CN102766494B - Brewing wastewater is prepared the technique of water-coal-slurry - Google Patents

Brewing wastewater is prepared the technique of water-coal-slurry Download PDF

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CN102766494B
CN102766494B CN201210280502.5A CN201210280502A CN102766494B CN 102766494 B CN102766494 B CN 102766494B CN 201210280502 A CN201210280502 A CN 201210280502A CN 102766494 B CN102766494 B CN 102766494B
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coal
water
slurry
brewing wastewater
concentration
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CN102766494A (en
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高翔
邵士泉
陈业菊
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TAI'AN LANGDA NEW ENERGY CO Ltd
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TAI'AN LANGDA NEW ENERGY CO Ltd
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Abstract

The invention discloses a kind of brewing wastewater and prepare the technique of water-coal-slurry, relate to field of waste water treatment and water-coal-slurry preparation field, utilize brewing wastewater to prepare water-coal-slurry, take full advantage of the available heating value of brewing wastewater inside, realize the harmless treatment to brewing wastewater waste residue, alleviate environmental pollution, save a large amount of sewage disposal expenses, saved water resource simultaneously, the various indexs of water-coal-slurry that prepare meet the requirements, as Industrial Boiler, the fuel of station boiler, the superheated steam that boiler produces is for generating and heat supply, can be winery production technology and provide sufficient, cheap power source, coal resources are saved, greatly reduce production cost, as long as brewery, the capacity scheme balance of coal water mixture plant, just can thoroughly realize the zero-emission of brewing wastewater waste residue, can consume on a large scale winery waste water and dregs, reduce the discharge of winery pollutant.

Description

Brewing wastewater is prepared the technique of water-coal-slurry
Technical field
The present invention relates to field of waste water treatment and water-coal-slurry preparation field, specifically a kind of brewing wastewater is prepared the technique of water-coal-slurry.
Background technology
As everyone knows, light industry is quite serious to the pollution of water resource, wherein fermentation industry is only second to paper industry and occupies the second the pollution level of environment, and just shortage of China's water resource itself, the industrial pollution being on the rise has more caused the nervous situation of water resource today. In brewing wastewater, contain multiple accessory substance and discarded object that brewing process produces, the annual brewing wastewater producing of China is more than more than 4,000 ten thousand tons now, in waste water, COD is higher, the wastewater treatment expense of winery is greatly about 2 yuan/ton, disposal cost is higher, a lot of winerys are profit-seeking, waste water is not processed to direct discharge, not only waste resource, and cause serious industrial pollution, thereby fully and effectively brewing wastewater is fully utilized, both can alleviate environmental pollution, can save again the energy, reduce costs.
China is the country of a rich coal, oil-poor, weak breath, and coal has found that resource reaches 10141.02 hundred million tons, accounts for the more than 80% of fossil energy, petroleum resources relative shortage, and proved reserves are only 3 tons per capita, and are consumed in and increase rapidly. Water-coal-slurry is that coal is carried out to pulverizing and water and mixes containing surface-active dispersant solution, the pulpous state fluid being prepared from, then under carrying, power burns as heavy oil, the substitute products of heavy oil, residual oil, fallen by boiler combustion thereby reduce bulk petroleum, can save out bulk petroleum resource. Water-coal-slurry can improve the combustion rate of coal, reduces the pollution to environment, is the extremely promising Filter Tuber For Clean Coal fuel of one. The preparation technology of water-coal-slurry is quite ripe at present, mainly contains high concentration ore grinding pulping process, middle concentration ore grinding pulping process, height---middle concentration ore grinding associating pulping process. The coal resources of China's abundant, for water-coal-slurry preparation provides sufficient reliable coal on raw material is selected, various places are different different with quality requirement according to raw material, adopted suit measures to local conditions, diversified pulping process.
In brewing wastewater waste residue, existing moisture has again caloric value, be well suited for for the preparation of water-coal-slurry, can utilize its moisture can utilize again its available heating value, the harmless treatment of brewing wastewater waste residue can be fallen again simultaneously, kill two birds with one stone, the technique of utilizing at present brewing wastewater to prepare water-coal-slurry has no report.
