth run quickly between warp thread, and form passing through and interweave one on the other with it, the preparation of weaving cotton cloth has been accomplished in various pre-treatments to this.
Weave cotton cloth: the method for weaving cotton cloth commonly used at present is the shuttle less loom method that drives the weft yarn yarn with compressed air or water.The method of weaving cotton cloth has multiple different types, but is used for the glass cloth of substrate, but from start to finish all only with a kind of flat weaving method soon through the weft yarn up and down weaving, the tool stability of the size of its cloth of flat weaving method is also least yielding, and weight and thickness are also the most even.
Boil off: claim to burn clean again.When glass fabric has woven completion, will to obtain clean glass fabric, make it can do further silicon coupling again and handle removing for the convenient slurry of temporarily coating of processing procedure.Because of glass fabric can not burn, but the organic matter that its adhering on surface can be decomposed into gas and break away from the glass fabric that so can obtain cleaning.Usually can be divided into the processing of two steps, at first be that continuous aerobic burns, and furnace temperature reaches 593～816 ℃, can burn 91～98% slurry, and then long-time low temperature batch processing; Next is that discontinuous batch of formula handled, and it is the glass cloth overline to be wrapped on the metal cylinder of porous put in the baker again, in 260 ℃～371 ℃, burns 55～80 hours, and the organic matter in the cloth is not approachingly had by further evaporating into fully.Batch formula K cryogenic treatment method is slowly left grease and fugitive constituent in the slurry, unlikelyly causes great amount of heat energy to pour in and generates the reduction that tensile strength should be arranged.
Grey cloth check: in this step, adopt the mode of desk checking, confirm whether the quality of glass fabric meets standard fully, for incongruent product, need choose, or graduation is handled.
Silicon alkane is handled: claim silicon alkane coupling processing again.Because glass surface is very smooth, other material such as water, resin etc. are not easy glass surface or fiberglass surfacing wetting well, just can not combine well between resin and the glass fibre like this, thereby produce quality problem.Silane treated glass fiber surface is coated with a "coincidence" of the cortex, so that the resin in addition to the original mechanical properties, and then provide a molecular level "bond relay", drastic changes in temperature to maintain a combination of both strength , it can be called "adhesion promoter" (Adhesion? promoter).If silicon alkane processing layer can cover glass the surface, make its unlikely adhesive force that loses with resin under the encirclement of moisture content, and then can keep the insulating properties of dielectric material.This kind coupling agent is essentially a kind of material that blendes together (Hybrid Material), and an end has the very strong organic functional base of a kind of reagency in its molecule, and the other end then is the functional group of inorganic nature, and is middle then be the trunk of silicon alkane.The in-between monolayer of this kind " coupling epithelium " has promptly formed at the film of B-stage intact man-hour.If the above silanes which compound coupling agent such as molecular structure: X-Si-R-(OCH3) 3, X is amino group, an epoxy group, and styrene.
Reduction glass fibre mechanical strength
One of processing methodFor: the mechanical strength that adopts the method reduction glass fibre of long-time high-temperature baking.
We know that the composition that constitutes glass mainly contains following: SiO
2, Al
2O
3, B
2O
3, CaO, MgO, R
2O, the produced glass of normal condition, these compositions can be mixed equably, form whole uniformly formation, promptly belong to the glass of not phase-splitting.As glass is heat-treated under 400～650 ℃ of temperature, it can be transformed into Na
2O-B
2O
3With SiO
2Two phases, i.e. the glass of phase-splitting.After the glass process phase-splitting heat treatment, its mechanical strength can descend, and becomes more crisp, thereby when machining, is more conducive to be cut disconnected.One of method of long-time high-temperature baking is minimum to comprise following processing: under 400 ℃～650 ℃ temperature conditions, toasted 90～120 hours; Two of the method for long-time high-temperature baking minimumly comprises following processing: under 200 ℃～400 ℃ temperature conditions, toasted 200～400 hours.Different heat treatment degrees, the fragility of glass fibre are also different, and temperature is high more, the processing time is long more, and then fragility is big more, when machining then easy more be cut disconnected; And temperature is low more, the processing time is short more, and then pliability keeps fully more, when machining then difficulty be cut disconnected.After such high-temperature baking processing, the mechanical strength of glass fibre can descend 20%～80%.Above-mentioned treatment conditions can also be divided into several kinds of class, to obtain the glass fibre of different mechanical strength sizes.
Reduction glass fibre mechanical strength
Two of processing methodFor: the diameter of described glass fibre is controlled between 0.5um～5um, to reduce the mechanical strength of glass fibre.