Summary of the invention
For solving the technical problem of above-mentioned existence, the invention provides a kind of brewing wastewater and prepare the technique of water-coal-slurry, make full use of brewing wastewater and replace slurrying water, make full use of the heat in brewing wastewater waste residue, saving water resource again, realize the pollution-free processing of brewing wastewater, the pollution of the discharge of minimizing waste water and dregs to environment simultaneously.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of brewing wastewater is prepared coal water slurry process, realizes as follows:
(1) wastewater: gather cleaning of evaporator waste water, washer bottle waste water, distillation waste water that distillery's concentration is 3%~6%, enter buffer tank through links such as transport, buffer memory, pretreatment, conveying and meterings stand-by;
(2) feed coal is prepared: with bucket elevator, feed coal lifting is entered to two counter beating hammer type disintegrators by chute again and carry out fragmentation, the granularity after fragmentation is less than 5 millimeters, and it is stand-by that the feed coal after fragmentation enters buffering coal bin;
(3) dispersant adds: first dry powder dispersant or high concentration liquid dispersant being diluted with water to concentration is 10%~15%, is delivered to dispersant storage pool stand-by;
(4) stabilizing agent adds: first stabilizing agent is carried out to dissolved dilution and arrive concentration 14%~20%, then input stabilizing agent buffer tank stand-by;
(5) slurrying: by closed-loop control system by setting requirement slurrying, the concentration of setting preparation water-coal-slurry is controlled between 64%~67%, feed coal in buffering coal bin feeds Ф 2.4 × 8.5m ball mill with the brewing wastewater in buffer tank together with mass ratio 64%~67%:36%~33% of setting, 0.4%~0.7% the dispersant solution that the good addition of pre-coordination is accounted for to dry coal quality adds ball mill simultaneously, carries out high concentration ore grinding;
(6) stable processing: the product of ball mill outlet is water-coal-slurry primary product, after coarse filtration, enter surge tank, carry out essence filter through being pumped into pulp filter again, the foreign matter in slurry is sneaked in elimination, after essence filter, to reach more than 300 microns content and be less than 0.5%, be less than 75 microns of content and be greater than 75%, from filtering, pulp filter flows into disposal of stability bucket, 0.10%~0.2% the stabiliser solution that simultaneously addition is accounted for to dry coal quality feeds disposal of stability bucket, make stabilizing agent fully mix with coal slurry and contact through stirring, the disposal of stability bucket of each series is established two, tandem working, water-coal slurry pump after disposal of stability is sent into and is mixed mixing cirtern and carry out the suitable processing that stirs and evenly mixs, through being pumped into slurry can.
Described dispersant adopts naphthalene sulfonic dipersant.
Described stabilizing agent adopts technical grade ferrous sulfate.
The present invention utilizes brewing wastewater to prepare water-coal-slurry, take full advantage of the available heating value of brewing wastewater inside, realize the harmless treatment to brewing wastewater waste residue, alleviate environmental pollution, save a large amount of sewage disposal expenses, saved water resource simultaneously, the various indexs of water-coal-slurry that prepare meet the requirements, as Industrial Boiler, the fuel of station boiler, the superheated steam that boiler produces is for generating and heat supply, can be winery production technology and provide sufficient, cheap power source, coal resources are saved, greatly reduce production cost, as long as brewery, the capacity scheme balance of coal water mixture plant, just can thoroughly realize the zero-emission of brewing wastewater waste residue, can consume on a large scale winery waste water and dregs, reduce the discharge of winery pollutant, thereby set up brewing wastewater waste residue scale processing, the Recycling Economy System of comprehensive utilization of resources, there is social benefit significantly, economic benefit and environmental benefit.