The diameter of wall scroll glass fibre is big more, and then its mechanical strength is also just big more, and when machining, then difficulty is cut disconnectedly more, causes the possibility of quality problem just big more after processing; The diameter of wall scroll glass fibre is more little, and then its mechanical strength is also just more little, when machining, then is cut disconnectedly more easily, causes the possibility of quality problem just more little after processing.Adopt less glass fibre spelling to become the glass fiber bundle of identical size; Or adopt more glass fibre bar number to be placed in the material; Can obtain that final mechanical strength does not descend or descend on a small quantity but but be more conducive to the Teflon high frequency material of machining (the meaning here is meant: when materials such as resin, glass fibre, Copper Foil are processed high frequency material sheet material; Or after these high frequency material sheet materials processed printed wiring board, this this high frequency material or printed wiring board were not easy to occur bending and deformation etc.).With the glass fiber diameter that is fit to size, the diameter of glass fibre is controlled between 0.5um～5um, make and the requirement that both can satisfy overall mechanical strength can improve the required required precision of machining again.
Reduction glass fibre mechanical strength
Three of processing methodFor: the diameter of described glass fibre is controlled between 0.5um～5um, and adopts the method for long-time high-temperature baking, to reduce the mechanical strength of glass fibre.The method be above-mentioned "
One of processing method" and "
Two of processing method" combine and draw, when a kind of in above-mentioned any one method all can not satisfy the demand of machining accuracy, adopt the method for two kinds of method superpositions, can further improve problem, to satisfy the technical need of different levels.
Reduction glass fibre mechanical strength
Four of processing methodFor: the diameter of described glass fibre is controlled between 0.5um～5um, and again fiberglass surfacing is stung the erosion alligatoring after adopting long-time high-temperature baking, to reduce the mechanical strength of glass fibre.The method of fiberglass surfacing being stung the erosion alligatoring has two kinds: a kind of is to sting the erosion minimum composition that contains fluorine of chemicals that glass fibre adopted; Another kind is to adopt the chemicals with acidity that fiberglass surfacing is stung erosion, thereby makes original more smooth fiberglass surfacing become coarse.Be described in detail below:
Sting etching method one: adopt the chemicals that contains fluorine that fiberglass surfacing is stung erosion, thereby make original more smooth fiberglass surfacing become coarse.Fluorine-containing material can corrode the material of category of glass; Thereby cause the effect of etching; And hydrogen fluoride is the most frequently used and more facile a kind of material; Hydrogen fluoride and all can the material of category of glass be corroded with the mixture of other materials is so containing of stinging erosion glass fibre adopted minimumly in the fluorine chemistry medicine comprises hydrofluoric composition and promptly can realize the erosion of stinging to glass.Stinging erosion fluorine-containing chemicals that glass fibre adopted can be to be in liquid material, also can be the material that is in gaseous state, if during liquid, needs glass fiber is immersed in the fluorine-containing liquid, to realize the erosion of stinging to glass fibre; If during gaseous material, need glass fiber is placed fluorine-containing gas, to realize the erosion of stinging to glass fibre.The benefit that adopts gaseous material to sting erosion is, stings after erosion finishes, and can dry, and that glass fibre is still is dry; If when adopting liquid to sting erosion; Glass fibre or glass fabric itself understood impregnation and adhered to liquid; The next treatment process that can be transported to these liquid causes the pollution of operation down, and in the process of transporting, the fluorine-containing material that is contained in the liquid can continue to sting the erosion glass fibre; Cause that to sting erosion inhomogeneous or out of control, be unfavorable for producing and steadily carry out.The more important thing is; Glass fibre is not easy to be soaked into by liquid; Local location maybe by soaked with liquid to and cause stinging the erosion poor or basic just not stinging lost, such result does not play the effect of processing, the quality of product also is not assurance.If adopt gaseous material to sting the erosion glass fibre, when glass fibre is placed in the gaseous state fluorine-containing material, will be snapped erosion at once, there is not the problem that can't soak into.In addition, adopt the gaseous state fluorine-containing material to sting the erosion glass fibre, can also make that the surface of glass fibre is more coarse, thereby make the adhesion between glass fibre and the resin more strengthen.Strict control is stung the degree of depth that erosion advances fiberglass surfacing accounting between 1%～20% the scope of glass fiber diameter, can obtain alligatoring effect preferably, and can not cause other problems.Shown in 1 among Fig. 2, the 1st, do not pass through the sketch map of segment of the glass fibre of roughening treatment, its surface is smooth; As shown in Figure 3,1 passed through roughening treatment after, its surface becomes more coarse; A and b are illustrated respectively in the erosion amount of stinging of upper and lower two positions of fiberglass surfacing; Under the normal production conditions, a is to equate basically with b, and this stings the erosion amount and is controlled between 0.02 micron to 2 microns and gets final product.In process of production, the gaseous state fluorine-containing material need cooperate with suitable agitating or blowing, so that glass fibre is in the uniform gaseous state fluorine-containing material of the concentration space, is beneficial to the carrying out that stings the erosion reaction simultaneously.Also have, fluorine-containing material is a poisonous and harmful substance, cannot directly be discharged in the air or in the external environment, needs to cooperate with enough recovery systems to accomplish such purpose.