Detailed description of the invention
Brewing wastewater set forth in the present invention is prepared the technique of water-coal-slurry, realizes as follows:
(1) wastewater: gather cleaning of evaporator waste water, washer bottle waste water, distillation waste water that distillery's concentration is 3%~6%, enter buffer tank through links such as transport, buffer memory, pretreatment, conveying and meterings stand-by, wherein pretreatment is to carry out pH value mensuration, neutralize and stir, carry and adopt metering single screw-rod pump, adopt electromagnetic flowmeter to measure;
(2) feed coal is prepared: with bucket elevator, feed coal is promoted to 27 meters and enters two counter beating hammer type disintegrators by chute again and carry out fragmentation, the granularity after fragmentation is less than 5 millimeters, and it is stand-by that the feed coal after fragmentation enters buffering coal bin;
(3) dispersant adds: adopt naphthalene sulfonic dipersant, first dry powder dispersant or high concentration liquid dispersant being diluted with water to concentration is 10%~15%, is delivered to dispersant storage pool, stand-by;
(4) stabilizing agent adds: stabilizing agent adopts technical grade ferrous sulfate, first stabilizing agent is carried out in dilution agitator to dissolved dilution and arrives concentration between 14%~20%, then inputs stabilizing agent buffer tank, stand-by;
(5) slurrying: by closed-loop control system by setting requirement slurrying, the concentration of setting preparation water-coal-slurry is controlled between 64%~67%, feed coal in buffering coal bin feeds Ф 2.4 × 8.5m ball mill with the brewing wastewater in buffer tank together with mass ratio 64%~67%:36%~33% of setting, 0.4%~0.7% the dispersant solution that the good addition of pre-coordination is accounted for to dry coal quality adds ball mill simultaneously, carries out high concentration ore grinding; In the process of adding brewing wastewater, not add water as principle, farthest utilize brewing wastewater;
(6) stable processing: the product of ball mill outlet is water-coal-slurry primary product, after vibratory sieve coarse filtration, enter surge tank, again through being pumped into the filter of pulp filter essence, the rear more than 300 microns content of essence filter is less than 0.5%, be less than 75 microns of content and be greater than 75%, elimination is sneaked into foreign matter in slurry (as large granular materials, less wood chip, plastic optical fibre etc.) after, feed disposal of stability bucket, 0.10%~0.2% the stabiliser solution that simultaneously addition is accounted for to dry coal quality feeds disposal of stability bucket, make stabilizing agent fully mix with coal slurry and contact through stirring, the disposal of stability bucket of each series is established two, tandem working, a full rear overflow enters another, so that press the addition of constant volume method control stabilizing agent and extend stabilizing agent mixing time. water-coal slurry pump after disposal of stability is sent into and is mixed mixing cirtern and carry out the suitable processing that stirs and evenly mixs, and it is finally become and both had good fluidity, has again the finished product water-coal-slurry of stronger yield stress. through mixing the water-coal-slurry after treatment of sizing mixing, be finished product water-coal-slurry through being pumped into slurry can.
Whole technique realizes by closed-loop control system, describes the present invention in detail below by the technological parameter in specific embodiment and experimental data.
Embodiment 1:
Process conditions: set paste producing amount 13t/h, slurry concentration 64%, the full water 8% of known coal, brewing wastewater waste residue concentration is 3%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 10% solution, addition is pressed 0.4% of dry coal amount, stabilizing agent diluted concentration 20%, and addition is pressed 0.1% of dry coal amount, wet coal consumption 8.93t/h, brewing wastewater consumption 3.74m3/ h, the mass ratio of dry coal used and waste water is 64.25%:35.75%, adds 0.317m through dispersant3/ h, stabilizing agent addition is 0.0392m3/ h, the concentration of the water-coal-slurry finally making is after measured 64.25%, viscosity is 948mPaS, is qualified products.
Embodiment 2:
Process conditions: set paste producing amount 13t/h, slurry concentration 64%, the full water 8% of known coal, brewing wastewater waste residue concentration is 4%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 12% solution, addition is pressed 0.55% of dry coal amount, stabilizing agent diluted concentration 15.5%, and addition is pressed 0.15% of dry coal amount, wet coal consumption 8.89t/h, brewing wastewater consumption 3.75m3/ h, the mass ratio of dry coal used and waste water is 64.03%:35.97%, dispersant adds 0.364m3/ h, stabilizing agent addition is 0.076m3/ h, the concentration of the water-coal-slurry finally making is after measured 64.03%, viscosity is 925mPaS, is qualified products.
Embodiment 3:
Process conditions: set paste producing amount 13.5t/h, slurry concentration 64.5%, the full water 7.5% of known coal, brewing wastewater waste residue concentration is 3.52%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 13.64% solution, addition is pressed 0.58% of dry coal amount, stabilizing agent diluted concentration 15.85%, and addition is pressed 0.13% of dry coal amount, wet coal consumption 9.28t/h, brewing wastewater consumption 3.85m3/ h, the mass ratio of dry coal used and waste water is 64.48%:35.52%, dispersant adds 0.353m3/ h, stabilizing agent addition is 0.067m3/ h, the concentration of the water-coal-slurry finally making is after measured 64.48%, viscosity is 986mPaS, is qualified products.
Embodiment 4:
Process conditions: set paste producing amount 13.5t/h, slurry concentration 65%, the full water 8.3% of known coal, brewing wastewater waste residue concentration is 3.25%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 14.22% solution, addition is pressed 0.56% of dry coal amount, stabilizing agent diluted concentration 16.07%, and addition is pressed 0.12% of dry coal amount, wet coal consumption 9.45t/h, brewing wastewater consumption 3.71m3/ h, the mass ratio of dry coal used and waste water is 64.92%:35.08%, dispersant adds 0.329m3/ h, stabilizing agent addition is 0.0618m3/ h, the concentration of the water-coal-slurry finally making is after measured 64.92%, viscosity is 1034mPaS, is qualified products.
Embodiment 5:
Process conditions: set paste producing amount 13t/h, slurry concentration 64%, the full water 8% of known coal, brewing wastewater waste residue concentration is 6%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 15% solution, addition is pressed 0.7% of dry coal amount, stabilizing agent diluted concentration 14%, and addition is pressed 0.2% of dry coal amount, wet coal consumption 9.04t/h, brewing wastewater consumption 3.77m3/ h, the mass ratio of dry coal used and waste water is 64%:36%, dispersant adds 0.396m3/ h, stabilizing agent addition is 0.112m3/ h, the concentration of the water-coal-slurry finally making is after measured 64%, viscosity is 987mPaS, is qualified products.
Embodiment 6:
Process conditions: set paste producing amount 13.5t/h, slurry concentration 65.5%, the full water 8.5% of known coal, brewing wastewater waste residue concentration is 3.38%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 12.68% solution, addition is pressed 0.57% of dry coal amount, stabilizing agent diluted concentration 16.25%, and addition is pressed 0.12% of dry coal amount, wet coal consumption 9.54t/h, brewing wastewater consumption 3.56m3/ h, the mass ratio of dry coal used and waste water is 65.63%:34.37%, dispersant adds 0.0.379m3/ h, stabilizing agent addition is 0.0616m3/ h, the concentration of the water-coal-slurry finally making is after measured 65.63%, viscosity is 1087mPaS, is qualified products.
Embodiment 5:
Process conditions: set paste producing amount 13.5t/h, slurry concentration 66%, the full water 8.0% of known coal, brewing wastewater waste residue concentration is 3.55%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 12.05% solution, addition is pressed 0.58% of dry coal amount, stabilizing agent diluted concentration 16.78%, and addition is pressed 0.12% of dry coal amount, wet coal consumption 9.56t/h, brewing wastewater consumption 3.51m3/ h, the mass ratio of dry coal used and waste water is 66.07%:33.93%, dispersant adds 0.408m3/ h, stabilizing agent addition is 0.060m3/ h, the concentration of the water-coal-slurry finally making is after measured 66.07%, viscosity is 1156mPaS, is qualified products.