Sting etching method two: adopt chemicals that fiberglass surfacing is stung erosion with acidity.We know that the composition that constitutes glass mainly contains following: SiO
2, Al
2O
3, B
2O
3, CaO, MgO, R
2O, the produced glass of normal condition, these compositions can be mixed equably, form whole uniformly formation, promptly belong to the glass of not phase-splitting.As glass is heat-treated under 400～650 ℃ of temperature, it can be transformed into Na
2O-B
2O
3With SiO
2Two phases, i.e. the glass of phase-splitting.After the glass process phase-splitting heat treatment, its mechanical strength can descend, and becomes more crisp, thereby when machining, is more conducive to be cut disconnected.Make the granularity of glassy phase of glassy phase and the silicic acid matter of boronic acid containing and alkali metal oxide be about the order of magnitude of tens dusts, form two kinds of fine structures that glassy phase mixes, such glass under 90 ℃ with processing such as hydrochloric acid and hot water, the Na of solubility
2O-B
2O
3Glassy phase is dissolved out, and remaining just becomes with SiO
2Be Main Ingredients and Appearance, it is the glass with micropore shape that has kept original shape of glass, and its surface promptly has coarse characteristic.Certainly, also can adopt and contain sulfuric acid or other sour solution is done this processing, but processing speed can be slow.According to use occasion and needs, control the variation of heat treatment time and temperature etc., can change aperture, pore size distribution, the pore volume of micropore, process the micropore of aperture homogeneous.Excess processes can cause the Na of solubility in the whole glass fibre
2O-B
2O
3Glassy phase all is snapped eating away, makes glass fibre become the cellular strand shape material as the sponge shape, and not only mechanical strength descends greatly and cannot meet the demands; And the as easy as rolling off a log moisture absorption and storage pollutant; In the manufacture process of printed wiring board, the moisture absorption can cause printed wiring board itself to have steam, can run into processing such as water and need baking in the mill in the journey repeatedly; Thereby water evaporates goes out to cause problems such as plate bursting, layering during baking, and a large amount of quality problem will be following.Strict control is stung the degree of depth that erosion advances fiberglass surfacing and is being accounted between 1%～20% the scope of glass fiber diameter; Both can obtain coarse fiberglass surfacing; Can guarantee again follow-up quality problem not to take place, thereby meet the use of printed wiring board industry.Shown in 1 among Fig. 2, the 1st, do not pass through the sketch map of segment of the glass fibre of roughening treatment, its surface is smooth; As shown in Figure 3,1 passed through roughening treatment after, its surface becomes more coarse; A and b are illustrated respectively in the erosion amount of stinging of upper and lower two positions of fiberglass surfacing; Under the normal production conditions, a is to equate basically with b, and this stings the erosion amount and is controlled between 0.02 micron to 2 microns and gets final product.Employing has acid chemicals fiberglass surfacing is stung erosion, thereby makes original more smooth fiberglass surfacing become coarse.Sting the material that the erosion chemicals with acidity that glass fibre adopted can adopt the composition that comprises hydrogen chloride, also can adopt to comprise sulfuric acid (H
2SO
4) or other sour compositions, or by the material that more than one acid mixes, in stinging the erosion process, need to cooperate with suitable heating, sting the process of erosion glass fibre to quicken alligatoring.Through stinging erosion alligatoring glass fibre afterwards; Its mechanical strength can further descend; And because there is more coarse shape in fiberglass surfacing; The local stress that matsurface produces when machining can so that glass fibre be more prone to be cut disconnected, thereby obtain better machining accuracy.
Reduction glass fibre mechanical strength
Five of processing methodFor: the diameter of described glass fibre is controlled between 0.5um～5um, and fiberglass surfacing is stung the erosion alligatoring, to reduce the mechanical strength of glass fibre.With fiberglass surfacing sting the erosion alligatoring method with above-mentioned
Four of processing methodIn " stinging etching method one " describe.
Above content is to combine concrete preferred implementation to the further explain that the present invention did, and can not assert that practical implementation of the present invention is confined to these explanations.For the those of ordinary skill of technical field under the present invention, under the prerequisite that does not break away from the present invention's design, can also make some simple deduction or replace, all should be regarded as belonging to protection scope of the present invention.
Claims (10)
1. the manufacturing technology of a high frequency material; It is characterized in that; The minimum materials such as Copper Foil, Teflon (being polytetrafluoroethylene (PTFE)) resin, glass fibre that comprise of this material, Copper Foil is made up of at interior material crisscross glass fibre and the minimum polyflon that comprises between the Copper Foil of two sides as the constituent material on these two surfaces of material; Crisscross glass fibre is provided with for the bulk strength of reinforcing material; And used glass fibre is through reducing the processing of mechanical strength, is more conducive to processing when making the machining of glass fibre in subsequent manufacturing processes.