Embodiment 6:
Process conditions: set paste producing amount 13.5t/h, slurry concentration 66.5%, the full water 7.8% of known coal, brewing wastewater waste residue concentration is 3.48%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 12.11% solution, addition is pressed 0.60% of dry coal amount, stabilizing agent diluted concentration 16.42%, and addition is pressed 0.11% of dry coal amount, wet coal consumption 9.62t/h, brewing wastewater consumption 3.44m3/ h, the mass ratio of dry coal used and waste water is 66.44%:33.56%, dispersant adds 0.424m3/ h, stabilizing agent addition is 0.0567m3/ h, the concentration of the water-coal-slurry finally making is after measured 66.44%, viscosity is 1231mPaS, is qualified products.
Embodiment 7:
Process conditions: set paste producing amount 13.5t/h, slurry concentration 67%, the full water 8.2% of known coal, brewing wastewater waste residue concentration is 3.63%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 13.38% solution, addition is pressed 0.62% of dry coal amount, stabilizing agent diluted concentration 15.66%, and addition is pressed 0.11% of dry coal amount, wet coal consumption 9.73t/h, brewing wastewater consumption 3.62m3/ h, the mass ratio of dry coal used and waste water is 67%:33%, dispersant adds 0.405m3/ h, stabilizing agent addition is 0.0599m3/ h, the concentration of the water-coal-slurry finally making is after measured 66.98%, viscosity is 1282mPaS, is qualified products.
Embodiment 8:
Process conditions: set paste producing amount 14.5t/h, slurrying concentration 65%, the full water 6.5% of known coal, brewing wastewater waste residue concentration is 5.25%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 10.56% solution, addition is pressed 0.45% of dry coal amount, stabilizing agent diluted concentration 14.36%, and addition is pressed 0.18% of dry coal amount, wet coal consumption 9.86t/h, brewing wastewater consumption 4.24m3/ h, the mass ratio of dry coal used and waste water is 65.28%:34.72%, dispersant adds 0.383m3/ h, stabilizing agent addition is 0.111m3/ h, the concentration of the water-coal-slurry finally making is after measured 65.28%, viscosity is 1014mPaS, is qualified products.
Embodiment 9:
Process conditions: set paste producing amount 15t/h, slurry concentration 65%, the full water 9.8% of known coal, brewing wastewater waste residue concentration is 4.28%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 14.7% solution, addition is pressed 0.66% of dry coal amount, stabilizing agent diluted concentration 17.45%, and addition is pressed 0.15% of dry coal amount, wet coal consumption 10.64t/h, brewing wastewater consumption 3.92m3/ h, the mass ratio of dry coal used and waste water is 64.45%:35.55%, dispersant adds 0.417m3/ h, stabilizing agent addition is 0.079m3/ h, the concentration of the water-coal-slurry finally making is after measured 64.45%, viscosity is 1065mPaS, is qualified products.
Embodiment 10:
Process conditions: set paste producing amount 15.5t/h, slurry concentration 65%, the full water 8.55% of known coal, brewing wastewater waste residue concentration is 3.73%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 11.98% solution, addition is pressed 0.55% of dry coal amount, stabilizing agent diluted concentration 15.48%, and addition is pressed 0.13% of dry coal amount, wet coal consumption 10.86t/h, brewing wastewater consumption 4.18m3/ h, the mass ratio of dry coal used and waste water is 65.24%:34.76%, dispersant adds 0.441m3/ h, stabilizing agent addition is 0.0798m3/ h, the concentration of the water-coal-slurry finally making is after measured 65.24%, viscosity is 1126mPaS, is qualified products.
Embodiment 11:
Process conditions: set paste producing amount 16t/h, slurry concentration 67%, the full water 6.85% of known coal, brewing wastewater waste residue concentration is 5.66%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 11.44% solution, addition is pressed 0.48% of dry coal amount, stabilizing agent diluted concentration 19.3%, and addition is pressed 0.14% of dry coal amount, wet coal consumption 11.51t/h, brewing wastewater consumption 4.28m3/ h, the mass ratio of dry coal used and waste water is 66.95%:33.05%, dispersant adds 0.428m3/ h, stabilizing agent addition is 0.0711m3/ h, the concentration of the water-coal-slurry finally making is after measured 66.95%, viscosity is 1255mPaS, is qualified products.
Embodiment 12:
Process conditions: set paste producing amount 17t/h, slurry concentration 65%, the full water 9.47% of known coal, brewing wastewater waste residue concentration is 4.64%, brewing wastewater is principle by no longer adding water, dispersant is diluted to 11.88% solution, addition is pressed 0.65% of dry coal amount, stabilizing agent diluted concentration 18.35%, and addition is pressed 0.17% of dry coal amount, wet coal consumption 12t/h, brewing wastewater consumption 4.39m3/ h, the mass ratio of dry coal used and waste water is 65.22%:34.78%, dispersant adds 0.576m3/ h, stabilizing agent addition is 0.0965m3/ h, the concentration of the water-coal-slurry finally making is after measured 65.22%, viscosity is 1164mPaS, is qualified products.
Certainly, above-mentioned explanation is not limitation of the present invention, and the present invention is also not limited in above-mentioned giving an example, and variation, remodeling, interpolation or replacement that those skilled in the art make in essential scope of the present invention, also should belong to protection scope of the present invention.

Claims (3)

1. brewing wastewater is prepared a technique for water-coal-slurry, it is characterized in that, realizes as follows:
(1) wastewater: cleaning of evaporator waste water, washer bottle waste water, distillation waste water that to gather distillery concentration be 3%~6%, through transport, buffer memory, pretreatment, that conveying and metering link enters buffer tank is stand-by;
(2) feed coal is prepared: with bucket elevator, feed coal lifting is entered to two counter beating hammer type disintegrators by chute again and carry out fragmentation, the granularity after fragmentation is less than 5 millimeters, and it is stand-by that the feed coal after fragmentation enters buffering coal bin;
(3) dispersant adds: first dry powder dispersant or high concentration liquid dispersant being diluted with water to concentration is 10%~15%, is delivered to dispersant storage pool stand-by;
(4) stabilizing agent adds: first stabilizing agent is carried out to dissolved dilution and arrive concentration 14%~20%, then input stabilizing agent buffer tank stand-by;
(5) slurrying: by closed-loop control system by setting requirement slurrying, the concentration of setting preparation water-coal-slurry is controlled between 64%~67%, feed coal in buffering coal bin feeds Ф 2.4 × 8.5m ball mill with the brewing wastewater in buffer tank together with mass ratio 64%~67%:36%~33% of setting, 0.4%~0.7% the dispersant solution that the good addition of pre-coordination is accounted for to dry coal quality adds ball mill simultaneously, carries out high concentration ore grinding;
(6) stable processing: the product of ball mill outlet is water-coal-slurry primary product, after coarse filtration, enter surge tank, carry out essence filter through being pumped into pulp filter again, the foreign matter in slurry is sneaked in elimination, after essence filter, to reach more than 300 microns content and be less than 0.5%, be less than 75 microns of content and be greater than 75%, from filtering, pulp filter flows into disposal of stability bucket, 0.10%~0.2% the stabiliser solution that simultaneously addition is accounted for to dry coal quality feeds disposal of stability bucket, make stabilizing agent fully mix with coal slurry and contact through stirring, the disposal of stability bucket of each series is established two, tandem working, a full rear overflow enters another, so that press the addition of constant volume method control stabilizing agent and extend stabilizing agent mixing time, water-coal slurry pump after disposal of stability is sent into and is mixed mixing cirtern and carry out the suitable processing that stirs and evenly mixs, through being pumped into slurry can.
2. brewing wastewater according to claim 1 is prepared the technique of water-coal-slurry, it is characterized in that, described dispersant adopts naphthalene sulfonic dipersant.
3. brewing wastewater according to claim 1 is prepared the technique of water-coal-slurry, it is characterized in that, described stabilizing agent adopts technical grade ferrous sulfate.
CN201210280502.5A 2012-08-09 2012-08-09 Brewing wastewater is prepared the technique of water-coal-slurry Expired - Fee Related CN102766494B (en)

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CN105542887B (en) * 2014-10-30 2017-12-08 中国石油化工股份有限公司 Water-coal-slurry is prepared using high slat-containing wastewater
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