2. the processing method of the reduction glass fibre mechanical strength in the manufacturing technology of a kind of high frequency material according to claim 1 is characterized in that, adopts the mechanical strength of the method reduction glass fibre of long-time high-temperature baking.
3. the processing method of the reduction glass fibre mechanical strength in the manufacturing technology of a kind of high frequency material according to claim 1 is characterized in that the diameter of described glass fibre is controlled between 0.5um～5um, to reduce the mechanical strength of glass fibre.
4. the processing method of the reduction glass fibre mechanical strength in the manufacturing technology of a kind of high frequency material according to claim 1; It is characterized in that; The diameter of described glass fibre is controlled between 0.5um～5um; And adopt the method for long-time high-temperature baking, to reduce the mechanical strength of glass fibre.
5. the processing method of the reduction glass fibre mechanical strength in the manufacturing technology of a kind of high frequency material according to claim 1; It is characterized in that; The diameter of described glass fibre is controlled between 0.5um～5um; And again fiberglass surfacing is stung the erosion alligatoring after adopting long-time high-temperature baking, to reduce the mechanical strength of glass fibre.
6. the processing method of the reduction glass fibre mechanical strength in the manufacturing technology of a kind of high frequency material according to claim 1; It is characterized in that; The diameter of described glass fibre is controlled between 0.5um～5um; And fiberglass surfacing is stung the erosion alligatoring, to reduce the mechanical strength of glass fibre.
7. according to the method for the long-time high-temperature baking in the manufacturing technology of claim 2, claim 4 and the described a kind of high frequency material of claim 5; It is characterized in that; The method of long-time high-temperature baking is the minimum following processing that comprises: under 400 ℃～650 ℃ temperature conditions, toasted 90～120 hours.
8. according to the method for the long-time high-temperature baking in the manufacturing technology of claim 2, claim 4 and the described a kind of high frequency material of claim 5; It is characterized in that; The method of long-time high-temperature baking is the minimum following processing that comprises: under 200 ℃～400 ℃ temperature conditions, toasted 200～400 hours.
9. sting the method for erosion fiberglass surfacing according to the alligatoring in the manufacturing technology of claim 3, claim 5 and the described a kind of high frequency material of claim 6, it is characterized in that, sting the erosion minimum composition that contains fluorine of chemicals that glass fibre adopted.
10. the method for erosion fiberglass surfacing is stung in the alligatoring in the manufacturing technology of a kind of high frequency material according to claim 5; It is characterized in that; Employing has acid chemicals fiberglass surfacing is stung erosion, thereby makes original more smooth fiberglass surfacing become coarse.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115847957A (en) * | 2022-08-25 | 2023-03-28 | 山东森荣新材料股份有限公司 | PTFE copper-clad plate for 5G high-frequency communication and manufacturing method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403253A (en) * | 2001-09-06 | 2003-03-19 | 财团法人工业技术研究院 | Making process of composite fluoric material plate |
| CN1586876A (en) * | 2004-08-10 | 2005-03-02 | 华南理工大学 | Process for preparing high performance copper-clad polytetrafluoroethylene plate |
| CN101838431A (en) * | 2010-05-21 | 2010-09-22 | 广东生益科技股份有限公司 | Fluororesin mixture, copper-clad plate prepared therefrom and manufacturing method thereof |
| CN101856900A (en) * | 2009-04-08 | 2010-10-13 | 深圳市信特科技有限公司 | Preparation method of low-loss high-frequency copper-clad plate |
-
2011
- 2011-05-09 CN CN2011101201080A patent/CN102774081A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403253A (en) * | 2001-09-06 | 2003-03-19 | 财团法人工业技术研究院 | Making process of composite fluoric material plate |
| CN1586876A (en) * | 2004-08-10 | 2005-03-02 | 华南理工大学 | Process for preparing high performance copper-clad polytetrafluoroethylene plate |
| CN101856900A (en) * | 2009-04-08 | 2010-10-13 | 深圳市信特科技有限公司 | Preparation method of low-loss high-frequency copper-clad plate |
| CN101838431A (en) * | 2010-05-21 | 2010-09-22 | 广东生益科技股份有限公司 | Fluororesin mixture, copper-clad plate prepared therefrom and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 西北轻工业学院主编: "《玻璃工艺学》", 31 January 1982, article "玻璃纤维", pages: 586-592 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115847957A (en) * | 2022-08-25 | 2023-03-28 | 山东森荣新材料股份有限公司 | PTFE copper-clad plate for 5G high-frequency communication and manufacturing method thereof |
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